Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3
Apstrakt
A potentially tridentate Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol was synthesized in the condensation reaction of 3-picolylamine and acetylacetone. The compound was characterized by H-1, C-13-NMR and IR spectra. The reaction of Schiff base with Fe(III) in the acetone solution and the presence of pyridine led to its hydrolysis and the formation of the octahedral complex [Fe(acac)Cl-2(py)(2)]. The structure of the complex was determined by the single crystal X-ray diffraction analysis. The magnetic properties and the molar conductivity of the complex compound were also derived.
Ključne reči:
Schiff base / 3-picolylamine / acetylacetone / Fe(III) complex / crystal structureIzvor:
Structural Chemistry, 2007, 18, 3, 337-341
DOI: 10.1007/s11224-007-9148-z
ISSN: 1040-0400
WoS: 000248049300013
Scopus: 2-s2.0-34447520012
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Leovac, Vukadin M. AU - Novaković, Slađana B. AU - Bogdanović, Goran A. AU - Joksović, Milan D. PY - 2007 UR - https://vinar.vin.bg.ac.rs/handle/123456789/3216 AB - A potentially tridentate Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol was synthesized in the condensation reaction of 3-picolylamine and acetylacetone. The compound was characterized by H-1, C-13-NMR and IR spectra. The reaction of Schiff base with Fe(III) in the acetone solution and the presence of pyridine led to its hydrolysis and the formation of the octahedral complex [Fe(acac)Cl-2(py)(2)]. The structure of the complex was determined by the single crystal X-ray diffraction analysis. The magnetic properties and the molar conductivity of the complex compound were also derived. T2 - Structural Chemistry T1 - Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3 VL - 18 IS - 3 SP - 337 EP - 341 DO - 10.1007/s11224-007-9148-z ER -
@article{ author = "Leovac, Vukadin M. and Novaković, Slađana B. and Bogdanović, Goran A. and Joksović, Milan D.", year = "2007", abstract = "A potentially tridentate Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol was synthesized in the condensation reaction of 3-picolylamine and acetylacetone. The compound was characterized by H-1, C-13-NMR and IR spectra. The reaction of Schiff base with Fe(III) in the acetone solution and the presence of pyridine led to its hydrolysis and the formation of the octahedral complex [Fe(acac)Cl-2(py)(2)]. The structure of the complex was determined by the single crystal X-ray diffraction analysis. The magnetic properties and the molar conductivity of the complex compound were also derived.", journal = "Structural Chemistry", title = "Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3", volume = "18", number = "3", pages = "337-341", doi = "10.1007/s11224-007-9148-z" }
Leovac, V. M., Novaković, S. B., Bogdanović, G. A.,& Joksović, M. D.. (2007). Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3. in Structural Chemistry, 18(3), 337-341. https://doi.org/10.1007/s11224-007-9148-z
Leovac VM, Novaković SB, Bogdanović GA, Joksović MD. Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3. in Structural Chemistry. 2007;18(3):337-341. doi:10.1007/s11224-007-9148-z .
Leovac, Vukadin M., Novaković, Slađana B., Bogdanović, Goran A., Joksović, Milan D., "Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3" in Structural Chemistry, 18, no. 3 (2007):337-341, https://doi.org/10.1007/s11224-007-9148-z . .