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dc.creatorMiodragovic, Djenana U.
dc.creatorJovanovic, Dragoljub
dc.creatorBogdanović, Goran A.
dc.creatorMitic, Dragana
dc.creatorAnđelković, Katarina
dc.date.accessioned2018-03-01T21:26:14Z
dc.date.available2018-03-01T21:26:14Z
dc.date.issued2010
dc.identifier.issn0352-5139
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/4108
dc.description.abstractIn the reaction of ZnCl(2) with tacrine hydrochloride in water novel tetracoordinated (C(13)H(15)N(2))(2)[ZnCl(4)]-H(2)O complex was obtained and characterized by elemental analysis, molar conductivity and X-ray analysis. The complex crystallizes in the space group P-1 of the triclinic crystal system. The structure contains two crystallographically different molecules of protonated tacrine present as counter cations, the [ZnCl(4)](2-) complex anion and one water solvent molecule. The counter cations slightly differ in the puckering of the cyclohexene ring. The molecules of protonated tacrine are involved in different intermolecular hydrogen bonds. In the crystal, the hydrogen bonding generates a 3D assembly. In the crystal, pi center dot center dot center dot pi stacking interactions between the rings of protonated tacrine were evidenced. The [ZnCl(4)](2-) complex anion has a distorted tetrahedral geometry. Three out of the four Cl atoms are involved in intermolecular hydrogen bonding. The intermolecular H-bond interactions involving the Cl atoms affect the Zn-CI bond lengths.en
dc.relationMinistry of Science and Technological Development of the Republic of Serbia [142010, 142026]
dc.rightsopenAccessen
dc.sourceJournal of the Serbian Chemical Societyen
dc.subjectZincen
dc.subjecttacrineen
dc.subjectX-ray analysisen
dc.titleSynthesis and crystal structure of 1,2,3,4-tetrahydro-9-aminoacridine tetrachlorozincate(II) monohydrateen
dc.typearticleen
dcterms.abstractБогдановић Горан; Aндјелковиц, Катарина; Митиц, Драгана; Јовановиц, Драгољуб; Миодраговиц, Дјенана У.;
dc.citation.volume75
dc.citation.issue9
dc.citation.spage1209
dc.citation.epage1218
dc.identifier.wos000283207200005
dc.identifier.doi10.2298/JSC100302059M
dc.citation.rankM23
dc.identifier.scopus2-s2.0-77958531719
dc.identifier.fulltexthttp://vinar.vin.bg.ac.rs//bitstream/id/12668/4104.pdf


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