The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline
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2023
Authors
Mutić, TijanaOgnjanović, Miloš

Kodranov, Igor
Robić, Marko
Savić, Slađana

Krehula, Stjepko

Stanković, Dalibor M.

Article (Published version)

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In this work, we investigated the morphological and electrochemical properties of gallium/bismuth mixed oxide. The bismuth concentration was varied from 0 to 100%. The correct ratio was determined with inductively coupled plasma-optical emission spectroscopy (ICP-OES), while surface characteristics were determined using scanning electron microscopy (SEM) and X-ray diffraction (XRD) measurement. Electrochemical characteristics were studied using electrochemical impedance spectroscopy (EIS) in the Fe2+/3+ couple. The obtained materials were tested for adrenaline detection. After square wave voltammetry (SWV) optimization, the best electrode showed a wide linear working range from 7 to 100 µM at pH 6 of the Britton–Robinson buffer solution (BRBS) supporting electrolyte. The limit of detection (LOD) for the proposed method was calculated as 1.9 µM, with a limit of quantification (LOQ) of 5.8 µM. The excellent selectivity of the proposed method, with good repeatability and reproducibility, ...strongly suggests the possible application of the procedure for the determination of adrenaline in artificially prepared real samples. The practical applicability with good recovery values indicates that the morphology of the materials is closely connected with other parameters, which further suggests that the developed approach can offer a low-cost, rapid, selective, and sensitive method for adrenaline monitoring. Graphical abstract: [Figure not available: see fulltext.] © 2023, Springer-Verlag GmbH Germany, part of Springer Nature.
Keywords:
Determination / Epinephrine / Gallium/bismuth oxide / Oxidation / VoltammetrySource:
Analytical and Bioanalytical Chemistry, 2023, InPressFunding / projects:
- Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200168 (University of Belgrade, Faculty of Chemistry) (RS-200168)
- EUREKA [Project E!13303]
- Serbia-Croatia bilateral project [337-00-205/2019-09/03]
Note:
- Contains correction: 10.1007/s00216-023-04674-y
- Contains correction: https://vinar.vin.bg.ac.rs/handle/123456789/10855
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https://vinar.vin.bg.ac.rs/handle/123456789/10855
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VinčaTY - JOUR AU - Mutić, Tijana AU - Ognjanović, Miloš AU - Kodranov, Igor AU - Robić, Marko AU - Savić, Slađana AU - Krehula, Stjepko AU - Stanković, Dalibor M. PY - 2023 UR - https://vinar.vin.bg.ac.rs/handle/123456789/10737 AB - In this work, we investigated the morphological and electrochemical properties of gallium/bismuth mixed oxide. The bismuth concentration was varied from 0 to 100%. The correct ratio was determined with inductively coupled plasma-optical emission spectroscopy (ICP-OES), while surface characteristics were determined using scanning electron microscopy (SEM) and X-ray diffraction (XRD) measurement. Electrochemical characteristics were studied using electrochemical impedance spectroscopy (EIS) in the Fe2+/3+ couple. The obtained materials were tested for adrenaline detection. After square wave voltammetry (SWV) optimization, the best electrode showed a wide linear working range from 7 to 100 µM at pH 6 of the Britton–Robinson buffer solution (BRBS) supporting electrolyte. The limit of detection (LOD) for the proposed method was calculated as 1.9 µM, with a limit of quantification (LOQ) of 5.8 µM. The excellent selectivity of the proposed method, with good repeatability and reproducibility, strongly suggests the possible application of the procedure for the determination of adrenaline in artificially prepared real samples. The practical applicability with good recovery values indicates that the morphology of the materials is closely connected with other parameters, which further suggests that the developed approach can offer a low-cost, rapid, selective, and sensitive method for adrenaline monitoring. Graphical abstract: [Figure not available: see fulltext.] © 2023, Springer-Verlag GmbH Germany, part of Springer Nature. T2 - Analytical and Bioanalytical Chemistry T1 - The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline IS - InPress DO - 10.1007/s00216-023-04617-7 ER -
@article{ author = "Mutić, Tijana and Ognjanović, Miloš and Kodranov, Igor and Robić, Marko and Savić, Slađana and Krehula, Stjepko and Stanković, Dalibor M.", year = "2023", abstract = "In this work, we investigated the morphological and electrochemical properties of gallium/bismuth mixed oxide. The bismuth concentration was varied from 0 to 100%. The correct ratio was determined with inductively coupled plasma-optical emission spectroscopy (ICP-OES), while surface characteristics were determined using scanning electron microscopy (SEM) and X-ray diffraction (XRD) measurement. Electrochemical characteristics were studied using electrochemical impedance spectroscopy (EIS) in the Fe2+/3+ couple. The obtained materials were tested for adrenaline detection. After square wave voltammetry (SWV) optimization, the best electrode showed a wide linear working range from 7 to 100 µM at pH 6 of the Britton–Robinson buffer solution (BRBS) supporting electrolyte. The limit of detection (LOD) for the proposed method was calculated as 1.9 µM, with a limit of quantification (LOQ) of 5.8 µM. The excellent selectivity of the proposed method, with good repeatability and reproducibility, strongly suggests the possible application of the procedure for the determination of adrenaline in artificially prepared real samples. The practical applicability with good recovery values indicates that the morphology of the materials is closely connected with other parameters, which further suggests that the developed approach can offer a low-cost, rapid, selective, and sensitive method for adrenaline monitoring. Graphical abstract: [Figure not available: see fulltext.] © 2023, Springer-Verlag GmbH Germany, part of Springer Nature.", journal = "Analytical and Bioanalytical Chemistry", title = "The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline", number = "InPress", doi = "10.1007/s00216-023-04617-7" }
Mutić, T., Ognjanović, M., Kodranov, I., Robić, M., Savić, S., Krehula, S.,& Stanković, D. M.. (2023). The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline. in Analytical and Bioanalytical Chemistry(InPress). https://doi.org/10.1007/s00216-023-04617-7
Mutić T, Ognjanović M, Kodranov I, Robić M, Savić S, Krehula S, Stanković DM. The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline. in Analytical and Bioanalytical Chemistry. 2023;(InPress). doi:10.1007/s00216-023-04617-7 .
Mutić, Tijana, Ognjanović, Miloš, Kodranov, Igor, Robić, Marko, Savić, Slađana, Krehula, Stjepko, Stanković, Dalibor M., "The influence of bismuth participation on the morphological and electrochemical characteristics of gallium oxide for the detection of adrenaline" in Analytical and Bioanalytical Chemistry, no. InPress (2023), https://doi.org/10.1007/s00216-023-04617-7 . .