Experimental and theoretical investigation of octahedral and square-planar isothiocyanato complexes of Ni(II) with acylhydrazones of 2-(diphenylphosphino)benzaldehyde
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Octahedral and square-planar isothiocyanato complexes of Ni(II) with the condensation derivative of 2-(diphenylphosphino)benzaldehyde and Girards T reagent were synthesized and characterized by elemental analysis, IR spectroscopy and X-ray crystallography. Results of magnetic measurements for octahedral Ni(II) complex were also reported. In all the complexes the ligand is coordinated as tridentate via the phosphorus, the imine nitrogen and the carbonyl oxygen atoms while the remaining coordination positions are occupied with thiocyanato anions. Coordination of deprotonated phosphine ligand results in formation of square-planar complexes, while the octahedral complex was formed with protonated ligand. Reaction energetics with both forms of ligand were studied by the means of DFT and results were in complete agreement with experimental observations. Furthermore, ligand field splitting analysis gave the deeper insight in the relationship of the isolated complex coordination environment an...d protonation of the ligand. (C) 2015 Elsevier Ltd. All rights reserved.
Ključne reči:Hydrazones / Ni(II) complex / PNO ligands / DFT calculations / X-ray structure
Izvor:Polyhedron, 2015, 89, 271-279
- Interakcije prirodnih proizvoda, njihovih derivata i kompleksnih jedinjenja sa proteinima i nukleinskim kiselinama (RS-172055)
- Slovenian Research Agency (ARRS) [P-0175], EN-FIST Centre of Excellence, Ministerio de Ciencia e Innovacion (MICINN) [CTQ2011-25086/BQU], DIUE of the Generalitat de Catalunya [20145GR1202], DIUE of the Generalitat de Catalunya (XRQTC), MICINN (Ministry of Science and Innovation, Spain), FEDER fund (European Fund for Regional Development) [UNGI08-4E-003], COST Action [CM1305], ICREA