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Synthesis under self-controlled reaction conditions: Reaction of tetraamminezinc(II) chloride with 3,5-dimethyl-1-thiocarboxamide pyrazole
dc.creator | Kovacs, Attila | |
dc.creator | Meszaros Szecsenyi, Katalin | |
dc.creator | Leovac, Vukadin M. | |
dc.creator | Tomić, Zoran D. | |
dc.creator | Pokol, Gyoergy | |
dc.date.accessioned | 2018-03-01T20:04:37Z | |
dc.date.available | 2018-03-01T20:04:37Z | |
dc.date.issued | 2007 | |
dc.identifier.issn | 0022-328X | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/3200 | |
dc.description.abstract | The trinuclear [Zn-3(Hdmpz)(2)(dmpz)(4)(NCS)(2)] complex (Hdmpz: 3,5-dimethylpyrazole) has been synthesized by the reaction of tetraamminezinc(II) chloride with 3,5-dimethyl-1-thiocarboxamidepyrazole. The ammonia evolving gradually from [Zn(NH3)(4)]Cl-2 ensured a mild gradually increasing basic pH during the synthesis which caused a cleavage of the 1-N-substituent. Moreover, the changing pH controlled the pyrazolate anion-neutral ligand equilibrium, and in this way the formation of the precipitate complex. The structure of the complex was investigated by X-ray diffraction and quantum chemical computations. The complex was characterized in detail by FT-IR-spectroscopy and thermal analysis. The bonding interactions between Zn2+ and the ligands were analysed on the basis of the computed data. (c) 2007 Elsevier B.V. All rights reserved. | en |
dc.rights | restrictedAccess | en |
dc.source | Journal of Organometallic Chemistry | en |
dc.subject | crystal growth | en |
dc.subject | XRD | en |
dc.subject | FT-IR | en |
dc.subject | thermal analysis | en |
dc.subject | DFT computations | en |
dc.title | Synthesis under self-controlled reaction conditions: Reaction of tetraamminezinc(II) chloride with 3,5-dimethyl-1-thiocarboxamide pyrazole | en |
dc.type | article | en |
dcterms.abstract | Ковацс, Aттила; Леовац, Вукадин М.; Покол, Гyоергy; Месзарос Сзецсенyи, Каталин; Томић Зоран; | |
dc.citation.volume | 692 | |
dc.citation.issue | 12 | |
dc.citation.spage | 2582 | |
dc.citation.epage | 2592 | |
dc.identifier.wos | 000246819600026 | |
dc.identifier.doi | 10.1016/j.jorganchem.2007.03.003 | |
dc.citation.rank | M21 | |
dc.identifier.scopus | 2-s2.0-34247463389 |
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