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Assessment of synergistic effect on performing the co-pyrolysis process of coal and waste blends based on thermal analysis

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2022
Main article [PDF] (1.864Mb)
Authors
Brat, Zagorka
Janković, Bojan
Stojiljković, Dragoslava
Radojević, Miloš
Manić, Nebojša G.
Article (Published version)
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Abstract
The preliminary thermogravimetric studies of co-pyrolyzed low rank coals (lignites Kostolac and Kolubara) with waste materials (spent coffee ground and waste rubber granulate) in a form of blends have been performed. Thermal analysis measurements of blend samples were carried out in a nitrogen, atmosphere at three different heating rates of 10, 15, and 20 K per minute. The coal-waste blends were prepared in the percentage ratios of 90:10, 80:20, and 70:30. This work analyzed the synergy analysis for considered blends shown via descriptive parameters during co-pyrolysis process. According to the performed analysis, the presence of synergistic effect was identified, where strong interactions were also observed. For lignite-spent coffee ground blends, it was found that two factors which affect the synergy effect with coal are concentration of added biomass material and the heating rate. For lignite-tire rubber granulate blends, the blending ratio take on a decisive role for positive conse...quences of a synergistic effect (ratios below 30% of tire rubber granulate in coals are desirable). Also, in this work the influence of micro-scale condition parameters such as heating rate (as the experimental regulatory factor) was analyzed on the magnitude response of synergism during co-pyrolysis.

Keywords:
low-rank coals / waste / blend ratio / synergy effect / heating rate
Source:
Thermal Science, 2022, 26, 3 Part A, 2211-2224
Funding / projects:
  • Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 200105 (University of Belgrade, Faculty of Mechanical Engineering) (RS-200105)

DOI: 10.2298/TSCI210516310B

ISSN: 0354-9836

Scopus: 2-s2.0-85131408361
[ Google Scholar ]
URI
https://vinar.vin.bg.ac.rs/handle/123456789/10307
Collections
  • Radovi istraživača
Institution/Community
Vinča
TY  - JOUR
AU  - Brat, Zagorka
AU  - Janković, Bojan
AU  - Stojiljković, Dragoslava
AU  - Radojević, Miloš
AU  - Manić, Nebojša G.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10307
AB  - The preliminary thermogravimetric studies of co-pyrolyzed low rank coals (lignites Kostolac and Kolubara) with waste materials (spent coffee ground and waste rubber granulate) in a form of blends have been performed. Thermal analysis measurements of blend samples were carried out in a nitrogen, atmosphere at three different heating rates of 10, 15, and 20 K per minute. The coal-waste blends were prepared in the percentage ratios of 90:10, 80:20, and 70:30. This work analyzed the synergy analysis for considered blends shown via descriptive parameters during co-pyrolysis process. According to the performed analysis, the presence of synergistic effect was identified, where strong interactions were also observed. For lignite-spent coffee ground blends, it was found that two factors which affect the synergy effect with coal are concentration of added biomass material and the heating rate. For lignite-tire rubber granulate blends, the blending ratio take on a decisive role for positive consequences of a synergistic effect (ratios below 30% of tire rubber granulate in coals are desirable). Also, in this work the influence of micro-scale condition parameters such as heating rate (as the experimental regulatory factor) was analyzed on the magnitude response of synergism during co-pyrolysis.
T2  - Thermal Science
T1  - Assessment of synergistic effect on performing the co-pyrolysis process of coal and waste blends based on thermal analysis
VL  - 26
IS  - 3 Part A
SP  - 2211
EP  - 2224
DO  - 10.2298/TSCI210516310B
ER  - 
@article{
author = "Brat, Zagorka and Janković, Bojan and Stojiljković, Dragoslava and Radojević, Miloš and Manić, Nebojša G.",
year = "2022",
abstract = "The preliminary thermogravimetric studies of co-pyrolyzed low rank coals (lignites Kostolac and Kolubara) with waste materials (spent coffee ground and waste rubber granulate) in a form of blends have been performed. Thermal analysis measurements of blend samples were carried out in a nitrogen, atmosphere at three different heating rates of 10, 15, and 20 K per minute. The coal-waste blends were prepared in the percentage ratios of 90:10, 80:20, and 70:30. This work analyzed the synergy analysis for considered blends shown via descriptive parameters during co-pyrolysis process. According to the performed analysis, the presence of synergistic effect was identified, where strong interactions were also observed. For lignite-spent coffee ground blends, it was found that two factors which affect the synergy effect with coal are concentration of added biomass material and the heating rate. For lignite-tire rubber granulate blends, the blending ratio take on a decisive role for positive consequences of a synergistic effect (ratios below 30% of tire rubber granulate in coals are desirable). Also, in this work the influence of micro-scale condition parameters such as heating rate (as the experimental regulatory factor) was analyzed on the magnitude response of synergism during co-pyrolysis.",
journal = "Thermal Science",
title = "Assessment of synergistic effect on performing the co-pyrolysis process of coal and waste blends based on thermal analysis",
volume = "26",
number = "3 Part A",
pages = "2211-2224",
doi = "10.2298/TSCI210516310B"
}
Brat, Z., Janković, B., Stojiljković, D., Radojević, M.,& Manić, N. G.. (2022). Assessment of synergistic effect on performing the co-pyrolysis process of coal and waste blends based on thermal analysis. in Thermal Science, 26(3 Part A), 2211-2224.
https://doi.org/10.2298/TSCI210516310B
Brat Z, Janković B, Stojiljković D, Radojević M, Manić NG. Assessment of synergistic effect on performing the co-pyrolysis process of coal and waste blends based on thermal analysis. in Thermal Science. 2022;26(3 Part A):2211-2224.
doi:10.2298/TSCI210516310B .
Brat, Zagorka, Janković, Bojan, Stojiljković, Dragoslava, Radojević, Miloš, Manić, Nebojša G., "Assessment of synergistic effect on performing the co-pyrolysis process of coal and waste blends based on thermal analysis" in Thermal Science, 26, no. 3 Part A (2022):2211-2224,
https://doi.org/10.2298/TSCI210516310B . .

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