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dc.creatorLeovac, VM
dc.creatorBogdanović, Goran A.
dc.creatorCesljevic, VI
dc.creatorDivjakovic, V
dc.date.accessioned2018-03-01T18:53:11Z
dc.date.available2018-03-01T18:53:11Z
dc.date.issued2000
dc.identifier.issn2053-2296 (print)
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/2370
dc.description.abstractThe title compound, [diacetylpyridine bis(S-methylisothiosemicarbazonato)]iodonickel(II), [Ni(C13H18N7S2)I], is the first example of a complex involving the N-2 coordination of the isothiosemicarbazide moiety. 2,6-Diacetylpyridine bis(S-methylisothiosemicarbazone), as a potentially pentadentate ligand (N-5), is coordinated as a tetradentate species, whereby one (deprotonated) isothiosemicarbazide moiety is coordinated in the usual way ((NN)-N-1-N-4), but the other (neutral) is bonded via the N-2 atom only, the fourth ligator being the pyridine nitrogen. The difference in coordination mode of the isothiosemicarbazide moiety is reflected in the N-1-N-2 bond lengths of 1.359 (4) and 1.379 (3) Angstrom in the deprotonated and undeprotonated moieties, respectively. The structure contains three fused chelate rings in a 5:5:6 arrangement. The six-membered ring has a non-planar conformation.en
dc.rightsrestrictedAccessen
dc.sourceActa crystallographica. Section C: Structural chemistryen
dc.titleTransition metal complexes with thiosemicarbazide-based ligands. XV. A square-pyramidal Ni-II complex with an asymmetric coordination of 2,6-diacetylpyridine bis(S-methylisothiosemicarbazone)en
dc.typearticleen
dcterms.abstractЛеовац, ВМ; Цесљевиц, ВИ; Дивјаковиц, В; Богдановић Горан;
dc.citation.volume56
dc.citation.spage936
dc.citation.epage938
dc.identifier.wos000088694400010
dc.identifier.doi10.1107/S0108270100007228
dc.citation.otherPart number: 8
dc.identifier.scopus2-s2.0-0034239237


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