Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone)
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Vojinović-Ješić, Ljiljana S.
Češljević, Valerija I.
Bogdanović, Goran A.

Leovac, Vukadin M.
Szecsenyi, Katalin Meszaros

Divjakovic, Vladimir
Joksović, Milan D.

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The article describes the synthesis and crystal structure of the Mn(II) complex with 2,6-diacetylpyridine bis (Girard-T hydrazone), (H(2)dap(GT)(2))(2+), of the formula [Mn(H(2)dap(GT)(2))(NCS)(2)](NCS)(2)center dot MeOH. The complex has a pentagonal-bipyramidal coordination geometry, with pentadentate N(3)O(2) ligand in the equatorial plane and two isothiocyanato groups in the axial positions. Both the ligand and the complex are characterized by their FT-IR spectra and thermal data. (C) 2010 Elsevier B.V. All rights reserved.
Keywords:
Mn(II) complex / bis(Girard-T hydrazone) / Crystal structure / Pentagonal-bipyramidal coordinationSource:
Inorganic Chemistry Communications, 2010, 13, 9, 1085-1088Funding / projects:
- Ministry of Science and Technological Development of the Republic of Serbia [142028], Provincial Secretariat for Science and Technological Development of Vojvodina
DOI: 10.1016/j.inoche.2010.06.022
ISSN: 1387-7003
WoS: 000281011900021
Scopus: 2-s2.0-77955424448
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VinčaTY - JOUR AU - Vojinović-Ješić, Ljiljana S. AU - Češljević, Valerija I. AU - Bogdanović, Goran A. AU - Leovac, Vukadin M. AU - Szecsenyi, Katalin Meszaros AU - Divjakovic, Vladimir AU - Joksović, Milan D. PY - 2010 UR - https://vinar.vin.bg.ac.rs/handle/123456789/4079 AB - The article describes the synthesis and crystal structure of the Mn(II) complex with 2,6-diacetylpyridine bis (Girard-T hydrazone), (H(2)dap(GT)(2))(2+), of the formula [Mn(H(2)dap(GT)(2))(NCS)(2)](NCS)(2)center dot MeOH. The complex has a pentagonal-bipyramidal coordination geometry, with pentadentate N(3)O(2) ligand in the equatorial plane and two isothiocyanato groups in the axial positions. Both the ligand and the complex are characterized by their FT-IR spectra and thermal data. (C) 2010 Elsevier B.V. All rights reserved. T2 - Inorganic Chemistry Communications T1 - Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone) VL - 13 IS - 9 SP - 1085 EP - 1088 DO - 10.1016/j.inoche.2010.06.022 ER -
@article{ author = "Vojinović-Ješić, Ljiljana S. and Češljević, Valerija I. and Bogdanović, Goran A. and Leovac, Vukadin M. and Szecsenyi, Katalin Meszaros and Divjakovic, Vladimir and Joksović, Milan D.", year = "2010", abstract = "The article describes the synthesis and crystal structure of the Mn(II) complex with 2,6-diacetylpyridine bis (Girard-T hydrazone), (H(2)dap(GT)(2))(2+), of the formula [Mn(H(2)dap(GT)(2))(NCS)(2)](NCS)(2)center dot MeOH. The complex has a pentagonal-bipyramidal coordination geometry, with pentadentate N(3)O(2) ligand in the equatorial plane and two isothiocyanato groups in the axial positions. Both the ligand and the complex are characterized by their FT-IR spectra and thermal data. (C) 2010 Elsevier B.V. All rights reserved.", journal = "Inorganic Chemistry Communications", title = "Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone)", volume = "13", number = "9", pages = "1085-1088", doi = "10.1016/j.inoche.2010.06.022" }
Vojinović-Ješić, L. S., Češljević, V. I., Bogdanović, G. A., Leovac, V. M., Szecsenyi, K. M., Divjakovic, V.,& Joksović, M. D.. (2010). Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone). in Inorganic Chemistry Communications, 13(9), 1085-1088. https://doi.org/10.1016/j.inoche.2010.06.022
Vojinović-Ješić LS, Češljević VI, Bogdanović GA, Leovac VM, Szecsenyi KM, Divjakovic V, Joksović MD. Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone). in Inorganic Chemistry Communications. 2010;13(9):1085-1088. doi:10.1016/j.inoche.2010.06.022 .
Vojinović-Ješić, Ljiljana S., Češljević, Valerija I., Bogdanović, Goran A., Leovac, Vukadin M., Szecsenyi, Katalin Meszaros, Divjakovic, Vladimir, Joksović, Milan D., "Transition metal complexes with Girard reagent-based ligands. Part V. Synthesis, characterization and crystal structure of pentagonal-bipyramidal manganese(II) complex with 2,6-diacetylpyridine bis(Girard-T hydrazone)" in Inorganic Chemistry Communications, 13, no. 9 (2010):1085-1088, https://doi.org/10.1016/j.inoche.2010.06.022 . .