mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI)
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1996
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In the molecule of the title compound, [MoO2(L)(CH3-OH)] [L is the dianion of 2-(2-benzoyl-1-methylethylidene)-1-naphthohydrazide, C21H16N2O2], the Mo atom displays distorted octahedral coordination geometry, being coordinated by two mutually cis oxo ligands, the methanol O atom and the tridentate ligand L bonded through the azomethine N atom, the enolic O atom and the oxazine O atom (equatorially disposed). The packing in the crystal structure involves a hydrogen bond from the methanol OH as donor to an oxo ligand as acceptor.
Izvor:
Acta Crystallographica. Section C: Crystal Structure Communications, 1996, 52, 1375-1377
DOI: 10.1107/S010827019600039X
ISSN: 0108-2701
WoS: A1996UX29800025
Scopus: 2-s2.0-3142570781
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VinčaTY - JOUR AU - Prelesnik, Bogdan V. AU - Ivanović, Ivana AU - Leovac, Vukadin M. AU - Anđelković, Katarina PY - 1996 UR - https://vinar.vin.bg.ac.rs/handle/123456789/1996 AB - In the molecule of the title compound, [MoO2(L)(CH3-OH)] [L is the dianion of 2-(2-benzoyl-1-methylethylidene)-1-naphthohydrazide, C21H16N2O2], the Mo atom displays distorted octahedral coordination geometry, being coordinated by two mutually cis oxo ligands, the methanol O atom and the tridentate ligand L bonded through the azomethine N atom, the enolic O atom and the oxazine O atom (equatorially disposed). The packing in the crystal structure involves a hydrogen bond from the methanol OH as donor to an oxo ligand as acceptor. T2 - Acta Crystallographica. Section C: Crystal Structure Communications T1 - mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI) VL - 52 SP - 1375 EP - 1377 DO - 10.1107/S010827019600039X ER -
@article{ author = "Prelesnik, Bogdan V. and Ivanović, Ivana and Leovac, Vukadin M. and Anđelković, Katarina", year = "1996", abstract = "In the molecule of the title compound, [MoO2(L)(CH3-OH)] [L is the dianion of 2-(2-benzoyl-1-methylethylidene)-1-naphthohydrazide, C21H16N2O2], the Mo atom displays distorted octahedral coordination geometry, being coordinated by two mutually cis oxo ligands, the methanol O atom and the tridentate ligand L bonded through the azomethine N atom, the enolic O atom and the oxazine O atom (equatorially disposed). The packing in the crystal structure involves a hydrogen bond from the methanol OH as donor to an oxo ligand as acceptor.", journal = "Acta Crystallographica. Section C: Crystal Structure Communications", title = "mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI)", volume = "52", pages = "1375-1377", doi = "10.1107/S010827019600039X" }
Prelesnik, B. V., Ivanović, I., Leovac, V. M.,& Anđelković, K.. (1996). mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI). in Acta Crystallographica. Section C: Crystal Structure Communications, 52, 1375-1377. https://doi.org/10.1107/S010827019600039X
Prelesnik BV, Ivanović I, Leovac VM, Anđelković K. mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI). in Acta Crystallographica. Section C: Crystal Structure Communications. 1996;52:1375-1377. doi:10.1107/S010827019600039X .
Prelesnik, Bogdan V., Ivanović, Ivana, Leovac, Vukadin M., Anđelković, Katarina, "mer-[2-(2-Benzoyl-1-methylethylidene)-1-napthtohydrazido(2-)](methanol)-cis-dioxo-molybdenum(VI)" in Acta Crystallographica. Section C: Crystal Structure Communications, 52 (1996):1375-1377, https://doi.org/10.1107/S010827019600039X . .