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dc.creatorMiodragovic, Djenana U.
dc.creatorMitic, Dragana M.
dc.creatorMiodragovic, Zoran M.
dc.creatorBogdanović, Goran A.
dc.creatorVitnik, Željko J.
dc.creatorVitorovic, Maja D.
dc.creatorRadulovic, Milanka D.
dc.creatorNastasijević, Branislav J.
dc.creatorJuranic, Ivan O.
dc.creatorAnđelković, Katarina K.
dc.date.accessioned2018-03-01T20:18:30Z
dc.date.available2018-03-01T20:18:30Z
dc.date.issued2008
dc.identifier.issn0020-1693 (print)
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/3363
dc.description.abstractFor the first time, complexes of Zn(II), Cd(II) and Co(II) (1-3) with N-benzyloxycarbonylglycine have been synthesized and characterized. The complexes adopt tetrahedral, pentagonal-bipyramidal and octahedral geometry, respectively. The structure of the polymeric cadmium complex was resolved by single crystal X-ray analysis. The cadmium ion has a distorted pentagonal-bipyramidal coordination formed by two water molecules and two N-benzyloxycarbonylglycinato ligands (N-Boc) coordinated in different fashions, one as bidentate and the second connecting three cadmium atoms. In a rather complicated 2D supramolecular structure, the phenyl rings interact mutually exclusively by the CH center dot center dot center dot pi interactions. Investigation of the antimicrobial activity of the obtained complexes and N-benzyloxycarbonylglycine revealed that the ligand does not inhibit the growth of Candida albicans, whereas the newly synthesized complexes suppress the growth of this human fungal pathogen. (c) 2007 Elsevier B.V. All rights reserved.en
dc.rightsrestrictedAccessen
dc.sourceInorganica Chimica Actaen
dc.subjectzinc(II)en
dc.subjectcadmium(II) and cobalt(II) complexesen
dc.subjectN-Boc-glycineen
dc.subjectX-rayen
dc.subjectDFTen
dc.subjectmicrobiological assayen
dc.titleSyntheses, characterization and antimicrobial activity of the first complexes of Zn(II), Cd(II) and Co(II) with N-benzyloxycarbonylglycine - X-ray crystal structure of the polymeric Cd(II) complexen
dc.typearticleen
dcterms.abstractМиодраговиц, Дјенана У.; Митиц, Драгана М.; Миодраговиц, Зоран М.; Радуловиц, Миланка Д.; Јураниц, Иван О.; Aнделковиц, Катарина К.; Витник, Зељко Ј.; Виторовиц, Маја Д.; Богдановић Горан; Настасијевић Бранислав;
dc.citation.volume361
dc.citation.issue1
dc.citation.spage86
dc.citation.epage94
dc.identifier.wos000253226700012
dc.identifier.doi10.1016/j.ica.2007.06.041
dc.citation.rankM22
dc.identifier.scopus2-s2.0-36649002024


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