Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study
Само за регистроване кориснике
2022
Аутори
Pijović, MilenaManić, Nebojša G.
Vasić Anićijević, Dragana D.
Krstić, Aleksandar
Mitrić, Miodrag
Matić, Tamara
Janković, Bojan Ž.
Чланак у часопису (Објављена верзија)
Метаподаци
Приказ свих података о документуАпстракт
Pyrolytic tire (PT) chars were first produced from waste car tires (WCT) through carbonization process at 800 °C, for different retention times. Then, best PT-char sample by its physicochemical properties (WCT 800(1 h)) was further tested for its ability to adsorb Rhodamine B (RhB) dye from aqueous solutions. Structural characterization of synthesized material showed existence of graphene-based material, with average pore diameter of 22.8 nm and specific surface area of 55.8 m2·g−1. Obtained carbon material meets specifications of commercial carbon black (CB). The yield of 33.6% of CB recovered has been achieved. Under the optimal conditions, 99.57% of RhB was removed. Adsorption of RhB obeys pseudo second-order model and Langmuir isotherm model. DFT (the density functional theory) was revealed that effective bonding of RhB onto WCT 800 originates from π-electron interactions with aromatic moieties and chemical (or at least the electrostatic) interactions, between positive nitrogen and... electron-rich surface groups.
Кључне речи:
DFT / Graphene-based adsorbent / Pyrolysis / Recycling / Surface properties / Waste tiresИзвор:
Diamond and Related Materials, 2022, 121, 108768-Финансирање / пројекти:
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200105 (Универзитет у Београду, Машински факултет) (RS-MESTD-inst-2020-200105)
- Министарство науке, технолошког развоја и иновација Републике Србије, институционално финансирање - 200017 (Универзитет у Београду, Институт за нуклеарне науке Винча, Београд-Винча) (RS-MESTD-inst-2020-200017)
DOI: 10.1016/j.diamond.2021.108768
ISSN: 0925-9635
WoS: 000733634900004
Scopus: 2-s2.0-85121014167
Колекције
Институција/група
VinčaTY - JOUR AU - Pijović, Milena AU - Manić, Nebojša G. AU - Vasić Anićijević, Dragana D. AU - Krstić, Aleksandar AU - Mitrić, Miodrag AU - Matić, Tamara AU - Janković, Bojan Ž. PY - 2022 UR - https://vinar.vin.bg.ac.rs/handle/123456789/10077 AB - Pyrolytic tire (PT) chars were first produced from waste car tires (WCT) through carbonization process at 800 °C, for different retention times. Then, best PT-char sample by its physicochemical properties (WCT 800(1 h)) was further tested for its ability to adsorb Rhodamine B (RhB) dye from aqueous solutions. Structural characterization of synthesized material showed existence of graphene-based material, with average pore diameter of 22.8 nm and specific surface area of 55.8 m2·g−1. Obtained carbon material meets specifications of commercial carbon black (CB). The yield of 33.6% of CB recovered has been achieved. Under the optimal conditions, 99.57% of RhB was removed. Adsorption of RhB obeys pseudo second-order model and Langmuir isotherm model. DFT (the density functional theory) was revealed that effective bonding of RhB onto WCT 800 originates from π-electron interactions with aromatic moieties and chemical (or at least the electrostatic) interactions, between positive nitrogen and electron-rich surface groups. T2 - Diamond and Related Materials T1 - Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study VL - 121 SP - 108768 DO - 10.1016/j.diamond.2021.108768 ER -
@article{ author = "Pijović, Milena and Manić, Nebojša G. and Vasić Anićijević, Dragana D. and Krstić, Aleksandar and Mitrić, Miodrag and Matić, Tamara and Janković, Bojan Ž.", year = "2022", abstract = "Pyrolytic tire (PT) chars were first produced from waste car tires (WCT) through carbonization process at 800 °C, for different retention times. Then, best PT-char sample by its physicochemical properties (WCT 800(1 h)) was further tested for its ability to adsorb Rhodamine B (RhB) dye from aqueous solutions. Structural characterization of synthesized material showed existence of graphene-based material, with average pore diameter of 22.8 nm and specific surface area of 55.8 m2·g−1. Obtained carbon material meets specifications of commercial carbon black (CB). The yield of 33.6% of CB recovered has been achieved. Under the optimal conditions, 99.57% of RhB was removed. Adsorption of RhB obeys pseudo second-order model and Langmuir isotherm model. DFT (the density functional theory) was revealed that effective bonding of RhB onto WCT 800 originates from π-electron interactions with aromatic moieties and chemical (or at least the electrostatic) interactions, between positive nitrogen and electron-rich surface groups.", journal = "Diamond and Related Materials", title = "Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study", volume = "121", pages = "108768", doi = "10.1016/j.diamond.2021.108768" }
Pijović, M., Manić, N. G., Vasić Anićijević, D. D., Krstić, A., Mitrić, M., Matić, T.,& Janković, B. Ž.. (2022). Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study. in Diamond and Related Materials, 121, 108768. https://doi.org/10.1016/j.diamond.2021.108768
Pijović M, Manić NG, Vasić Anićijević DD, Krstić A, Mitrić M, Matić T, Janković BŽ. Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study. in Diamond and Related Materials. 2022;121:108768. doi:10.1016/j.diamond.2021.108768 .
Pijović, Milena, Manić, Nebojša G., Vasić Anićijević, Dragana D., Krstić, Aleksandar, Mitrić, Miodrag, Matić, Tamara, Janković, Bojan Ž., "Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study" in Diamond and Related Materials, 121 (2022):108768, https://doi.org/10.1016/j.diamond.2021.108768 . .