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Photoluminescence of Y3NbO7:Eu3+ powders
dc.creator | Đačanin Far, Ljubica | |
dc.creator | Ćirić, Aleksandar | |
dc.creator | Ristić, Zoran | |
dc.creator | Periša, Jovana | |
dc.creator | Dramićanin, Tatjana | |
dc.creator | Lukić-Petrović, Svetlana R. | |
dc.creator | Dramićanin, Miroslav | |
dc.date.accessioned | 2022-07-04T11:26:25Z | |
dc.date.available | 2022-07-04T11:26:25Z | |
dc.date.issued | 2022 | |
dc.identifier.issn | 0272-8842 | |
dc.identifier.uri | https://vinar.vin.bg.ac.rs/handle/123456789/10342 | |
dc.description.abstract | Y3NbO7:xEu3+ powders (x = 0.25, 0.5, 0.75, 2, 3, 5, 10 at%) were synthesized by a two-step vibrational milling, alternating with annealing. All the samples crystallize as fluorite-type structure (space group Fm3‾m), with crystallite size 50–60 nm and show a strong orange/red luminescence with an excited state lifetime around 1.2 ms. Photoluminescence excitation and emission spectra show rapid intensity decline after 3 at% of Eu3+ content, indicating this concentration as critical for the concentration quenching, and we predicted multipolar interaction as the dominant mechanism behind it. Judd–Ofelt intensity parameters (Ω2 = 0.941∙10−20 cm2, Ω4 = 0.277∙10−20 cm2, Ω6 = 0.277∙10−20 cm2) were obtained from the excitation spectrum of Y3NbO7:3 at%Eu3+. The emission of this luminescent powder is characterized by radiative and nonradiative lifetimes of 2.3 ms and 2.4 ms, respectively, and an intrinsic quantum yield of 51.5%. | en |
dc.language | en | |
dc.relation | Ministry of Education, Science and Technological Development of the Republic of Serbia. | |
dc.rights | restrictedAccess | |
dc.source | Ceramics International | |
dc.subject | Judd ofelt | en |
dc.subject | Lifetime | en |
dc.subject | Milling | en |
dc.subject | Niobates | en |
dc.subject | Optical properties | en |
dc.title | Photoluminescence of Y3NbO7:Eu3+ powders | en |
dc.type | article | en |
dc.rights.license | ARR | |
dc.identifier.doi | 10.1016/j.ceramint.2022.06.130 | |
dc.type.version | publishedVersion | |
dc.identifier.scopus | 2-s2.0-85132748926 |
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