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dc.creatorNovaković, Slađana B.
dc.creatorBogdanović, Goran A.
dc.creatorLeovac, Vukadin M.
dc.creatorRodic, Marko V.
dc.creatorVojinović-Ješić, Ljiljana S.
dc.creatorIvkovic, Sonja
dc.date.accessioned2018-03-01T23:32:46Z
dc.date.available2018-03-01T23:32:46Z
dc.date.issued2013
dc.identifier.issn0108-2701
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/5580
dc.description.abstractThe title compound, C9H13N4O3+center dot NO3-, is the first structurally characterized Schiff base derived from semicarbazide and pyridoxal. Unusually for an unsubstituted semicarbazone, the compound adopts a syn conformation, in which the carbonyl O atom is in a cis disposition relative to the azomethine N atom. This arrangement is supported by a pair of hydrogen bonds between the organic cation and the nitrate anion. The cation is essentially planar, with only a hydroxymethyl O atom deviating significantly from the mean plane of the remaining atoms (r.m.s. deviation of the remaining non-H atoms = 0.01 angstrom). The molecules are linked into flat layers by N-H center dot center dot center dot O and C-H center dot center dot center dot O hydrogen bonds. O-H center dot center dot center dot O hydrogen bonds involving the hydroxymethyl group as a donor interconnect the layers into a three-dimensional structure.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/Basic Research (BR or ON)/172014/RS//
dc.rightsrestrictedAccessen
dc.sourceActa Crystallographica. Section C: Crystal Structure Communicationsen
dc.title(E)-4-[(2-Carbamoylhydrazinylidene)methyl]-3-hydroxy-5-hydroxymethyl-2-methylpyridin-1-ium nitrateen
dc.typearticleen
dcterms.abstractВојиновиц-Јесиц, Љиљана С.; Леовац, Вукадин М.; Ивковиц, Соња; Новаковић Слађана; Богдановић Горан; Родиц, Марко В.;
dc.citation.volume69
dc.citation.spage761
dc.citation.epage+
dc.identifier.wos000321458200017
dc.identifier.doi10.1107/S0108270113013929
dc.citation.otherPart number: 7
dc.citation.rankM23
dc.identifier.pmid23832038
dc.identifier.scopus2-s2.0-84880179167


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