The influence of chronopotentiometry response on the morphology and structure of galvanostatically synthesized tin dendriticparticles has been investigated. Sn dendrites were electrodeposited at the current density 1.5 times larger than the limiting diffusioncurrent density (− 3 mA cm−2) with various amounts of the electricity (200 and 400 mC), and the obtained morphologyand structure of the particles were characterized by SEM and XRD techniques, respectively. The strong effect of the amountof spent electricity on the morphology and structure of the particles was observed, and it is explained by morphological andstructural analysis of Sn particles produced potentiostatically at various cathodic potentials selected to be in line with therecorded chronopotentiometry response. The strong correlation among chronopotentiometry response, morphology, andstructure of the Sn dendrites was established. The spear-like and the dendrites with prismatic branches possessed the strong(200),(400) prefe...rred orientation, and they were obtained with a chronopotentiometry response of about − 1200 mV vs. Ag/AgCl. The chronopotentiometry responses in the − 1210 ÷ − 1740 mV vs. Ag/AgCl range caused a formation of the fern-likedendrites with the strong (220),(440) preferred orientation. Based on the obtained results, it follows that the chronopotentiometryanalysis represents good diagnostic criteria for obtaining Sn powder particles of desired morphology and structure.
TY - JOUR
AU - Lović, Jelena
AU - Nikolić, Nebojša D.
AU - Maksimović, Vesna
PY - 2023
UR - https://vinar.vin.bg.ac.rs/handle/123456789/10608
AB - The influence of chronopotentiometry response on the morphology and structure of galvanostatically synthesized tin dendriticparticles has been investigated. Sn dendrites were electrodeposited at the current density 1.5 times larger than the limiting diffusioncurrent density (− 3 mA cm−2) with various amounts of the electricity (200 and 400 mC), and the obtained morphologyand structure of the particles were characterized by SEM and XRD techniques, respectively. The strong effect of the amountof spent electricity on the morphology and structure of the particles was observed, and it is explained by morphological andstructural analysis of Sn particles produced potentiostatically at various cathodic potentials selected to be in line with therecorded chronopotentiometry response. The strong correlation among chronopotentiometry response, morphology, andstructure of the Sn dendrites was established. The spear-like and the dendrites with prismatic branches possessed the strong(200),(400) preferred orientation, and they were obtained with a chronopotentiometry response of about − 1200 mV vs. Ag/AgCl. The chronopotentiometry responses in the − 1210 ÷ − 1740 mV vs. Ag/AgCl range caused a formation of the fern-likedendrites with the strong (220),(440) preferred orientation. Based on the obtained results, it follows that the chronopotentiometryanalysis represents good diagnostic criteria for obtaining Sn powder particles of desired morphology and structure.
T2 - Journal of Solid State Electrochemistry
T1 - The control of morphology and structure of galvanostatically produced tin dendrites by analysis of chronopotentiometry response
DO - 10.1007/s10008-023-05380-6
ER -
@article{
author = "Lović, Jelena and Nikolić, Nebojša D. and Maksimović, Vesna",
year = "2023",
abstract = "The influence of chronopotentiometry response on the morphology and structure of galvanostatically synthesized tin dendriticparticles has been investigated. Sn dendrites were electrodeposited at the current density 1.5 times larger than the limiting diffusioncurrent density (− 3 mA cm−2) with various amounts of the electricity (200 and 400 mC), and the obtained morphologyand structure of the particles were characterized by SEM and XRD techniques, respectively. The strong effect of the amountof spent electricity on the morphology and structure of the particles was observed, and it is explained by morphological andstructural analysis of Sn particles produced potentiostatically at various cathodic potentials selected to be in line with therecorded chronopotentiometry response. The strong correlation among chronopotentiometry response, morphology, andstructure of the Sn dendrites was established. The spear-like and the dendrites with prismatic branches possessed the strong(200),(400) preferred orientation, and they were obtained with a chronopotentiometry response of about − 1200 mV vs. Ag/AgCl. The chronopotentiometry responses in the − 1210 ÷ − 1740 mV vs. Ag/AgCl range caused a formation of the fern-likedendrites with the strong (220),(440) preferred orientation. Based on the obtained results, it follows that the chronopotentiometryanalysis represents good diagnostic criteria for obtaining Sn powder particles of desired morphology and structure.",
journal = "Journal of Solid State Electrochemistry",
title = "The control of morphology and structure of galvanostatically produced tin dendrites by analysis of chronopotentiometry response",
doi = "10.1007/s10008-023-05380-6"
}
Lović, J., Nikolić, N. D.,& Maksimović, V.. (2023). The control of morphology and structure of galvanostatically produced tin dendrites by analysis of chronopotentiometry response. in Journal of Solid State Electrochemistry.
https://doi.org/10.1007/s10008-023-05380-6
Lović J, Nikolić ND, Maksimović V. The control of morphology and structure of galvanostatically produced tin dendrites by analysis of chronopotentiometry response. in Journal of Solid State Electrochemistry. 2023;.
doi:10.1007/s10008-023-05380-6 .
Lović, Jelena, Nikolić, Nebojša D., Maksimović, Vesna, "The control of morphology and structure of galvanostatically produced tin dendrites by analysis of chronopotentiometry response" in Journal of Solid State Electrochemistry (2023),
https://doi.org/10.1007/s10008-023-05380-6 . .
