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Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)

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Authors
Novaković, Slađana B.
Bogdanović, Goran A.
Brceski, Ilija D.
Leovac, Vukadin M.
Article
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Abstract
The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains.
Source:
Acta Crystallographica. Section C: Crystal Structure Communications, 2009, 65, M263-M265
Funding / projects:
  • Ministry of Science and Technological Development of the Republic of Serbia [142028]

DOI: 10.1107/S0108270109021970

ISSN: 0108-2701

PubMed: 19578259

WoS: 000268436500012

Scopus: 2-s2.0-67651165477
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https://vinar.vin.bg.ac.rs/handle/123456789/3754
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Vinča
TY  - JOUR
AU  - Novaković, Slađana B.
AU  - Bogdanović, Goran A.
AU  - Brceski, Ilija D.
AU  - Leovac, Vukadin M.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3754
AB  - The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains.
T2  - Acta Crystallographica. Section C: Crystal Structure Communications
T1  - Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)
VL  - 65
SP  - M263
EP  - M265
DO  - 10.1107/S0108270109021970
ER  - 
@article{
author = "Novaković, Slađana B. and Bogdanović, Goran A. and Brceski, Ilija D. and Leovac, Vukadin M.",
year = "2009",
abstract = "The title compound, [Ni(C20H17N3OP)(N-3)], is the first complex with a semicarbazide-based ligand having a P atom as one of the donors. The influence of the P atom on the deformation of the coordination geometry of the Ni-II ion is evident but less expressed than in the cases of complexes with analogous seleno-and thiosemicarbazide ligands. The torsion angles involving the two bonds formed by the P atom within the six-membered chelate ring have the largest values [C-P-Ni-N = 24.3 (2)degrees and C-C-P-Ni = -24.2 (4)degrees], suggesting that the P atom considerably influences the conformation of the ring. Two types of N-H center dot center dot center dot N hydrogen bond connect the complex units into chains.",
journal = "Acta Crystallographica. Section C: Crystal Structure Communications",
title = "Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)",
volume = "65",
pages = "M263-M265",
doi = "10.1107/S0108270109021970"
}
Novaković, S. B., Bogdanović, G. A., Brceski, I. D.,& Leovac, V. M.. (2009). Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II). in Acta Crystallographica. Section C: Crystal Structure Communications, 65, M263-M265.
https://doi.org/10.1107/S0108270109021970
Novaković SB, Bogdanović GA, Brceski ID, Leovac VM. Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II). in Acta Crystallographica. Section C: Crystal Structure Communications. 2009;65:M263-M265.
doi:10.1107/S0108270109021970 .
Novaković, Slađana B., Bogdanović, Goran A., Brceski, Ilija D., Leovac, Vukadin M., "Different intermolecular interactions in azido[2-(diphenylphosphino)benzaldehyde semicarbazonato-kappa P-2,N-1,O]nickel(II)" in Acta Crystallographica. Section C: Crystal Structure Communications, 65 (2009):M263-M265,
https://doi.org/10.1107/S0108270109021970 . .

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