Serbian Academy of Sciences and Arts [F-7/II]

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Serbian Academy of Sciences and Arts [F-7/II]

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Publications

Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA

Obradovic, Nina; Dordevic, Natasa; Filipovic, Suzana; Markovic, Smilja; Kosanovic, Darko; Mitrić, Miodrag; Pavlović, Vladimir B.

(2016)

TY  - JOUR
AU  - Obradovic, Nina
AU  - Dordevic, Natasa
AU  - Filipovic, Suzana
AU  - Markovic, Smilja
AU  - Kosanovic, Darko
AU  - Mitrić, Miodrag
AU  - Pavlović, Vladimir B.
PY  - 2016
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/999
AB  - Since cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2) (MAS), is a very useful high-temperature ceramic material, it is important to decrease its sintering temperature. In order to accelerate the process of sintering, 5.00 mass% MoO3 was added to the starting mixtures. The mechanical activation of the starting mixtures was performed in a high-energy ball mill in time intervals from 0 to 160 min. After the activation, starting mixtures were sintered at 1300 A degrees C for 2 h. In order to determine the impact of mechanical activation on particle size distribution and powders morphology, the mechanically treated powders were characterized by a laser light-scattering particle size analyzer and scanning electron microscopy. The phase composition of the starting mixtures and sintered samples was analyzed by the X-ray diffraction method. In order to determine temperature intervals of chemical reactions and phase transitions, differential thermal analyses (DTA) and thermo-gravimetric analysis were used. Kissingers equation was employed to calculate apparent activation energies of various processes that occur within the system during heating. Based on the obtained DTA results, it was established that mechanical activation along with MoO3 additive has influence on sintering temperature which was decreased for more than 100 A degrees C, comparing to the literature data.
T2  - Journal of Thermal Analysis and Calorimetry
T1  - Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA
VL  - 124
IS  - 2
SP  - 667
EP  - 673
DO  - 10.1007/s10973-015-5132-9
ER  - 
@article{
author = "Obradovic, Nina and Dordevic, Natasa and Filipovic, Suzana and Markovic, Smilja and Kosanovic, Darko and Mitrić, Miodrag and Pavlović, Vladimir B.",
year = "2016",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/999",
abstract = "Since cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2) (MAS), is a very useful high-temperature ceramic material, it is important to decrease its sintering temperature. In order to accelerate the process of sintering, 5.00 mass% MoO3 was added to the starting mixtures. The mechanical activation of the starting mixtures was performed in a high-energy ball mill in time intervals from 0 to 160 min. After the activation, starting mixtures were sintered at 1300 A degrees C for 2 h. In order to determine the impact of mechanical activation on particle size distribution and powders morphology, the mechanically treated powders were characterized by a laser light-scattering particle size analyzer and scanning electron microscopy. The phase composition of the starting mixtures and sintered samples was analyzed by the X-ray diffraction method. In order to determine temperature intervals of chemical reactions and phase transitions, differential thermal analyses (DTA) and thermo-gravimetric analysis were used. Kissingers equation was employed to calculate apparent activation energies of various processes that occur within the system during heating. Based on the obtained DTA results, it was established that mechanical activation along with MoO3 additive has influence on sintering temperature which was decreased for more than 100 A degrees C, comparing to the literature data.",
journal = "Journal of Thermal Analysis and Calorimetry",
title = "Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA",
volume = "124",
number = "2",
pages = "667-673",
doi = "10.1007/s10973-015-5132-9"
}
Obradovic, N., Dordevic, N., Filipovic, S., Markovic, S., Kosanovic, D., Mitrić, M.,& Pavlović, V. B. (2016). Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA.
Journal of Thermal Analysis and Calorimetry, 124(2), 667-673.
https://doi.org/10.1007/s10973-015-5132-9
Obradovic N, Dordevic N, Filipovic S, Markovic S, Kosanovic D, Mitrić M, Pavlović VB. Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA. Journal of Thermal Analysis and Calorimetry. 2016;124(2):667-673
Obradovic Nina, Dordevic Natasa, Filipovic Suzana, Markovic Smilja, Kosanovic Darko, Mitrić Miodrag, Pavlović Vladimir B., "Reaction kinetics of mechanically activated cordierite-based ceramics studied via DTA" Journal of Thermal Analysis and Calorimetry, 124, no. 2 (2016):667-673,
https://doi.org/10.1007/s10973-015-5132-9 .
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Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive

Obradovic, N.; Dordevic, N.; Filipovic, S.; Nikolic, N.; Kosanovic, D.; Mitrić, Miodrag; Markovic, S.; Pavlović, Vladimir B.

(2012)

TY  - JOUR
AU  - Obradovic, N.
AU  - Dordevic, N.
AU  - Filipovic, S.
AU  - Nikolic, N.
AU  - Kosanovic, D.
AU  - Mitrić, Miodrag
AU  - Markovic, S.
AU  - Pavlović, Vladimir B.
PY  - 2012
UR  - http://vinar.vin.bg.ac.rs/handle/123456789/4702
AB  - Due to its outstanding electrical characteristics, such as the low temperature expansion coefficient, low dielectric constant and good mechanical properties, cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2), is a very attractive high-temperature ceramic material. In order to accelerate the process of sintering, 2.50 mass% Bi2O3 has been added to the starting mixtures. Liquid phase sintering caused by the presence of bismuth-oxide lowers the temperature of cordierite formation. The mechanical activation of the starting mixtures (0-56 min in vibro-mill) additionally lowers sintering temperatures. The sintering process was performed at 1200, 1300, 1350 and 1400 degrees C, for 2 h. The particle size analysis (PSA) was employed in order to determine the changes in the particle size of the mechanically treated powders. The phase composition of the starting powders and sintered materials was analyzed by the X-ray diffraction method. Furthermore, scanning electron microscopy (SEM) was used in the analysis of the powder morphology. (C) 2011 Elsevier B.V. All rights reserved.
T2  - Powder Technology
T1  - Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive
VL  - 218
SP  - 157
EP  - 161
DO  - 10.1016/j.powtec.2011.12.012
ER  - 
@article{
author = "Obradovic, N. and Dordevic, N. and Filipovic, S. and Nikolic, N. and Kosanovic, D. and Mitrić, Miodrag and Markovic, S. and Pavlović, Vladimir B.",
year = "2012",
url = "http://vinar.vin.bg.ac.rs/handle/123456789/4702",
abstract = "Due to its outstanding electrical characteristics, such as the low temperature expansion coefficient, low dielectric constant and good mechanical properties, cordierite, 2MgO center dot 2Al(2)O(3)center dot 5SiO(2), is a very attractive high-temperature ceramic material. In order to accelerate the process of sintering, 2.50 mass% Bi2O3 has been added to the starting mixtures. Liquid phase sintering caused by the presence of bismuth-oxide lowers the temperature of cordierite formation. The mechanical activation of the starting mixtures (0-56 min in vibro-mill) additionally lowers sintering temperatures. The sintering process was performed at 1200, 1300, 1350 and 1400 degrees C, for 2 h. The particle size analysis (PSA) was employed in order to determine the changes in the particle size of the mechanically treated powders. The phase composition of the starting powders and sintered materials was analyzed by the X-ray diffraction method. Furthermore, scanning electron microscopy (SEM) was used in the analysis of the powder morphology. (C) 2011 Elsevier B.V. All rights reserved.",
journal = "Powder Technology",
title = "Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive",
volume = "218",
pages = "157-161",
doi = "10.1016/j.powtec.2011.12.012"
}
Obradovic, N., Dordevic, N., Filipovic, S., Nikolic, N., Kosanovic, D., Mitrić, M., Markovic, S.,& Pavlović, V. B. (2012). Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive.
Powder Technology, 218, 157-161.
https://doi.org/10.1016/j.powtec.2011.12.012
Obradovic N, Dordevic N, Filipovic S, Nikolic N, Kosanovic D, Mitrić M, Markovic S, Pavlović VB. Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive. Powder Technology. 2012;218:157-161
Obradovic N., Dordevic N., Filipovic S., Nikolic N., Kosanovic D., Mitrić Miodrag, Markovic S., Pavlović Vladimir B., "Influence of mechanochemical activation on the sintering of cordierite ceramics in the presence of Bi2O3 as a functional additive" Powder Technology, 218 (2012):157-161,
https://doi.org/10.1016/j.powtec.2011.12.012 .
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