TY  - JOUR
AU  - Laušević, Zoran
AU  - Apel, Pavel Yu
AU  - Krstić, Jugoslav B.
AU  - Blonskaya, Irina V.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5702
AB  - Activation effects on carbon films, derived from commercial aromatic polyimide films (Kapton, DuPont), in CO2 atmosphere at 1203 K on capacitance properties were studied. Two thicknesses of polyimide films were used: 7 and 25 gm. Pore formation during the activation process progresses in two steps due to the existence of a denser surface layer and a more porous core material. In the first step micropores are opening in the dense surface region of the material with average pore diameter smaller than 1 nm. During the second step, mesopores start opening, while micropore volume remains constant with the average micropore diameter of over 1 nm, producing bimodal texture. The first step finishes after 30 min for the thinner samples while for the thicker samples it finishes after 60 mm of activation. As a consequence of such textural changes during activation, the thicker sample has a maximum areal capacitance of 0.35 F/cm(2). The thinner sample activated for 30 min has a maximum volumetric capacitance of 220 F/cm(3) and achieves a maximum gravimetric capacitance of 240 F/g when the texture becomes bimodal after 240 min of activation. These results confirm that activation of carbonized Kapton films gives promising electrode materials for supercapacitors. (C) 2013 Elsevier Ltd. All rights reserved.
T2  - Carbon
T1  - Porous carbon thin films for electrochemical capacitors
VL  - 64
SP  - 456
EP  - 463
DO  - 10.1016/j.carbon.2013.07.098
ER  - 

@article{
author = "Laušević, Zoran and Apel, Pavel Yu and Krstić, Jugoslav B. and Blonskaya, Irina V.",
year = "2013",
abstract = "Activation effects on carbon films, derived from commercial aromatic polyimide films (Kapton, DuPont), in CO2 atmosphere at 1203 K on capacitance properties were studied. Two thicknesses of polyimide films were used: 7 and 25 gm. Pore formation during the activation process progresses in two steps due to the existence of a denser surface layer and a more porous core material. In the first step micropores are opening in the dense surface region of the material with average pore diameter smaller than 1 nm. During the second step, mesopores start opening, while micropore volume remains constant with the average micropore diameter of over 1 nm, producing bimodal texture. The first step finishes after 30 min for the thinner samples while for the thicker samples it finishes after 60 mm of activation. As a consequence of such textural changes during activation, the thicker sample has a maximum areal capacitance of 0.35 F/cm(2). The thinner sample activated for 30 min has a maximum volumetric capacitance of 220 F/cm(3) and achieves a maximum gravimetric capacitance of 240 F/g when the texture becomes bimodal after 240 min of activation. These results confirm that activation of carbonized Kapton films gives promising electrode materials for supercapacitors. (C) 2013 Elsevier Ltd. All rights reserved.",
journal = "Carbon",
title = "Porous carbon thin films for electrochemical capacitors",
volume = "64",
pages = "456-463",
doi = "10.1016/j.carbon.2013.07.098"
}

Laušević, Z., Apel, P. Y., Krstić, J. B.,& Blonskaya, I. V.. (2013). Porous carbon thin films for electrochemical capacitors. in Carbon, 64, 456-463.
https://doi.org/10.1016/j.carbon.2013.07.098

Laušević Z, Apel PY, Krstić JB, Blonskaya IV. Porous carbon thin films for electrochemical capacitors. in Carbon. 2013;64:456-463.
doi:10.1016/j.carbon.2013.07.098 .

Laušević, Zoran, Apel, Pavel Yu, Krstić, Jugoslav B., Blonskaya, Irina V., "Porous carbon thin films for electrochemical capacitors" in Carbon, 64 (2013):456-463,
https://doi.org/10.1016/j.carbon.2013.07.098 . .