Magnetic Properties of Cr(III) and Fe(III) Ions in Hexaaqua-Nitrate-Trihydrates
Апстракт
The manuscript contains new measurements and calculations of magnetic susceptibility of Cr(III) and Fe(III) ions in hexaaqua-nitrate-trihydrate. The magnetic properties of the ion M=Cr(III), Fe(III) in hexaaqua-nitrate-trihydrate M(H2O)6(NO3)3·3H2O were studied from the temperature dependence of magnetic susceptibility determined using the SQUID susceptometer, within the temperature range 4 K ≤ T ≤ 290 K. The detected deviation from the CurieWeiss law is explained by the splitting of the ground state energies of the magnetic ions under the influence of the crystalline field (splitting in the zero field) and the contribution of the temperature independent Van-Vleck paramagnetism.
Кључне речи:
Magnetic susceptibility / Cr(III) and Fe(III) ions / crystalline fieldИзвор:
Journal of Research in Physics, 2002, 29, 1, 79-83Финансирање / пројекти:
- Ministry of Science, Technologies and Development of the Republic of Serbia ”Physical Properties of Bulk and Nanoparticled Rare Earths and Transition Metal Based Magnetic Materials” [Grant No.2022-OI]
Колекције
Институција/група
VinčaTY - JOUR AU - Vučinić, M. AU - Mitrić, Miodrag AU - Kusigerski, Vladan AU - Kapor, Agneš AU - Szytula, Andrzej PY - 2002 UR - https://vinar.vin.bg.ac.rs/handle/123456789/10424 AB - The manuscript contains new measurements and calculations of magnetic susceptibility of Cr(III) and Fe(III) ions in hexaaqua-nitrate-trihydrate. The magnetic properties of the ion M=Cr(III), Fe(III) in hexaaqua-nitrate-trihydrate M(H2O)6(NO3)3·3H2O were studied from the temperature dependence of magnetic susceptibility determined using the SQUID susceptometer, within the temperature range 4 K ≤ T ≤ 290 K. The detected deviation from the CurieWeiss law is explained by the splitting of the ground state energies of the magnetic ions under the influence of the crystalline field (splitting in the zero field) and the contribution of the temperature independent Van-Vleck paramagnetism. T2 - Journal of Research in Physics T1 - Magnetic Properties of Cr(III) and Fe(III) Ions in Hexaaqua-Nitrate-Trihydrates VL - 29 IS - 1 SP - 79 EP - 83 UR - https://hdl.handle.net/21.15107/rcub_vinar_10424 ER -
@article{ author = "Vučinić, M. and Mitrić, Miodrag and Kusigerski, Vladan and Kapor, Agneš and Szytula, Andrzej", year = "2002", abstract = "The manuscript contains new measurements and calculations of magnetic susceptibility of Cr(III) and Fe(III) ions in hexaaqua-nitrate-trihydrate. The magnetic properties of the ion M=Cr(III), Fe(III) in hexaaqua-nitrate-trihydrate M(H2O)6(NO3)3·3H2O were studied from the temperature dependence of magnetic susceptibility determined using the SQUID susceptometer, within the temperature range 4 K ≤ T ≤ 290 K. The detected deviation from the CurieWeiss law is explained by the splitting of the ground state energies of the magnetic ions under the influence of the crystalline field (splitting in the zero field) and the contribution of the temperature independent Van-Vleck paramagnetism.", journal = "Journal of Research in Physics", title = "Magnetic Properties of Cr(III) and Fe(III) Ions in Hexaaqua-Nitrate-Trihydrates", volume = "29", number = "1", pages = "79-83", url = "https://hdl.handle.net/21.15107/rcub_vinar_10424" }
Vučinić, M., Mitrić, M., Kusigerski, V., Kapor, A.,& Szytula, A.. (2002). Magnetic Properties of Cr(III) and Fe(III) Ions in Hexaaqua-Nitrate-Trihydrates. in Journal of Research in Physics, 29(1), 79-83. https://hdl.handle.net/21.15107/rcub_vinar_10424
Vučinić M, Mitrić M, Kusigerski V, Kapor A, Szytula A. Magnetic Properties of Cr(III) and Fe(III) Ions in Hexaaqua-Nitrate-Trihydrates. in Journal of Research in Physics. 2002;29(1):79-83. https://hdl.handle.net/21.15107/rcub_vinar_10424 .
Vučinić, M., Mitrić, Miodrag, Kusigerski, Vladan, Kapor, Agneš, Szytula, Andrzej, "Magnetic Properties of Cr(III) and Fe(III) Ions in Hexaaqua-Nitrate-Trihydrates" in Journal of Research in Physics, 29, no. 1 (2002):79-83, https://hdl.handle.net/21.15107/rcub_vinar_10424 .