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Effect of montmorillonite activation method on formaldehyde content in urea-formaldehyde composites

Authorized Users Only
2023
Authors
Kostić, Marija
Samaržija-Jovanović, Suzana
Ristić, Mirjana
Jovanović, Tijana
Jovanović, Vojislav
Marković, Gordana
Marinović-Cincović, Milena
Article (Published version)
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Abstract
In this paper, the synthesis of modified urea-formaldehyde (UF) composites with differently activated montmorillonite KSF (UF/KSF) was performed. Two types of montmorillonite (MMT) KSF were used: sample activated with sulfuric acid-KSF(H2SO4) and sample activated with acid and stirring-KSF(H2SO4+stirrer). In order to examine the effect of KSF activation mode on the thermal and hydrolytic stability of UF resins, thermogravimetric analysis (TGA) was performed, as well as A determination of the amount of liberated formaldehyde (FA) after acid hydrolysis. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) analysis were used to characterize the samples of modified UF/KSF composites and differently activated KSF. Activation of KSF led to a decrease in its specific surface area (SSA) and to an increase in cation exchange capacity (CEC). SEM analysis showed that in the KSF(H2SO4+stirrer) sample, the layered microstructure was disrupted. Free formaldehyde was not detecte...d in the sample of UF resin with KSF(H2SO4), and in the sample with KSF(H2SO4+stirrer) it was 0.06%. The UF/KSF(H2SO4) composite showed higher hydrolytic stability (3.9%) compared to UF/KSF(H2SO4+stirrer) (4.62%), but lower compared to the UF/KSF(inactive) (1.23%). TG analysis showed that the KSF(H2SO4) sample had better thermal stability than the KSF(H2SO4+stirrer) sample, but this did not contribute to the better thermal stability of UF/KSF(H2SO4) compared to UF/KSF(H2SO4+stirrer), both samples had a T5% value of 112 °C.

Keywords:
Acid activation / Formaldehyde / Montmorillonite / Thermal stability / UF resin
Source:
International Journal of Adhesion and Adhesives, 2023, 124, 103390-
Funding / projects:
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200123 (University of Priština - Kosovska Mitrovica, Faculty of Natural Sciences and Mathematics) (RS-200123)
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) (RS-200017)

DOI: 10.1016/j.ijadhadh.2023.103390

ISSN: 0143-7496

Scopus: 2-s2.0-85153937932
[ Google Scholar ]
URI
https://vinar.vin.bg.ac.rs/handle/123456789/10923
Collections
  • Radovi istraživača
  • 030 - Laboratorija za radijacionu hemiju i fiziku
Institution/Community
Vinča
TY  - JOUR
AU  - Kostić, Marija
AU  - Samaržija-Jovanović, Suzana
AU  - Ristić, Mirjana
AU  - Jovanović, Tijana
AU  - Jovanović, Vojislav
AU  - Marković, Gordana
AU  - Marinović-Cincović, Milena
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10923
AB  - In this paper, the synthesis of modified urea-formaldehyde (UF) composites with differently activated montmorillonite KSF (UF/KSF) was performed. Two types of montmorillonite (MMT) KSF were used: sample activated with sulfuric acid-KSF(H2SO4) and sample activated with acid and stirring-KSF(H2SO4+stirrer). In order to examine the effect of KSF activation mode on the thermal and hydrolytic stability of UF resins, thermogravimetric analysis (TGA) was performed, as well as A determination of the amount of liberated formaldehyde (FA) after acid hydrolysis. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) analysis were used to characterize the samples of modified UF/KSF composites and differently activated KSF. Activation of KSF led to a decrease in its specific surface area (SSA) and to an increase in cation exchange capacity (CEC). SEM analysis showed that in the KSF(H2SO4+stirrer) sample, the layered microstructure was disrupted. Free formaldehyde was not detected in the sample of UF resin with KSF(H2SO4), and in the sample with KSF(H2SO4+stirrer) it was 0.06%. The UF/KSF(H2SO4) composite showed higher hydrolytic stability (3.9%) compared to UF/KSF(H2SO4+stirrer) (4.62%), but lower compared to the UF/KSF(inactive) (1.23%). TG analysis showed that the KSF(H2SO4) sample had better thermal stability than the KSF(H2SO4+stirrer) sample, but this did not contribute to the better thermal stability of UF/KSF(H2SO4) compared to UF/KSF(H2SO4+stirrer), both samples had a T5% value of 112 °C.
T2  - International Journal of Adhesion and Adhesives
T1  - Effect of montmorillonite activation method on formaldehyde content in urea-formaldehyde composites
VL  - 124
SP  - 103390
DO  - 10.1016/j.ijadhadh.2023.103390
ER  - 
@article{
author = "Kostić, Marija and Samaržija-Jovanović, Suzana and Ristić, Mirjana and Jovanović, Tijana and Jovanović, Vojislav and Marković, Gordana and Marinović-Cincović, Milena",
year = "2023",
abstract = "In this paper, the synthesis of modified urea-formaldehyde (UF) composites with differently activated montmorillonite KSF (UF/KSF) was performed. Two types of montmorillonite (MMT) KSF were used: sample activated with sulfuric acid-KSF(H2SO4) and sample activated with acid and stirring-KSF(H2SO4+stirrer). In order to examine the effect of KSF activation mode on the thermal and hydrolytic stability of UF resins, thermogravimetric analysis (TGA) was performed, as well as A determination of the amount of liberated formaldehyde (FA) after acid hydrolysis. Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction (XRD) analysis were used to characterize the samples of modified UF/KSF composites and differently activated KSF. Activation of KSF led to a decrease in its specific surface area (SSA) and to an increase in cation exchange capacity (CEC). SEM analysis showed that in the KSF(H2SO4+stirrer) sample, the layered microstructure was disrupted. Free formaldehyde was not detected in the sample of UF resin with KSF(H2SO4), and in the sample with KSF(H2SO4+stirrer) it was 0.06%. The UF/KSF(H2SO4) composite showed higher hydrolytic stability (3.9%) compared to UF/KSF(H2SO4+stirrer) (4.62%), but lower compared to the UF/KSF(inactive) (1.23%). TG analysis showed that the KSF(H2SO4) sample had better thermal stability than the KSF(H2SO4+stirrer) sample, but this did not contribute to the better thermal stability of UF/KSF(H2SO4) compared to UF/KSF(H2SO4+stirrer), both samples had a T5% value of 112 °C.",
journal = "International Journal of Adhesion and Adhesives",
title = "Effect of montmorillonite activation method on formaldehyde content in urea-formaldehyde composites",
volume = "124",
pages = "103390",
doi = "10.1016/j.ijadhadh.2023.103390"
}
Kostić, M., Samaržija-Jovanović, S., Ristić, M., Jovanović, T., Jovanović, V., Marković, G.,& Marinović-Cincović, M.. (2023). Effect of montmorillonite activation method on formaldehyde content in urea-formaldehyde composites. in International Journal of Adhesion and Adhesives, 124, 103390.
https://doi.org/10.1016/j.ijadhadh.2023.103390
Kostić M, Samaržija-Jovanović S, Ristić M, Jovanović T, Jovanović V, Marković G, Marinović-Cincović M. Effect of montmorillonite activation method on formaldehyde content in urea-formaldehyde composites. in International Journal of Adhesion and Adhesives. 2023;124:103390.
doi:10.1016/j.ijadhadh.2023.103390 .
Kostić, Marija, Samaržija-Jovanović, Suzana, Ristić, Mirjana, Jovanović, Tijana, Jovanović, Vojislav, Marković, Gordana, Marinović-Cincović, Milena, "Effect of montmorillonite activation method on formaldehyde content in urea-formaldehyde composites" in International Journal of Adhesion and Adhesives, 124 (2023):103390,
https://doi.org/10.1016/j.ijadhadh.2023.103390 . .

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