A consideration of the correct calculation of thermodynamic parameters of adsorption
Апстракт
The Langmuir and Freundlich isotherm equations have been widely used for interpreting various adsorption processes. There are, however, many serious mistakes in the literature in determination or calculation of thermodynamic parameters, especially in the determination of the change in the free energy of adsorption using Langmuir, Freundlich and Henry constants. Many authors used these constants for the determination of Delta G expressed instead of dimensionless in some concentration units (for example: 1 mol(-1), 1 g(-1), ml mg(-1), etc.).
Кључне речи:
Adsorption / thermodynamic parameters / correct calculationИзвор:
Journal of the Serbian Chemical Society, 2007, 72, 12, 1363-1367Финансирање / пројекти:
- Синтеза, карактеризација и примена колоидних дисперзија неорганских материјала нанометарских величина (RS-MESTD-MPN2006-2010-142004)
DOI: 10.2298/JSC0712363M
ISSN: 0352-5139
WoS: 000252412100020
Scopus: 2-s2.0-36949017230
Колекције
Институција/група
VinčaTY - JOUR AU - Milonjić, Slobodan K. PY - 2007 UR - https://vinar.vin.bg.ac.rs/handle/123456789/3345 AB - The Langmuir and Freundlich isotherm equations have been widely used for interpreting various adsorption processes. There are, however, many serious mistakes in the literature in determination or calculation of thermodynamic parameters, especially in the determination of the change in the free energy of adsorption using Langmuir, Freundlich and Henry constants. Many authors used these constants for the determination of Delta G expressed instead of dimensionless in some concentration units (for example: 1 mol(-1), 1 g(-1), ml mg(-1), etc.). T2 - Journal of the Serbian Chemical Society T1 - A consideration of the correct calculation of thermodynamic parameters of adsorption VL - 72 IS - 12 SP - 1363 EP - 1367 DO - 10.2298/JSC0712363M ER -
@article{ author = "Milonjić, Slobodan K.", year = "2007", abstract = "The Langmuir and Freundlich isotherm equations have been widely used for interpreting various adsorption processes. There are, however, many serious mistakes in the literature in determination or calculation of thermodynamic parameters, especially in the determination of the change in the free energy of adsorption using Langmuir, Freundlich and Henry constants. Many authors used these constants for the determination of Delta G expressed instead of dimensionless in some concentration units (for example: 1 mol(-1), 1 g(-1), ml mg(-1), etc.).", journal = "Journal of the Serbian Chemical Society", title = "A consideration of the correct calculation of thermodynamic parameters of adsorption", volume = "72", number = "12", pages = "1363-1367", doi = "10.2298/JSC0712363M" }
Milonjić, S. K.. (2007). A consideration of the correct calculation of thermodynamic parameters of adsorption. in Journal of the Serbian Chemical Society, 72(12), 1363-1367. https://doi.org/10.2298/JSC0712363M
Milonjić SK. A consideration of the correct calculation of thermodynamic parameters of adsorption. in Journal of the Serbian Chemical Society. 2007;72(12):1363-1367. doi:10.2298/JSC0712363M .
Milonjić, Slobodan K., "A consideration of the correct calculation of thermodynamic parameters of adsorption" in Journal of the Serbian Chemical Society, 72, no. 12 (2007):1363-1367, https://doi.org/10.2298/JSC0712363M . .