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dc.creatorCobeljic, Bozidar
dc.creatorPevec, Andrej
dc.creatorTurel, Iztok
dc.creatorSpasojević, Vojislav
dc.creatorMilcic, Milos
dc.creatorMitic, Dragana
dc.creatorSladić, Dušan M.
dc.creatorAnđelković, Katarina
dc.date.accessioned2018-03-01T23:59:23Z
dc.date.available2018-03-01T23:59:23Z
dc.date.issued2014
dc.identifier.issn0277-5387 (print)
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/5887
dc.description.abstract3-Acetylpyridine thiosemicarbazone hydrochloride was synthesized and structurally characterized. Complexes of Cu(II) with this ligand could not be obtained by direct synthesis. By synthesis in situ mixing Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine (3-Acpy) and semicarbazide, a Cu(I) polymer, {[Cu(SCN)(3-Acpy)(2)]}(n) was obtained and structurally characterized. Reaction of Cu(BF4)(2)center dot 6H(2)O, 3-acetylpyridine and ammonium thiocyanate afforded a dinuclear Cu(II) complex with two thiocyanate ions in bridges, which was structurally characterized. Magnetic measurements were performed for the dinuclear complex. OFT calculations provided explanation for inability to obtain a mononuclear complex. (C) 2013 Elsevier Ltd. All rights reserved.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172055/RS//
dc.relationSlovenian Research Agency (ARRS) [P-0175]
dc.rightsrestrictedAccessen
dc.sourcePolyhedronen
dc.subjectCu(I) and Cu(II) complexesen
dc.subject3-Acetylpyridineen
dc.subjectThiocyanateen
dc.subjectDFT calculationsen
dc.subjectMagnetic propertiesen
dc.titleAnalysis of the structures of the Cu(I) and Cu(II) complexes with 3-acetylpyridine and thiocyanateen
dc.typearticleen
dcterms.abstractМитиц, Драгана; Цобељиц, Бозидар; Милциц, Милос; Сладиц, Дусан; Aнделковиц, Катарина; Спасојевић Војислав; Певец, Aндреј; Турел, Изток;
dc.citation.volume69
dc.citation.spage77
dc.citation.epage83
dc.identifier.wos000331502500011
dc.identifier.doi10.1016/j.poly.2013.11.027
dc.citation.rankM22
dc.identifier.scopus2-s2.0-84890443353


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