Michael addition of diethyl malonate, ethyl acetoacetate, acetylacetone, and cyanide anion to acryloylferrocene promoted by a catalyst in situ generated from a sacrificial zirconium anode is described. Most of the obtained compounds were identified by comparison of their spectral and physical data with those published elsewhere, whereas the only newly synthesized compound - diethyl 2,2-bis(3-ferrocenyl-3-oxopropyl)malonate - was completely characterized by spectral (IR, 1H- and 13C-NMR), physical and crystallographic (single-crystal X-ray) data.
Opisana je Majklova adicija dietil-malonata, etil-acetoacetata, acetilacetona i cijanidnog anjona na akriloilferocen pomoću katalizatora generisanog in situ sa rastvorne anode od cirkonijuma. Većina dobijenih jedinjenja je identifikovana poređenjem njihovih fizičkih i spektroskopskih podataka sa literaturnim, a jedino novo jedinjenje je potpuno opisano spektroskopskim (IR, 1H- i 13C-NMR) i fizičkim podacima, kao i podacima iz kristalografske analize X-zracima.
TY - JOUR
AU - Stevanović, Dragana
AU - Pejović, Anka
AU - Damljanović, Ivan
AU - Vukićević, Mirjana
AU - Novaković, Slađana B.
AU - Bogdanović, Goran
AU - Vukićević, Rastko
PY - 2015
UR - https://vinar.vin.bg.ac.rs/handle/123456789/11003
AB - Michael addition of diethyl malonate, ethyl acetoacetate, acetylacetone, and cyanide anion to acryloylferrocene promoted by a catalyst in situ generated from a sacrificial zirconium anode is described. Most of the obtained compounds were identified by comparison of their spectral and physical data with those published elsewhere, whereas the only newly synthesized compound - diethyl 2,2-bis(3-ferrocenyl-3-oxopropyl)malonate - was completely characterized by spectral (IR, 1H- and 13C-NMR), physical and crystallographic (single-crystal X-ray) data.
AB - Opisana je Majklova adicija dietil-malonata, etil-acetoacetata, acetilacetona i cijanidnog anjona na akriloilferocen pomoću katalizatora generisanog in situ sa rastvorne anode od cirkonijuma. Većina dobijenih jedinjenja je identifikovana poređenjem njihovih fizičkih i spektroskopskih podataka sa literaturnim, a jedino novo jedinjenje je potpuno opisano spektroskopskim (IR, 1H- i 13C-NMR) i fizičkim podacima, kao i podacima iz kristalografske analize X-zracima.
T2 - Facta universitatis - series: Physics, Chemistry and Technology
T1 - Electrochemical generation of a catalyst for Мichael addition of dicarbonyl compounds and cyanide anion to acryloylferrocene
T1 - Elektrohemijsko generisanje katalizatora za Majklovu adiciju dikarbonilnih jedinjenja i cijanida na akriloilferocen
VL - 13
IS - 2
SP - 67
EP - 76
DO - 10.2298/FUPCT1502067S
ER -
@article{
author = "Stevanović, Dragana and Pejović, Anka and Damljanović, Ivan and Vukićević, Mirjana and Novaković, Slađana B. and Bogdanović, Goran and Vukićević, Rastko",
year = "2015",
abstract = "Michael addition of diethyl malonate, ethyl acetoacetate, acetylacetone, and cyanide anion to acryloylferrocene promoted by a catalyst in situ generated from a sacrificial zirconium anode is described. Most of the obtained compounds were identified by comparison of their spectral and physical data with those published elsewhere, whereas the only newly synthesized compound - diethyl 2,2-bis(3-ferrocenyl-3-oxopropyl)malonate - was completely characterized by spectral (IR, 1H- and 13C-NMR), physical and crystallographic (single-crystal X-ray) data., Opisana je Majklova adicija dietil-malonata, etil-acetoacetata, acetilacetona i cijanidnog anjona na akriloilferocen pomoću katalizatora generisanog in situ sa rastvorne anode od cirkonijuma. Većina dobijenih jedinjenja je identifikovana poređenjem njihovih fizičkih i spektroskopskih podataka sa literaturnim, a jedino novo jedinjenje je potpuno opisano spektroskopskim (IR, 1H- i 13C-NMR) i fizičkim podacima, kao i podacima iz kristalografske analize X-zracima.",
journal = "Facta universitatis - series: Physics, Chemistry and Technology",
title = "Electrochemical generation of a catalyst for Мichael addition of dicarbonyl compounds and cyanide anion to acryloylferrocene, Elektrohemijsko generisanje katalizatora za Majklovu adiciju dikarbonilnih jedinjenja i cijanida na akriloilferocen",
volume = "13",
number = "2",
pages = "67-76",
doi = "10.2298/FUPCT1502067S"
}
Stevanović, D., Pejović, A., Damljanović, I., Vukićević, M., Novaković, S. B., Bogdanović, G.,& Vukićević, R.. (2015). Electrochemical generation of a catalyst for Мichael addition of dicarbonyl compounds and cyanide anion to acryloylferrocene. in Facta universitatis - series: Physics, Chemistry and Technology, 13(2), 67-76.
https://doi.org/10.2298/FUPCT1502067S
Stevanović D, Pejović A, Damljanović I, Vukićević M, Novaković SB, Bogdanović G, Vukićević R. Electrochemical generation of a catalyst for Мichael addition of dicarbonyl compounds and cyanide anion to acryloylferrocene. in Facta universitatis - series: Physics, Chemistry and Technology. 2015;13(2):67-76.
doi:10.2298/FUPCT1502067S .
Stevanović, Dragana, Pejović, Anka, Damljanović, Ivan, Vukićević, Mirjana, Novaković, Slađana B., Bogdanović, Goran, Vukićević, Rastko, "Electrochemical generation of a catalyst for Мichael addition of dicarbonyl compounds and cyanide anion to acryloylferrocene" in Facta universitatis - series: Physics, Chemistry and Technology, 13, no. 2 (2015):67-76,
https://doi.org/10.2298/FUPCT1502067S . .
