Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide
Нема приказа
Аутори
Pejović, AnkaDamljanović, Ivan S.
Stevanović, Dragana D.
Ilic, Danijela
Vukićević, Mirjana
Bogdanović, Goran A.
Vukićević, Rastko D.
Чланак у часопису
Метаподаци
Приказ свих података о документуАпстракт
Dimethyl(2-ferrocenoylethyl)sulfonium iodide was synthesized by reacting 1-ferroceny1-4-thiapentan-1-one with iodomethane and characterized from spectral data and single crystal X-ray structure analysis. This compound was capable of reacting with different N-, S-, and O-nucleophiles giving the corresponding beta-functionalized ferrocene-containing ketones. Furthermore, dimethyl sulfide can be displaced from the dimethyl(2-ferrocenoylethyl)sulfonium ion with cyanide or carbanions derived from 1,3-bifunctional compounds and nitropropane, leading to products with a new carbon-carbon bond. (C) 2013 Elsevier Ltd. All rights reserved.
Кључне речи:
Ferrocene / Sulfonium salt / Nucleophilic substitution / beta-Functionalized ferrocenyl ketones / 1,3-Dicarbonyls / X-ray analysisИзвор:
Tetrahedron Letters, 2013, 54, 35, 4776-4780Финансирање / пројекти:
- Нове електрохемијске и хемијске методе у синтези органских једињења од интереса за медицину и хемију материјала (RS-MESTD-Basic Research (BR or ON)-172034)
- Рационални дизајн и синтеза биолошки активних и координационих једињења и функционалних материјала, релевантних у (био)нанотехнологији (RS-MESTD-Basic Research (BR or ON)-172035)
DOI: 10.1016/j.tetlet.2013.06.130
ISSN: 0040-4039
WoS: 000323020400044
Scopus: 2-s2.0-84880839901
Колекције
Институција/група
VinčaTY - JOUR AU - Pejović, Anka AU - Damljanović, Ivan S. AU - Stevanović, Dragana D. AU - Ilic, Danijela AU - Vukićević, Mirjana AU - Bogdanović, Goran A. AU - Vukićević, Rastko D. PY - 2013 UR - https://vinar.vin.bg.ac.rs/handle/123456789/5623 AB - Dimethyl(2-ferrocenoylethyl)sulfonium iodide was synthesized by reacting 1-ferroceny1-4-thiapentan-1-one with iodomethane and characterized from spectral data and single crystal X-ray structure analysis. This compound was capable of reacting with different N-, S-, and O-nucleophiles giving the corresponding beta-functionalized ferrocene-containing ketones. Furthermore, dimethyl sulfide can be displaced from the dimethyl(2-ferrocenoylethyl)sulfonium ion with cyanide or carbanions derived from 1,3-bifunctional compounds and nitropropane, leading to products with a new carbon-carbon bond. (C) 2013 Elsevier Ltd. All rights reserved. T2 - Tetrahedron Letters T1 - Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide VL - 54 IS - 35 SP - 4776 EP - 4780 DO - 10.1016/j.tetlet.2013.06.130 ER -
@article{ author = "Pejović, Anka and Damljanović, Ivan S. and Stevanović, Dragana D. and Ilic, Danijela and Vukićević, Mirjana and Bogdanović, Goran A. and Vukićević, Rastko D.", year = "2013", abstract = "Dimethyl(2-ferrocenoylethyl)sulfonium iodide was synthesized by reacting 1-ferroceny1-4-thiapentan-1-one with iodomethane and characterized from spectral data and single crystal X-ray structure analysis. This compound was capable of reacting with different N-, S-, and O-nucleophiles giving the corresponding beta-functionalized ferrocene-containing ketones. Furthermore, dimethyl sulfide can be displaced from the dimethyl(2-ferrocenoylethyl)sulfonium ion with cyanide or carbanions derived from 1,3-bifunctional compounds and nitropropane, leading to products with a new carbon-carbon bond. (C) 2013 Elsevier Ltd. All rights reserved.", journal = "Tetrahedron Letters", title = "Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide", volume = "54", number = "35", pages = "4776-4780", doi = "10.1016/j.tetlet.2013.06.130" }
Pejović, A., Damljanović, I. S., Stevanović, D. D., Ilic, D., Vukićević, M., Bogdanović, G. A.,& Vukićević, R. D.. (2013). Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide. in Tetrahedron Letters, 54(35), 4776-4780. https://doi.org/10.1016/j.tetlet.2013.06.130
Pejović A, Damljanović IS, Stevanović DD, Ilic D, Vukićević M, Bogdanović GA, Vukićević RD. Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide. in Tetrahedron Letters. 2013;54(35):4776-4780. doi:10.1016/j.tetlet.2013.06.130 .
Pejović, Anka, Damljanović, Ivan S., Stevanović, Dragana D., Ilic, Danijela, Vukićević, Mirjana, Bogdanović, Goran A., Vukićević, Rastko D., "Synthesis, characterization, and nucleophilic substitutions of dimethyl(2-ferrocenoylethyl)sulfonium iodide" in Tetrahedron Letters, 54, no. 35 (2013):4776-4780, https://doi.org/10.1016/j.tetlet.2013.06.130 . .