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dc.creatorVasić, Vesna M.
dc.creatorTosic, MS
dc.creatorJovanovic, T
dc.creatorVujisic, LS
dc.creatorNedeljković, Jovan
dc.date.accessioned2018-03-01T18:30:28Z
dc.date.available2018-03-01T18:30:28Z
dc.date.issued1998
dc.identifier.issn0277-5387 (print)
dc.identifier.urihttp://vinar.vin.bg.ac.rs/handle/123456789/2112
dc.description.abstractThe kinetics of the complex formation between S-carboxymethyl-L-cysteine and palladium(II) was studied by using stopped-flow technique in the acidity range from pH 1 to 4 at 25 degrees C. The reaction rate of the formation of 1 : 1 chelate species is strongly affected by the acidity. The reaction mechanism consisting of five parallel paths which involve Pd2+ and PdOH+, as well as LH-, LH2 and LH3+ ligand species was proposed. Fairly good agreement between the computed and experimentally determined rate constants was found. The equilibrium constants of the complex formation were determined. (C) 1998 Elsevier Science Ltd. All rights reserved.en
dc.rightsrestrictedAccessen
dc.sourcePolyhedronen
dc.subjectS-carboxymethyl-L-cysteineen
dc.subjectpalladium(II)en
dc.subjectstopped-flowen
dc.subjectcomplex formationen
dc.titleKinetics of chelate formation between Pd-II and S-carboxymethyl-L-cysteineen
dc.typearticleen
dcterms.abstractВујисиц, ЛС; Васић Весна М; Тосиц, МС; Недељковић Јован; Јовановиц, Т;
dc.citation.volume17
dc.citation.issue4
dc.citation.spage399
dc.citation.epage403
dc.identifier.wos000072113100001
dc.identifier.doi10.1016/S0277-5387(97)00388-4
dc.citation.rankM22
dc.identifier.scopus2-s2.0-0012716974


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