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Role of excess electrons in TiO2 nanoparticles coated with Pt in reduction reactions studied in radiolysis of aqueous solutions
dc.creator | Kasarevic-Popovic, Z | |
dc.creator | Behar, D | |
dc.creator | Rabani, J | |
dc.date.accessioned | 2018-03-01T19:33:52Z | |
dc.date.available | 2018-03-01T19:33:52Z | |
dc.date.issued | 2004 | |
dc.identifier.issn | 1520-6106 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/2839 | |
dc.description.abstract | Surface modification of TiO2 nanocrystallites in aqueous solution was carried out by reduction of chloroplatinic acid with TiO2 electrons (e(TiO2)(-)). The TiO2 electrons had been generated through electron injection from 2-propanol radicals, hydrogen atoms, and hydrated electrons produced by gamma or pulse radiolysis prior to the addition of the chloroplatinic acid. Upon addition of the latter, Pt-0 clusters are produced by multistep reduction of the chloroplatinic acid on the TiO2 surface. The present work concerns the material balance and chemical kinetics of the Pt-0 mediated reduction of water and H+ to molecular hydrogen by the TiO2 electron. Pt-0 showed no effect on the rate of oxygen reduction, compared to bare TiO2. The effect of surface Pt-0 on increasing photocatalytic yields, claimed by a number of laboratories, is apparently due to electron capture by the Pt-0 rather than electron removal by oxygen. | en |
dc.rights | restrictedAccess | en |
dc.source | Journal of Physical Chemistry. Part B: Condensed Matter, Materials, Surfaces, Interfaces and Biophysical | en |
dc.title | Role of excess electrons in TiO2 nanoparticles coated with Pt in reduction reactions studied in radiolysis of aqueous solutions | en |
dc.type | article | en |
dcterms.abstract | Касаревиц-Поповиц, З; Бехар, Д; Рабани, Ј; | |
dc.citation.volume | 108 | |
dc.citation.issue | 52 | |
dc.citation.spage | 20291 | |
dc.citation.epage | 20295 | |
dc.identifier.wos | 000225925100057 | |
dc.identifier.doi | 10.1021/jp045989g | |
dc.citation.rank | M21 | |
dc.identifier.scopus | 2-s2.0-11344271064 |
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