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In Silico Investigation of Selected Pesticides and Their Determination in Agricultural Products Using QuEChERS Methodology and HPLC-DAD

Petrović, Stefan; Arsić, Biljana; Zlatanović, Ivana; Milićević, Jelena; Glišić, Sanja; Mitić, Milan; Đurović-Pejčev, Rada; Stojanović, Gordana

(2023)

TY  - JOUR
AU  - Petrović, Stefan
AU  - Arsić, Biljana
AU  - Zlatanović, Ivana
AU  - Milićević, Jelena
AU  - Glišić, Sanja
AU  - Mitić, Milan
AU  - Đurović-Pejčev, Rada
AU  - Stojanović, Gordana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11025
AB  - In this study, we considered some pesticides as active substances within formulations for the protection of plant-based food in the Republic of Serbia in silico, because these pesticides have not often been investigated in this way previously, and in an analytical way, because there are not very many available fast, cheap, and easy methods for their determination in real agricultural samples. Seven pesticides were detected in selected agricultural products (tomatoes, cucumbers, peppers, and grapes) using the QuEChERS methodology and HPLC-DAD. Standard curves for the investigated pesticides (chlorantraniliprole, methomyl, metalaxyl, thiacloprid, acetamiprid, emamectin benzoate, and cymoxanil) show good linearity, with R2 values from 0.9785 to 0.9996. The HPLC-DAD method is fast, and these pesticides can be determined in real spiked samples in less than 15 min. We further characterized the pesticides we found in food based on physicochemical properties and molecular descriptors to predict the absorption, distribution, metabolism, elimination, and toxicity (ADMET) of the compounds. We summarized the data supporting their effects on humans using various computational tools to determine their potential adverse effects. The results of our prediction study show that all of the selected pesticides considered in this study have good oral bioavailability, and those with high toxicity, therefore, could be harmful to human health. Chlorantraniliprole was shown in a molecular docking study as a good starting point for a new Alzheimer’s disease drug candidate.
T2  - International Journal of Molecular Sciences
T1  - In Silico Investigation of Selected Pesticides and Their Determination in Agricultural Products Using QuEChERS Methodology and HPLC-DAD
VL  - 24
IS  - 9
SP  - 8003
DO  - 10.3390/ijms24098003
ER  - 
@article{
author = "Petrović, Stefan and Arsić, Biljana and Zlatanović, Ivana and Milićević, Jelena and Glišić, Sanja and Mitić, Milan and Đurović-Pejčev, Rada and Stojanović, Gordana",
year = "2023",
abstract = "In this study, we considered some pesticides as active substances within formulations for the protection of plant-based food in the Republic of Serbia in silico, because these pesticides have not often been investigated in this way previously, and in an analytical way, because there are not very many available fast, cheap, and easy methods for their determination in real agricultural samples. Seven pesticides were detected in selected agricultural products (tomatoes, cucumbers, peppers, and grapes) using the QuEChERS methodology and HPLC-DAD. Standard curves for the investigated pesticides (chlorantraniliprole, methomyl, metalaxyl, thiacloprid, acetamiprid, emamectin benzoate, and cymoxanil) show good linearity, with R2 values from 0.9785 to 0.9996. The HPLC-DAD method is fast, and these pesticides can be determined in real spiked samples in less than 15 min. We further characterized the pesticides we found in food based on physicochemical properties and molecular descriptors to predict the absorption, distribution, metabolism, elimination, and toxicity (ADMET) of the compounds. We summarized the data supporting their effects on humans using various computational tools to determine their potential adverse effects. The results of our prediction study show that all of the selected pesticides considered in this study have good oral bioavailability, and those with high toxicity, therefore, could be harmful to human health. Chlorantraniliprole was shown in a molecular docking study as a good starting point for a new Alzheimer’s disease drug candidate.",
journal = "International Journal of Molecular Sciences",
title = "In Silico Investigation of Selected Pesticides and Their Determination in Agricultural Products Using QuEChERS Methodology and HPLC-DAD",
volume = "24",
number = "9",
pages = "8003",
doi = "10.3390/ijms24098003"
}
Petrović, S., Arsić, B., Zlatanović, I., Milićević, J., Glišić, S., Mitić, M., Đurović-Pejčev, R.,& Stojanović, G.. (2023). In Silico Investigation of Selected Pesticides and Their Determination in Agricultural Products Using QuEChERS Methodology and HPLC-DAD. in International Journal of Molecular Sciences, 24(9), 8003.
https://doi.org/10.3390/ijms24098003
Petrović S, Arsić B, Zlatanović I, Milićević J, Glišić S, Mitić M, Đurović-Pejčev R, Stojanović G. In Silico Investigation of Selected Pesticides and Their Determination in Agricultural Products Using QuEChERS Methodology and HPLC-DAD. in International Journal of Molecular Sciences. 2023;24(9):8003.
doi:10.3390/ijms24098003 .
Petrović, Stefan, Arsić, Biljana, Zlatanović, Ivana, Milićević, Jelena, Glišić, Sanja, Mitić, Milan, Đurović-Pejčev, Rada, Stojanović, Gordana, "In Silico Investigation of Selected Pesticides and Their Determination in Agricultural Products Using QuEChERS Methodology and HPLC-DAD" in International Journal of Molecular Sciences, 24, no. 9 (2023):8003,
https://doi.org/10.3390/ijms24098003 . .

Inhibition of SARS-CoV-2 Mpro with Vitamin C, L-Arginine and a Vitamin C/L-Arginine Combination

Đukić, Ivana; Kaličanin, Nevena; Senćanski, Milan V.; Pajović, Snežana B.; Milićević, Jelena S.; Prljić, Jelena; Paessler, Slobodan; Prodanović, Radivoje; Glišić, Sanja

(2023)

TY  - JOUR
AU  - Đukić, Ivana
AU  - Kaličanin, Nevena
AU  - Senćanski, Milan V.
AU  - Pajović, Snežana B.
AU  - Milićević, Jelena S.
AU  - Prljić, Jelena
AU  - Paessler, Slobodan
AU  - Prodanović, Radivoje
AU  - Glišić, Sanja
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10629
AB  - Drug resistance is a critical problem in health care that affects therapy outcomes and requires new approaches to drugdesign. SARS-CoV-2 Mpro mutations are of concern as they can potentially reduce therapeutic efficacy. Viral infections are amongst themany disorders for which nutraceuticals have been employed as an adjunct therapy. The aim of this study was to examine the potentialin vitro activity of L-arginine and vitamin C against SARS-CoV-2 Mpro. Methods: The Mpro inhibition assay was developed by cloning,expression, purification, and characterization of Mpro. Selected compounds were then screened for protease inhibition. Results: Largininewas found to be active against SARS-CoV-2 Mpro, while a vitamin C/L-arginine combination had a synergistic antiviral actionagainst Mpro. These findings confirm the results of our previous in silico repurposing study that showed L-arginine and vitamin C werepotential Mpro inhibitors. Moreover, they suggest a possible molecular mechanism to explain the beneficial effect of arginine in COVIDpatients. Conclusions: The findings of the current study are important because they help to identify COVID-19 treatments that areefficient, inexpensive, and have a favorable safety profile. The results of this study also suggest a possible adjuvant nutritional strategyfor COVID-19 that could be used in conjunction with pharmacological agents.
T2  - Frontiers in Bioscience - Landmark
T1  - Inhibition of SARS-CoV-2 Mpro with Vitamin C, L-Arginine and a Vitamin C/L-Arginine Combination
VL  - 28
IS  - 1
SP  - 8
DO  - 10.31083/j.fbl2801008
ER  - 
@article{
author = "Đukić, Ivana and Kaličanin, Nevena and Senćanski, Milan V. and Pajović, Snežana B. and Milićević, Jelena S. and Prljić, Jelena and Paessler, Slobodan and Prodanović, Radivoje and Glišić, Sanja",
year = "2023",
abstract = "Drug resistance is a critical problem in health care that affects therapy outcomes and requires new approaches to drugdesign. SARS-CoV-2 Mpro mutations are of concern as they can potentially reduce therapeutic efficacy. Viral infections are amongst themany disorders for which nutraceuticals have been employed as an adjunct therapy. The aim of this study was to examine the potentialin vitro activity of L-arginine and vitamin C against SARS-CoV-2 Mpro. Methods: The Mpro inhibition assay was developed by cloning,expression, purification, and characterization of Mpro. Selected compounds were then screened for protease inhibition. Results: Largininewas found to be active against SARS-CoV-2 Mpro, while a vitamin C/L-arginine combination had a synergistic antiviral actionagainst Mpro. These findings confirm the results of our previous in silico repurposing study that showed L-arginine and vitamin C werepotential Mpro inhibitors. Moreover, they suggest a possible molecular mechanism to explain the beneficial effect of arginine in COVIDpatients. Conclusions: The findings of the current study are important because they help to identify COVID-19 treatments that areefficient, inexpensive, and have a favorable safety profile. The results of this study also suggest a possible adjuvant nutritional strategyfor COVID-19 that could be used in conjunction with pharmacological agents.",
journal = "Frontiers in Bioscience - Landmark",
title = "Inhibition of SARS-CoV-2 Mpro with Vitamin C, L-Arginine and a Vitamin C/L-Arginine Combination",
volume = "28",
number = "1",
pages = "8",
doi = "10.31083/j.fbl2801008"
}
Đukić, I., Kaličanin, N., Senćanski, M. V., Pajović, S. B., Milićević, J. S., Prljić, J., Paessler, S., Prodanović, R.,& Glišić, S.. (2023). Inhibition of SARS-CoV-2 Mpro with Vitamin C, L-Arginine and a Vitamin C/L-Arginine Combination. in Frontiers in Bioscience - Landmark, 28(1), 8.
https://doi.org/10.31083/j.fbl2801008
Đukić I, Kaličanin N, Senćanski MV, Pajović SB, Milićević JS, Prljić J, Paessler S, Prodanović R, Glišić S. Inhibition of SARS-CoV-2 Mpro with Vitamin C, L-Arginine and a Vitamin C/L-Arginine Combination. in Frontiers in Bioscience - Landmark. 2023;28(1):8.
doi:10.31083/j.fbl2801008 .
Đukić, Ivana, Kaličanin, Nevena, Senćanski, Milan V., Pajović, Snežana B., Milićević, Jelena S., Prljić, Jelena, Paessler, Slobodan, Prodanović, Radivoje, Glišić, Sanja, "Inhibition of SARS-CoV-2 Mpro with Vitamin C, L-Arginine and a Vitamin C/L-Arginine Combination" in Frontiers in Bioscience - Landmark, 28, no. 1 (2023):8,
https://doi.org/10.31083/j.fbl2801008 . .
1
1

In Silico and In Vitro Inhibition of SARS-CoV-2 PLpro with Gramicidin D

Protić, Sara; Kaličanin, Nevena; Senćanski, Milan; Prodanović, Olivera; Milićević, Jelena S.; Perović, Vladimir; Paessler, Slobodan; Prodanović, Radivoje; Glišić, Sanja

(2023)

TY  - JOUR
AU  - Protić, Sara
AU  - Kaličanin, Nevena
AU  - Senćanski, Milan
AU  - Prodanović, Olivera
AU  - Milićević, Jelena S.
AU  - Perović, Vladimir
AU  - Paessler, Slobodan
AU  - Prodanović, Radivoje
AU  - Glišić, Sanja
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10644
AB  - Finding an effective drug to prevent or treat COVID-19 is of utmost importance in tcurrentpandemic. Since developing a new treatment takes a significant amount of time, drug repurposingcan be an effective option for achieving a rapid response. This study used a combined in silico virtualscreening protocol for candidate SARS-CoV-2 PLpro inhibitors. The Drugbank database was searchedfirst, using the Informational Spectrum Method for Small Molecules, followed by molecular docking.Gramicidin D was selected as a peptide drug, showing the best in silico interaction profile with PLpro.After the expression and purification of PLpro, gramicidin D was screened for protease inhibitionin vitro and was found to be active against PLpro. The current study’s findings are significantbecause it is critical to identify COVID-19 therapies that are efficient, affordable, and have a favorablesafety profile.
T2  - International Journal of Molecular Sciences
T1  - In Silico and In Vitro Inhibition of SARS-CoV-2 PLpro with Gramicidin D
VL  - 24
IS  - 3
SP  - 1955
DO  - 10.3390/ijms24031955
ER  - 
@article{
author = "Protić, Sara and Kaličanin, Nevena and Senćanski, Milan and Prodanović, Olivera and Milićević, Jelena S. and Perović, Vladimir and Paessler, Slobodan and Prodanović, Radivoje and Glišić, Sanja",
year = "2023",
abstract = "Finding an effective drug to prevent or treat COVID-19 is of utmost importance in tcurrentpandemic. Since developing a new treatment takes a significant amount of time, drug repurposingcan be an effective option for achieving a rapid response. This study used a combined in silico virtualscreening protocol for candidate SARS-CoV-2 PLpro inhibitors. The Drugbank database was searchedfirst, using the Informational Spectrum Method for Small Molecules, followed by molecular docking.Gramicidin D was selected as a peptide drug, showing the best in silico interaction profile with PLpro.After the expression and purification of PLpro, gramicidin D was screened for protease inhibitionin vitro and was found to be active against PLpro. The current study’s findings are significantbecause it is critical to identify COVID-19 therapies that are efficient, affordable, and have a favorablesafety profile.",
journal = "International Journal of Molecular Sciences",
title = "In Silico and In Vitro Inhibition of SARS-CoV-2 PLpro with Gramicidin D",
volume = "24",
number = "3",
pages = "1955",
doi = "10.3390/ijms24031955"
}
Protić, S., Kaličanin, N., Senćanski, M., Prodanović, O., Milićević, J. S., Perović, V., Paessler, S., Prodanović, R.,& Glišić, S.. (2023). In Silico and In Vitro Inhibition of SARS-CoV-2 PLpro with Gramicidin D. in International Journal of Molecular Sciences, 24(3), 1955.
https://doi.org/10.3390/ijms24031955
Protić S, Kaličanin N, Senćanski M, Prodanović O, Milićević JS, Perović V, Paessler S, Prodanović R, Glišić S. In Silico and In Vitro Inhibition of SARS-CoV-2 PLpro with Gramicidin D. in International Journal of Molecular Sciences. 2023;24(3):1955.
doi:10.3390/ijms24031955 .
Protić, Sara, Kaličanin, Nevena, Senćanski, Milan, Prodanović, Olivera, Milićević, Jelena S., Perović, Vladimir, Paessler, Slobodan, Prodanović, Radivoje, Glišić, Sanja, "In Silico and In Vitro Inhibition of SARS-CoV-2 PLpro with Gramicidin D" in International Journal of Molecular Sciences, 24, no. 3 (2023):1955,
https://doi.org/10.3390/ijms24031955 . .

Patterns of human and porcine gammaherpesvirus-encoded BILF1 receptor endocytosis

Mavri, Maša; Glišić, Sanja; Senćanski, Milan; Vrecl, Milka; Rosenkilde, Mette M.; Spiess, Katja; Kubale, Valentina

(2023)

TY  - JOUR
AU  - Mavri, Maša
AU  - Glišić, Sanja
AU  - Senćanski, Milan
AU  - Vrecl, Milka
AU  - Rosenkilde, Mette M.
AU  - Spiess, Katja
AU  - Kubale, Valentina
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10682
AB  - The viral G-protein-coupled receptor (vGPCR) BILF1 encoded by the Epstein–Barr virus (EBV) is an oncogene and immunoevasin and can downregulate MHC-I molecules at the surface of infected cells. MHC-I downregulation, which presumably occurs through co-internalization with EBV-BILF1, is preserved among BILF1 receptors, including the three BILF1 orthologs encoded by porcine lymphotropic herpesviruses (PLHV BILFs). This study aimed to understand the detailed mechanisms of BILF1 receptor constitutive internalization, to explore the translational potential of PLHV BILFs compared with EBV-BILF1.
T2  - Cellular and Molecular Biology Letters
T1  - Patterns of human and porcine gammaherpesvirus-encoded BILF1 receptor endocytosis
VL  - 28
IS  - 1
SP  - 14
DO  - 10.1186/s11658-023-00427-y
ER  - 
@article{
author = "Mavri, Maša and Glišić, Sanja and Senćanski, Milan and Vrecl, Milka and Rosenkilde, Mette M. and Spiess, Katja and Kubale, Valentina",
year = "2023",
abstract = "The viral G-protein-coupled receptor (vGPCR) BILF1 encoded by the Epstein–Barr virus (EBV) is an oncogene and immunoevasin and can downregulate MHC-I molecules at the surface of infected cells. MHC-I downregulation, which presumably occurs through co-internalization with EBV-BILF1, is preserved among BILF1 receptors, including the three BILF1 orthologs encoded by porcine lymphotropic herpesviruses (PLHV BILFs). This study aimed to understand the detailed mechanisms of BILF1 receptor constitutive internalization, to explore the translational potential of PLHV BILFs compared with EBV-BILF1.",
journal = "Cellular and Molecular Biology Letters",
title = "Patterns of human and porcine gammaherpesvirus-encoded BILF1 receptor endocytosis",
volume = "28",
number = "1",
pages = "14",
doi = "10.1186/s11658-023-00427-y"
}
Mavri, M., Glišić, S., Senćanski, M., Vrecl, M., Rosenkilde, M. M., Spiess, K.,& Kubale, V.. (2023). Patterns of human and porcine gammaherpesvirus-encoded BILF1 receptor endocytosis. in Cellular and Molecular Biology Letters, 28(1), 14.
https://doi.org/10.1186/s11658-023-00427-y
Mavri M, Glišić S, Senćanski M, Vrecl M, Rosenkilde MM, Spiess K, Kubale V. Patterns of human and porcine gammaherpesvirus-encoded BILF1 receptor endocytosis. in Cellular and Molecular Biology Letters. 2023;28(1):14.
doi:10.1186/s11658-023-00427-y .
Mavri, Maša, Glišić, Sanja, Senćanski, Milan, Vrecl, Milka, Rosenkilde, Mette M., Spiess, Katja, Kubale, Valentina, "Patterns of human and porcine gammaherpesvirus-encoded BILF1 receptor endocytosis" in Cellular and Molecular Biology Letters, 28, no. 1 (2023):14,
https://doi.org/10.1186/s11658-023-00427-y . .
2

Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant

Dragović, Snežana; Smičiklas, Ivana; Jović, Mihajlo; Čupić, Aleksandar; Dragović, Ranko; Gajić, Boško; Onjia, Antonije

(2023)

TY  - JOUR
AU  - Dragović, Snežana
AU  - Smičiklas, Ivana
AU  - Jović, Mihajlo
AU  - Čupić, Aleksandar
AU  - Dragović, Ranko
AU  - Gajić, Boško
AU  - Onjia, Antonije
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11024
AB  - Despite presenting a practical approach for the characterization of the environmental risk of potentially toxic elements (PTEs) derived from steel production facilities, the analysis of the spatial distribution of bioavailable PTEs concentrations in the soil is frequently overlooked in the management of polluted sites. In this study, the diethylenetriaminepentaacetic acid (DTPA)-extractable forms of PTEs were investigated in soils surrounding the largest Serbian steel production plant. The correlation and geostatistical analysis indicated their pronounced variability suggesting the anthropogenic origin of most investigated elements, apparently from the steel production facility. The detailed visualization of variables and observations derived by self-organizing maps (SOMs) revealed the homologies in PTEs’ distribution patterns, implying the common origin of some elements. These observations were confirmed by principal component analysis (PCA) and positive matrix factorization (PMF). The аpplied approach supports a comprehensive assessment of contaminated sites' ecological and health risks and provides a basis for soil remediation.
T2  - Heliyon
T1  - Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant
VL  - 9
IS  - 5
SP  - e16307
DO  - 10.1016/j.heliyon.2023.e16307
ER  - 
@article{
author = "Dragović, Snežana and Smičiklas, Ivana and Jović, Mihajlo and Čupić, Aleksandar and Dragović, Ranko and Gajić, Boško and Onjia, Antonije",
year = "2023",
abstract = "Despite presenting a practical approach for the characterization of the environmental risk of potentially toxic elements (PTEs) derived from steel production facilities, the analysis of the spatial distribution of bioavailable PTEs concentrations in the soil is frequently overlooked in the management of polluted sites. In this study, the diethylenetriaminepentaacetic acid (DTPA)-extractable forms of PTEs were investigated in soils surrounding the largest Serbian steel production plant. The correlation and geostatistical analysis indicated their pronounced variability suggesting the anthropogenic origin of most investigated elements, apparently from the steel production facility. The detailed visualization of variables and observations derived by self-organizing maps (SOMs) revealed the homologies in PTEs’ distribution patterns, implying the common origin of some elements. These observations were confirmed by principal component analysis (PCA) and positive matrix factorization (PMF). The аpplied approach supports a comprehensive assessment of contaminated sites' ecological and health risks and provides a basis for soil remediation.",
journal = "Heliyon",
title = "Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant",
volume = "9",
number = "5",
pages = "e16307",
doi = "10.1016/j.heliyon.2023.e16307"
}
Dragović, S., Smičiklas, I., Jović, M., Čupić, A., Dragović, R., Gajić, B.,& Onjia, A.. (2023). Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant. in Heliyon, 9(5), e16307.
https://doi.org/10.1016/j.heliyon.2023.e16307
Dragović S, Smičiklas I, Jović M, Čupić A, Dragović R, Gajić B, Onjia A. Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant. in Heliyon. 2023;9(5):e16307.
doi:10.1016/j.heliyon.2023.e16307 .
Dragović, Snežana, Smičiklas, Ivana, Jović, Mihajlo, Čupić, Aleksandar, Dragović, Ranko, Gajić, Boško, Onjia, Antonije, "Spatial distribution and source apportionment of DTPA-extractable metals in soils surrounding the largest Serbian steel production plant" in Heliyon, 9, no. 5 (2023):e16307,
https://doi.org/10.1016/j.heliyon.2023.e16307 . .

Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes

Lučić, Milica; Momčilović, Milan Z.; Marković, Jelena; Jović, Mihajlo D.; Smičiklas, Ivana D.; Onjia, Antonije E.

(2023)

TY  - JOUR
AU  - Lučić, Milica
AU  - Momčilović, Milan Z.
AU  - Marković, Jelena
AU  - Jović, Mihajlo D.
AU  - Smičiklas, Ivana D.
AU  - Onjia, Antonije E.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10695
AB  - The human health risks of cadmium (Cd), lead (Pb), and nickel (Ni) in fifty regular and slim cigarette brands available in the Serbian market were evaluated. Distributions on per-cigarette basis concentrations of these metals, as determined by graphite furnace atomic absorption spectrometry, were used as inputs in the probabilistic risk assessment. The contents of these metals in cigarettes varied significantly. Larger quantities of the studied metals were observed in regular cigarettes than in slim cigarettes, but the concentration levels per cigarette tobacco mass were higher in slim cigarettes. The metal concentrations in counterfeit cigarettes were marginally higher than those in authentic brands. Based on the mean concentrations, Pb was the most abundant toxic metal, followed by Ni and Cd. The calculated values of the cumulative hazard index (HI) and incremental lifetime cancer risk (ILCR) indicated a low noncarcinogenic risk and low but not negligible carcinogenic risk from Cd, Pb, and Ni. The mean HI and ILCR values obtained using probabilistic and deterministic approaches were similar. A Monte Carlo simulation was employed to minimize the uncertainty of health risk estimation. The sensitivity analysis revealed that the most influential factor was cigarette mass followed by Cd content.
T2  - Toxicological and Environmental Chemistry
T1  - Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes
IS  - inPress
SP  - 1
EP  - 19
DO  - 10.1080/02772248.2023.2177291
ER  - 
@article{
author = "Lučić, Milica and Momčilović, Milan Z. and Marković, Jelena and Jović, Mihajlo D. and Smičiklas, Ivana D. and Onjia, Antonije E.",
year = "2023",
abstract = "The human health risks of cadmium (Cd), lead (Pb), and nickel (Ni) in fifty regular and slim cigarette brands available in the Serbian market were evaluated. Distributions on per-cigarette basis concentrations of these metals, as determined by graphite furnace atomic absorption spectrometry, were used as inputs in the probabilistic risk assessment. The contents of these metals in cigarettes varied significantly. Larger quantities of the studied metals were observed in regular cigarettes than in slim cigarettes, but the concentration levels per cigarette tobacco mass were higher in slim cigarettes. The metal concentrations in counterfeit cigarettes were marginally higher than those in authentic brands. Based on the mean concentrations, Pb was the most abundant toxic metal, followed by Ni and Cd. The calculated values of the cumulative hazard index (HI) and incremental lifetime cancer risk (ILCR) indicated a low noncarcinogenic risk and low but not negligible carcinogenic risk from Cd, Pb, and Ni. The mean HI and ILCR values obtained using probabilistic and deterministic approaches were similar. A Monte Carlo simulation was employed to minimize the uncertainty of health risk estimation. The sensitivity analysis revealed that the most influential factor was cigarette mass followed by Cd content.",
journal = "Toxicological and Environmental Chemistry",
title = "Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes",
number = "inPress",
pages = "1-19",
doi = "10.1080/02772248.2023.2177291"
}
Lučić, M., Momčilović, M. Z., Marković, J., Jović, M. D., Smičiklas, I. D.,& Onjia, A. E.. (2023). Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes. in Toxicological and Environmental Chemistry(inPress), 1-19.
https://doi.org/10.1080/02772248.2023.2177291
Lučić M, Momčilović MZ, Marković J, Jović MD, Smičiklas ID, Onjia AE. Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes. in Toxicological and Environmental Chemistry. 2023;(inPress):1-19.
doi:10.1080/02772248.2023.2177291 .
Lučić, Milica, Momčilović, Milan Z., Marković, Jelena, Jović, Mihajlo D., Smičiklas, Ivana D., Onjia, Antonije E., "Monte Carlo simulation of health risk from cadmium, lead, and nickel in cigarettes" in Toxicological and Environmental Chemistry, no. inPress (2023):1-19,
https://doi.org/10.1080/02772248.2023.2177291 . .

Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties

Gojgić-Cvijović, Gordana; Jakovljević, Dragica; Živković, Ljiljana; Ćosović, Vladan; Pavlović, Vladimir; Nikolić, Ivana; Maravić, Nikola; Dokić, Ljubica

(2023)

TY  - JOUR
AU  - Gojgić-Cvijović, Gordana
AU  - Jakovljević, Dragica
AU  - Živković, Ljiljana
AU  - Ćosović, Vladan
AU  - Pavlović, Vladimir
AU  - Nikolić, Ivana
AU  - Maravić, Nikola
AU  - Dokić, Ljubica
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11023
AB  - In this study, levan from Bacillus licheniformis NS032 was modified in an aqueous medium by octenyl succinic anhydride (OSA), and the properties of the obtained derivatives were studied. The maximum efficiency in the synthesis reaction was achieved at 40 °C and a polysaccharide slurry concentration of 30 %. Increasing the reagent concentration (2–10 %) led to an increase in the degree of substitution (0.016–0.048). Structures of derivatives were confirmed by FTIR and NMR. Scanning electronic microscopy, thermogravimetry, and dynamic light scattering analyses showed that the derivatives with degrees of substitution of 0.025 and 0.036 retained levan's porous structure and thermostability and showed better colloidal stability than the native polysaccharide. The intrinsic viscosity of derivatives increased upon modification, while the surface tension of the 1 % solution was lowered to 61 mN/m. Oil-in-water emulsions prepared with sunflower oil (10 % and 20 %) by mechanical homogenization and 2 and 10 % derivatives in the continuous phase showed mean oil droplet sizes of 106–195 μm, while the distribution curves exhibited bimodal character. The studied derivatives have a good capacity to stabilize emulsions, as they have a creaming index ranging from 73 % to 94 %. The OSA-modified levans could have potential applications in new formulations of emulsion-based systems.
T2  - International Journal of Biological Macromolecules
T1  - Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties
VL  - 242
SP  - 124837
DO  - 10.1016/j.ijbiomac.2023.124837
ER  - 
@article{
author = "Gojgić-Cvijović, Gordana and Jakovljević, Dragica and Živković, Ljiljana and Ćosović, Vladan and Pavlović, Vladimir and Nikolić, Ivana and Maravić, Nikola and Dokić, Ljubica",
year = "2023",
abstract = "In this study, levan from Bacillus licheniformis NS032 was modified in an aqueous medium by octenyl succinic anhydride (OSA), and the properties of the obtained derivatives were studied. The maximum efficiency in the synthesis reaction was achieved at 40 °C and a polysaccharide slurry concentration of 30 %. Increasing the reagent concentration (2–10 %) led to an increase in the degree of substitution (0.016–0.048). Structures of derivatives were confirmed by FTIR and NMR. Scanning electronic microscopy, thermogravimetry, and dynamic light scattering analyses showed that the derivatives with degrees of substitution of 0.025 and 0.036 retained levan's porous structure and thermostability and showed better colloidal stability than the native polysaccharide. The intrinsic viscosity of derivatives increased upon modification, while the surface tension of the 1 % solution was lowered to 61 mN/m. Oil-in-water emulsions prepared with sunflower oil (10 % and 20 %) by mechanical homogenization and 2 and 10 % derivatives in the continuous phase showed mean oil droplet sizes of 106–195 μm, while the distribution curves exhibited bimodal character. The studied derivatives have a good capacity to stabilize emulsions, as they have a creaming index ranging from 73 % to 94 %. The OSA-modified levans could have potential applications in new formulations of emulsion-based systems.",
journal = "International Journal of Biological Macromolecules",
title = "Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties",
volume = "242",
pages = "124837",
doi = "10.1016/j.ijbiomac.2023.124837"
}
Gojgić-Cvijović, G., Jakovljević, D., Živković, L., Ćosović, V., Pavlović, V., Nikolić, I., Maravić, N.,& Dokić, L.. (2023). Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties. in International Journal of Biological Macromolecules, 242, 124837.
https://doi.org/10.1016/j.ijbiomac.2023.124837
Gojgić-Cvijović G, Jakovljević D, Živković L, Ćosović V, Pavlović V, Nikolić I, Maravić N, Dokić L. Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties. in International Journal of Biological Macromolecules. 2023;242:124837.
doi:10.1016/j.ijbiomac.2023.124837 .
Gojgić-Cvijović, Gordana, Jakovljević, Dragica, Živković, Ljiljana, Ćosović, Vladan, Pavlović, Vladimir, Nikolić, Ivana, Maravić, Nikola, Dokić, Ljubica, "Synthesis of octenyl succinic anhydride-modified levan and investigation of its microstructural, physicochemical, and emulsifying properties" in International Journal of Biological Macromolecules, 242 (2023):124837,
https://doi.org/10.1016/j.ijbiomac.2023.124837 . .

Enhanced resonance energy transfer in gold nanoparticles bifunctionalized by tryptophan and riboflavin and its application in fluorescence bioimaging

Pajović, Jelena D.; Dojčilović, Radovan J.; Kaščáková, Slávka; Réfrégiers, Matthieu; Božanić, Dušan K.; Đoković, Vladimir

(2023)

TY  - JOUR
AU  - Pajović, Jelena D.
AU  - Dojčilović, Radovan J.
AU  - Kaščáková, Slávka
AU  - Réfrégiers, Matthieu
AU  - Božanić, Dušan K.
AU  - Đoković, Vladimir
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11022
AB  - Gold nanoparticles were functionalized by amino acid tryptophan and vitamin riboflavin - a resonance energy transfer (RET) pair of biomolecules. The presence of the gold nanoparticles resulted in 65% increase in RET efficiency. Because of enhanced RET efficiency, the photobleaching dynamics of the fluorescent molecules at the surface of the nanoparticles is different from that of molecules in solution. The observed effect was used for detection of the functionalized nanoparticles within biological material rich with autofluorescent species. Synchrotron radiation deep-ultraviolet fluorescence microscopy is used to study the photobleaching dynamics of the fluorescence centers within human hepatocellular carcinoma Huh7.5.1 cells incubated with the nanoparticles. The fluorescent centers were classified according to their photobleaching dynamics, which enabled the discrimination of the cell areas where the accumulation of the nanoparticles takes place, even though the particles were smaller than the spatial resolution of the images.
T2  - Colloids and Surfaces B: Biointerfaces
T1  - Enhanced resonance energy transfer in gold nanoparticles bifunctionalized by tryptophan and riboflavin and its application in fluorescence bioimaging
VL  - 227
SP  - 113340
DO  - 10.1016/j.colsurfb.2023.113340
ER  - 
@article{
author = "Pajović, Jelena D. and Dojčilović, Radovan J. and Kaščáková, Slávka and Réfrégiers, Matthieu and Božanić, Dušan K. and Đoković, Vladimir",
year = "2023",
abstract = "Gold nanoparticles were functionalized by amino acid tryptophan and vitamin riboflavin - a resonance energy transfer (RET) pair of biomolecules. The presence of the gold nanoparticles resulted in 65% increase in RET efficiency. Because of enhanced RET efficiency, the photobleaching dynamics of the fluorescent molecules at the surface of the nanoparticles is different from that of molecules in solution. The observed effect was used for detection of the functionalized nanoparticles within biological material rich with autofluorescent species. Synchrotron radiation deep-ultraviolet fluorescence microscopy is used to study the photobleaching dynamics of the fluorescence centers within human hepatocellular carcinoma Huh7.5.1 cells incubated with the nanoparticles. The fluorescent centers were classified according to their photobleaching dynamics, which enabled the discrimination of the cell areas where the accumulation of the nanoparticles takes place, even though the particles were smaller than the spatial resolution of the images.",
journal = "Colloids and Surfaces B: Biointerfaces",
title = "Enhanced resonance energy transfer in gold nanoparticles bifunctionalized by tryptophan and riboflavin and its application in fluorescence bioimaging",
volume = "227",
pages = "113340",
doi = "10.1016/j.colsurfb.2023.113340"
}
Pajović, J. D., Dojčilović, R. J., Kaščáková, S., Réfrégiers, M., Božanić, D. K.,& Đoković, V.. (2023). Enhanced resonance energy transfer in gold nanoparticles bifunctionalized by tryptophan and riboflavin and its application in fluorescence bioimaging. in Colloids and Surfaces B: Biointerfaces, 227, 113340.
https://doi.org/10.1016/j.colsurfb.2023.113340
Pajović JD, Dojčilović RJ, Kaščáková S, Réfrégiers M, Božanić DK, Đoković V. Enhanced resonance energy transfer in gold nanoparticles bifunctionalized by tryptophan and riboflavin and its application in fluorescence bioimaging. in Colloids and Surfaces B: Biointerfaces. 2023;227:113340.
doi:10.1016/j.colsurfb.2023.113340 .
Pajović, Jelena D., Dojčilović, Radovan J., Kaščáková, Slávka, Réfrégiers, Matthieu, Božanić, Dušan K., Đoković, Vladimir, "Enhanced resonance energy transfer in gold nanoparticles bifunctionalized by tryptophan and riboflavin and its application in fluorescence bioimaging" in Colloids and Surfaces B: Biointerfaces, 227 (2023):113340,
https://doi.org/10.1016/j.colsurfb.2023.113340 . .
2

Effects of biomass particles size and shape on combustion process in the swirl-stabilized burner reactor: CFD and machine learning approach

Milićević, Aleksandar; Belošević, Srđan; Žarković, Mileta; Tomanović, Ivan; Crnomarković, Nenad; Stojanović, Andrijana; Stupar, Goran; Deng, Lei; Che, Defu

(2023)

TY  - JOUR
AU  - Milićević, Aleksandar
AU  - Belošević, Srđan
AU  - Žarković, Mileta
AU  - Tomanović, Ivan
AU  - Crnomarković, Nenad
AU  - Stojanović, Andrijana
AU  - Stupar, Goran
AU  - Deng, Lei
AU  - Che, Defu
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11021
AB  - When planning the development of the energy sector, significant attention is given to the energy from the renewable sources, amongst which the biomass has an important role. Computational fluid mechanics and machine learning models are the powerful and efficient tools which allow the analysis of various heat and mass transfer phenomena in energy facilities. In this study, the in-house developed CFD code and machine learning models (Random Forest, Gradient Boosting and Artificial Neural Network) for predicting the biomass trajectories, particle mass burnout and residence time in a swirl burner reactor are presented. Pulverized biomass combustion cases (fine straw, pinewood and switch grass) with various mean diameters (ranging between 60 and 650 μm) and different shape factors (within the range 0–1) are considered. The results of numerical simulations revealed a noticeably nonlinear dependence between the input values (particle types, sizes and shapes) and the output values (particle trajectories, mass burnout and residence time), mostly due to the complex swirling flow in the reactor. For particles with the mean diameters within the ranges considered, the mass burnout of particles generally decreases as the biomass particle shape factor increases. The residence time of pulverized biomass in the reactor shows in most cases a decreasing trend as the particle shape factor increases. Artificial Neural Network showed the best predictions for both particle mass burnout (RMSE = 0.083 and R2 = 0.937) and particle residence time (RMSE = 1.145 s and R2 = 0.900), providing the reliable assessment of these important indicators in the combustion process.
T2  - Biomass and Bioenergy
T1  - Effects of biomass particles size and shape on combustion process in the swirl-stabilized burner reactor: CFD and machine learning approach
VL  - 174
SP  - 106817
DO  - 10.1016/j.biombioe.2023.106817
ER  - 
@article{
author = "Milićević, Aleksandar and Belošević, Srđan and Žarković, Mileta and Tomanović, Ivan and Crnomarković, Nenad and Stojanović, Andrijana and Stupar, Goran and Deng, Lei and Che, Defu",
year = "2023",
abstract = "When planning the development of the energy sector, significant attention is given to the energy from the renewable sources, amongst which the biomass has an important role. Computational fluid mechanics and machine learning models are the powerful and efficient tools which allow the analysis of various heat and mass transfer phenomena in energy facilities. In this study, the in-house developed CFD code and machine learning models (Random Forest, Gradient Boosting and Artificial Neural Network) for predicting the biomass trajectories, particle mass burnout and residence time in a swirl burner reactor are presented. Pulverized biomass combustion cases (fine straw, pinewood and switch grass) with various mean diameters (ranging between 60 and 650 μm) and different shape factors (within the range 0–1) are considered. The results of numerical simulations revealed a noticeably nonlinear dependence between the input values (particle types, sizes and shapes) and the output values (particle trajectories, mass burnout and residence time), mostly due to the complex swirling flow in the reactor. For particles with the mean diameters within the ranges considered, the mass burnout of particles generally decreases as the biomass particle shape factor increases. The residence time of pulverized biomass in the reactor shows in most cases a decreasing trend as the particle shape factor increases. Artificial Neural Network showed the best predictions for both particle mass burnout (RMSE = 0.083 and R2 = 0.937) and particle residence time (RMSE = 1.145 s and R2 = 0.900), providing the reliable assessment of these important indicators in the combustion process.",
journal = "Biomass and Bioenergy",
title = "Effects of biomass particles size and shape on combustion process in the swirl-stabilized burner reactor: CFD and machine learning approach",
volume = "174",
pages = "106817",
doi = "10.1016/j.biombioe.2023.106817"
}
Milićević, A., Belošević, S., Žarković, M., Tomanović, I., Crnomarković, N., Stojanović, A., Stupar, G., Deng, L.,& Che, D.. (2023). Effects of biomass particles size and shape on combustion process in the swirl-stabilized burner reactor: CFD and machine learning approach. in Biomass and Bioenergy, 174, 106817.
https://doi.org/10.1016/j.biombioe.2023.106817
Milićević A, Belošević S, Žarković M, Tomanović I, Crnomarković N, Stojanović A, Stupar G, Deng L, Che D. Effects of biomass particles size and shape on combustion process in the swirl-stabilized burner reactor: CFD and machine learning approach. in Biomass and Bioenergy. 2023;174:106817.
doi:10.1016/j.biombioe.2023.106817 .
Milićević, Aleksandar, Belošević, Srđan, Žarković, Mileta, Tomanović, Ivan, Crnomarković, Nenad, Stojanović, Andrijana, Stupar, Goran, Deng, Lei, Che, Defu, "Effects of biomass particles size and shape on combustion process in the swirl-stabilized burner reactor: CFD and machine learning approach" in Biomass and Bioenergy, 174 (2023):106817,
https://doi.org/10.1016/j.biombioe.2023.106817 . .

Petkovska, Jovana; Mladenović, Nina; Marković, Darka; Radoičić, Marija; Chiang, Hsu-Cheng; Palen, Bethany; Mirakovski, Dejan; Dimova, Vesna; Radetić, Maja; Grunlan, Jaime C.; Jordanov, Igor

(2023)

TY  - JOUR
AU  - Petkovska, Jovana
AU  - Mladenović, Nina
AU  - Marković, Darka
AU  - Radoičić, Marija
AU  - Chiang, Hsu-Cheng
AU  - Palen, Bethany
AU  - Mirakovski, Dejan
AU  - Dimova, Vesna
AU  - Radetić, Maja
AU  - Grunlan, Jaime C.
AU  - Jordanov, Igor
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/11020
AB  - The flammability of polyester textiles remains a significant challenge that must be overcome to allow their use in a variety of clothing and upholstery applications. In this work, water-based polyelectrolyte solutions composed of chitosan (CH) and pectin (P), as carbon-rich biomacromolecules, and mono ammonium phosphate (MAP) were deposited on enzyme/corona modified polyester via layer-by-layer (LbL) deposition. Four bilayers (BL) of 1% CH3/(1% P-30% MAP)4.2 renders the polyester fabric self-extinguishing in vertical flame testing. This recipe yields a 42.6% lower peak heat release rate and a nearly 40% reduction in the fire growth capacity, compared to uncoated polyester, as measured by micro cone calorimetry. The enzyme/corona modification, combined with the CH/(P-MAP) intumescent system, results in a very effective flame retardant treatment with few BL deposited.
T2  - Polymer Degradation and Stability
VL  - 214
SP  - 110406
DO  - 10.1016/j.polymdegradstab.2023.110406
ER  - 
@article{
author = "Petkovska, Jovana and Mladenović, Nina and Marković, Darka and Radoičić, Marija and Chiang, Hsu-Cheng and Palen, Bethany and Mirakovski, Dejan and Dimova, Vesna and Radetić, Maja and Grunlan, Jaime C. and Jordanov, Igor",
year = "2023",
abstract = "The flammability of polyester textiles remains a significant challenge that must be overcome to allow their use in a variety of clothing and upholstery applications. In this work, water-based polyelectrolyte solutions composed of chitosan (CH) and pectin (P), as carbon-rich biomacromolecules, and mono ammonium phosphate (MAP) were deposited on enzyme/corona modified polyester via layer-by-layer (LbL) deposition. Four bilayers (BL) of 1% CH3/(1% P-30% MAP)4.2 renders the polyester fabric self-extinguishing in vertical flame testing. This recipe yields a 42.6% lower peak heat release rate and a nearly 40% reduction in the fire growth capacity, compared to uncoated polyester, as measured by micro cone calorimetry. The enzyme/corona modification, combined with the CH/(P-MAP) intumescent system, results in a very effective flame retardant treatment with few BL deposited.",
journal = "Polymer Degradation and Stability",
volume = "214",
pages = "110406",
doi = "10.1016/j.polymdegradstab.2023.110406"
}
Petkovska, J., Mladenović, N., Marković, D., Radoičić, M., Chiang, H., Palen, B., Mirakovski, D., Dimova, V., Radetić, M., Grunlan, J. C.,& Jordanov, I.. (2023). in Polymer Degradation and Stability, 214, 110406.
https://doi.org/10.1016/j.polymdegradstab.2023.110406
Petkovska J, Mladenović N, Marković D, Radoičić M, Chiang H, Palen B, Mirakovski D, Dimova V, Radetić M, Grunlan JC, Jordanov I. in Polymer Degradation and Stability. 2023;214:110406.
doi:10.1016/j.polymdegradstab.2023.110406 .
Petkovska, Jovana, Mladenović, Nina, Marković, Darka, Radoičić, Marija, Chiang, Hsu-Cheng, Palen, Bethany, Mirakovski, Dejan, Dimova, Vesna, Radetić, Maja, Grunlan, Jaime C., Jordanov, Igor, in Polymer Degradation and Stability, 214 (2023):110406,
https://doi.org/10.1016/j.polymdegradstab.2023.110406 . .

Sex-specific role of hippocampal NMDA-Erk-mTOR signaling in fear extinction of adolescent mice

Glavonić, Emilija; Mitić, Miloš; Francija, Ester; Petrović, Zorica; Adžić, Miroslav

(2023)

TY  - JOUR
AU  - Glavonić, Emilija
AU  - Mitić, Miloš
AU  - Francija, Ester
AU  - Petrović, Zorica
AU  - Adžić, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10514
AB  - Adolescence is a key phase of development for perturbations in fear extinction, with inability to adequately manage fear a potent factor for developing psychiatric disorders in adulthood. However, while behavioral correlates of adolescent fear regulation are established to a degree, molecular mediators of extinction learning in adolescence remain largely unknown. In this study, we observed fear acquisition and fear extinction (across 4 and 7 days) of adolescent and adult mice of both sexes and investigated how hippocampal levels of different plasticity markers relate to extinction learning. While fear was acquired evenly in males and females of both ages, fear extinction was found to be impaired in adolescent males. We also observed lower levels of GluA1, GLUN2A and GLUN2B subunits in male adolescents following fear acquisition, with an increase in their expression, as well as the activity of Erk-mTOR pathway over subsequent extinction sessions, which was paralleled with improved extinction learning. On the other hand, we detected no changes in plasticity-related proteins after fear acquisition in females, with alterations in GluA1, GluA4 and GLUN2B levels across fear extinction sessions. Additionally, we did not discern any pattern regarding the Erk-mTOR activity in female mice associated with their extinction performance. Overall, our research identifies sex-specific synaptic properties in the hippocampus that underlie developmentally regulated differences in fear extinction learning. We also point out hippocampal NMDA-Erk-mTOR signaling as the driving force behind successful fear extinction in male adolescents, highlighting this pathway as a potential therapeutic target for fear-related disorders in the adolescent population. © 2022 The Authors
T2  - Brain Research Bulletin
T1  - Sex-specific role of hippocampal NMDA-Erk-mTOR signaling in fear extinction of adolescent mice
VL  - 192
SP  - 156
EP  - 167
DO  - 10.1016/j.brainresbull.2022.11.011
ER  - 
@article{
author = "Glavonić, Emilija and Mitić, Miloš and Francija, Ester and Petrović, Zorica and Adžić, Miroslav",
year = "2023",
abstract = "Adolescence is a key phase of development for perturbations in fear extinction, with inability to adequately manage fear a potent factor for developing psychiatric disorders in adulthood. However, while behavioral correlates of adolescent fear regulation are established to a degree, molecular mediators of extinction learning in adolescence remain largely unknown. In this study, we observed fear acquisition and fear extinction (across 4 and 7 days) of adolescent and adult mice of both sexes and investigated how hippocampal levels of different plasticity markers relate to extinction learning. While fear was acquired evenly in males and females of both ages, fear extinction was found to be impaired in adolescent males. We also observed lower levels of GluA1, GLUN2A and GLUN2B subunits in male adolescents following fear acquisition, with an increase in their expression, as well as the activity of Erk-mTOR pathway over subsequent extinction sessions, which was paralleled with improved extinction learning. On the other hand, we detected no changes in plasticity-related proteins after fear acquisition in females, with alterations in GluA1, GluA4 and GLUN2B levels across fear extinction sessions. Additionally, we did not discern any pattern regarding the Erk-mTOR activity in female mice associated with their extinction performance. Overall, our research identifies sex-specific synaptic properties in the hippocampus that underlie developmentally regulated differences in fear extinction learning. We also point out hippocampal NMDA-Erk-mTOR signaling as the driving force behind successful fear extinction in male adolescents, highlighting this pathway as a potential therapeutic target for fear-related disorders in the adolescent population. © 2022 The Authors",
journal = "Brain Research Bulletin",
title = "Sex-specific role of hippocampal NMDA-Erk-mTOR signaling in fear extinction of adolescent mice",
volume = "192",
pages = "156-167",
doi = "10.1016/j.brainresbull.2022.11.011"
}
Glavonić, E., Mitić, M., Francija, E., Petrović, Z.,& Adžić, M.. (2023). Sex-specific role of hippocampal NMDA-Erk-mTOR signaling in fear extinction of adolescent mice. in Brain Research Bulletin, 192, 156-167.
https://doi.org/10.1016/j.brainresbull.2022.11.011
Glavonić E, Mitić M, Francija E, Petrović Z, Adžić M. Sex-specific role of hippocampal NMDA-Erk-mTOR signaling in fear extinction of adolescent mice. in Brain Research Bulletin. 2023;192:156-167.
doi:10.1016/j.brainresbull.2022.11.011 .
Glavonić, Emilija, Mitić, Miloš, Francija, Ester, Petrović, Zorica, Adžić, Miroslav, "Sex-specific role of hippocampal NMDA-Erk-mTOR signaling in fear extinction of adolescent mice" in Brain Research Bulletin, 192 (2023):156-167,
https://doi.org/10.1016/j.brainresbull.2022.11.011 . .

Polymer-Lipid Matrices based on Carboxymethyl Cellulose/Solagum and Liposomes for Controlled Release of Folic Acid

Batinić, Petar M.; Đorđević, Verica B.; Obradović, Nataša; Krstić, Aleksandar D.; Stevanović, Sanja I.; Balanč, Bojana; Marković, Smilja; Pjanović, Rada V.; Mijin, Dušan Ž.; Bugarski, Branko M.

(2023)

TY  - JOUR
AU  - Batinić, Petar M.
AU  - Đorđević, Verica B.
AU  - Obradović, Nataša
AU  - Krstić, Aleksandar D.
AU  - Stevanović, Sanja I.
AU  - Balanč, Bojana
AU  - Marković, Smilja
AU  - Pjanović, Rada V.
AU  - Mijin, Dušan Ž.
AU  - Bugarski, Branko M.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10851
AB  - Liposome-encapsulated folic acid is incorporated into the films made from sodium carboxymethyl cellulose (CMC) (2 mas%) and a mixture of CMC and solagum (9:1 w/w) using the film-forming cast solution method. Histidine is used to increase solubility for folic acid in liposomes (1–5 mg mL−1), and propylene glycol is used as a film plasticizer (2.6 mas%). The obtained films (50–60 µm tick) containing 3.12–20.19 mg of folic acid per gram of film are envisaged to be used as patches for transdermal delivery of folic acid. Therefore, some physical, mechanical, release and structural attributes of the films are scrutinized. Folic acid gives yellow color to the films and contributes to stronger chemical bonds which result in improved strength of the film. Liposomes prolong the release of folic acid from films to 24 h without adverse effects on mechanical properties of the films, but degrade homogeneity of the films, which can be ascribed to its agglomeration within the film matrix as revealed by atomic force microscopy. According to the release at pH 5.5, the film formulation based on a blend of CMC and solagum containing 3 mg mL−1 liposome-encapsulated folic acid is recommended. Practical Application: Folic acid is effective in reducing oxidative stress levels in the skin and neutralizing the harmful free radicals and is also essential for various metabolic reactions in the body. However, the limited solubility of folic acid linked with its poor absorption in an organism, low storage stability, short half-life upon oral consumption, specific food preferences of some people, extensive liver metabolism, and pregnancy-induced vomiting point to a large potential in transdermal usage of folic acid. This has motivated us to design new multicomponent polymer-lipid systems as an alternative solution to overcome some of these drawbacks. The results obtained for these multicomponent films pointed to their potential for prolonged release of folic acid to 24 h, which can also be useful for scientists interested in encapsulating similar poorly soluble compounds in CMC patches. The finding can be also valuable information for pharmaceutical manufacturers and scientists worldwide.
T2  - European Journal of Lipid Science and Technology
T1  - Polymer-Lipid Matrices based on Carboxymethyl Cellulose/Solagum and Liposomes for Controlled Release of Folic Acid
SP  - 2200169
DO  - 10.1002/ejlt.202200169
ER  - 
@article{
author = "Batinić, Petar M. and Đorđević, Verica B. and Obradović, Nataša and Krstić, Aleksandar D. and Stevanović, Sanja I. and Balanč, Bojana and Marković, Smilja and Pjanović, Rada V. and Mijin, Dušan Ž. and Bugarski, Branko M.",
year = "2023",
abstract = "Liposome-encapsulated folic acid is incorporated into the films made from sodium carboxymethyl cellulose (CMC) (2 mas%) and a mixture of CMC and solagum (9:1 w/w) using the film-forming cast solution method. Histidine is used to increase solubility for folic acid in liposomes (1–5 mg mL−1), and propylene glycol is used as a film plasticizer (2.6 mas%). The obtained films (50–60 µm tick) containing 3.12–20.19 mg of folic acid per gram of film are envisaged to be used as patches for transdermal delivery of folic acid. Therefore, some physical, mechanical, release and structural attributes of the films are scrutinized. Folic acid gives yellow color to the films and contributes to stronger chemical bonds which result in improved strength of the film. Liposomes prolong the release of folic acid from films to 24 h without adverse effects on mechanical properties of the films, but degrade homogeneity of the films, which can be ascribed to its agglomeration within the film matrix as revealed by atomic force microscopy. According to the release at pH 5.5, the film formulation based on a blend of CMC and solagum containing 3 mg mL−1 liposome-encapsulated folic acid is recommended. Practical Application: Folic acid is effective in reducing oxidative stress levels in the skin and neutralizing the harmful free radicals and is also essential for various metabolic reactions in the body. However, the limited solubility of folic acid linked with its poor absorption in an organism, low storage stability, short half-life upon oral consumption, specific food preferences of some people, extensive liver metabolism, and pregnancy-induced vomiting point to a large potential in transdermal usage of folic acid. This has motivated us to design new multicomponent polymer-lipid systems as an alternative solution to overcome some of these drawbacks. The results obtained for these multicomponent films pointed to their potential for prolonged release of folic acid to 24 h, which can also be useful for scientists interested in encapsulating similar poorly soluble compounds in CMC patches. The finding can be also valuable information for pharmaceutical manufacturers and scientists worldwide.",
journal = "European Journal of Lipid Science and Technology",
title = "Polymer-Lipid Matrices based on Carboxymethyl Cellulose/Solagum and Liposomes for Controlled Release of Folic Acid",
pages = "2200169",
doi = "10.1002/ejlt.202200169"
}
Batinić, P. M., Đorđević, V. B., Obradović, N., Krstić, A. D., Stevanović, S. I., Balanč, B., Marković, S., Pjanović, R. V., Mijin, D. Ž.,& Bugarski, B. M.. (2023). Polymer-Lipid Matrices based on Carboxymethyl Cellulose/Solagum and Liposomes for Controlled Release of Folic Acid. in European Journal of Lipid Science and Technology, 2200169.
https://doi.org/10.1002/ejlt.202200169
Batinić PM, Đorđević VB, Obradović N, Krstić AD, Stevanović SI, Balanč B, Marković S, Pjanović RV, Mijin DŽ, Bugarski BM. Polymer-Lipid Matrices based on Carboxymethyl Cellulose/Solagum and Liposomes for Controlled Release of Folic Acid. in European Journal of Lipid Science and Technology. 2023;:2200169.
doi:10.1002/ejlt.202200169 .
Batinić, Petar M., Đorđević, Verica B., Obradović, Nataša, Krstić, Aleksandar D., Stevanović, Sanja I., Balanč, Bojana, Marković, Smilja, Pjanović, Rada V., Mijin, Dušan Ž., Bugarski, Branko M., "Polymer-Lipid Matrices based on Carboxymethyl Cellulose/Solagum and Liposomes for Controlled Release of Folic Acid" in European Journal of Lipid Science and Technology (2023):2200169,
https://doi.org/10.1002/ejlt.202200169 . .

Cholecalciferol affects cardiac proteins regulating malonyl-CoA availability and intracellular calcium level

Ivković, Tamara; Tepavčević, Snežana; Romić, Snježana Đ.; Stojiljković, Mojca D.; Kostić, Milan; Stanišić, Jelena; Korićanac, Goran; Ćulafić, Tijana

(2023)

TY  - JOUR
AU  - Ivković, Tamara
AU  - Tepavčević, Snežana
AU  - Romić, Snježana Đ.
AU  - Stojiljković, Mojca D.
AU  - Kostić, Milan
AU  - Stanišić, Jelena
AU  - Korićanac, Goran
AU  - Ćulafić, Tijana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10924
AB  - Cholecalciferol improves insulin signaling and glucose metabolism in the heart and reduces
circulating non-esterified fatty acids. Cholecalciferol effects on the cardiac fatty acid (FA) metabolism
and the consequences on calcium handling were examined. Blood lipid profile was determined.
Western blot and qRT-PCR were used to examine protein and mRNA expression. Cholecalciferoltreated rats had increased acetyl CoA carboxylase 2 protein expression and decreased expression of
malonyl CoA decarboxylase. In addition, the expression of uncoupling protein 3 was elevated. Also,
the level of peroxisome proliferator-activated receptor-gamma coactivator in the nucleus of heart
cells was increased along with the level of sarcoplasmic/endoplasmic reticulum Ca2+ATPase in the
microsomal fraction. In parallel, the L-type calcium channel and ryanodine receptor expression was
reduced. In the heart of healthy rats, cholecalciferol affects proteins regulating malonyl CoA availability and intracellular Ca2+ handling proteins.
T2  - General physiology and biophysics
T1  - Cholecalciferol affects cardiac proteins regulating malonyl-CoA availability and intracellular calcium level
VL  - 42
IS  - 03
SP  - 241
EP  - 250
DO  - 10.4149/gpb_2023005
ER  - 
@article{
author = "Ivković, Tamara and Tepavčević, Snežana and Romić, Snježana Đ. and Stojiljković, Mojca D. and Kostić, Milan and Stanišić, Jelena and Korićanac, Goran and Ćulafić, Tijana",
year = "2023",
abstract = "Cholecalciferol improves insulin signaling and glucose metabolism in the heart and reduces
circulating non-esterified fatty acids. Cholecalciferol effects on the cardiac fatty acid (FA) metabolism
and the consequences on calcium handling were examined. Blood lipid profile was determined.
Western blot and qRT-PCR were used to examine protein and mRNA expression. Cholecalciferoltreated rats had increased acetyl CoA carboxylase 2 protein expression and decreased expression of
malonyl CoA decarboxylase. In addition, the expression of uncoupling protein 3 was elevated. Also,
the level of peroxisome proliferator-activated receptor-gamma coactivator in the nucleus of heart
cells was increased along with the level of sarcoplasmic/endoplasmic reticulum Ca2+ATPase in the
microsomal fraction. In parallel, the L-type calcium channel and ryanodine receptor expression was
reduced. In the heart of healthy rats, cholecalciferol affects proteins regulating malonyl CoA availability and intracellular Ca2+ handling proteins.",
journal = "General physiology and biophysics",
title = "Cholecalciferol affects cardiac proteins regulating malonyl-CoA availability and intracellular calcium level",
volume = "42",
number = "03",
pages = "241-250",
doi = "10.4149/gpb_2023005"
}
Ivković, T., Tepavčević, S., Romić, S. Đ., Stojiljković, M. D., Kostić, M., Stanišić, J., Korićanac, G.,& Ćulafić, T.. (2023). Cholecalciferol affects cardiac proteins regulating malonyl-CoA availability and intracellular calcium level. in General physiology and biophysics, 42(03), 241-250.
https://doi.org/10.4149/gpb_2023005
Ivković T, Tepavčević S, Romić SĐ, Stojiljković MD, Kostić M, Stanišić J, Korićanac G, Ćulafić T. Cholecalciferol affects cardiac proteins regulating malonyl-CoA availability and intracellular calcium level. in General physiology and biophysics. 2023;42(03):241-250.
doi:10.4149/gpb_2023005 .
Ivković, Tamara, Tepavčević, Snežana, Romić, Snježana Đ., Stojiljković, Mojca D., Kostić, Milan, Stanišić, Jelena, Korićanac, Goran, Ćulafić, Tijana, "Cholecalciferol affects cardiac proteins regulating malonyl-CoA availability and intracellular calcium level" in General physiology and biophysics, 42, no. 03 (2023):241-250,
https://doi.org/10.4149/gpb_2023005 . .

Lights and Dots toward Therapy—Carbon-Based Quantum Dots as New Agents for Photodynamic Therapy

Jovanović, Svetlana P.; Marković, Zoran M.; Budimir, Milica; Prekodravac, Jovana; Zmejkoski, Danica; Kepić, Dejan; Bonasera, Aurelio; Todorović-Marković, Biljana

(2023)

TY  - JOUR
AU  - Jovanović, Svetlana P.
AU  - Marković, Zoran M.
AU  - Budimir, Milica
AU  - Prekodravac, Jovana
AU  - Zmejkoski, Danica
AU  - Kepić, Dejan
AU  - Bonasera, Aurelio
AU  - Todorović-Marković, Biljana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10926
AB  - The large number of deaths induced by carcinoma and infections indicates that the need for new, better, targeted therapy is higher than ever. Apart from classical treatments and medication, photodynamic therapy (PDT) is one of the possible approaches to cure these clinical conditions. This strategy offers several advantages, such as lower toxicity, selective treatment, faster recovery time, avoidance of systemic toxic effects, and others. Unfortunately, there is a small number of agents that are approved for usage in clinical PDT. Novel, efficient, biocompatible PDT agents are, thus, highly desired. One of the most promising candidates is represented by the broad family of carbon-based quantum dots, such as graphene quantum dots (GQDs), carbon quantum dots (CQDs), carbon nanodots (CNDs), and carbonized polymer dots (CPDs). In this review paper, these new smart nanomaterials are discussed as potential PDT agents, detailing their toxicity in the dark, and when they are exposed to light, as well as their effects on carcinoma and bacterial cells. The photoinduced effects of carbon-based quantum dots on bacteria and viruses are particularly interesting, since dots usually generate several highly toxic reactive oxygen species under blue light. These species are acting as bombs on pathogen cells, causing various devastating and toxic effects on those targets.
T2  - Pharmaceutics
T1  - Lights and Dots toward Therapy—Carbon-Based Quantum Dots as New Agents for Photodynamic Therapy
VL  - 15
IS  - 4
SP  - 1170
DO  - 10.3390/pharmaceutics15041170
ER  - 
@article{
author = "Jovanović, Svetlana P. and Marković, Zoran M. and Budimir, Milica and Prekodravac, Jovana and Zmejkoski, Danica and Kepić, Dejan and Bonasera, Aurelio and Todorović-Marković, Biljana",
year = "2023",
abstract = "The large number of deaths induced by carcinoma and infections indicates that the need for new, better, targeted therapy is higher than ever. Apart from classical treatments and medication, photodynamic therapy (PDT) is one of the possible approaches to cure these clinical conditions. This strategy offers several advantages, such as lower toxicity, selective treatment, faster recovery time, avoidance of systemic toxic effects, and others. Unfortunately, there is a small number of agents that are approved for usage in clinical PDT. Novel, efficient, biocompatible PDT agents are, thus, highly desired. One of the most promising candidates is represented by the broad family of carbon-based quantum dots, such as graphene quantum dots (GQDs), carbon quantum dots (CQDs), carbon nanodots (CNDs), and carbonized polymer dots (CPDs). In this review paper, these new smart nanomaterials are discussed as potential PDT agents, detailing their toxicity in the dark, and when they are exposed to light, as well as their effects on carcinoma and bacterial cells. The photoinduced effects of carbon-based quantum dots on bacteria and viruses are particularly interesting, since dots usually generate several highly toxic reactive oxygen species under blue light. These species are acting as bombs on pathogen cells, causing various devastating and toxic effects on those targets.",
journal = "Pharmaceutics",
title = "Lights and Dots toward Therapy—Carbon-Based Quantum Dots as New Agents for Photodynamic Therapy",
volume = "15",
number = "4",
pages = "1170",
doi = "10.3390/pharmaceutics15041170"
}
Jovanović, S. P., Marković, Z. M., Budimir, M., Prekodravac, J., Zmejkoski, D., Kepić, D., Bonasera, A.,& Todorović-Marković, B.. (2023). Lights and Dots toward Therapy—Carbon-Based Quantum Dots as New Agents for Photodynamic Therapy. in Pharmaceutics, 15(4), 1170.
https://doi.org/10.3390/pharmaceutics15041170
Jovanović SP, Marković ZM, Budimir M, Prekodravac J, Zmejkoski D, Kepić D, Bonasera A, Todorović-Marković B. Lights and Dots toward Therapy—Carbon-Based Quantum Dots as New Agents for Photodynamic Therapy. in Pharmaceutics. 2023;15(4):1170.
doi:10.3390/pharmaceutics15041170 .
Jovanović, Svetlana P., Marković, Zoran M., Budimir, Milica, Prekodravac, Jovana, Zmejkoski, Danica, Kepić, Dejan, Bonasera, Aurelio, Todorović-Marković, Biljana, "Lights and Dots toward Therapy—Carbon-Based Quantum Dots as New Agents for Photodynamic Therapy" in Pharmaceutics, 15, no. 4 (2023):1170,
https://doi.org/10.3390/pharmaceutics15041170 . .

Optical conductivity and vibrational spectra of the narrow-gap semiconductor FeGa3

Martin, Catalin; Martinez, V. A.; Opačić, Marko R.; Đurđić-Mijin, Sanja; Mitrić, Petar; Umićević, Ana; Poudel, A.; Sydoryk, Ihor; Ren, Weijun; Martin, Ruaridh M.; Tanner, David B.; Lazarević, Nenad; Petrović, Čedomir; Tanasković, Darko

(2023)

TY  - JOUR
AU  - Martin, Catalin
AU  - Martinez, V. A.
AU  - Opačić, Marko R.
AU  - Đurđić-Mijin, Sanja
AU  - Mitrić, Petar
AU  - Umićević, Ana
AU  - Poudel, A.
AU  - Sydoryk, Ihor
AU  - Ren, Weijun
AU  - Martin, Ruaridh M.
AU  - Tanner, David B.
AU  - Lazarević, Nenad
AU  - Petrović, Čedomir
AU  - Tanasković, Darko
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10987
AB  - Intermetallic narrow-gap semiconductors have been intensively explored due to their large thermoelectric power at low temperatures and a possible role of strong electronic correlations in their unusual thermodynamic and transport properties. Here we study the optical spectra and vibrational properties of FeGa3 single crystal. The optical conductivity indicates that FeGa3 has a direct band gap of ≈0.7 eV, consistent with density functional theory (DFT) calculations. Most importantly, we find a substantial spectral weight also below 0.4 eV, which is the energy of the indirect (charge) gap found in resistivity measurements and ab initio calculations. We find that the spectral weight below the gap decreases with increasing temperature, which indicates that it originates from the impurity states and not from the electronic correlations. Interestingly, we did not find any signatures of the impurity states in vibrational spectra. The infrared and Raman vibrational lines are narrow and weakly temperature dependent. The vibrational frequencies are in excellent agreement with our DFT calculations, implying a modest role of electronic correlations. Narrow Mössbauer spectral lines also indicate high crystallinity of the sample. © 2023 American Physical Society.
T2  - Physical Review B
T1  - Optical conductivity and vibrational spectra of the narrow-gap semiconductor FeGa3
VL  - 107
IS  - 16
DO  - 10.1103/PhysRevB.107.165151
ER  - 
@article{
author = "Martin, Catalin and Martinez, V. A. and Opačić, Marko R. and Đurđić-Mijin, Sanja and Mitrić, Petar and Umićević, Ana and Poudel, A. and Sydoryk, Ihor and Ren, Weijun and Martin, Ruaridh M. and Tanner, David B. and Lazarević, Nenad and Petrović, Čedomir and Tanasković, Darko",
year = "2023",
abstract = "Intermetallic narrow-gap semiconductors have been intensively explored due to their large thermoelectric power at low temperatures and a possible role of strong electronic correlations in their unusual thermodynamic and transport properties. Here we study the optical spectra and vibrational properties of FeGa3 single crystal. The optical conductivity indicates that FeGa3 has a direct band gap of ≈0.7 eV, consistent with density functional theory (DFT) calculations. Most importantly, we find a substantial spectral weight also below 0.4 eV, which is the energy of the indirect (charge) gap found in resistivity measurements and ab initio calculations. We find that the spectral weight below the gap decreases with increasing temperature, which indicates that it originates from the impurity states and not from the electronic correlations. Interestingly, we did not find any signatures of the impurity states in vibrational spectra. The infrared and Raman vibrational lines are narrow and weakly temperature dependent. The vibrational frequencies are in excellent agreement with our DFT calculations, implying a modest role of electronic correlations. Narrow Mössbauer spectral lines also indicate high crystallinity of the sample. © 2023 American Physical Society.",
journal = "Physical Review B",
title = "Optical conductivity and vibrational spectra of the narrow-gap semiconductor FeGa3",
volume = "107",
number = "16",
doi = "10.1103/PhysRevB.107.165151"
}
Martin, C., Martinez, V. A., Opačić, M. R., Đurđić-Mijin, S., Mitrić, P., Umićević, A., Poudel, A., Sydoryk, I., Ren, W., Martin, R. M., Tanner, D. B., Lazarević, N., Petrović, Č.,& Tanasković, D.. (2023). Optical conductivity and vibrational spectra of the narrow-gap semiconductor FeGa3. in Physical Review B, 107(16).
https://doi.org/10.1103/PhysRevB.107.165151
Martin C, Martinez VA, Opačić MR, Đurđić-Mijin S, Mitrić P, Umićević A, Poudel A, Sydoryk I, Ren W, Martin RM, Tanner DB, Lazarević N, Petrović Č, Tanasković D. Optical conductivity and vibrational spectra of the narrow-gap semiconductor FeGa3. in Physical Review B. 2023;107(16).
doi:10.1103/PhysRevB.107.165151 .
Martin, Catalin, Martinez, V. A., Opačić, Marko R., Đurđić-Mijin, Sanja, Mitrić, Petar, Umićević, Ana, Poudel, A., Sydoryk, Ihor, Ren, Weijun, Martin, Ruaridh M., Tanner, David B., Lazarević, Nenad, Petrović, Čedomir, Tanasković, Darko, "Optical conductivity and vibrational spectra of the narrow-gap semiconductor FeGa3" in Physical Review B, 107, no. 16 (2023),
https://doi.org/10.1103/PhysRevB.107.165151 . .
2

Nonlinearity and lasing topological zero-mode in distorted photonic lattice

Nedić, Milica; Gligorić, Goran; Petrović, Jovana; Maluckov, Aleksandra

(2023)

TY  - JOUR
AU  - Nedić, Milica
AU  - Gligorić, Goran
AU  - Petrović, Jovana
AU  - Maluckov, Aleksandra
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10986
AB  - Recently we have witnessed experimental realization of a Majorana zero-mode bound at vortex distortion induced in bipartite hexagonal photonic lattices. Here, we address an open question of the impact of nonlinearity on the zero-mode dynamics by theoretically investigating the abilities of topologically protected zero-modes to guide, couple and lase light in the presence of nonlinear effects. Light-intensity related nonlinearity enters the scene through a local nonlinear lattice response and driving properties: saturable nonlinear gain and linear loss. We demonstrate an efficient steady zero-mode lasing regime by managing the lattice and driving parameters. Obtained results open up possibilities for design of new topological lasers in length-scalable photonic platforms, such as multicore optical fibers. © 2023 Elsevier B.V.
T2  - Physics Letters, Section A: General, Atomic and Solid State Physics
T1  - Nonlinearity and lasing topological zero-mode in distorted photonic lattice
VL  - 477
DO  - 10.1016/j.physleta.2023.128893
ER  - 
@article{
author = "Nedić, Milica and Gligorić, Goran and Petrović, Jovana and Maluckov, Aleksandra",
year = "2023",
abstract = "Recently we have witnessed experimental realization of a Majorana zero-mode bound at vortex distortion induced in bipartite hexagonal photonic lattices. Here, we address an open question of the impact of nonlinearity on the zero-mode dynamics by theoretically investigating the abilities of topologically protected zero-modes to guide, couple and lase light in the presence of nonlinear effects. Light-intensity related nonlinearity enters the scene through a local nonlinear lattice response and driving properties: saturable nonlinear gain and linear loss. We demonstrate an efficient steady zero-mode lasing regime by managing the lattice and driving parameters. Obtained results open up possibilities for design of new topological lasers in length-scalable photonic platforms, such as multicore optical fibers. © 2023 Elsevier B.V.",
journal = "Physics Letters, Section A: General, Atomic and Solid State Physics",
title = "Nonlinearity and lasing topological zero-mode in distorted photonic lattice",
volume = "477",
doi = "10.1016/j.physleta.2023.128893"
}
Nedić, M., Gligorić, G., Petrović, J.,& Maluckov, A.. (2023). Nonlinearity and lasing topological zero-mode in distorted photonic lattice. in Physics Letters, Section A: General, Atomic and Solid State Physics, 477.
https://doi.org/10.1016/j.physleta.2023.128893
Nedić M, Gligorić G, Petrović J, Maluckov A. Nonlinearity and lasing topological zero-mode in distorted photonic lattice. in Physics Letters, Section A: General, Atomic and Solid State Physics. 2023;477.
doi:10.1016/j.physleta.2023.128893 .
Nedić, Milica, Gligorić, Goran, Petrović, Jovana, Maluckov, Aleksandra, "Nonlinearity and lasing topological zero-mode in distorted photonic lattice" in Physics Letters, Section A: General, Atomic and Solid State Physics, 477 (2023),
https://doi.org/10.1016/j.physleta.2023.128893 . .

Structural, optical, and bioimaging characterization of carbon quantum dots solvothermally synthesized from o-phenylenediamine

Marković, Zoran M.; Budimir, Milica; Danko, Martin; Milivojević, Dušan; Kubat, Pavel; Zmejkoski, Danica; Pavlović, Vladimir B.; Mojsin, Marija; Stevanović, Milena J.; Todorović-Marković, Biljana

(2023)

TY  - JOUR
AU  - Marković, Zoran M.
AU  - Budimir, Milica
AU  - Danko, Martin
AU  - Milivojević, Dušan
AU  - Kubat, Pavel
AU  - Zmejkoski, Danica
AU  - Pavlović, Vladimir B.
AU  - Mojsin, Marija
AU  - Stevanović, Milena J.
AU  - Todorović-Marković, Biljana
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10632
AB  - Carbon quantum dots as a novel type of carbon nanomaterials have attracted the attention of many researchers because of their unique optical, antibacterial, and anticancer properties as well as their biocompatibility. In this study, for the first time, carbon quantum dots were prepared from o-phenylenediamine dissolved in toluene by a solvothermal route. Subsequently, the prepared carbon quantum dots were encapsulated into polyurethane films by a swelling–encapsulation–shrink method. Analyses of the results obtained by different characterization methods (AFM, TEM, EDS, FTIR, photoluminescence, and EPR) indicate the significant influence of the precursor on structural, chemical, and optical properties. Antibacterial and cytotoxicity tests showed that these dots did not have any antibacterial potential, because of the low extent of reactive oxygen species production, and showed low dark cytotoxicity. By investigating the cellular uptake, it was established that these dots penetrated the HeLa cells and could be used as probes for bioimaging.
T2  - Beilstein Journal of Nanotechnology
T1  - Structural, optical, and bioimaging characterization of carbon quantum dots solvothermally synthesized from o-phenylenediamine
VL  - 14
IS  - 1
SP  - 165
EP  - 174
DO  - 10.3762/bjnano.14.17
ER  - 
@article{
author = "Marković, Zoran M. and Budimir, Milica and Danko, Martin and Milivojević, Dušan and Kubat, Pavel and Zmejkoski, Danica and Pavlović, Vladimir B. and Mojsin, Marija and Stevanović, Milena J. and Todorović-Marković, Biljana",
year = "2023",
abstract = "Carbon quantum dots as a novel type of carbon nanomaterials have attracted the attention of many researchers because of their unique optical, antibacterial, and anticancer properties as well as their biocompatibility. In this study, for the first time, carbon quantum dots were prepared from o-phenylenediamine dissolved in toluene by a solvothermal route. Subsequently, the prepared carbon quantum dots were encapsulated into polyurethane films by a swelling–encapsulation–shrink method. Analyses of the results obtained by different characterization methods (AFM, TEM, EDS, FTIR, photoluminescence, and EPR) indicate the significant influence of the precursor on structural, chemical, and optical properties. Antibacterial and cytotoxicity tests showed that these dots did not have any antibacterial potential, because of the low extent of reactive oxygen species production, and showed low dark cytotoxicity. By investigating the cellular uptake, it was established that these dots penetrated the HeLa cells and could be used as probes for bioimaging.",
journal = "Beilstein Journal of Nanotechnology",
title = "Structural, optical, and bioimaging characterization of carbon quantum dots solvothermally synthesized from o-phenylenediamine",
volume = "14",
number = "1",
pages = "165-174",
doi = "10.3762/bjnano.14.17"
}
Marković, Z. M., Budimir, M., Danko, M., Milivojević, D., Kubat, P., Zmejkoski, D., Pavlović, V. B., Mojsin, M., Stevanović, M. J.,& Todorović-Marković, B.. (2023). Structural, optical, and bioimaging characterization of carbon quantum dots solvothermally synthesized from o-phenylenediamine. in Beilstein Journal of Nanotechnology, 14(1), 165-174.
https://doi.org/10.3762/bjnano.14.17
Marković ZM, Budimir M, Danko M, Milivojević D, Kubat P, Zmejkoski D, Pavlović VB, Mojsin M, Stevanović MJ, Todorović-Marković B. Structural, optical, and bioimaging characterization of carbon quantum dots solvothermally synthesized from o-phenylenediamine. in Beilstein Journal of Nanotechnology. 2023;14(1):165-174.
doi:10.3762/bjnano.14.17 .
Marković, Zoran M., Budimir, Milica, Danko, Martin, Milivojević, Dušan, Kubat, Pavel, Zmejkoski, Danica, Pavlović, Vladimir B., Mojsin, Marija, Stevanović, Milena J., Todorović-Marković, Biljana, "Structural, optical, and bioimaging characterization of carbon quantum dots solvothermally synthesized from o-phenylenediamine" in Beilstein Journal of Nanotechnology, 14, no. 1 (2023):165-174,
https://doi.org/10.3762/bjnano.14.17 . .
3
1

Risk Evaluation of Pollutants Emission from Coal and Coal Waste Combustion Plants and Environmental Impact of Fly Ash Landfilling

Buha-Marković, Jovana Z.; Marinković, Ana D.; Savić, Jasmina; Mladenović, Milica R.; Erić, Milić D.; Marković, Zoran J.; Ristić, Mirjana Đ.

(2023)

TY  - JOUR
AU  - Buha-Marković, Jovana Z.
AU  - Marinković, Ana D.
AU  - Savić, Jasmina
AU  - Mladenović, Milica R.
AU  - Erić, Milić D.
AU  - Marković, Zoran J.
AU  - Ristić, Mirjana Đ.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10932
AB  - Emission factors (EFs) of gaseous pollutants, particulate matter, certain harmful trace elements, and polycyclic aromatic hydrocarbons (PAHs) from three thermal power plants (TPPs) and semi-industrial fluidized bed boiler (FBB) were compared. EFs of particulate matter, trace elements (except Cd and Pb), benzo[a]pyrene, and benzo[b]fluoranthene exceed the upper limits specified in the EMEP inventory guidebook for all combustion facilities. The comparison of trace elements and PAHs content in fly ashes (FAs) from lignite and coal waste combustion in TPPs and FBB, respectively, as well as the potential environmental impact of FAs disposal, was performed by employing a set of ecological indicators such as crustal enrichment factor, risk assessment code, risk indices for trace elements, and benzo[a]pyrene equivalent concentration for PAHs. Sequential analysis shows that the trace elements portion is the lowest for water-soluble and exchangeable fractions. The highest enrichment levels in FAs are noticed for As and Hg. Based on toxic trace elements content, FAs from TPPs represent a very high ecological risk, whereas fly ash from FBB poses a moderate ecological risk but has the highest benzo[a]pyrene equivalent concentration, indicating its increased carcinogenic potential. Lead isotope ratios for Serbian coals and FAs can contribute to a lead pollution global database.
T2  - Toxics
T1  - Risk Evaluation of Pollutants Emission from Coal and Coal Waste Combustion Plants and Environmental Impact of Fly Ash Landfilling
VL  - 11
IS  - 4
SP  - 396
DO  - 10.3390/toxics11040396
ER  - 
@article{
author = "Buha-Marković, Jovana Z. and Marinković, Ana D. and Savić, Jasmina and Mladenović, Milica R. and Erić, Milić D. and Marković, Zoran J. and Ristić, Mirjana Đ.",
year = "2023",
abstract = "Emission factors (EFs) of gaseous pollutants, particulate matter, certain harmful trace elements, and polycyclic aromatic hydrocarbons (PAHs) from three thermal power plants (TPPs) and semi-industrial fluidized bed boiler (FBB) were compared. EFs of particulate matter, trace elements (except Cd and Pb), benzo[a]pyrene, and benzo[b]fluoranthene exceed the upper limits specified in the EMEP inventory guidebook for all combustion facilities. The comparison of trace elements and PAHs content in fly ashes (FAs) from lignite and coal waste combustion in TPPs and FBB, respectively, as well as the potential environmental impact of FAs disposal, was performed by employing a set of ecological indicators such as crustal enrichment factor, risk assessment code, risk indices for trace elements, and benzo[a]pyrene equivalent concentration for PAHs. Sequential analysis shows that the trace elements portion is the lowest for water-soluble and exchangeable fractions. The highest enrichment levels in FAs are noticed for As and Hg. Based on toxic trace elements content, FAs from TPPs represent a very high ecological risk, whereas fly ash from FBB poses a moderate ecological risk but has the highest benzo[a]pyrene equivalent concentration, indicating its increased carcinogenic potential. Lead isotope ratios for Serbian coals and FAs can contribute to a lead pollution global database.",
journal = "Toxics",
title = "Risk Evaluation of Pollutants Emission from Coal and Coal Waste Combustion Plants and Environmental Impact of Fly Ash Landfilling",
volume = "11",
number = "4",
pages = "396",
doi = "10.3390/toxics11040396"
}
Buha-Marković, J. Z., Marinković, A. D., Savić, J., Mladenović, M. R., Erić, M. D., Marković, Z. J.,& Ristić, M. Đ.. (2023). Risk Evaluation of Pollutants Emission from Coal and Coal Waste Combustion Plants and Environmental Impact of Fly Ash Landfilling. in Toxics, 11(4), 396.
https://doi.org/10.3390/toxics11040396
Buha-Marković JZ, Marinković AD, Savić J, Mladenović MR, Erić MD, Marković ZJ, Ristić MĐ. Risk Evaluation of Pollutants Emission from Coal and Coal Waste Combustion Plants and Environmental Impact of Fly Ash Landfilling. in Toxics. 2023;11(4):396.
doi:10.3390/toxics11040396 .
Buha-Marković, Jovana Z., Marinković, Ana D., Savić, Jasmina, Mladenović, Milica R., Erić, Milić D., Marković, Zoran J., Ristić, Mirjana Đ., "Risk Evaluation of Pollutants Emission from Coal and Coal Waste Combustion Plants and Environmental Impact of Fly Ash Landfilling" in Toxics, 11, no. 4 (2023):396,
https://doi.org/10.3390/toxics11040396 . .

Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers

Ahmetović, Sanita; Vasiljević, Zorka Ž.; Rajić, Vladimir; Bartolić, Dragana; Novaković, Mirjana M.; Tadić, Nenad B.; Cvjetićanin, Nikola; Nikolić, Maria Vesna

(2023)

TY  - JOUR
AU  - Ahmetović, Sanita
AU  - Vasiljević, Zorka Ž.
AU  - Rajić, Vladimir
AU  - Bartolić, Dragana
AU  - Novaković, Mirjana M.
AU  - Tadić, Nenad B.
AU  - Cvjetićanin, Nikola
AU  - Nikolić, Maria Vesna
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10448
AB  - Pure and samarium (Sm3+) - or zirconium (Zr4+)-doped TiO2 nanofibers were synthesized by electrospinning method followed by calcination at 500 °C for 1 h. As-spun fibers were smooth, straight and continuous, whilst EDS analysis confirmed the fiber composition and incorporation of dopants in the fibers. Doping with Sm3+ and Zr4+ greatly inhibited the phase transformation of anatase to rutile, by surrounding of Sm3+ ions through formation of Ti-O-Sm bonds and by replacement of Ti4+ ions with larger Zr4+ ions. This was confirmed by HRTEM and SAED analysis. The size of nanofibers was determined to be 133 nm, 175 nm and 155 nm for pure, (0.5%)Sm3+:TiO2 and (1%)Zr4+:TiO2, respectively. After calcination, TiO2 crystal lattice with interplanar spacing of 0.353 nm of (101) crystal plane was not significantly disturbed by Sm doping whilst crystal lattice spacing of 0.357 nm of (101) planes of anatase phase in case TiO2:1.0%Zr4+, significantly differs from the value of pure TiO2 (0.352 nm), thus implying that Zr was doped into substitutional sites of the TiO2 lattice. The indirect band gaps were calculated to be in the range 3.07–3.24 eV. TiO2:0.5%Sm3+ and TiO2:1.0%Zr4+ exhibited higher specific surface area, of 47.1 and 59.4 m2/g, respectively, than pure TiO2 fibers (19.7 m2/g). Effects of Sm3+ and Zr4+ dopant content on the photodegradation efficiency of methylene blue (MB) were studied. TiO2:0.5%Sm3+ and TiO2:1.0%Zr4+ nanofibers have shown the highest photocatalytic activity of 97% and 98% with constant rates 0.01768 min−1 and 0.01939 min−1, respectively, within180 min irradiation under visible light.
T2  - Journal of Alloys and Compounds
T1  - Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers
VL  - 930
SP  - 167423
DO  - 10.1016/j.jallcom.2022.167423
ER  - 
@article{
author = "Ahmetović, Sanita and Vasiljević, Zorka Ž. and Rajić, Vladimir and Bartolić, Dragana and Novaković, Mirjana M. and Tadić, Nenad B. and Cvjetićanin, Nikola and Nikolić, Maria Vesna",
year = "2023",
abstract = "Pure and samarium (Sm3+) - or zirconium (Zr4+)-doped TiO2 nanofibers were synthesized by electrospinning method followed by calcination at 500 °C for 1 h. As-spun fibers were smooth, straight and continuous, whilst EDS analysis confirmed the fiber composition and incorporation of dopants in the fibers. Doping with Sm3+ and Zr4+ greatly inhibited the phase transformation of anatase to rutile, by surrounding of Sm3+ ions through formation of Ti-O-Sm bonds and by replacement of Ti4+ ions with larger Zr4+ ions. This was confirmed by HRTEM and SAED analysis. The size of nanofibers was determined to be 133 nm, 175 nm and 155 nm for pure, (0.5%)Sm3+:TiO2 and (1%)Zr4+:TiO2, respectively. After calcination, TiO2 crystal lattice with interplanar spacing of 0.353 nm of (101) crystal plane was not significantly disturbed by Sm doping whilst crystal lattice spacing of 0.357 nm of (101) planes of anatase phase in case TiO2:1.0%Zr4+, significantly differs from the value of pure TiO2 (0.352 nm), thus implying that Zr was doped into substitutional sites of the TiO2 lattice. The indirect band gaps were calculated to be in the range 3.07–3.24 eV. TiO2:0.5%Sm3+ and TiO2:1.0%Zr4+ exhibited higher specific surface area, of 47.1 and 59.4 m2/g, respectively, than pure TiO2 fibers (19.7 m2/g). Effects of Sm3+ and Zr4+ dopant content on the photodegradation efficiency of methylene blue (MB) were studied. TiO2:0.5%Sm3+ and TiO2:1.0%Zr4+ nanofibers have shown the highest photocatalytic activity of 97% and 98% with constant rates 0.01768 min−1 and 0.01939 min−1, respectively, within180 min irradiation under visible light.",
journal = "Journal of Alloys and Compounds",
title = "Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers",
volume = "930",
pages = "167423",
doi = "10.1016/j.jallcom.2022.167423"
}
Ahmetović, S., Vasiljević, Z. Ž., Rajić, V., Bartolić, D., Novaković, M. M., Tadić, N. B., Cvjetićanin, N.,& Nikolić, M. V.. (2023). Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers. in Journal of Alloys and Compounds, 930, 167423.
https://doi.org/10.1016/j.jallcom.2022.167423
Ahmetović S, Vasiljević ZŽ, Rajić V, Bartolić D, Novaković MM, Tadić NB, Cvjetićanin N, Nikolić MV. Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers. in Journal of Alloys and Compounds. 2023;930:167423.
doi:10.1016/j.jallcom.2022.167423 .
Ahmetović, Sanita, Vasiljević, Zorka Ž., Rajić, Vladimir, Bartolić, Dragana, Novaković, Mirjana M., Tadić, Nenad B., Cvjetićanin, Nikola, Nikolić, Maria Vesna, "Examination of the doping effects of samarium (Sm3+) and zirconium (Zr4+) on the photocatalytic activity of TiO2 nanofibers" in Journal of Alloys and Compounds, 930 (2023):167423,
https://doi.org/10.1016/j.jallcom.2022.167423 . .
6
1

Accuracy of the numerical inversion of irrational and transcendental Laplace transform using Haar wavelet operational matrix

Stanimirović, Zdravko; Stanimirović, Ivanka; Galović, Slobodanka; Đorđević, Katarina Lj.; Suljovrujić, Edin

(Istočno Sarajevo : Elektrotehnički fakultet, 2023)

TY  - CONF
AU  - Stanimirović, Zdravko
AU  - Stanimirović, Ivanka
AU  - Galović, Slobodanka
AU  - Đorđević, Katarina Lj.
AU  - Suljovrujić, Edin
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10967
AB  - Irrational and transcendental functions can often be seen in signal processing or physical phenomena analysis as consequences of fractional-order and distributed-order models that result in fractional or partial differential equations. In cases when finding solution in analytical form tends to be difficult or impossible, numerical calculations such as Haar wavelet operational matrix method can be used. In order to evaluate accuracy of the numerical inversion of irrational and transcendental Laplace transform using Haar wavelet operational matrix, a number inverse Laplace transforms are numerically solved and compared with the analytical solutions and solutions provided by Invlap and NILT algorithms.
PB  - Istočno Sarajevo : Elektrotehnički fakultet
C3  - InfoTeh-Jahorina : 22. međunarodni simpozijum INFOTEH-JAHORINA 2023 : zbornik radova; Mart 15-17; Jahorina
T1  - Accuracy of the numerical inversion of irrational and transcendental Laplace transform using Haar wavelet operational matrix
SP  - 278
EP  - 284
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10967
ER  - 
@conference{
author = "Stanimirović, Zdravko and Stanimirović, Ivanka and Galović, Slobodanka and Đorđević, Katarina Lj. and Suljovrujić, Edin",
year = "2023",
abstract = "Irrational and transcendental functions can often be seen in signal processing or physical phenomena analysis as consequences of fractional-order and distributed-order models that result in fractional or partial differential equations. In cases when finding solution in analytical form tends to be difficult or impossible, numerical calculations such as Haar wavelet operational matrix method can be used. In order to evaluate accuracy of the numerical inversion of irrational and transcendental Laplace transform using Haar wavelet operational matrix, a number inverse Laplace transforms are numerically solved and compared with the analytical solutions and solutions provided by Invlap and NILT algorithms.",
publisher = "Istočno Sarajevo : Elektrotehnički fakultet",
journal = "InfoTeh-Jahorina : 22. međunarodni simpozijum INFOTEH-JAHORINA 2023 : zbornik radova; Mart 15-17; Jahorina",
title = "Accuracy of the numerical inversion of irrational and transcendental Laplace transform using Haar wavelet operational matrix",
pages = "278-284",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10967"
}
Stanimirović, Z., Stanimirović, I., Galović, S., Đorđević, K. Lj.,& Suljovrujić, E.. (2023). Accuracy of the numerical inversion of irrational and transcendental Laplace transform using Haar wavelet operational matrix. in InfoTeh-Jahorina : 22. međunarodni simpozijum INFOTEH-JAHORINA 2023 : zbornik radova; Mart 15-17; Jahorina
Istočno Sarajevo : Elektrotehnički fakultet., 278-284.
https://hdl.handle.net/21.15107/rcub_vinar_10967
Stanimirović Z, Stanimirović I, Galović S, Đorđević KL, Suljovrujić E. Accuracy of the numerical inversion of irrational and transcendental Laplace transform using Haar wavelet operational matrix. in InfoTeh-Jahorina : 22. međunarodni simpozijum INFOTEH-JAHORINA 2023 : zbornik radova; Mart 15-17; Jahorina. 2023;:278-284.
https://hdl.handle.net/21.15107/rcub_vinar_10967 .
Stanimirović, Zdravko, Stanimirović, Ivanka, Galović, Slobodanka, Đorđević, Katarina Lj., Suljovrujić, Edin, "Accuracy of the numerical inversion of irrational and transcendental Laplace transform using Haar wavelet operational matrix" in InfoTeh-Jahorina : 22. međunarodni simpozijum INFOTEH-JAHORINA 2023 : zbornik radova; Mart 15-17; Jahorina (2023):278-284,
https://hdl.handle.net/21.15107/rcub_vinar_10967 .

Thermal and mechanical piston influence on photoacoustic signal

Dragaš, Milica A.; Miletić, Vesna; Galović, Slobodanka; Nešić, Mioljub; Đorđević, Katarina Lj.

(Istočno Sarajevo : Elektrotehnički fakultet, 2023)

TY  - CONF
AU  - Dragaš, Milica A.
AU  - Miletić, Vesna
AU  - Galović, Slobodanka
AU  - Nešić, Mioljub
AU  - Đorđević, Katarina Lj.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10966
AB  - In this work, the influence of the thermal and mechanical piston effects over the frequency at which the amplitudes of the components of the photoacoustic signal resulting from these two effects are equalized. The analysis was done in the measuring range 10 to 20kHz. An aluminum sample illuminated with modulated light, whose thickness varies from 10 to 1000 microns, was considered. It is important for development reliable inverse procedures and determination various properties of samples from experimental measurement.
PB  - Istočno Sarajevo : Elektrotehnički fakultet
C3  - InfoTeh-Jahorina : 22. međunarodni simpozijum INFOTEH-JAHORINA 2023 : zbornik radova; Mart 15-17; Jahorina
T1  - Thermal and mechanical piston influence on photoacoustic signal
SP  - 236
EP  - 240
UR  - https://hdl.handle.net/21.15107/rcub_vinar_10966
ER  - 
@conference{
author = "Dragaš, Milica A. and Miletić, Vesna and Galović, Slobodanka and Nešić, Mioljub and Đorđević, Katarina Lj.",
year = "2023",
abstract = "In this work, the influence of the thermal and mechanical piston effects over the frequency at which the amplitudes of the components of the photoacoustic signal resulting from these two effects are equalized. The analysis was done in the measuring range 10 to 20kHz. An aluminum sample illuminated with modulated light, whose thickness varies from 10 to 1000 microns, was considered. It is important for development reliable inverse procedures and determination various properties of samples from experimental measurement.",
publisher = "Istočno Sarajevo : Elektrotehnički fakultet",
journal = "InfoTeh-Jahorina : 22. međunarodni simpozijum INFOTEH-JAHORINA 2023 : zbornik radova; Mart 15-17; Jahorina",
title = "Thermal and mechanical piston influence on photoacoustic signal",
pages = "236-240",
url = "https://hdl.handle.net/21.15107/rcub_vinar_10966"
}
Dragaš, M. A., Miletić, V., Galović, S., Nešić, M.,& Đorđević, K. Lj.. (2023). Thermal and mechanical piston influence on photoacoustic signal. in InfoTeh-Jahorina : 22. međunarodni simpozijum INFOTEH-JAHORINA 2023 : zbornik radova; Mart 15-17; Jahorina
Istočno Sarajevo : Elektrotehnički fakultet., 236-240.
https://hdl.handle.net/21.15107/rcub_vinar_10966
Dragaš MA, Miletić V, Galović S, Nešić M, Đorđević KL. Thermal and mechanical piston influence on photoacoustic signal. in InfoTeh-Jahorina : 22. međunarodni simpozijum INFOTEH-JAHORINA 2023 : zbornik radova; Mart 15-17; Jahorina. 2023;:236-240.
https://hdl.handle.net/21.15107/rcub_vinar_10966 .
Dragaš, Milica A., Miletić, Vesna, Galović, Slobodanka, Nešić, Mioljub, Đorđević, Katarina Lj., "Thermal and mechanical piston influence on photoacoustic signal" in InfoTeh-Jahorina : 22. međunarodni simpozijum INFOTEH-JAHORINA 2023 : zbornik radova; Mart 15-17; Jahorina (2023):236-240,
https://hdl.handle.net/21.15107/rcub_vinar_10966 .

Mn5+ Lifetime-Based Thermal Imaging in the Optical Transparency Windows Through Skin-Mimicking Tissue Phantom

Piotrowski, Wojciech M.; Marin, Riccardo; Szymczak, Maja; Martín Rodríguez, Emma; Ortgies, Dirk H.; Rodríguez-Sevilla, Paloma; Dramićanin, Miroslav; Jaque, Daniel; Marciniak, Lukasz

(2023)

TY  - JOUR
AU  - Piotrowski, Wojciech M.
AU  - Marin, Riccardo
AU  - Szymczak, Maja
AU  - Martín Rodríguez, Emma
AU  - Ortgies, Dirk H.
AU  - Rodríguez-Sevilla, Paloma
AU  - Dramićanin, Miroslav
AU  - Jaque, Daniel
AU  - Marciniak, Lukasz
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10546
AB  - Lifetime-based luminescence thermometry has been shown to enable accurate deep-tissue monitoring of temperature changes – even at the in vivo level – in a minimally invasive way. However, major limiting factors to the performance of this approach are short lifetimes and poor brightness. These are characteristics, respectively, of semiconductor nanocrystals and lanthanide-doped nanoparticles, of which most luminescent nanothermometers are made. To address these limitations, the composition of luminescent nanothermometers co-doped with transition metal (Mn5+) and Er3+ ions are designed and optimized. The salient features of these nanothermometers are strong, near-infrared emission and long, temperature-dependent photoluminescence lifetime. The potential of these luminescent nanophosphors for thermal sensing is then showcased by monitoring a thermal gradient using a one-of-a-kind piece of equipment designed for lifetime-based luminescence thermometry measurements. The combination of the newly developed nanothermometers and the custom-made instrument allows for obtaining 2D thermal maps both in the absence and presence of tissue phantoms mimicking the optical properties of the skin. The results presented in this study thus provide credible foundations for the deployment of lifetime-based thermometry for accurate deep-tissue thermal mapping at the preclinical level.
T2  - Advanced Optical Materials
T1  - Mn5+ Lifetime-Based Thermal Imaging in the Optical Transparency Windows Through Skin-Mimicking Tissue Phantom
VL  - 11
IS  - 3
SP  - 2202366
DO  - 10.1002/adom.202202366
ER  - 
@article{
author = "Piotrowski, Wojciech M. and Marin, Riccardo and Szymczak, Maja and Martín Rodríguez, Emma and Ortgies, Dirk H. and Rodríguez-Sevilla, Paloma and Dramićanin, Miroslav and Jaque, Daniel and Marciniak, Lukasz",
year = "2023",
abstract = "Lifetime-based luminescence thermometry has been shown to enable accurate deep-tissue monitoring of temperature changes – even at the in vivo level – in a minimally invasive way. However, major limiting factors to the performance of this approach are short lifetimes and poor brightness. These are characteristics, respectively, of semiconductor nanocrystals and lanthanide-doped nanoparticles, of which most luminescent nanothermometers are made. To address these limitations, the composition of luminescent nanothermometers co-doped with transition metal (Mn5+) and Er3+ ions are designed and optimized. The salient features of these nanothermometers are strong, near-infrared emission and long, temperature-dependent photoluminescence lifetime. The potential of these luminescent nanophosphors for thermal sensing is then showcased by monitoring a thermal gradient using a one-of-a-kind piece of equipment designed for lifetime-based luminescence thermometry measurements. The combination of the newly developed nanothermometers and the custom-made instrument allows for obtaining 2D thermal maps both in the absence and presence of tissue phantoms mimicking the optical properties of the skin. The results presented in this study thus provide credible foundations for the deployment of lifetime-based thermometry for accurate deep-tissue thermal mapping at the preclinical level.",
journal = "Advanced Optical Materials",
title = "Mn5+ Lifetime-Based Thermal Imaging in the Optical Transparency Windows Through Skin-Mimicking Tissue Phantom",
volume = "11",
number = "3",
pages = "2202366",
doi = "10.1002/adom.202202366"
}
Piotrowski, W. M., Marin, R., Szymczak, M., Martín Rodríguez, E., Ortgies, D. H., Rodríguez-Sevilla, P., Dramićanin, M., Jaque, D.,& Marciniak, L.. (2023). Mn5+ Lifetime-Based Thermal Imaging in the Optical Transparency Windows Through Skin-Mimicking Tissue Phantom. in Advanced Optical Materials, 11(3), 2202366.
https://doi.org/10.1002/adom.202202366
Piotrowski WM, Marin R, Szymczak M, Martín Rodríguez E, Ortgies DH, Rodríguez-Sevilla P, Dramićanin M, Jaque D, Marciniak L. Mn5+ Lifetime-Based Thermal Imaging in the Optical Transparency Windows Through Skin-Mimicking Tissue Phantom. in Advanced Optical Materials. 2023;11(3):2202366.
doi:10.1002/adom.202202366 .
Piotrowski, Wojciech M., Marin, Riccardo, Szymczak, Maja, Martín Rodríguez, Emma, Ortgies, Dirk H., Rodríguez-Sevilla, Paloma, Dramićanin, Miroslav, Jaque, Daniel, Marciniak, Lukasz, "Mn5+ Lifetime-Based Thermal Imaging in the Optical Transparency Windows Through Skin-Mimicking Tissue Phantom" in Advanced Optical Materials, 11, no. 3 (2023):2202366,
https://doi.org/10.1002/adom.202202366 . .
2
1

Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations

Đačanin Far, Ljubica; Ćirić, Aleksandar; Sekulić, Milica; Periša, Jovana; Ristić, Zoran; Antić, Željka; Dramićanin, Miroslav

(2023)

TY  - JOUR
AU  - Đačanin Far, Ljubica
AU  - Ćirić, Aleksandar
AU  - Sekulić, Milica
AU  - Periša, Jovana
AU  - Ristić, Zoran
AU  - Antić, Željka
AU  - Dramićanin, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10551
AB  - YNbO4:xEu3+ powders (0.1, 0.25, 0.5, 0.75, 1, 3, 5, 7.5, 10, 15, 20 mol %) were synthesized by a solid-state reaction, after homogenization in a vibrational mill. All the samples crystallize in a monoclinic Fergusonite-beta-(Y) structure (C2/c space group), with 45–65 nm crystallite sizes and show a strong orange/red luminescence with 5D0 excited state lifetimes of around 0.6 ms. Photoluminescence emission spectra showed no concentration quenching within the examined concentration range. Judd–Ofelt intensity parameters show a slight increase with rising concentration, up to Ω2 = 8.13∙10−20 cm2, Ω4 = 2.67∙10−20 cm2, and Ω6 is concentration invariant with the 0.35∙10−20 cm2 value. Emission lifetimes of the 5D0 state are almost constant with ∼0.6 ms, and a slight decrease is observed with the highest concentrations. The intrinsic quantum yield of all the samples is about 0.5.
T2  - Optik
T1  - Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations
VL  - 272
SP  - 170398
DO  - 10.1016/j.ijleo.2022.170398
ER  - 
@article{
author = "Đačanin Far, Ljubica and Ćirić, Aleksandar and Sekulić, Milica and Periša, Jovana and Ristić, Zoran and Antić, Željka and Dramićanin, Miroslav",
year = "2023",
abstract = "YNbO4:xEu3+ powders (0.1, 0.25, 0.5, 0.75, 1, 3, 5, 7.5, 10, 15, 20 mol %) were synthesized by a solid-state reaction, after homogenization in a vibrational mill. All the samples crystallize in a monoclinic Fergusonite-beta-(Y) structure (C2/c space group), with 45–65 nm crystallite sizes and show a strong orange/red luminescence with 5D0 excited state lifetimes of around 0.6 ms. Photoluminescence emission spectra showed no concentration quenching within the examined concentration range. Judd–Ofelt intensity parameters show a slight increase with rising concentration, up to Ω2 = 8.13∙10−20 cm2, Ω4 = 2.67∙10−20 cm2, and Ω6 is concentration invariant with the 0.35∙10−20 cm2 value. Emission lifetimes of the 5D0 state are almost constant with ∼0.6 ms, and a slight decrease is observed with the highest concentrations. The intrinsic quantum yield of all the samples is about 0.5.",
journal = "Optik",
title = "Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations",
volume = "272",
pages = "170398",
doi = "10.1016/j.ijleo.2022.170398"
}
Đačanin Far, L., Ćirić, A., Sekulić, M., Periša, J., Ristić, Z., Antić, Ž.,& Dramićanin, M.. (2023). Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations. in Optik, 272, 170398.
https://doi.org/10.1016/j.ijleo.2022.170398
Đačanin Far L, Ćirić A, Sekulić M, Periša J, Ristić Z, Antić Ž, Dramićanin M. Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations. in Optik. 2023;272:170398.
doi:10.1016/j.ijleo.2022.170398 .
Đačanin Far, Ljubica, Ćirić, Aleksandar, Sekulić, Milica, Periša, Jovana, Ristić, Zoran, Antić, Željka, Dramićanin, Miroslav, "Judd-Ofelt description of radiative properties of YNbO4 activated with different Eu3+ concentrations" in Optik, 272 (2023):170398,
https://doi.org/10.1016/j.ijleo.2022.170398 . .

Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy

Racu, Andrei V.; Ristić, Zoran; Ćirić, Aleksandar; Ðorđević, Vesna; Buse, Gabriel; Poienar, Maria; Gutmann, Michael J.; Ivashko, Oleh; Stef, Marius; Vizman, Daniel; Dramićanin, Miroslav; Piasecki, Michal; Brik, Mikhail G.

(2023)

TY  - JOUR
AU  - Racu, Andrei V.
AU  - Ristić, Zoran
AU  - Ćirić, Aleksandar
AU  - Ðorđević, Vesna
AU  - Buse, Gabriel
AU  - Poienar, Maria
AU  - Gutmann, Michael J.
AU  - Ivashko, Oleh
AU  - Stef, Marius
AU  - Vizman, Daniel
AU  - Dramićanin, Miroslav
AU  - Piasecki, Michal
AU  - Brik, Mikhail G.
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10561
AB  - The understanding of complex relationships between luminescent properties, local symmetry of an emitting center, and the host crystal structure provides a better insight into optical properties of materials. In this work, the alkaline earths CaF2 and BaF2 fluoride crystals doped with 0.1 mol% ErF3 were investigated. The crystals structure has been studied using a synchrotron and laboratory X-ray diffraction. The C3v and C4v sites symmetry were determined using erbium probed high resolution emission spectroscopy (HRPL) at low temperature (LT) of 10 K. The considerable difference in room temperature (RT) optical properties for CaF2 compared to BaF2 crystals was observed. Such difference in absorption intensity of 4.7 times of erbium 4G11/2 manifold in UV, and 7.5 times in green emission from 4S3/2 manifold, could be due to the distinction in the host crystals cationic radius (ΔrCa,Ba) and the dopant-host ionic radius (ΔrCa-Er, ΔrBa-Er). Those Δr differences influence the structure and lead to the following symmetry formation: In CaF2, the C4v and C3v isolated centers were identified, with the determined Er3+- F−i bond lengths of 2.734 Å and 4.735 Å respectively; In BaF2, only C3v isolated centers were identified with the determined Er3+- F−i bond lengths of 5.380 Å. The present work is the first study that takes into account correlations of optical properties, the local symmetry and the structure in mentioned fluorides crystals, and it could be a step forward in the lanthanide doped optical materials systematics.
T2  - Optical Materials
T1  - Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy
VL  - 136
SP  - 113337
DO  - 10.1016/j.optmat.2022.113337
ER  - 
@article{
author = "Racu, Andrei V. and Ristić, Zoran and Ćirić, Aleksandar and Ðorđević, Vesna and Buse, Gabriel and Poienar, Maria and Gutmann, Michael J. and Ivashko, Oleh and Stef, Marius and Vizman, Daniel and Dramićanin, Miroslav and Piasecki, Michal and Brik, Mikhail G.",
year = "2023",
abstract = "The understanding of complex relationships between luminescent properties, local symmetry of an emitting center, and the host crystal structure provides a better insight into optical properties of materials. In this work, the alkaline earths CaF2 and BaF2 fluoride crystals doped with 0.1 mol% ErF3 were investigated. The crystals structure has been studied using a synchrotron and laboratory X-ray diffraction. The C3v and C4v sites symmetry were determined using erbium probed high resolution emission spectroscopy (HRPL) at low temperature (LT) of 10 K. The considerable difference in room temperature (RT) optical properties for CaF2 compared to BaF2 crystals was observed. Such difference in absorption intensity of 4.7 times of erbium 4G11/2 manifold in UV, and 7.5 times in green emission from 4S3/2 manifold, could be due to the distinction in the host crystals cationic radius (ΔrCa,Ba) and the dopant-host ionic radius (ΔrCa-Er, ΔrBa-Er). Those Δr differences influence the structure and lead to the following symmetry formation: In CaF2, the C4v and C3v isolated centers were identified, with the determined Er3+- F−i bond lengths of 2.734 Å and 4.735 Å respectively; In BaF2, only C3v isolated centers were identified with the determined Er3+- F−i bond lengths of 5.380 Å. The present work is the first study that takes into account correlations of optical properties, the local symmetry and the structure in mentioned fluorides crystals, and it could be a step forward in the lanthanide doped optical materials systematics.",
journal = "Optical Materials",
title = "Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy",
volume = "136",
pages = "113337",
doi = "10.1016/j.optmat.2022.113337"
}
Racu, A. V., Ristić, Z., Ćirić, A., Ðorđević, V., Buse, G., Poienar, M., Gutmann, M. J., Ivashko, O., Stef, M., Vizman, D., Dramićanin, M., Piasecki, M.,& Brik, M. G.. (2023). Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy. in Optical Materials, 136, 113337.
https://doi.org/10.1016/j.optmat.2022.113337
Racu AV, Ristić Z, Ćirić A, Ðorđević V, Buse G, Poienar M, Gutmann MJ, Ivashko O, Stef M, Vizman D, Dramićanin M, Piasecki M, Brik MG. Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy. in Optical Materials. 2023;136:113337.
doi:10.1016/j.optmat.2022.113337 .
Racu, Andrei V., Ristić, Zoran, Ćirić, Aleksandar, Ðorđević, Vesna, Buse, Gabriel, Poienar, Maria, Gutmann, Michael J., Ivashko, Oleh, Stef, Marius, Vizman, Daniel, Dramićanin, Miroslav, Piasecki, Michal, Brik, Mikhail G., "Analysis of site symmetries of Er3+ doped CaF2 and BaF2 crystals by high resolution photoluminescence spectroscopy" in Optical Materials, 136 (2023):113337,
https://doi.org/10.1016/j.optmat.2022.113337 . .

Hydrothermal Synthesis and Properties of Yb3+/Tm3+ Doped Sr2LaF7 Upconversion Nanoparticles

Milićević, Bojana R.; Periša, Jovana; Ristić, Zoran; Milenković, Katarina; Antić, Željka; Smits, Krisjanis; Kemere, Meldra; Vitols, Kaspars; Sarakovskis, Anatolijs; Dramićanin, Miroslav

(2023)

TY  - JOUR
AU  - Milićević, Bojana R.
AU  - Periša, Jovana
AU  - Ristić, Zoran
AU  - Milenković, Katarina
AU  - Antić, Željka
AU  - Smits, Krisjanis
AU  - Kemere, Meldra
AU  - Vitols, Kaspars
AU  - Sarakovskis, Anatolijs
AU  - Dramićanin, Miroslav
PY  - 2023
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10590
AB  - We report the procedure for hydrothermal synthesis of ultrasmall Yb3+/Tm3+ co-doped Sr2LaF7 (SLF) upconversion phosphors. These phosphors were synthesized by varying the concentrations of Yb3+ (x = 10, 15, 20, and 25 mol%) and Tm3+ (y = 0.75, 1, 2, and 3 mol%) with the aim to analyze their emissions in the near IR spectral range. According to the detailed structural analysis, Yb3+ and Tm3+ occupy the La3+ sites in the SLF host. The addition of Yb3+/Tm3+ ions has a huge impact on the lattice constant, particle size, and PL emission properties of the synthesized SLF nanophosphor. The results show that the optimal dopant concentrations for upconversion luminescence of Yb3+/Tm3+ co-doped SLF are 20 mol% Yb3+ and 1 mol% Tm3+ with EDTA as the chelating agent. Under 980 nm light excitation, a strong upconversion emission of Tm3+ ions around 800 nm was achieved. In addition, the experimental photoluminescence lifetime of Tm3+ emission in the SLF host is reported. This study discovered that efficient near IR emission from ultrasmall Yb3+/Tm3+ co-doped SLF phosphors may have potential applications in the fields of fluorescent labels in bioimaging and security applications.
T2  - Nanomaterials
T1  - Hydrothermal Synthesis and Properties of Yb3+/Tm3+ Doped Sr2LaF7 Upconversion Nanoparticles
VL  - 13
IS  - 1
SP  - 30
DO  - 10.3390/nano13010030
ER  - 
@article{
author = "Milićević, Bojana R. and Periša, Jovana and Ristić, Zoran and Milenković, Katarina and Antić, Željka and Smits, Krisjanis and Kemere, Meldra and Vitols, Kaspars and Sarakovskis, Anatolijs and Dramićanin, Miroslav",
year = "2023",
abstract = "We report the procedure for hydrothermal synthesis of ultrasmall Yb3+/Tm3+ co-doped Sr2LaF7 (SLF) upconversion phosphors. These phosphors were synthesized by varying the concentrations of Yb3+ (x = 10, 15, 20, and 25 mol%) and Tm3+ (y = 0.75, 1, 2, and 3 mol%) with the aim to analyze their emissions in the near IR spectral range. According to the detailed structural analysis, Yb3+ and Tm3+ occupy the La3+ sites in the SLF host. The addition of Yb3+/Tm3+ ions has a huge impact on the lattice constant, particle size, and PL emission properties of the synthesized SLF nanophosphor. The results show that the optimal dopant concentrations for upconversion luminescence of Yb3+/Tm3+ co-doped SLF are 20 mol% Yb3+ and 1 mol% Tm3+ with EDTA as the chelating agent. Under 980 nm light excitation, a strong upconversion emission of Tm3+ ions around 800 nm was achieved. In addition, the experimental photoluminescence lifetime of Tm3+ emission in the SLF host is reported. This study discovered that efficient near IR emission from ultrasmall Yb3+/Tm3+ co-doped SLF phosphors may have potential applications in the fields of fluorescent labels in bioimaging and security applications.",
journal = "Nanomaterials",
title = "Hydrothermal Synthesis and Properties of Yb3+/Tm3+ Doped Sr2LaF7 Upconversion Nanoparticles",
volume = "13",
number = "1",
pages = "30",
doi = "10.3390/nano13010030"
}
Milićević, B. R., Periša, J., Ristić, Z., Milenković, K., Antić, Ž., Smits, K., Kemere, M., Vitols, K., Sarakovskis, A.,& Dramićanin, M.. (2023). Hydrothermal Synthesis and Properties of Yb3+/Tm3+ Doped Sr2LaF7 Upconversion Nanoparticles. in Nanomaterials, 13(1), 30.
https://doi.org/10.3390/nano13010030
Milićević BR, Periša J, Ristić Z, Milenković K, Antić Ž, Smits K, Kemere M, Vitols K, Sarakovskis A, Dramićanin M. Hydrothermal Synthesis and Properties of Yb3+/Tm3+ Doped Sr2LaF7 Upconversion Nanoparticles. in Nanomaterials. 2023;13(1):30.
doi:10.3390/nano13010030 .
Milićević, Bojana R., Periša, Jovana, Ristić, Zoran, Milenković, Katarina, Antić, Željka, Smits, Krisjanis, Kemere, Meldra, Vitols, Kaspars, Sarakovskis, Anatolijs, Dramićanin, Miroslav, "Hydrothermal Synthesis and Properties of Yb3+/Tm3+ Doped Sr2LaF7 Upconversion Nanoparticles" in Nanomaterials, 13, no. 1 (2023):30,
https://doi.org/10.3390/nano13010030 . .