A potentially tridentate Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol was synthesized in the condensation reaction of 3-picolylamine and acetylacetone. The compound was characterized by H-1, C-13-NMR and IR spectra. The reaction of Schiff base with Fe(III) in the acetone solution and the presence of pyridine led to its hydrolysis and the formation of the octahedral complex [Fe(acac)Cl-2(py)(2)]. The structure of the complex was determined by the single crystal X-ray diffraction analysis. The magnetic properties and the molar conductivity of the complex compound were also derived.
TY - JOUR
AU - Leovac, Vukadin M.
AU - Novaković, Slađana B.
AU - Bogdanović, Goran A.
AU - Joksović, Milan D.
PY - 2007
UR - https://vinar.vin.bg.ac.rs/handle/123456789/3216
AB - A potentially tridentate Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol was synthesized in the condensation reaction of 3-picolylamine and acetylacetone. The compound was characterized by H-1, C-13-NMR and IR spectra. The reaction of Schiff base with Fe(III) in the acetone solution and the presence of pyridine led to its hydrolysis and the formation of the octahedral complex [Fe(acac)Cl-2(py)(2)]. The structure of the complex was determined by the single crystal X-ray diffraction analysis. The magnetic properties and the molar conductivity of the complex compound were also derived.
T2 - Structural Chemistry
T1 - Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3
VL - 18
IS - 3
SP - 337
EP - 341
DO - 10.1007/s11224-007-9148-z
ER -
@article{
author = "Leovac, Vukadin M. and Novaković, Slađana B. and Bogdanović, Goran A. and Joksović, Milan D.",
year = "2007",
abstract = "A potentially tridentate Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol was synthesized in the condensation reaction of 3-picolylamine and acetylacetone. The compound was characterized by H-1, C-13-NMR and IR spectra. The reaction of Schiff base with Fe(III) in the acetone solution and the presence of pyridine led to its hydrolysis and the formation of the octahedral complex [Fe(acac)Cl-2(py)(2)]. The structure of the complex was determined by the single crystal X-ray diffraction analysis. The magnetic properties and the molar conductivity of the complex compound were also derived.",
journal = "Structural Chemistry",
title = "Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3",
volume = "18",
number = "3",
pages = "337-341",
doi = "10.1007/s11224-007-9148-z"
}
Leovac, V. M., Novaković, S. B., Bogdanović, G. A.,& Joksović, M. D.. (2007). Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3. in Structural Chemistry, 18(3), 337-341.
https://doi.org/10.1007/s11224-007-9148-z
Leovac VM, Novaković SB, Bogdanović GA, Joksović MD. Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3. in Structural Chemistry. 2007;18(3):337-341.
doi:10.1007/s11224-007-9148-z .
Leovac, Vukadin M., Novaković, Slađana B., Bogdanović, Goran A., Joksović, Milan D., "Synthesis and reaction of Schiff base 4-(pyridin-3-ylmethylimino)-pent-2-en-2-ol with FeCl3" in Structural Chemistry, 18, no. 3 (2007):337-341,
https://doi.org/10.1007/s11224-007-9148-z . .
