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Perturbed Angular Correlation Investigation of the Electric Field Gradient At Ta-181 Probe in the Hf2ni7 Compound

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2012
4921.pdf (914.8Kb)
Authors
Cekić, Božidar Đ.
Umićević, Ana
Ivanovski, Valentin N.
Hu, Rongwei
Petrovic, Cedomir
David, Bohumil
Barudžija, Tanja
Article
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Abstract
The perturbed angular correlation method was employed to study the temperature dependence of electric field gradients at the Ta-181 probe in the polycrystalline Hf2Ni7 compound. The temperature evolution of the sample content was measured using high-temperature X-ray diffraction. To check the magnetic order of the sample, magnetization measurements and additional perturbed angular correlation measurements with externally applied magnetic field were performed. All obtained spectra showed no evidence of magnetic order of the Hf2Ni7 phase. Within the experimental resolution of the apparatus, the measured electric field gradients at Ta-181 probe for the two inequivalent Hf-181/Ta-181 sites in the Hf2Ni7 compound appeared as one in the range of 78-944 K. A single quadrupole interaction implies that the electric field gradients at the two Hf sites must be quite similar. At 293 K, the measured quadrupole interaction parameters are v(Q) = 433(1) MHz and eta = 0.300(4). An increase of the quadr...upole frequency and a gradual rising of the asymmetry parameter were observed with increasing temperature. The high-temperature X-ray diffraction indicated a build up of HfO2 above 693 K.

Keywords:
intermetallics / hyperfine interactions / perturbed angular correlation / magnetization / X-ray diffraction
Source:
Nuclear technology and radiation protection, 2012, 27, 2, 95-102
Funding / projects:
  • Investigation of intermetallics and semiconductors and possible application in renewable energy sources (RS-171001)
  • Office of Basic Energy Sciences, U.S. Department of Energy [DE-Ac02-98CH10886]

DOI: 10.2298/NTRP1202095C

ISSN: 1451-3994

WoS: 000306036600001

Scopus: 2-s2.0-84864219698
[ Google Scholar ]
URI
https://vinar.vin.bg.ac.rs/handle/123456789/4925
Collections
  • WoS Import
Institution/Community
Vinča
TY  - JOUR
AU  - Cekić, Božidar Đ.
AU  - Umićević, Ana
AU  - Ivanovski, Valentin N.
AU  - Hu, Rongwei
AU  - Petrovic, Cedomir
AU  - David, Bohumil
AU  - Barudžija, Tanja
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4925
AB  - The perturbed angular correlation method was employed to study the temperature dependence of electric field gradients at the Ta-181 probe in the polycrystalline Hf2Ni7 compound. The temperature evolution of the sample content was measured using high-temperature X-ray diffraction. To check the magnetic order of the sample, magnetization measurements and additional perturbed angular correlation measurements with externally applied magnetic field were performed. All obtained spectra showed no evidence of magnetic order of the Hf2Ni7 phase. Within the experimental resolution of the apparatus, the measured electric field gradients at Ta-181 probe for the two inequivalent Hf-181/Ta-181 sites in the Hf2Ni7 compound appeared as one in the range of 78-944 K. A single quadrupole interaction implies that the electric field gradients at the two Hf sites must be quite similar. At 293 K, the measured quadrupole interaction parameters are v(Q) = 433(1) MHz and eta = 0.300(4). An increase of the quadrupole frequency and a gradual rising of the asymmetry parameter were observed with increasing temperature. The high-temperature X-ray diffraction indicated a build up of HfO2 above 693 K.
T2  - Nuclear technology and radiation protection
T1  - Perturbed Angular Correlation Investigation of the Electric Field Gradient At Ta-181 Probe in the Hf2ni7 Compound
VL  - 27
IS  - 2
SP  - 95
EP  - 102
DO  - 10.2298/NTRP1202095C
ER  - 
@article{
author = "Cekić, Božidar Đ. and Umićević, Ana and Ivanovski, Valentin N. and Hu, Rongwei and Petrovic, Cedomir and David, Bohumil and Barudžija, Tanja",
year = "2012",
abstract = "The perturbed angular correlation method was employed to study the temperature dependence of electric field gradients at the Ta-181 probe in the polycrystalline Hf2Ni7 compound. The temperature evolution of the sample content was measured using high-temperature X-ray diffraction. To check the magnetic order of the sample, magnetization measurements and additional perturbed angular correlation measurements with externally applied magnetic field were performed. All obtained spectra showed no evidence of magnetic order of the Hf2Ni7 phase. Within the experimental resolution of the apparatus, the measured electric field gradients at Ta-181 probe for the two inequivalent Hf-181/Ta-181 sites in the Hf2Ni7 compound appeared as one in the range of 78-944 K. A single quadrupole interaction implies that the electric field gradients at the two Hf sites must be quite similar. At 293 K, the measured quadrupole interaction parameters are v(Q) = 433(1) MHz and eta = 0.300(4). An increase of the quadrupole frequency and a gradual rising of the asymmetry parameter were observed with increasing temperature. The high-temperature X-ray diffraction indicated a build up of HfO2 above 693 K.",
journal = "Nuclear technology and radiation protection",
title = "Perturbed Angular Correlation Investigation of the Electric Field Gradient At Ta-181 Probe in the Hf2ni7 Compound",
volume = "27",
number = "2",
pages = "95-102",
doi = "10.2298/NTRP1202095C"
}
Cekić, B. Đ., Umićević, A., Ivanovski, V. N., Hu, R., Petrovic, C., David, B.,& Barudžija, T.. (2012). Perturbed Angular Correlation Investigation of the Electric Field Gradient At Ta-181 Probe in the Hf2ni7 Compound. in Nuclear technology and radiation protection, 27(2), 95-102.
https://doi.org/10.2298/NTRP1202095C
Cekić BĐ, Umićević A, Ivanovski VN, Hu R, Petrovic C, David B, Barudžija T. Perturbed Angular Correlation Investigation of the Electric Field Gradient At Ta-181 Probe in the Hf2ni7 Compound. in Nuclear technology and radiation protection. 2012;27(2):95-102.
doi:10.2298/NTRP1202095C .
Cekić, Božidar Đ., Umićević, Ana, Ivanovski, Valentin N., Hu, Rongwei, Petrovic, Cedomir, David, Bohumil, Barudžija, Tanja, "Perturbed Angular Correlation Investigation of the Electric Field Gradient At Ta-181 Probe in the Hf2ni7 Compound" in Nuclear technology and radiation protection, 27, no. 2 (2012):95-102,
https://doi.org/10.2298/NTRP1202095C . .

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