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dc.creatorTadić, Marin
dc.creatorPanjan, Matjaž
dc.creatorMarkovic, Dragana
dc.creatorMilosevic, Irena
dc.creatorSpasojević, Vojislav
dc.date.accessioned2018-03-01T21:44:20Z
dc.date.available2018-03-01T21:44:20Z
dc.date.issued2011
dc.identifier.issn0925-8388 (print)
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/4318
dc.description.abstractWe have observed unusual magnetic properties of NiO (nickel oxide) nanoparticles embedded in a silica matrix. The sample was synthesized by a method based on the contribution of sol-gel and combustion processes. X-ray powder diffraction (XRPD) of the sample shows the formation of the nanocrystalline NiO phase whereas transmission electron microscope (TEM) reveals spherical-shaped nanoparticles of about 4 nm diameter. Moreover, HRTEM images show lattice fringes of the nanoparticles and defects in the crystal structure. The temperature and field dependence of the magnetization are also measured. The zero-field-cooled (ZFC) measurements show two maximums, one sharp and narrow at low temperatures similar to 6.5K and an other broad one at higher temperature similar to 64 K. The FC magnetization shows a continuous increase upon lowering the temperature. The M(H) measurements reveal that NiO nanoparticles display anomalous hysteretic behaviors at low temperatures (below the low temperature maximum in the ZFC curve, 2K and 5K) showing that the magnetization initial curve lies below the hysteresis loop for a certain field range. Moreover, jump of the magnetization at low temperatures (2K and 5K) are also observed. These features represent novel magnetic properties for nanosized NiO which may be attributed to the surface spins. Moreover, these results indicate that the NiO nanoparticle consists of magnetically disorder shell and antiferromagnetically order core with an uncompensated magnetic moment. (C) 2011 Elsevier B. V. All rights reserved.en
dc.relationinfo:eu-repo/grantAgreement/MESTD/Integrated and Interdisciplinary Research (IIR or III)/45015/RS//
dc.rightsrestrictedAccessen
dc.sourceJournal of Alloys and Compoundsen
dc.subjectNickel oxide (NiO)en
dc.subjectHysteresis loopen
dc.subjectNanomaterialsen
dc.subjectSol-gel synthesisen
dc.subjectMagnetic materialsen
dc.titleUnusual magnetic properties of NiO nanoparticles embedded in a silica matrixen
dc.typearticleen
dcterms.abstractТадић Марин; Пањан, Матјаз; Милосевиц, Ирена; Спасојевић Војислав; Марковиц, Драгана;
dc.citation.volume509
dc.citation.issue25
dc.citation.spage7134
dc.citation.epage7138
dc.identifier.wos000290794000027
dc.identifier.doi10.1016/j.jallcom.2011.04.032
dc.citation.rankM21a
dc.identifier.scopus2-s2.0-79956351545


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