Temperature-programmed desorption mass spectrometric study of the surface properties of glassy carbon
Samo za registrovane korisnike
1996
Autori
Perić, Aleksandra A.Nešković, Olivera M.
Veljković, Miomir V.
Miletić, Miodrag B.
Zmbov, K
Petrović, S
Laušević, Mila D.
Laušević, Zoran
Članak u časopisu (Objavljena verzija)
Metapodaci
Prikaz svih podataka o dokumentuApstrakt
The temperature-programmed desorption (TPD) method combined with mass spectrometric analysis has been applied to the characterization of glassy carbon (GC) and modified glassy carbon surfaces. Five different samples of GC were obtained from a commercial resol type of phenol formaldehyde resin that bad undergone several treatments: the samples were either pure GC, GC treated with boron and phosphorus, or GC modified by metal (silver and palladium). Mass spectrometric analysis has shown that the thermal decomposition of surface oxide species results in desorption of H2O, CO and CO2, these being the major gas products. On the basis of the TPD spectra obtained, desorption energies have been calculated using a peak position method. The influence of CO2 oxidation on the surface properties of the samples was also investigated. It was concluded that metal deposition on a glassy carbon surface contributes to increased stability of surface oxide species, the most stable surface being one that ha...s been modified by palladium deposition.
Izvor:
Rapid Communications in Mass Spectrometry, 1996, 10, 10, 1233-1236
DOI: 10.1002/(SICI)1097-0231(19960731)10:10<1233::AID-RCM268>3.0.CO;2-V
ISSN: 0951-4198
WoS: A1996VB55500011
Scopus: 2-s2.0-0029785109
Kolekcije
Institucija/grupa
VinčaTY - JOUR AU - Perić, Aleksandra A. AU - Nešković, Olivera M. AU - Veljković, Miomir V. AU - Miletić, Miodrag B. AU - Zmbov, K AU - Petrović, S AU - Laušević, Mila D. AU - Laušević, Zoran PY - 1996 UR - https://vinar.vin.bg.ac.rs/handle/123456789/2004 AB - The temperature-programmed desorption (TPD) method combined with mass spectrometric analysis has been applied to the characterization of glassy carbon (GC) and modified glassy carbon surfaces. Five different samples of GC were obtained from a commercial resol type of phenol formaldehyde resin that bad undergone several treatments: the samples were either pure GC, GC treated with boron and phosphorus, or GC modified by metal (silver and palladium). Mass spectrometric analysis has shown that the thermal decomposition of surface oxide species results in desorption of H2O, CO and CO2, these being the major gas products. On the basis of the TPD spectra obtained, desorption energies have been calculated using a peak position method. The influence of CO2 oxidation on the surface properties of the samples was also investigated. It was concluded that metal deposition on a glassy carbon surface contributes to increased stability of surface oxide species, the most stable surface being one that has been modified by palladium deposition. T2 - Rapid Communications in Mass Spectrometry T1 - Temperature-programmed desorption mass spectrometric study of the surface properties of glassy carbon VL - 10 IS - 10 SP - 1233 EP - 1236 DO - 10.1002/(SICI)1097-0231(19960731)10:10<1233::AID-RCM268>3.0.CO;2-V UR - https://hdl.handle.net/21.15107/rcub_vinar_2004 ER -
@article{ author = "Perić, Aleksandra A. and Nešković, Olivera M. and Veljković, Miomir V. and Miletić, Miodrag B. and Zmbov, K and Petrović, S and Laušević, Mila D. and Laušević, Zoran", year = "1996", abstract = "The temperature-programmed desorption (TPD) method combined with mass spectrometric analysis has been applied to the characterization of glassy carbon (GC) and modified glassy carbon surfaces. Five different samples of GC were obtained from a commercial resol type of phenol formaldehyde resin that bad undergone several treatments: the samples were either pure GC, GC treated with boron and phosphorus, or GC modified by metal (silver and palladium). Mass spectrometric analysis has shown that the thermal decomposition of surface oxide species results in desorption of H2O, CO and CO2, these being the major gas products. On the basis of the TPD spectra obtained, desorption energies have been calculated using a peak position method. The influence of CO2 oxidation on the surface properties of the samples was also investigated. It was concluded that metal deposition on a glassy carbon surface contributes to increased stability of surface oxide species, the most stable surface being one that has been modified by palladium deposition.", journal = "Rapid Communications in Mass Spectrometry", title = "Temperature-programmed desorption mass spectrometric study of the surface properties of glassy carbon", volume = "10", number = "10", pages = "1233-1236", doi = "10.1002/(SICI)1097-0231(19960731)10:10<1233::AID-RCM268>3.0.CO;2-V", url = "https://hdl.handle.net/21.15107/rcub_vinar_2004" }
Perić, A. A., Nešković, O. M., Veljković, M. V., Miletić, M. B., Zmbov, K., Petrović, S., Laušević, M. D.,& Laušević, Z.. (1996). Temperature-programmed desorption mass spectrometric study of the surface properties of glassy carbon. in Rapid Communications in Mass Spectrometry, 10(10), 1233-1236. https://doi.org/10.1002/(SICI)1097-0231(19960731)10:10<1233::AID-RCM268>3.0.CO;2-V https://hdl.handle.net/21.15107/rcub_vinar_2004
Perić AA, Nešković OM, Veljković MV, Miletić MB, Zmbov K, Petrović S, Laušević MD, Laušević Z. Temperature-programmed desorption mass spectrometric study of the surface properties of glassy carbon. in Rapid Communications in Mass Spectrometry. 1996;10(10):1233-1236. doi:10.1002/(SICI)1097-0231(19960731)10:10<1233::AID-RCM268>3.0.CO;2-V https://hdl.handle.net/21.15107/rcub_vinar_2004 .
Perić, Aleksandra A., Nešković, Olivera M., Veljković, Miomir V., Miletić, Miodrag B., Zmbov, K, Petrović, S, Laušević, Mila D., Laušević, Zoran, "Temperature-programmed desorption mass spectrometric study of the surface properties of glassy carbon" in Rapid Communications in Mass Spectrometry, 10, no. 10 (1996):1233-1236, https://doi.org/10.1002/(SICI)1097-0231(19960731)10:10<1233::AID-RCM268>3.0.CO;2-V ., https://hdl.handle.net/21.15107/rcub_vinar_2004 .