TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor M.
AU  - Fabian, Martin
AU  - Vranješ-Đurić, Sanja
AU  - Antić, Bratislav
AU  - Dojčinović, Biljana P.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8810
AB  - Iron oxide nanoparticles (IONP) with different distinctive morphologies (spherical, cubic, flower-like and needles) were utilized for modification of screen-printed carbon electrodes (SPCE) to be used for synthetic organic dye degradation by an electrochemical approach. This platform was implemented for removal of the synthetic organic dye, Reactive Black 5 (RB5) in aqueous solution. Modified SPCE with spherically shaped IONP (IONS) had the highest dye removal efficiency. Thus, IONS were then used for surface decoration of the most common carbon-based materials (graphene, graphene oxide, carboxylated graphene, graphene nanoribbons, graphene nanoplatelets, single- and multi-wall carbon nanotubes), and the nanocomposites formed were deposited on the electrode surfaces. Using IONS/graphene composite (IONS@GN) for electrode modification resulted in the best effect. Removal of RB5 with this electrode was 51% better in comparison with bare SPCE, reducing the time required for complete dye degradation from 61 to 30 min Using IONS-modified SPCE, total RB5 removal occurred in 51 min, improving the performance by 16% over that of bare SPCE. The effects determined, i.e., the best IONP morphology and best type of carbon-based material for nanocomposite formation to enhance RB5 removal will provide guidelines for further modifications of SPCE with nanomaterials and nanocomposites, for application of this electrochemical approach in the degradation of organic pollutants. © 2020 The Author(s). Published by IOP Publishing Ltd.
T2  - Materials Research Express
T1  - Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye
VL  - 7
IS  - 1
SP  - 015509
DO  - 10.1088/2053-1591/ab6490
ER  - 

@article{
author = "Ognjanović, Miloš and Stanković, Dalibor M. and Fabian, Martin and Vranješ-Đurić, Sanja and Antić, Bratislav and Dojčinović, Biljana P.",
year = "2020",
abstract = "Iron oxide nanoparticles (IONP) with different distinctive morphologies (spherical, cubic, flower-like and needles) were utilized for modification of screen-printed carbon electrodes (SPCE) to be used for synthetic organic dye degradation by an electrochemical approach. This platform was implemented for removal of the synthetic organic dye, Reactive Black 5 (RB5) in aqueous solution. Modified SPCE with spherically shaped IONP (IONS) had the highest dye removal efficiency. Thus, IONS were then used for surface decoration of the most common carbon-based materials (graphene, graphene oxide, carboxylated graphene, graphene nanoribbons, graphene nanoplatelets, single- and multi-wall carbon nanotubes), and the nanocomposites formed were deposited on the electrode surfaces. Using IONS/graphene composite (IONS@GN) for electrode modification resulted in the best effect. Removal of RB5 with this electrode was 51% better in comparison with bare SPCE, reducing the time required for complete dye degradation from 61 to 30 min Using IONS-modified SPCE, total RB5 removal occurred in 51 min, improving the performance by 16% over that of bare SPCE. The effects determined, i.e., the best IONP morphology and best type of carbon-based material for nanocomposite formation to enhance RB5 removal will provide guidelines for further modifications of SPCE with nanomaterials and nanocomposites, for application of this electrochemical approach in the degradation of organic pollutants. © 2020 The Author(s). Published by IOP Publishing Ltd.",
journal = "Materials Research Express",
title = "Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye",
volume = "7",
number = "1",
pages = "015509",
doi = "10.1088/2053-1591/ab6490"
}

Ognjanović, M., Stanković, D. M., Fabian, M., Vranješ-Đurić, S., Antić, B.,& Dojčinović, B. P.. (2020). Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye. in Materials Research Express, 7(1), 015509.
https://doi.org/10.1088/2053-1591/ab6490

Ognjanović M, Stanković DM, Fabian M, Vranješ-Đurić S, Antić B, Dojčinović BP. Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye. in Materials Research Express. 2020;7(1):015509.
doi:10.1088/2053-1591/ab6490 .

Ognjanović, Miloš, Stanković, Dalibor M., Fabian, Martin, Vranješ-Đurić, Sanja, Antić, Bratislav, Dojčinović, Biljana P., "Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye" in Materials Research Express, 7, no. 1 (2020):015509,
https://doi.org/10.1088/2053-1591/ab6490 . .

TY  - JOUR
AU  - Mariano, Jose F. M. L.
AU  - Bessergenev, Valentim G
AU  - Lourenço, João P
AU  - Hantusch, Martin
AU  - Burkel, Eberhard
AU  - do Rego, Ana M Botelho
AU  - Rajňák, Michal
AU  - Timko, Milan
AU  - Kopčanský, Peter
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8802
AB  - The present work reports on the structural and magnetic properties of TiO2 P25 Degussa powder doped with cobalt. Dissolution of cobalt in TiO2 matrix was achieved by precipitation of tris(diethyldithiocarbamato) cobalt(III) (CoDtc - Co[S2CN(C2H5)2]3 in chloroform (CHCl3) and consequent thermal treatment. Five different Co atomic percentage contents were chosen, e.g., 0.5%, 1%, 2%, 5% and 10%. It was shown that cobalt atoms are uniformly distributed across TiO2 matrix and exhibit antiferromagnetic interactions at low temperatures. © 2020 Elsevier B.V.
T2  - Journal of Magnetism and Magnetic Materials
T1  - Structural and magnetic properties of P25 TiO2 nanoparticles doped by Co
VL  - 501
SP  - 166442
DO  - 10.1016/j.jmmm.2020.166442
ER  - 

@article{
author = "Mariano, Jose F. M. L. and Bessergenev, Valentim G and Lourenço, João P and Hantusch, Martin and Burkel, Eberhard and do Rego, Ana M Botelho and Rajňák, Michal and Timko, Milan and Kopčanský, Peter",
year = "2020",
abstract = "The present work reports on the structural and magnetic properties of TiO2 P25 Degussa powder doped with cobalt. Dissolution of cobalt in TiO2 matrix was achieved by precipitation of tris(diethyldithiocarbamato) cobalt(III) (CoDtc - Co[S2CN(C2H5)2]3 in chloroform (CHCl3) and consequent thermal treatment. Five different Co atomic percentage contents were chosen, e.g., 0.5%, 1%, 2%, 5% and 10%. It was shown that cobalt atoms are uniformly distributed across TiO2 matrix and exhibit antiferromagnetic interactions at low temperatures. © 2020 Elsevier B.V.",
journal = "Journal of Magnetism and Magnetic Materials",
title = "Structural and magnetic properties of P25 TiO2 nanoparticles doped by Co",
volume = "501",
pages = "166442",
doi = "10.1016/j.jmmm.2020.166442"
}

Mariano, J. F. M. L., Bessergenev, V. G., Lourenço, J. P., Hantusch, M., Burkel, E., do Rego, A. M. B., Rajňák, M., Timko, M.,& Kopčanský, P.. (2020). Structural and magnetic properties of P25 TiO2 nanoparticles doped by Co. in Journal of Magnetism and Magnetic Materials, 501, 166442.
https://doi.org/10.1016/j.jmmm.2020.166442

Mariano JFML, Bessergenev VG, Lourenço JP, Hantusch M, Burkel E, do Rego AMB, Rajňák M, Timko M, Kopčanský P. Structural and magnetic properties of P25 TiO2 nanoparticles doped by Co. in Journal of Magnetism and Magnetic Materials. 2020;501:166442.
doi:10.1016/j.jmmm.2020.166442 .

Mariano, Jose F. M. L., Bessergenev, Valentim G, Lourenço, João P, Hantusch, Martin, Burkel, Eberhard, do Rego, Ana M Botelho, Rajňák, Michal, Timko, Milan, Kopčanský, Peter, "Structural and magnetic properties of P25 TiO2 nanoparticles doped by Co" in Journal of Magnetism and Magnetic Materials, 501 (2020):166442,
https://doi.org/10.1016/j.jmmm.2020.166442 . .

TY  - JOUR
AU  - Zavišova, Vlasta
AU  - Koneracka, Martina
AU  - Gabelova, Alena
AU  - Svitkova, Barbora
AU  - Ursinyova, Monika
AU  - Kubovčikova, Martina
AU  - Antal, Iryna
AU  - Khmara, Iryna
AU  - Jurikova, Alena
AU  - Molčan, Matuš
AU  - Ognjanović, Miloš
AU  - Antić, Bratislav
AU  - Kopčansky, Peter
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0304885318320183
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7906
AB  - Magnetic iron oxide nanoparticles (MNPs) are one of the most promising types of nanoparticles for biomedical applications, primarily in the context of nanomedicine-based diagnostics and therapy. They are used as contrast agents in magnetic resonance imaging and magnetite cell labelling. Furthermore, they are promising heating mediator in magnetic hyperthermia-based therapy, and can serve as nanocarriers in targeted gene and drug delivery as well. In biomedical applications, coating plays an important role in nanoparticle dispersion stability and biocompatibility. However, the impact of nanoparticle surface chemistry on cell uptake and proliferation has not been sufficiently investigated. The objective of this study is to prepare magnetic nanoparticles with inner magnetite core and hydrophilic outer shell of surfactant, protein and polymers that are commonly used in biomedical research. MNPs were characterized in-depth by various physicochemical methods. Magnetic hyperthermia, applied to find out the influence of MNPs coating on heating characteristics of the samples, did not show any correlation between layer thickness and specific adsorption rate. To evaluate the impact of surface chemistry on cell proliferation and internalization, the human lung adenocarcinoma epithelial (A549) cells were utilized. Substantial differences were determined in the amount of internalized MNPs and cell viability in dependence on surface coating. Our results indicate that the surface chemistry not only protects particles from agglomeration but also affect the interaction between cell and MNPs. © 2018 Elsevier B.V.
T2  - Journal of Magnetism and Magnetic Materials
T1  - Effect of magnetic nanoparticles coating on cell proliferation and uptake
VL  - 472
SP  - 66
EP  - 73
DO  - 10.1016/j.jmmm.2018.09.116
ER  - 

@article{
author = "Zavišova, Vlasta and Koneracka, Martina and Gabelova, Alena and Svitkova, Barbora and Ursinyova, Monika and Kubovčikova, Martina and Antal, Iryna and Khmara, Iryna and Jurikova, Alena and Molčan, Matuš and Ognjanović, Miloš and Antić, Bratislav and Kopčansky, Peter",
year = "2019",
abstract = "Magnetic iron oxide nanoparticles (MNPs) are one of the most promising types of nanoparticles for biomedical applications, primarily in the context of nanomedicine-based diagnostics and therapy. They are used as contrast agents in magnetic resonance imaging and magnetite cell labelling. Furthermore, they are promising heating mediator in magnetic hyperthermia-based therapy, and can serve as nanocarriers in targeted gene and drug delivery as well. In biomedical applications, coating plays an important role in nanoparticle dispersion stability and biocompatibility. However, the impact of nanoparticle surface chemistry on cell uptake and proliferation has not been sufficiently investigated. The objective of this study is to prepare magnetic nanoparticles with inner magnetite core and hydrophilic outer shell of surfactant, protein and polymers that are commonly used in biomedical research. MNPs were characterized in-depth by various physicochemical methods. Magnetic hyperthermia, applied to find out the influence of MNPs coating on heating characteristics of the samples, did not show any correlation between layer thickness and specific adsorption rate. To evaluate the impact of surface chemistry on cell proliferation and internalization, the human lung adenocarcinoma epithelial (A549) cells were utilized. Substantial differences were determined in the amount of internalized MNPs and cell viability in dependence on surface coating. Our results indicate that the surface chemistry not only protects particles from agglomeration but also affect the interaction between cell and MNPs. © 2018 Elsevier B.V.",
journal = "Journal of Magnetism and Magnetic Materials",
title = "Effect of magnetic nanoparticles coating on cell proliferation and uptake",
volume = "472",
pages = "66-73",
doi = "10.1016/j.jmmm.2018.09.116"
}

Zavišova, V., Koneracka, M., Gabelova, A., Svitkova, B., Ursinyova, M., Kubovčikova, M., Antal, I., Khmara, I., Jurikova, A., Molčan, M., Ognjanović, M., Antić, B.,& Kopčansky, P.. (2019). Effect of magnetic nanoparticles coating on cell proliferation and uptake. in Journal of Magnetism and Magnetic Materials, 472, 66-73.
https://doi.org/10.1016/j.jmmm.2018.09.116

Zavišova V, Koneracka M, Gabelova A, Svitkova B, Ursinyova M, Kubovčikova M, Antal I, Khmara I, Jurikova A, Molčan M, Ognjanović M, Antić B, Kopčansky P. Effect of magnetic nanoparticles coating on cell proliferation and uptake. in Journal of Magnetism and Magnetic Materials. 2019;472:66-73.
doi:10.1016/j.jmmm.2018.09.116 .

Zavišova, Vlasta, Koneracka, Martina, Gabelova, Alena, Svitkova, Barbora, Ursinyova, Monika, Kubovčikova, Martina, Antal, Iryna, Khmara, Iryna, Jurikova, Alena, Molčan, Matuš, Ognjanović, Miloš, Antić, Bratislav, Kopčansky, Peter, "Effect of magnetic nanoparticles coating on cell proliferation and uptake" in Journal of Magnetism and Magnetic Materials, 472 (2019):66-73,
https://doi.org/10.1016/j.jmmm.2018.09.116 . .

TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor M.
AU  - Ming, Yue
AU  - Zhang, Hongguo
AU  - Jančar, Boštjan
AU  - Dojčinović, Biljana P.
AU  - Prijović, Željko
AU  - Antić, Bratislav
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0925838818340684
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7942
AB  - In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully applied for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration. © 2018 Elsevier B.V.
T2  - Journal of Alloys and Compounds
T1  - Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia
VL  - 777
SP  - 454
EP  - 462
DO  - 10.1016/j.jallcom.2018.10.369
ER  - 

@article{
author = "Ognjanović, Miloš and Stanković, Dalibor M. and Ming, Yue and Zhang, Hongguo and Jančar, Boštjan and Dojčinović, Biljana P. and Prijović, Željko and Antić, Bratislav",
year = "2019",
abstract = "In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully applied for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration. © 2018 Elsevier B.V.",
journal = "Journal of Alloys and Compounds",
title = "Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia",
volume = "777",
pages = "454-462",
doi = "10.1016/j.jallcom.2018.10.369"
}

Ognjanović, M., Stanković, D. M., Ming, Y., Zhang, H., Jančar, B., Dojčinović, B. P., Prijović, Ž.,& Antić, B.. (2019). Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia. in Journal of Alloys and Compounds, 777, 454-462.
https://doi.org/10.1016/j.jallcom.2018.10.369

Ognjanović M, Stanković DM, Ming Y, Zhang H, Jančar B, Dojčinović BP, Prijović Ž, Antić B. Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia. in Journal of Alloys and Compounds. 2019;777:454-462.
doi:10.1016/j.jallcom.2018.10.369 .

Ognjanović, Miloš, Stanković, Dalibor M., Ming, Yue, Zhang, Hongguo, Jančar, Boštjan, Dojčinović, Biljana P., Prijović, Željko, Antić, Bratislav, "Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia" in Journal of Alloys and Compounds, 777 (2019):454-462,
https://doi.org/10.1016/j.jallcom.2018.10.369 . .

TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Spasojević, Irena
AU  - Stanković, Dalibor M.
AU  - Ming, Yue
AU  - Jančar, Boštjan
AU  - Dojčinović, Biljana P.
AU  - Spasojević, Vojislav
AU  - Antić, Bratislav
PY  - 2019
UR  - https://www.ingentaconnect.com/content/10.1166/jnn.2019.16284
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8074
AB  - A series of MgxFe3-xO₄ (x ═ 0-1) nanoparticles was synthesized in order to prepare novel MgxFe3-xO₄/glassy carbon modified electrodes. Effects of magnesium content (x) on the analytical performance of the modified electrodes in the detection of gallic acid were evaluated. It was found that magnesium concentration and crystallite/particle size of the prepared nanoparticles play significant roles in the sensing properties of modified electrodes. The increase of magnesium concentration up to the value of x ═ 0.4 in MgxFe3-xO₄/glassy carbon paste was accompanied by an increase of the corresponding oxidation current of gallic acid. However, further growth of x value caused decline of the obtained oxidation current. An electroanalytical procedure was established, and the analytical performance of the proposed Mg0.4Fe2.6O₄/glassy carbon paste electrode was monitored using previously optimized experimental conditions. A working linear range from 1-39 µM gallic acid was obtained with detection limit of 0.29 µM. According to these results, the developed procedure can be applied for detection of low concentrations of gallic acid with satisfactory selectivity in the presence of some common naturally occurring compounds. Experimental results indicate that the developed procedure could be a novel approach in the detection of antioxidant, overcoming some known disadvantages such as passivation, and could be a promising replacement for sophisticated chromatographic methods.
T2  - Journal of Nanoscience and Nanotechnology
T1  - Enhancing Analytical Performance of (Mg,Fe)3O4/Glassy Carbon Electrodes by Tailoring Chemical Composition of (Mg,Fe)3O4 Nanoparticles
VL  - 19
IS  - 7
SP  - 4205
EP  - 4213
DO  - 10.1166/jnn.2019.16284
ER  - 

@article{
author = "Ognjanović, Miloš and Spasojević, Irena and Stanković, Dalibor M. and Ming, Yue and Jančar, Boštjan and Dojčinović, Biljana P. and Spasojević, Vojislav and Antić, Bratislav",
year = "2019",
abstract = "A series of MgxFe3-xO₄ (x ═ 0-1) nanoparticles was synthesized in order to prepare novel MgxFe3-xO₄/glassy carbon modified electrodes. Effects of magnesium content (x) on the analytical performance of the modified electrodes in the detection of gallic acid were evaluated. It was found that magnesium concentration and crystallite/particle size of the prepared nanoparticles play significant roles in the sensing properties of modified electrodes. The increase of magnesium concentration up to the value of x ═ 0.4 in MgxFe3-xO₄/glassy carbon paste was accompanied by an increase of the corresponding oxidation current of gallic acid. However, further growth of x value caused decline of the obtained oxidation current. An electroanalytical procedure was established, and the analytical performance of the proposed Mg0.4Fe2.6O₄/glassy carbon paste electrode was monitored using previously optimized experimental conditions. A working linear range from 1-39 µM gallic acid was obtained with detection limit of 0.29 µM. According to these results, the developed procedure can be applied for detection of low concentrations of gallic acid with satisfactory selectivity in the presence of some common naturally occurring compounds. Experimental results indicate that the developed procedure could be a novel approach in the detection of antioxidant, overcoming some known disadvantages such as passivation, and could be a promising replacement for sophisticated chromatographic methods.",
journal = "Journal of Nanoscience and Nanotechnology",
title = "Enhancing Analytical Performance of (Mg,Fe)3O4/Glassy Carbon Electrodes by Tailoring Chemical Composition of (Mg,Fe)3O4 Nanoparticles",
volume = "19",
number = "7",
pages = "4205-4213",
doi = "10.1166/jnn.2019.16284"
}

Ognjanović, M., Spasojević, I., Stanković, D. M., Ming, Y., Jančar, B., Dojčinović, B. P., Spasojević, V.,& Antić, B.. (2019). Enhancing Analytical Performance of (Mg,Fe)3O4/Glassy Carbon Electrodes by Tailoring Chemical Composition of (Mg,Fe)3O4 Nanoparticles. in Journal of Nanoscience and Nanotechnology, 19(7), 4205-4213.
https://doi.org/10.1166/jnn.2019.16284

Ognjanović M, Spasojević I, Stanković DM, Ming Y, Jančar B, Dojčinović BP, Spasojević V, Antić B. Enhancing Analytical Performance of (Mg,Fe)3O4/Glassy Carbon Electrodes by Tailoring Chemical Composition of (Mg,Fe)3O4 Nanoparticles. in Journal of Nanoscience and Nanotechnology. 2019;19(7):4205-4213.
doi:10.1166/jnn.2019.16284 .

Ognjanović, Miloš, Spasojević, Irena, Stanković, Dalibor M., Ming, Yue, Jančar, Boštjan, Dojčinović, Biljana P., Spasojević, Vojislav, Antić, Bratislav, "Enhancing Analytical Performance of (Mg,Fe)3O4/Glassy Carbon Electrodes by Tailoring Chemical Composition of (Mg,Fe)3O4 Nanoparticles" in Journal of Nanoscience and Nanotechnology, 19, no. 7 (2019):4205-4213,
https://doi.org/10.1166/jnn.2019.16284 . .

TY  - JOUR
AU  - Stanković, Dalibor M.
AU  - Ognjanović, Miloš
AU  - Jović, Milica
AU  - Cuplić, Valentina
AU  - Lesch, Andreas
AU  - Girault, Hubert H.
AU  - Gavrović-Jankulović, Marija
AU  - Antić, Bratislav
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8342
AB  - A disposable acetaminophen biosensor based on inkjet-printed CNT electrodes (IJPCNT) modified with amidase/cerium dioxide@graphene nanoribbons composite was developed (ACeO2@GNR/IJPCNT). The enzyme amidase A was used for the first time as a recognition element. Inkjet-printed CNT electrodes served as a basis for the construction of a biosensor that enables droplet detection using 5 μL sample volume. The biosensor showed high selectivity, sensitivity, a low detection limit of 0.18 μM and a wide working linear range from 1 to 100 μM. The proposed approach allows fast and reliable detection of acetaminophen in biological fluids with negligible matrix effect and remarkable reproducibility. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - Electroanalysis
T1  - Disposable Biosensor Based on Amidase/CeO2/GNR Modified Inkjet‐printed CNT Electrodes‐droplet Based Paracetamol Detection in Biological Fluids for “Point‐of‐care” Applications
VL  - 31
IS  - 8
SP  - 1517
EP  - 1525
DO  - 10.1002/elan.201900129
ER  - 

@article{
author = "Stanković, Dalibor M. and Ognjanović, Miloš and Jović, Milica and Cuplić, Valentina and Lesch, Andreas and Girault, Hubert H. and Gavrović-Jankulović, Marija and Antić, Bratislav",
year = "2019",
abstract = "A disposable acetaminophen biosensor based on inkjet-printed CNT electrodes (IJPCNT) modified with amidase/cerium dioxide@graphene nanoribbons composite was developed (ACeO2@GNR/IJPCNT). The enzyme amidase A was used for the first time as a recognition element. Inkjet-printed CNT electrodes served as a basis for the construction of a biosensor that enables droplet detection using 5 μL sample volume. The biosensor showed high selectivity, sensitivity, a low detection limit of 0.18 μM and a wide working linear range from 1 to 100 μM. The proposed approach allows fast and reliable detection of acetaminophen in biological fluids with negligible matrix effect and remarkable reproducibility. © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "Electroanalysis",
title = "Disposable Biosensor Based on Amidase/CeO2/GNR Modified Inkjet‐printed CNT Electrodes‐droplet Based Paracetamol Detection in Biological Fluids for “Point‐of‐care” Applications",
volume = "31",
number = "8",
pages = "1517-1525",
doi = "10.1002/elan.201900129"
}

Stanković, D. M., Ognjanović, M., Jović, M., Cuplić, V., Lesch, A., Girault, H. H., Gavrović-Jankulović, M.,& Antić, B.. (2019). Disposable Biosensor Based on Amidase/CeO2/GNR Modified Inkjet‐printed CNT Electrodes‐droplet Based Paracetamol Detection in Biological Fluids for “Point‐of‐care” Applications. in Electroanalysis, 31(8), 1517-1525.
https://doi.org/10.1002/elan.201900129

Stanković DM, Ognjanović M, Jović M, Cuplić V, Lesch A, Girault HH, Gavrović-Jankulović M, Antić B. Disposable Biosensor Based on Amidase/CeO2/GNR Modified Inkjet‐printed CNT Electrodes‐droplet Based Paracetamol Detection in Biological Fluids for “Point‐of‐care” Applications. in Electroanalysis. 2019;31(8):1517-1525.
doi:10.1002/elan.201900129 .

Stanković, Dalibor M., Ognjanović, Miloš, Jović, Milica, Cuplić, Valentina, Lesch, Andreas, Girault, Hubert H., Gavrović-Jankulović, Marija, Antić, Bratislav, "Disposable Biosensor Based on Amidase/CeO2/GNR Modified Inkjet‐printed CNT Electrodes‐droplet Based Paracetamol Detection in Biological Fluids for “Point‐of‐care” Applications" in Electroanalysis, 31, no. 8 (2019):1517-1525,
https://doi.org/10.1002/elan.201900129 . .

TY  - JOUR
AU  - Stanković, Dalibor M.
AU  - Jović, Milica
AU  - Ognjanović, Miloš
AU  - Lesch, Andreas
AU  - Fabian, Martin
AU  - Girault, Hubert H.
AU  - Antić, Bratislav
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8394
AB  - An electrochemical sensor is described for the determination of L-dopa (levodopa; 3,4-dihydroxyphenylalanine). An inkjet-printed carbon nanotube (IJPCNT) electrode was modified with manganese dioxide microspheres by drop-casting. They coating was characterized by field emission scanning electron microscopy, Fourier-transform infrared spectroscopy and X-ray powder diffraction. The sensor, best operated at a working voltage of 0.3 V, has a linear response in the 0.1 to 10 μM L-dopa concentration range, a 54 nM detection limit, excellent reproducibility, repeatability and selectivity. The amperometric approach was applied to the determination of L-dopa in spiked biological fluids and displayed satisfactory accuracy and precision. [Figure not available: see fulltext.]. © 2019, Springer-Verlag GmbH Austria, part of Springer Nature.
T2  - Microchimica Acta
T1  - Point-of-care amperometric determination of L-dopa using an inkjet-printed carbon nanotube electrode modified with dandelion-like MnO2 microspheres
VL  - 186
IS  - 8
SP  - 532
DO  - 10.1007/s00604-019-3644-x
ER  - 

@article{
author = "Stanković, Dalibor M. and Jović, Milica and Ognjanović, Miloš and Lesch, Andreas and Fabian, Martin and Girault, Hubert H. and Antić, Bratislav",
year = "2019",
abstract = "An electrochemical sensor is described for the determination of L-dopa (levodopa; 3,4-dihydroxyphenylalanine). An inkjet-printed carbon nanotube (IJPCNT) electrode was modified with manganese dioxide microspheres by drop-casting. They coating was characterized by field emission scanning electron microscopy, Fourier-transform infrared spectroscopy and X-ray powder diffraction. The sensor, best operated at a working voltage of 0.3 V, has a linear response in the 0.1 to 10 μM L-dopa concentration range, a 54 nM detection limit, excellent reproducibility, repeatability and selectivity. The amperometric approach was applied to the determination of L-dopa in spiked biological fluids and displayed satisfactory accuracy and precision. [Figure not available: see fulltext.]. © 2019, Springer-Verlag GmbH Austria, part of Springer Nature.",
journal = "Microchimica Acta",
title = "Point-of-care amperometric determination of L-dopa using an inkjet-printed carbon nanotube electrode modified with dandelion-like MnO2 microspheres",
volume = "186",
number = "8",
pages = "532",
doi = "10.1007/s00604-019-3644-x"
}

Stanković, D. M., Jović, M., Ognjanović, M., Lesch, A., Fabian, M., Girault, H. H.,& Antić, B.. (2019). Point-of-care amperometric determination of L-dopa using an inkjet-printed carbon nanotube electrode modified with dandelion-like MnO2 microspheres. in Microchimica Acta, 186(8), 532.
https://doi.org/10.1007/s00604-019-3644-x

Stanković DM, Jović M, Ognjanović M, Lesch A, Fabian M, Girault HH, Antić B. Point-of-care amperometric determination of L-dopa using an inkjet-printed carbon nanotube electrode modified with dandelion-like MnO2 microspheres. in Microchimica Acta. 2019;186(8):532.
doi:10.1007/s00604-019-3644-x .

Stanković, Dalibor M., Jović, Milica, Ognjanović, Miloš, Lesch, Andreas, Fabian, Martin, Girault, Hubert H., Antić, Bratislav, "Point-of-care amperometric determination of L-dopa using an inkjet-printed carbon nanotube electrode modified with dandelion-like MnO2 microspheres" in Microchimica Acta, 186, no. 8 (2019):532,
https://doi.org/10.1007/s00604-019-3644-x . .

TY  - JOUR
AU  - Dojčinović, Biljana P.
AU  - Jančar, Boštjan
AU  - Bessais, Lotfi
AU  - Kremenović, Aleksandar S.
AU  - Jović-Jovičić, Nataša P.
AU  - Banković, Predrag T.
AU  - Stanković, Dalibor M.
AU  - Ognjanović, Miloš
AU  - Antić, Bratislav
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8612
AB  - Herein we report effects of partial substitution of Fe3+ by Y3+ in magnetite (Fe3O4) on morphology and inorganic arsenic species adsorption efficiency of the Fe3-xYxO4 nanoparticles formed. The series of Fe3-xYxO4 (x = 0.00, 0.042 and 0.084, labeled as Y00, Y05 and Y10, respectively) was synthesized using co-precipitation followed by microwave-hydrothermal treatment (MW) at 200 degrees C. With increase of yttrium content (x value), both the morphological inhomogeneity of the samples and the fraction of spinel nanorods as compared to spinel pseudospherical particles increased. By both transmission electron microscopy and x-ray powder diffraction analyses, it was determined that the direction of growth of the spinel nanorods is along the [110] crystallographic direction. The Fe3-xYxO4 affinities of adsorption toward the inorganic arsenic species, As(III) (arsenite, AsO33-) and As(V) (arsenate, AsO43-), were investigated. Increased Y3+ content related to changes in sample morphology was followed by a decrease of As(III) removal efficiency and vice versa for As(V). The increase in Y3+ content, in addition to increasing the adsorption capacity for As(V), significantly expanded the optimum pH range for the maximum removal and decreased the contact time for necessary 50% removal (t(1/2)) of As(V) (Y00: pH 2-3, t(1/2) = 3.12 min; Y05: pH 2-6, t(1/2) = 2.12 min and Y10: pH 2-10, t(1/2) = 1.12 min). The results point to incorporation of Y3+ in the crystal lattice of magnetite, inducing nanorod spinel structure formation with significant changes in sorption properties important for the removal of inorganic arsenic from waters.
T2  - Nanotechnology
T1  - Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species
VL  - 30
IS  - 47
SP  - 475702
DO  - 10.1088/1361-6528/ab3ca2
ER  - 

@article{
author = "Dojčinović, Biljana P. and Jančar, Boštjan and Bessais, Lotfi and Kremenović, Aleksandar S. and Jović-Jovičić, Nataša P. and Banković, Predrag T. and Stanković, Dalibor M. and Ognjanović, Miloš and Antić, Bratislav",
year = "2019",
abstract = "Herein we report effects of partial substitution of Fe3+ by Y3+ in magnetite (Fe3O4) on morphology and inorganic arsenic species adsorption efficiency of the Fe3-xYxO4 nanoparticles formed. The series of Fe3-xYxO4 (x = 0.00, 0.042 and 0.084, labeled as Y00, Y05 and Y10, respectively) was synthesized using co-precipitation followed by microwave-hydrothermal treatment (MW) at 200 degrees C. With increase of yttrium content (x value), both the morphological inhomogeneity of the samples and the fraction of spinel nanorods as compared to spinel pseudospherical particles increased. By both transmission electron microscopy and x-ray powder diffraction analyses, it was determined that the direction of growth of the spinel nanorods is along the [110] crystallographic direction. The Fe3-xYxO4 affinities of adsorption toward the inorganic arsenic species, As(III) (arsenite, AsO33-) and As(V) (arsenate, AsO43-), were investigated. Increased Y3+ content related to changes in sample morphology was followed by a decrease of As(III) removal efficiency and vice versa for As(V). The increase in Y3+ content, in addition to increasing the adsorption capacity for As(V), significantly expanded the optimum pH range for the maximum removal and decreased the contact time for necessary 50% removal (t(1/2)) of As(V) (Y00: pH 2-3, t(1/2) = 3.12 min; Y05: pH 2-6, t(1/2) = 2.12 min and Y10: pH 2-10, t(1/2) = 1.12 min). The results point to incorporation of Y3+ in the crystal lattice of magnetite, inducing nanorod spinel structure formation with significant changes in sorption properties important for the removal of inorganic arsenic from waters.",
journal = "Nanotechnology",
title = "Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species",
volume = "30",
number = "47",
pages = "475702",
doi = "10.1088/1361-6528/ab3ca2"
}

Dojčinović, B. P., Jančar, B., Bessais, L., Kremenović, A. S., Jović-Jovičić, N. P., Banković, P. T., Stanković, D. M., Ognjanović, M.,& Antić, B.. (2019). Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species. in Nanotechnology, 30(47), 475702.
https://doi.org/10.1088/1361-6528/ab3ca2

Dojčinović BP, Jančar B, Bessais L, Kremenović AS, Jović-Jovičić NP, Banković PT, Stanković DM, Ognjanović M, Antić B. Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species. in Nanotechnology. 2019;30(47):475702.
doi:10.1088/1361-6528/ab3ca2 .

Dojčinović, Biljana P., Jančar, Boštjan, Bessais, Lotfi, Kremenović, Aleksandar S., Jović-Jovičić, Nataša P., Banković, Predrag T., Stanković, Dalibor M., Ognjanović, Miloš, Antić, Bratislav, "Differently shaped nanocrystalline (Fe, Y)3O4 and its adsorption efficiency toward inorganic arsenic species" in Nanotechnology, 30, no. 47 (2019):475702,
https://doi.org/10.1088/1361-6528/ab3ca2 . .

TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Radović, Magdalena
AU  - Mirković, Marija D.
AU  - Prijović, Željko
AU  - Puerto Morales, Maria del
AU  - Čeh, Miran
AU  - Vranješ-Đurić, Sanja
AU  - Antić, Bratislav
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8622
AB  - Development of a complex based on iron oxide nanoparticles (IONPs) for diagnosis and dual magnetic hyperthermia/radionuclide cancer therapy accomplishing high yields of radiolabeling and great magnetic heat induction is still a challenge. We report here the synthesis of citric acid, poly(acrylic acid) (PAA) and poly(ethylene glycol) coated IONPs and their labeling with three radionuclides, namely, technetium (99mTc), yttrium (90Y), and lutetium (177Lu), aiming at potential use in cancer diagnosis and therapy. Polyol-synthesized IONPs are a flowerlike structure with 13.5 nm spherically shaped cores and 24.8 nm diameter. PAA-coated nanoparticles (PAA@IONP) showed the best characteristics such as easy radiolabeling with very high yields (>97.5%) with all three radionuclides, and excellent in vitro stabilities with less than 10% of radionuclides detaching after 24 h. Heating ability of PAA@IONP in an alternating external magnetic field showed intrinsic loss power value of 7.3 nH m2/kg, which is one of higher reported values. Additionally, PAA@IONP itself presented no significant cytotoxicity to the CT-26 cancer cells, reaching IC50 at 60 μg/mL. However, under the external magnetic field, they show hyperthermia-mediated cells killing, which correlated with the magnetic field strength and time of exposure. Since PAA@IONP are easy to prepare, biocompatible, and with excellent magnetic heat induction, these nanoparticles radiolabeled with high-energy beta emitters 90Y and 177Lu have valuable potential as agent for dual magnetic hyperthermia/radionuclide therapy, while radiolabeled with 99mTc could be used in diagnostic imaging. Copyright © 2019 American Chemical Society.
T2  - ACS Applied Materials & Interfaces
T1  - 99m Tc-, 90 Y-, and 177 Lu-Labeled Iron Oxide Nanoflowers Designed for Potential Use in Dual Magnetic Hyperthermia/Radionuclide Cancer Therapy and Diagnosis
VL  - 11
IS  - 44
SP  - 41109
EP  - 41117
DO  - 10.1021/acsami.9b16428
ER  - 

@article{
author = "Ognjanović, Miloš and Radović, Magdalena and Mirković, Marija D. and Prijović, Željko and Puerto Morales, Maria del and Čeh, Miran and Vranješ-Đurić, Sanja and Antić, Bratislav",
year = "2019",
abstract = "Development of a complex based on iron oxide nanoparticles (IONPs) for diagnosis and dual magnetic hyperthermia/radionuclide cancer therapy accomplishing high yields of radiolabeling and great magnetic heat induction is still a challenge. We report here the synthesis of citric acid, poly(acrylic acid) (PAA) and poly(ethylene glycol) coated IONPs and their labeling with three radionuclides, namely, technetium (99mTc), yttrium (90Y), and lutetium (177Lu), aiming at potential use in cancer diagnosis and therapy. Polyol-synthesized IONPs are a flowerlike structure with 13.5 nm spherically shaped cores and 24.8 nm diameter. PAA-coated nanoparticles (PAA@IONP) showed the best characteristics such as easy radiolabeling with very high yields (>97.5%) with all three radionuclides, and excellent in vitro stabilities with less than 10% of radionuclides detaching after 24 h. Heating ability of PAA@IONP in an alternating external magnetic field showed intrinsic loss power value of 7.3 nH m2/kg, which is one of higher reported values. Additionally, PAA@IONP itself presented no significant cytotoxicity to the CT-26 cancer cells, reaching IC50 at 60 μg/mL. However, under the external magnetic field, they show hyperthermia-mediated cells killing, which correlated with the magnetic field strength and time of exposure. Since PAA@IONP are easy to prepare, biocompatible, and with excellent magnetic heat induction, these nanoparticles radiolabeled with high-energy beta emitters 90Y and 177Lu have valuable potential as agent for dual magnetic hyperthermia/radionuclide therapy, while radiolabeled with 99mTc could be used in diagnostic imaging. Copyright © 2019 American Chemical Society.",
journal = "ACS Applied Materials & Interfaces",
title = "99m Tc-, 90 Y-, and 177 Lu-Labeled Iron Oxide Nanoflowers Designed for Potential Use in Dual Magnetic Hyperthermia/Radionuclide Cancer Therapy and Diagnosis",
volume = "11",
number = "44",
pages = "41109-41117",
doi = "10.1021/acsami.9b16428"
}

Ognjanović, M., Radović, M., Mirković, M. D., Prijović, Ž., Puerto Morales, M. d., Čeh, M., Vranješ-Đurić, S.,& Antić, B.. (2019). 99m Tc-, 90 Y-, and 177 Lu-Labeled Iron Oxide Nanoflowers Designed for Potential Use in Dual Magnetic Hyperthermia/Radionuclide Cancer Therapy and Diagnosis. in ACS Applied Materials & Interfaces, 11(44), 41109-41117.
https://doi.org/10.1021/acsami.9b16428

Ognjanović M, Radović M, Mirković MD, Prijović Ž, Puerto Morales MD, Čeh M, Vranješ-Đurić S, Antić B. 99m Tc-, 90 Y-, and 177 Lu-Labeled Iron Oxide Nanoflowers Designed for Potential Use in Dual Magnetic Hyperthermia/Radionuclide Cancer Therapy and Diagnosis. in ACS Applied Materials & Interfaces. 2019;11(44):41109-41117.
doi:10.1021/acsami.9b16428 .

Ognjanović, Miloš, Radović, Magdalena, Mirković, Marija D., Prijović, Željko, Puerto Morales, Maria del, Čeh, Miran, Vranješ-Đurić, Sanja, Antić, Bratislav, "99m Tc-, 90 Y-, and 177 Lu-Labeled Iron Oxide Nanoflowers Designed for Potential Use in Dual Magnetic Hyperthermia/Radionuclide Cancer Therapy and Diagnosis" in ACS Applied Materials & Interfaces, 11, no. 44 (2019):41109-41117,
https://doi.org/10.1021/acsami.9b16428 . .

TY  - JOUR
AU  - Dimitrijević, Milena S.
AU  - Bogdanović-Pristov, Jelena
AU  - Žižić, Milan
AU  - Stanković, Dalibor M.
AU  - Bajuk-Bogdanović, Danica V.
AU  - Stanić, Marina
AU  - Spasić, Snežana D.
AU  - Hagen, Wilfred
AU  - Spasojević, Ivan
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8258
AB  - Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.
T2  - Dalton Transactions
T1  - Biliverdin-copper complex at physiological pH
VL  - 48
IS  - 18
SP  - 6061
EP  - 6070
DO  - 10.1039/c8dt04724c
ER  - 

@article{
author = "Dimitrijević, Milena S. and Bogdanović-Pristov, Jelena and Žižić, Milan and Stanković, Dalibor M. and Bajuk-Bogdanović, Danica V. and Stanić, Marina and Spasić, Snežana D. and Hagen, Wilfred and Spasojević, Ivan",
year = "2019",
abstract = "Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.",
journal = "Dalton Transactions",
title = "Biliverdin-copper complex at physiological pH",
volume = "48",
number = "18",
pages = "6061-6070",
doi = "10.1039/c8dt04724c"
}

Dimitrijević, M. S., Bogdanović-Pristov, J., Žižić, M., Stanković, D. M., Bajuk-Bogdanović, D. V., Stanić, M., Spasić, S. D., Hagen, W.,& Spasojević, I.. (2019). Biliverdin-copper complex at physiological pH. in Dalton Transactions, 48(18), 6061-6070.
https://doi.org/10.1039/c8dt04724c

Dimitrijević MS, Bogdanović-Pristov J, Žižić M, Stanković DM, Bajuk-Bogdanović DV, Stanić M, Spasić SD, Hagen W, Spasojević I. Biliverdin-copper complex at physiological pH. in Dalton Transactions. 2019;48(18):6061-6070.
doi:10.1039/c8dt04724c .

Dimitrijević, Milena S., Bogdanović-Pristov, Jelena, Žižić, Milan, Stanković, Dalibor M., Bajuk-Bogdanović, Danica V., Stanić, Marina, Spasić, Snežana D., Hagen, Wilfred, Spasojević, Ivan, "Biliverdin-copper complex at physiological pH" in Dalton Transactions, 48, no. 18 (2019):6061-6070,
https://doi.org/10.1039/c8dt04724c . .

TY  - JOUR
AU  - Dimitrijević, Milena S.
AU  - Bogdanović-Pristov, Jelena
AU  - Žižić, Milan
AU  - Stanković, Dalibor M.
AU  - Bajuk-Bogdanović, Danica V.
AU  - Stanić, Marina
AU  - Spasić, Snežana D.
AU  - Hagen, Wilfred
AU  - Spasojević, Ivan
PY  - 2019
UR  - http://cherry.chem.bg.ac.rs/handle/123456789/3066
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8200
AB  - Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.
T2  - Dalton Transactions
T1  - Biliverdin-copper complex at physiological pH
VL  - 48
IS  - 18
SP  - 6061
EP  - 6070
DO  - 10.1039/c8dt04724c
ER  - 

@article{
author = "Dimitrijević, Milena S. and Bogdanović-Pristov, Jelena and Žižić, Milan and Stanković, Dalibor M. and Bajuk-Bogdanović, Danica V. and Stanić, Marina and Spasić, Snežana D. and Hagen, Wilfred and Spasojević, Ivan",
year = "2019",
abstract = "Biliverdin (BV), a product of heme catabolism, is known to interact with transition metals, but the details of such interactions under physiological conditions are scarce. Herein, we examined coordinate/redox interactions of BV with Cu2+ in phosphate buffer at pH 7.4, using spectrophotometry, HESI-MS, Raman spectroscopy, 1 H NMR, EPR, fluorimetry, and electrochemical methods. BV formed a stable coordination complex with copper in 1 : 1 stoichiometry. The structure of BV was more planar and energetically stable in the complex. The complex showed strong paramagnetic effects that were attributed to an unpaired delocalized e−. The delocalized electron may come from BV or Cu2+, so the complex is formally composed either of BV radical cation and Cu1+ or of BV radical anion and Cu3+. The complex underwent oxidation only in the presence of both O2 and an excess of Cu2+, or a strong oxidizing agent, and it was resistant to reducing agents. The biological effects of the stable BV metallocomplex containing a delocalized unpaired electron should be further examined, and may provide an answer to the long-standing question of high energy investment in the catabolism of BV, which represents a relatively harmless molecule per se.",
journal = "Dalton Transactions",
title = "Biliverdin-copper complex at physiological pH",
volume = "48",
number = "18",
pages = "6061-6070",
doi = "10.1039/c8dt04724c"
}

Dimitrijević, M. S., Bogdanović-Pristov, J., Žižić, M., Stanković, D. M., Bajuk-Bogdanović, D. V., Stanić, M., Spasić, S. D., Hagen, W.,& Spasojević, I.. (2019). Biliverdin-copper complex at physiological pH. in Dalton Transactions, 48(18), 6061-6070.
https://doi.org/10.1039/c8dt04724c

Dimitrijević MS, Bogdanović-Pristov J, Žižić M, Stanković DM, Bajuk-Bogdanović DV, Stanić M, Spasić SD, Hagen W, Spasojević I. Biliverdin-copper complex at physiological pH. in Dalton Transactions. 2019;48(18):6061-6070.
doi:10.1039/c8dt04724c .

Dimitrijević, Milena S., Bogdanović-Pristov, Jelena, Žižić, Milan, Stanković, Dalibor M., Bajuk-Bogdanović, Danica V., Stanić, Marina, Spasić, Snežana D., Hagen, Wilfred, Spasojević, Ivan, "Biliverdin-copper complex at physiological pH" in Dalton Transactions, 48, no. 18 (2019):6061-6070,
https://doi.org/10.1039/c8dt04724c . .

TY  - JOUR
AU  - Jović-Jovičić, Nataša P.
AU  - Mojović, Miloš D.
AU  - Stanković, Dalibor M.
AU  - Vasiljević-Nedić, Bojana
AU  - Milutinović-Nikolić, Aleksandra D.
AU  - Banković, Predrag T.
AU  - Mojović, Zorica D.
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0013468618325039
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7979
AB  - Series of alkylammonium modified smectites with different alkylammoinum/clay ratios was synthesized (H series). The obtained organoclays were used as precursors for carbon-clay composite materials (C series). Both set of materials were characterized by X-ray diffraction (XRD), point of zero charge (pHPZC), N2 adsorption-desorption isotherms, Raman spectroscopy and electron paramagnetic resonance (EPR) analysis. XRD analysis of organomodified clays confirmed incorporation of HDTMA+ into interlamellar space of smectite. Series of carbonized clays showed constant d001 value of 1.4 nm. The pHPZC of two series differed indicating that carbonization changed the profile of pH dependent sites on the clay surface. Textural properties of the H series decreased throughout the series, while in the C series the most developed porous structure was obtained for sample where HDTMA+ loading was equal to cation exchange capacity. Raman spectroscopy showed that amorphous carbon was formed during carbonization process. The obtained materials were used as modifiers of carbon paste electrode and investigated using electrochemical impedance spectroscopy, cyclic voltammetry and square wave voltammetry. The comparison of electrochemical behavior of H series and C series showed the importance of interlamellar species for charge transfer process. The investigation of influence of composition of carbon paste and form of added carbon showed that performance of carbon-clay based electrodes depended on synergy of different factors. © 2018 Elsevier Ltd
T2  - Electrochimica Acta
T1  - Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay
VL  - 296
SP  - 387
EP  - 396
DO  - 10.1016/j.electacta.2018.11.031
ER  - 

@article{
author = "Jović-Jovičić, Nataša P. and Mojović, Miloš D. and Stanković, Dalibor M. and Vasiljević-Nedić, Bojana and Milutinović-Nikolić, Aleksandra D. and Banković, Predrag T. and Mojović, Zorica D.",
year = "2019",
abstract = "Series of alkylammonium modified smectites with different alkylammoinum/clay ratios was synthesized (H series). The obtained organoclays were used as precursors for carbon-clay composite materials (C series). Both set of materials were characterized by X-ray diffraction (XRD), point of zero charge (pHPZC), N2 adsorption-desorption isotherms, Raman spectroscopy and electron paramagnetic resonance (EPR) analysis. XRD analysis of organomodified clays confirmed incorporation of HDTMA+ into interlamellar space of smectite. Series of carbonized clays showed constant d001 value of 1.4 nm. The pHPZC of two series differed indicating that carbonization changed the profile of pH dependent sites on the clay surface. Textural properties of the H series decreased throughout the series, while in the C series the most developed porous structure was obtained for sample where HDTMA+ loading was equal to cation exchange capacity. Raman spectroscopy showed that amorphous carbon was formed during carbonization process. The obtained materials were used as modifiers of carbon paste electrode and investigated using electrochemical impedance spectroscopy, cyclic voltammetry and square wave voltammetry. The comparison of electrochemical behavior of H series and C series showed the importance of interlamellar species for charge transfer process. The investigation of influence of composition of carbon paste and form of added carbon showed that performance of carbon-clay based electrodes depended on synergy of different factors. © 2018 Elsevier Ltd",
journal = "Electrochimica Acta",
title = "Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay",
volume = "296",
pages = "387-396",
doi = "10.1016/j.electacta.2018.11.031"
}

Jović-Jovičić, N. P., Mojović, M. D., Stanković, D. M., Vasiljević-Nedić, B., Milutinović-Nikolić, A. D., Banković, P. T.,& Mojović, Z. D.. (2019). Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay. in Electrochimica Acta, 296, 387-396.
https://doi.org/10.1016/j.electacta.2018.11.031

Jović-Jovičić NP, Mojović MD, Stanković DM, Vasiljević-Nedić B, Milutinović-Nikolić AD, Banković PT, Mojović ZD. Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay. in Electrochimica Acta. 2019;296:387-396.
doi:10.1016/j.electacta.2018.11.031 .

Jović-Jovičić, Nataša P., Mojović, Miloš D., Stanković, Dalibor M., Vasiljević-Nedić, Bojana, Milutinović-Nikolić, Aleksandra D., Banković, Predrag T., Mojović, Zorica D., "Characterization and electrochemical properties of organomodified and corresponding derived carbonized clay" in Electrochimica Acta, 296 (2019):387-396,
https://doi.org/10.1016/j.electacta.2018.11.031 . .

TY  - JOUR
AU  - Mirković, Marija D.
AU  - Radović, Magdalena
AU  - Stanković, Dragana
AU  - Milanović, Zorana
AU  - Janković, Drina
AU  - Matović, Milovan D.
AU  - Jeremić, Marija
AU  - Antić, Bratislav
AU  - Vranješ-Đurić, Sanja
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8156
AB  - Novel theranostic nanoplatform is expected to integrate imaging for guiding and monitoring of the tumor therapy with great therapeutic efficacy and fewer side effects. Here we describe the preparation of a multifunctional 99mTc–bisphosphonate–coated magnetic nanoparticles (MNPs) based on Fe3O4 and coated with two hydrophilic bisphosphonate ligands, i.e., methylene diphosphonate (MDP) and 1–hydroxyethane-1,1- diphosphonate (HEDP). The presence of the bisphosphonates on the MNPs surface, enabled their biocompatibility, colloidal stability and successful binding of the radionuclide. The morphology, size, structure, surface charge and magnetic properties of obtained bisphosphonate–coated Fe3O4 MNPs were characterized by transmission electron microscopy, X–ray powder diffraction, dynamic light scattering, laser Doppler electrophoresis, Fourier transform infrared spectroscopy and vibrating sample magnetometer. The specific power absorption values for Fe3O4–MDP and Fe3O4–HEDP were 113 W/g and 141 W/g, respectively, indicated their heating ability under applied magnetic field. Coated MNPs were radiolabeled with 99mTc using stannous chloride as the reducing agent in a reproducible high yield (95% for Fe3O4–MDP and 97% for Fe3O4–HEDP MNPs) and were remained stable in saline and human serum for 24 h. Ex vivo biodistribution studies presented significant liver and spleen uptake in healthy Wistar rats after intravenous administration at all examined time points due to the colloidal nature of both 99mTc–MNPs. Results of scintigraphy studies are in accordance with ex vivo biodistribution studies, demonstrating high in vivo stability of radiolabeled MNPs and therefore results of both methods were proved as accurate information on the biodistribution profile of investigated MNPs. Overall, in vitro and in vivo stability as well as heating ability, indicate that biocompatible radiolabeled bisphosphonate magnetic nanoparticles exhibit promising potential as a theranostic nanoagent. © 2019 Elsevier B.V.
T2  - Materials Science and Engineering: C
T1  - 99mTc–bisphosphonate–coated magnetic nanoparticles as potential theranostic nanoagent
VL  - 102
SP  - 124
EP  - 133
DO  - 10.1016/j.msec.2019.04.034
ER  - 

@article{
author = "Mirković, Marija D. and Radović, Magdalena and Stanković, Dragana and Milanović, Zorana and Janković, Drina and Matović, Milovan D. and Jeremić, Marija and Antić, Bratislav and Vranješ-Đurić, Sanja",
year = "2019",
abstract = "Novel theranostic nanoplatform is expected to integrate imaging for guiding and monitoring of the tumor therapy with great therapeutic efficacy and fewer side effects. Here we describe the preparation of a multifunctional 99mTc–bisphosphonate–coated magnetic nanoparticles (MNPs) based on Fe3O4 and coated with two hydrophilic bisphosphonate ligands, i.e., methylene diphosphonate (MDP) and 1–hydroxyethane-1,1- diphosphonate (HEDP). The presence of the bisphosphonates on the MNPs surface, enabled their biocompatibility, colloidal stability and successful binding of the radionuclide. The morphology, size, structure, surface charge and magnetic properties of obtained bisphosphonate–coated Fe3O4 MNPs were characterized by transmission electron microscopy, X–ray powder diffraction, dynamic light scattering, laser Doppler electrophoresis, Fourier transform infrared spectroscopy and vibrating sample magnetometer. The specific power absorption values for Fe3O4–MDP and Fe3O4–HEDP were 113 W/g and 141 W/g, respectively, indicated their heating ability under applied magnetic field. Coated MNPs were radiolabeled with 99mTc using stannous chloride as the reducing agent in a reproducible high yield (95% for Fe3O4–MDP and 97% for Fe3O4–HEDP MNPs) and were remained stable in saline and human serum for 24 h. Ex vivo biodistribution studies presented significant liver and spleen uptake in healthy Wistar rats after intravenous administration at all examined time points due to the colloidal nature of both 99mTc–MNPs. Results of scintigraphy studies are in accordance with ex vivo biodistribution studies, demonstrating high in vivo stability of radiolabeled MNPs and therefore results of both methods were proved as accurate information on the biodistribution profile of investigated MNPs. Overall, in vitro and in vivo stability as well as heating ability, indicate that biocompatible radiolabeled bisphosphonate magnetic nanoparticles exhibit promising potential as a theranostic nanoagent. © 2019 Elsevier B.V.",
journal = "Materials Science and Engineering: C",
title = "99mTc–bisphosphonate–coated magnetic nanoparticles as potential theranostic nanoagent",
volume = "102",
pages = "124-133",
doi = "10.1016/j.msec.2019.04.034"
}

Mirković, M. D., Radović, M., Stanković, D., Milanović, Z., Janković, D., Matović, M. D., Jeremić, M., Antić, B.,& Vranješ-Đurić, S.. (2019). 99mTc–bisphosphonate–coated magnetic nanoparticles as potential theranostic nanoagent. in Materials Science and Engineering: C, 102, 124-133.
https://doi.org/10.1016/j.msec.2019.04.034

Mirković MD, Radović M, Stanković D, Milanović Z, Janković D, Matović MD, Jeremić M, Antić B, Vranješ-Đurić S. 99mTc–bisphosphonate–coated magnetic nanoparticles as potential theranostic nanoagent. in Materials Science and Engineering: C. 2019;102:124-133.
doi:10.1016/j.msec.2019.04.034 .

Mirković, Marija D., Radović, Magdalena, Stanković, Dragana, Milanović, Zorana, Janković, Drina, Matović, Milovan D., Jeremić, Marija, Antić, Bratislav, Vranješ-Đurić, Sanja, "99mTc–bisphosphonate–coated magnetic nanoparticles as potential theranostic nanoagent" in Materials Science and Engineering: C, 102 (2019):124-133,
https://doi.org/10.1016/j.msec.2019.04.034 . .

TY  - JOUR
AU  - Kusigerski, Vladan
AU  - Illés, Erzsébet
AU  - Blanuša, Jovan
AU  - Gyergyek, Sašo
AU  - Bošković, Marko
AU  - Perović, Marija M.
AU  - Spasojević, Vojislav
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7983
AB  - Ferrofluids based on magnesium substituted magnetite nanoparticles MgxFe3−xO4 (x = 0.1; 0.2; 0.4) were synthesised by a chemical co-precipitation method. Their physical properties have been compared with those of the magnetite based ferrofluid obtained by the same synthesis route. Both XRD and TEM studies showed particle size decrease with the increased Mg content while DLS experiments pointed to the more prominent aggregation of Mg-containing nanoparticles. Magnetic properties investigation conducted on the powder (i.e. dried) specimens showed decrease of magnetization values with increased Mg content except for the lowest concentration of x = 0.1 where substantial saturation magnetization rise of about 40% was recorded at room temperature. Heating abilities of the studied ferrofluids under the applied AC fields (SAR values) also showed decreasing trend with the increased Mg content even for x = 0.1 sample despite its elevated magnetization value. This trend has been understood as a consequence of the changed intrinsic nanoparticle properties such as size and magnetic anisotropy, as well as contribution of a collective behaviour due to an increased nanoparticle aggregation in Mg-doped systems.
T2  - Journal of Magnetism and Magnetic Materials
T1  - Magnetic properties and heating efficacy of magnesium doped magnetite nanoparticles obtained by co-precipitation method
VL  - 475
SP  - 470
EP  - 478
DO  - 10.1016/j.jmmm.2018.11.127
ER  - 

@article{
author = "Kusigerski, Vladan and Illés, Erzsébet and Blanuša, Jovan and Gyergyek, Sašo and Bošković, Marko and Perović, Marija M. and Spasojević, Vojislav",
year = "2019",
abstract = "Ferrofluids based on magnesium substituted magnetite nanoparticles MgxFe3−xO4 (x = 0.1; 0.2; 0.4) were synthesised by a chemical co-precipitation method. Their physical properties have been compared with those of the magnetite based ferrofluid obtained by the same synthesis route. Both XRD and TEM studies showed particle size decrease with the increased Mg content while DLS experiments pointed to the more prominent aggregation of Mg-containing nanoparticles. Magnetic properties investigation conducted on the powder (i.e. dried) specimens showed decrease of magnetization values with increased Mg content except for the lowest concentration of x = 0.1 where substantial saturation magnetization rise of about 40% was recorded at room temperature. Heating abilities of the studied ferrofluids under the applied AC fields (SAR values) also showed decreasing trend with the increased Mg content even for x = 0.1 sample despite its elevated magnetization value. This trend has been understood as a consequence of the changed intrinsic nanoparticle properties such as size and magnetic anisotropy, as well as contribution of a collective behaviour due to an increased nanoparticle aggregation in Mg-doped systems.",
journal = "Journal of Magnetism and Magnetic Materials",
title = "Magnetic properties and heating efficacy of magnesium doped magnetite nanoparticles obtained by co-precipitation method",
volume = "475",
pages = "470-478",
doi = "10.1016/j.jmmm.2018.11.127"
}

Kusigerski, V., Illés, E., Blanuša, J., Gyergyek, S., Bošković, M., Perović, M. M.,& Spasojević, V.. (2019). Magnetic properties and heating efficacy of magnesium doped magnetite nanoparticles obtained by co-precipitation method. in Journal of Magnetism and Magnetic Materials, 475, 470-478.
https://doi.org/10.1016/j.jmmm.2018.11.127

Kusigerski V, Illés E, Blanuša J, Gyergyek S, Bošković M, Perović MM, Spasojević V. Magnetic properties and heating efficacy of magnesium doped magnetite nanoparticles obtained by co-precipitation method. in Journal of Magnetism and Magnetic Materials. 2019;475:470-478.
doi:10.1016/j.jmmm.2018.11.127 .

Kusigerski, Vladan, Illés, Erzsébet, Blanuša, Jovan, Gyergyek, Sašo, Bošković, Marko, Perović, Marija M., Spasojević, Vojislav, "Magnetic properties and heating efficacy of magnesium doped magnetite nanoparticles obtained by co-precipitation method" in Journal of Magnetism and Magnetic Materials, 475 (2019):470-478,
https://doi.org/10.1016/j.jmmm.2018.11.127 . .

TY  - JOUR
AU  - Perić, Marko R.
AU  - Kyne, Sara H.
AU  - Gruden, Maja
AU  - Rodić, Marko V.
AU  - Jeremić, Dejan
AU  - Stanković, Dalibor M.
AU  - Brčeski, Ilija
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8381
AB  - In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.
T2  - Monatshefte fur Chemie
T1  - Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand
VL  - 150
IS  - 7
SP  - 1241
EP  - 1248
DO  - 10.1007/s00706-019-02405-7
ER  - 

@article{
author = "Perić, Marko R. and Kyne, Sara H. and Gruden, Maja and Rodić, Marko V. and Jeremić, Dejan and Stanković, Dalibor M. and Brčeski, Ilija",
year = "2019",
abstract = "In this work we present the synthesis, and experimental and theoretical analysis of a binuclear nickel(II) complex coordinated to a new phthalazine dihydrazone-based ligand. Single-crystal X-ray diffraction analysis of the metal complex shows that the coordination geometry around each nickel(II) atom is distorted octahedral. DFT calculations predict that the magnetic exchange coupling constant of the binuclear nickel(II) complex is predominantly anti-ferromagnetic.",
journal = "Monatshefte fur Chemie",
title = "Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand",
volume = "150",
number = "7",
pages = "1241-1248",
doi = "10.1007/s00706-019-02405-7"
}

Perić, M. R., Kyne, S. H., Gruden, M., Rodić, M. V., Jeremić, D., Stanković, D. M.,& Brčeski, I.. (2019). Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand. in Monatshefte fur Chemie, 150(7), 1241-1248.
https://doi.org/10.1007/s00706-019-02405-7

Perić MR, Kyne SH, Gruden M, Rodić MV, Jeremić D, Stanković DM, Brčeski I. Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand. in Monatshefte fur Chemie. 2019;150(7):1241-1248.
doi:10.1007/s00706-019-02405-7 .

Perić, Marko R., Kyne, Sara H., Gruden, Maja, Rodić, Marko V., Jeremić, Dejan, Stanković, Dalibor M., Brčeski, Ilija, "Synthesis, structural and DFT analysis of a binuclear nickel(II) complex with the 1,4-bis[2-[2-(diphenylphosphino)benzylidene]]phthalazinylhydrazone ligand" in Monatshefte fur Chemie, 150, no. 7 (2019):1241-1248,
https://doi.org/10.1007/s00706-019-02405-7 . .

TY  - JOUR
AU  - Vasić, Vesna M.
AU  - Gašić, Uroš M.
AU  - Stanković, Dalibor M.
AU  - Lušić, Dražen
AU  - Vukić-Lušić, Darija
AU  - Milojković-Opsenica, Dušanka M.
AU  - Tešić, Živoslav
AU  - Trifković, Jelena Đ.
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0308814618316169
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7868
AB  - Concerning the particular nutritive value of honeydew honey compared to blossom honey, and small number of studies defining botanical origin of honeydew honey, comprehensive analysis of phenolic profile of 64 honeydew honey samples of specific botanical origin was performed. Two advanced techniques of liquid chromatography hyphenated with mass spectrometry were used for identification of a total of 52 compounds and quantification of 25 of them. Pattern recognition analysis applied on data on phenolic compounds content confirmed that quercetin, naringenin, caffeoylquinic acid, hydroxyphenylacetic acid, apigenin and genistein, could be considered as potential markers of botanical origin of honeydew honey. Spectroscopic and electrochemical approaches were applied for the evaluation of the antioxidant capacity. Quercus sps. samples, Quercus frainetto and Quercus ilex, showed high biological activity and specific chemical composition. Additionally, cyclic voltammetry profiles were used for characterization and natural clustering of honeydew honey for the first time. © 2018 Elsevier Ltd
T2  - Food Chemistry
T1  - Towards better quality criteria of European honeydew honey: Phenolic profile and antioxidant capacity
VL  - 274
SP  - 629
EP  - 641
DO  - 10.1016/j.foodchem.2018.09.045
ER  - 

@article{
author = "Vasić, Vesna M. and Gašić, Uroš M. and Stanković, Dalibor M. and Lušić, Dražen and Vukić-Lušić, Darija and Milojković-Opsenica, Dušanka M. and Tešić, Živoslav and Trifković, Jelena Đ.",
year = "2019",
abstract = "Concerning the particular nutritive value of honeydew honey compared to blossom honey, and small number of studies defining botanical origin of honeydew honey, comprehensive analysis of phenolic profile of 64 honeydew honey samples of specific botanical origin was performed. Two advanced techniques of liquid chromatography hyphenated with mass spectrometry were used for identification of a total of 52 compounds and quantification of 25 of them. Pattern recognition analysis applied on data on phenolic compounds content confirmed that quercetin, naringenin, caffeoylquinic acid, hydroxyphenylacetic acid, apigenin and genistein, could be considered as potential markers of botanical origin of honeydew honey. Spectroscopic and electrochemical approaches were applied for the evaluation of the antioxidant capacity. Quercus sps. samples, Quercus frainetto and Quercus ilex, showed high biological activity and specific chemical composition. Additionally, cyclic voltammetry profiles were used for characterization and natural clustering of honeydew honey for the first time. © 2018 Elsevier Ltd",
journal = "Food Chemistry",
title = "Towards better quality criteria of European honeydew honey: Phenolic profile and antioxidant capacity",
volume = "274",
pages = "629-641",
doi = "10.1016/j.foodchem.2018.09.045"
}

Vasić, V. M., Gašić, U. M., Stanković, D. M., Lušić, D., Vukić-Lušić, D., Milojković-Opsenica, D. M., Tešić, Ž.,& Trifković, J. Đ.. (2019). Towards better quality criteria of European honeydew honey: Phenolic profile and antioxidant capacity. in Food Chemistry, 274, 629-641.
https://doi.org/10.1016/j.foodchem.2018.09.045

Vasić VM, Gašić UM, Stanković DM, Lušić D, Vukić-Lušić D, Milojković-Opsenica DM, Tešić Ž, Trifković JĐ. Towards better quality criteria of European honeydew honey: Phenolic profile and antioxidant capacity. in Food Chemistry. 2019;274:629-641.
doi:10.1016/j.foodchem.2018.09.045 .

Vasić, Vesna M., Gašić, Uroš M., Stanković, Dalibor M., Lušić, Dražen, Vukić-Lušić, Darija, Milojković-Opsenica, Dušanka M., Tešić, Živoslav, Trifković, Jelena Đ., "Towards better quality criteria of European honeydew honey: Phenolic profile and antioxidant capacity" in Food Chemistry, 274 (2019):629-641,
https://doi.org/10.1016/j.foodchem.2018.09.045 . .

TY  - JOUR
AU  - Pavić, Aleksandar B.
AU  - Savić, Nada D.
AU  - Glišić, Biljana Đ.
AU  - Crochet, Aurélien
AU  - Vojnović, Sandra
AU  - Kurutos, Atanas
AU  - Stanković, Dalibor M.
AU  - Fromm, Katharina M.
AU  - Nikodinović-Runić, Jasmina
AU  - Đuran, Miloš I.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8127
AB  - Five novel silver(I) complexes with 4,7-phenanthroline (4,7-phen), [Ag(NO 3 -O)(4,7-phen-μ-N4,N7)] n (1), [Ag(ClO 4 -О)(4,7-phen-μ-N4,N7)] n (2), [Ag(CF 3 COO-O)(4,7-phen-μ-N4,N7)] n (3), [Ag 2 (H 2 O) 0.58 (4,7-phen) 3 ](SbF 6 ) 2 (4) and {[Ag 2 (H 2 O)(4,7-phen-μ-N4,N7) 2 ](BF 4 ) 2 } n (5) were synthesized, structurally elucidated and biologically evaluated. These complexes showed selectivity towards Candida spp. in comparison to the tested bacteria and effectively inhibited the growth of four different Candida species, particularly of C. albicans strains, with minimal inhibitory concentrations (MICs) in the range of 2.0–10.0 μM. In order to evaluate the therapeutic potential of 1–5, in vivo toxicity studies were conducted in the zebrafish model. Based on the favorable therapeutic profiles, complexes 1, 3 and 5 were selected for the evaluation of their antifungal efficacy in vivo using the zebrafish model of lethal disseminated candidiasis. Complexes 1 and 3 efficiently controlled and prevented fungal filamentation even at sub-MIC doses, while drastically increased the survival of the infected embryos. Moreover, at the MIC doses, both complexes totally prevented C. albicans filamentation and rescued almost all infected fish of the fatal infection outcome. On the other side, complex 5, which demonstrated the highest antifungal activity in vitro, affected the neutrophils occurrence of the infected host, failed to inhibit the C. albicans cells filamentation and showed a poor potential to cure candidal infection, highlighting the importance of the in vivo activity evaluation early in the therapeutic design and development process. The mechanism of action of the investigated silver(I) complexes was related to the induction of reactive oxygen species (ROS) response in C. albicans, with DNA being one of the possible target biomolecules. © 2019 Elsevier Inc.
T2  - Journal of Inorganic Biochemistry
T1  - Silver(I) complexes with 4,7-phenanthroline efficient in rescuing the zebrafish embryos of lethal Candida albicans infection
VL  - 195
SP  - 149
EP  - 163
DO  - 10.1016/j.jinorgbio.2019.03.017
ER  - 

@article{
author = "Pavić, Aleksandar B. and Savić, Nada D. and Glišić, Biljana Đ. and Crochet, Aurélien and Vojnović, Sandra and Kurutos, Atanas and Stanković, Dalibor M. and Fromm, Katharina M. and Nikodinović-Runić, Jasmina and Đuran, Miloš I.",
year = "2019",
abstract = "Five novel silver(I) complexes with 4,7-phenanthroline (4,7-phen), [Ag(NO 3 -O)(4,7-phen-μ-N4,N7)] n (1), [Ag(ClO 4 -О)(4,7-phen-μ-N4,N7)] n (2), [Ag(CF 3 COO-O)(4,7-phen-μ-N4,N7)] n (3), [Ag 2 (H 2 O) 0.58 (4,7-phen) 3 ](SbF 6 ) 2 (4) and {[Ag 2 (H 2 O)(4,7-phen-μ-N4,N7) 2 ](BF 4 ) 2 } n (5) were synthesized, structurally elucidated and biologically evaluated. These complexes showed selectivity towards Candida spp. in comparison to the tested bacteria and effectively inhibited the growth of four different Candida species, particularly of C. albicans strains, with minimal inhibitory concentrations (MICs) in the range of 2.0–10.0 μM. In order to evaluate the therapeutic potential of 1–5, in vivo toxicity studies were conducted in the zebrafish model. Based on the favorable therapeutic profiles, complexes 1, 3 and 5 were selected for the evaluation of their antifungal efficacy in vivo using the zebrafish model of lethal disseminated candidiasis. Complexes 1 and 3 efficiently controlled and prevented fungal filamentation even at sub-MIC doses, while drastically increased the survival of the infected embryos. Moreover, at the MIC doses, both complexes totally prevented C. albicans filamentation and rescued almost all infected fish of the fatal infection outcome. On the other side, complex 5, which demonstrated the highest antifungal activity in vitro, affected the neutrophils occurrence of the infected host, failed to inhibit the C. albicans cells filamentation and showed a poor potential to cure candidal infection, highlighting the importance of the in vivo activity evaluation early in the therapeutic design and development process. The mechanism of action of the investigated silver(I) complexes was related to the induction of reactive oxygen species (ROS) response in C. albicans, with DNA being one of the possible target biomolecules. © 2019 Elsevier Inc.",
journal = "Journal of Inorganic Biochemistry",
title = "Silver(I) complexes with 4,7-phenanthroline efficient in rescuing the zebrafish embryos of lethal Candida albicans infection",
volume = "195",
pages = "149-163",
doi = "10.1016/j.jinorgbio.2019.03.017"
}

Pavić, A. B., Savić, N. D., Glišić, B. Đ., Crochet, A., Vojnović, S., Kurutos, A., Stanković, D. M., Fromm, K. M., Nikodinović-Runić, J.,& Đuran, M. I.. (2019). Silver(I) complexes with 4,7-phenanthroline efficient in rescuing the zebrafish embryos of lethal Candida albicans infection. in Journal of Inorganic Biochemistry, 195, 149-163.
https://doi.org/10.1016/j.jinorgbio.2019.03.017

Pavić AB, Savić ND, Glišić BĐ, Crochet A, Vojnović S, Kurutos A, Stanković DM, Fromm KM, Nikodinović-Runić J, Đuran MI. Silver(I) complexes with 4,7-phenanthroline efficient in rescuing the zebrafish embryos of lethal Candida albicans infection. in Journal of Inorganic Biochemistry. 2019;195:149-163.
doi:10.1016/j.jinorgbio.2019.03.017 .

Pavić, Aleksandar B., Savić, Nada D., Glišić, Biljana Đ., Crochet, Aurélien, Vojnović, Sandra, Kurutos, Atanas, Stanković, Dalibor M., Fromm, Katharina M., Nikodinović-Runić, Jasmina, Đuran, Miloš I., "Silver(I) complexes with 4,7-phenanthroline efficient in rescuing the zebrafish embryos of lethal Candida albicans infection" in Journal of Inorganic Biochemistry, 195 (2019):149-163,
https://doi.org/10.1016/j.jinorgbio.2019.03.017 . .

TY  - DATA
AU  - Pavić, Aleksandar B.
AU  - Savić, Nada D.
AU  - Glišić, Biljana Đ.
AU  - Crochet, Aurélien
AU  - Vojnović, Sandra
AU  - Kurutos, Atanas
AU  - Stanković, Dalibor M.
AU  - Fromm, Katharina M.
AU  - Nikodinović-Runić, Jasmina
AU  - Đuran, Miloš I.
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8130
AB  - Data associated with the article "Pavic, A., Savić, N. D., Glišić, B. Đ., Crochet, A., Vojnovic, S., Kurutos, A., ... & Djuran, M. I. (2019). Silver (I) complexes with 4, 7-phenanthroline efficient in rescuing the zebrafish embryos of lethal Candida albicans infection. Journal of Inorganic Biochemistry."
T2  - The Cambridge Crystallographic Data Centre (CCDC)
T1  - CCDC 1879001: Experimental Crystal Structure Determination
DO  - 10.5517/ccdc.csd.cc2127yb
ER  - 

@misc{
author = "Pavić, Aleksandar B. and Savić, Nada D. and Glišić, Biljana Đ. and Crochet, Aurélien and Vojnović, Sandra and Kurutos, Atanas and Stanković, Dalibor M. and Fromm, Katharina M. and Nikodinović-Runić, Jasmina and Đuran, Miloš I.",
year = "2019",
abstract = "Data associated with the article "Pavic, A., Savić, N. D., Glišić, B. Đ., Crochet, A., Vojnovic, S., Kurutos, A., ... & Djuran, M. I. (2019). Silver (I) complexes with 4, 7-phenanthroline efficient in rescuing the zebrafish embryos of lethal Candida albicans infection. Journal of Inorganic Biochemistry."",
journal = "The Cambridge Crystallographic Data Centre (CCDC)",
title = "CCDC 1879001: Experimental Crystal Structure Determination",
doi = "10.5517/ccdc.csd.cc2127yb"
}

Pavić, A. B., Savić, N. D., Glišić, B. Đ., Crochet, A., Vojnović, S., Kurutos, A., Stanković, D. M., Fromm, K. M., Nikodinović-Runić, J.,& Đuran, M. I.. (2019). CCDC 1879001: Experimental Crystal Structure Determination. in The Cambridge Crystallographic Data Centre (CCDC).
https://doi.org/10.5517/ccdc.csd.cc2127yb

Pavić AB, Savić ND, Glišić BĐ, Crochet A, Vojnović S, Kurutos A, Stanković DM, Fromm KM, Nikodinović-Runić J, Đuran MI. CCDC 1879001: Experimental Crystal Structure Determination. in The Cambridge Crystallographic Data Centre (CCDC). 2019;.
doi:10.5517/ccdc.csd.cc2127yb .

Pavić, Aleksandar B., Savić, Nada D., Glišić, Biljana Đ., Crochet, Aurélien, Vojnović, Sandra, Kurutos, Atanas, Stanković, Dalibor M., Fromm, Katharina M., Nikodinović-Runić, Jasmina, Đuran, Miloš I., "CCDC 1879001: Experimental Crystal Structure Determination" in The Cambridge Crystallographic Data Centre (CCDC) (2019),
https://doi.org/10.5517/ccdc.csd.cc2127yb . .

TY  - JOUR
AU  - Vukojević, Vesna
AU  - Đurđić, Slađana
AU  - Ognjanović, Miloš
AU  - Fabian, Martin
AU  - Samphao, Anchalee
AU  - Kalcher, Kurt
AU  - Stanković, Dalibor M.
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S157266571830479X
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7780
AB  - A disposable glucose biosensor was prepared using nanoparticles of MnO2 decorated on graphene nanoribbons by surface modification with drop coating with the GOx and Nafion®. Tested material was synthesized and characterized using several techniques. The biosensor could be operated under physiological conditions (0.1 M phosphate buffer, pH 7.4) and exhibited good reproducibility and stability. The linear range for the amperometric response of the biosensor at operating potential of +0.50 (versus Ag/AgCl) was from 0.1 to 1.4 mmol/l, with a detection limit of 0.05 mmol/l and high sensitivity of 56.32 μA/mmol cm2. Developed method was tested toward glucose quantification in real samples with satisfactory accuracy and precision.
T2  - Journal of Electroanalytical Chemistry
T1  - Enzymatic glucose biosensor based on manganese dioxide nanoparticles decorated on graphene nanoribbons
VL  - 823
SP  - 610
EP  - 616
DO  - 10.1016/j.jelechem.2018.07.013
ER  - 

@article{
author = "Vukojević, Vesna and Đurđić, Slađana and Ognjanović, Miloš and Fabian, Martin and Samphao, Anchalee and Kalcher, Kurt and Stanković, Dalibor M.",
year = "2018",
abstract = "A disposable glucose biosensor was prepared using nanoparticles of MnO2 decorated on graphene nanoribbons by surface modification with drop coating with the GOx and Nafion®. Tested material was synthesized and characterized using several techniques. The biosensor could be operated under physiological conditions (0.1 M phosphate buffer, pH 7.4) and exhibited good reproducibility and stability. The linear range for the amperometric response of the biosensor at operating potential of +0.50 (versus Ag/AgCl) was from 0.1 to 1.4 mmol/l, with a detection limit of 0.05 mmol/l and high sensitivity of 56.32 μA/mmol cm2. Developed method was tested toward glucose quantification in real samples with satisfactory accuracy and precision.",
journal = "Journal of Electroanalytical Chemistry",
title = "Enzymatic glucose biosensor based on manganese dioxide nanoparticles decorated on graphene nanoribbons",
volume = "823",
pages = "610-616",
doi = "10.1016/j.jelechem.2018.07.013"
}

Vukojević, V., Đurđić, S., Ognjanović, M., Fabian, M., Samphao, A., Kalcher, K.,& Stanković, D. M.. (2018). Enzymatic glucose biosensor based on manganese dioxide nanoparticles decorated on graphene nanoribbons. in Journal of Electroanalytical Chemistry, 823, 610-616.
https://doi.org/10.1016/j.jelechem.2018.07.013

Vukojević V, Đurđić S, Ognjanović M, Fabian M, Samphao A, Kalcher K, Stanković DM. Enzymatic glucose biosensor based on manganese dioxide nanoparticles decorated on graphene nanoribbons. in Journal of Electroanalytical Chemistry. 2018;823:610-616.
doi:10.1016/j.jelechem.2018.07.013 .

Vukojević, Vesna, Đurđić, Slađana, Ognjanović, Miloš, Fabian, Martin, Samphao, Anchalee, Kalcher, Kurt, Stanković, Dalibor M., "Enzymatic glucose biosensor based on manganese dioxide nanoparticles decorated on graphene nanoribbons" in Journal of Electroanalytical Chemistry, 823 (2018):610-616,
https://doi.org/10.1016/j.jelechem.2018.07.013 . .

TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor M.
AU  - Fabian, Martin
AU  - Vukadinović, Aleksandar
AU  - Prijović, Željko
AU  - Dojčinović, Biljana P.
AU  - Antić, Bratislav
PY  - 2018
UR  - http://doi.wiley.com/10.1002/elan.201800357
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7961
AB  - In this work facile one step synthesis of magnesium ferrite (MgFe2O4) nanoparticles decorated on reduced graphene oxide (MgFe@RGO) using a microwave assisted hydrothermal procedure is reported. The synthesized material was characterized with help of several techniques and applied for the modification of glassy carbon electrode. Such prepared electrode was utilized for successive simultaneous detection of structurally similar compounds, 1,2- and 1,4-dihydroxibenzenes (catechol (CC) and hydroquinone (HQ)), using differential pulse voltammetry technique. It was found that oxidation current increases linearly with the concentrations of both investigated compounds. Detection limits for both species are ≤0.31 μM. The best analytical response in the presence of both CC and HQ, taking into account peak shape and peak current, was obtained at pH 5.6 utilizing acetate buffer solution. The often-presented species in the surface waters as well as gallic acid and caffeine do not interfere with determination of CC and HQ, while ascorbic acid shows high interference. The method is successfully applied for detection of catechol and hydroquinone in real samples analyses. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
T2  - Electroanalysis
T1  - A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone
VL  - 30
IS  - 11
SP  - 2620
EP  - 2627
DO  - 10.1002/elan.201800357
ER  - 

@article{
author = "Ognjanović, Miloš and Stanković, Dalibor M. and Fabian, Martin and Vukadinović, Aleksandar and Prijović, Željko and Dojčinović, Biljana P. and Antić, Bratislav",
year = "2018",
abstract = "In this work facile one step synthesis of magnesium ferrite (MgFe2O4) nanoparticles decorated on reduced graphene oxide (MgFe@RGO) using a microwave assisted hydrothermal procedure is reported. The synthesized material was characterized with help of several techniques and applied for the modification of glassy carbon electrode. Such prepared electrode was utilized for successive simultaneous detection of structurally similar compounds, 1,2- and 1,4-dihydroxibenzenes (catechol (CC) and hydroquinone (HQ)), using differential pulse voltammetry technique. It was found that oxidation current increases linearly with the concentrations of both investigated compounds. Detection limits for both species are ≤0.31 μM. The best analytical response in the presence of both CC and HQ, taking into account peak shape and peak current, was obtained at pH 5.6 utilizing acetate buffer solution. The often-presented species in the surface waters as well as gallic acid and caffeine do not interfere with determination of CC and HQ, while ascorbic acid shows high interference. The method is successfully applied for detection of catechol and hydroquinone in real samples analyses. © 2018 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim",
journal = "Electroanalysis",
title = "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone",
volume = "30",
number = "11",
pages = "2620-2627",
doi = "10.1002/elan.201800357"
}

Ognjanović, M., Stanković, D. M., Fabian, M., Vukadinović, A., Prijović, Ž., Dojčinović, B. P.,& Antić, B.. (2018). A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone. in Electroanalysis, 30(11), 2620-2627.
https://doi.org/10.1002/elan.201800357

Ognjanović M, Stanković DM, Fabian M, Vukadinović A, Prijović Ž, Dojčinović BP, Antić B. A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone. in Electroanalysis. 2018;30(11):2620-2627.
doi:10.1002/elan.201800357 .

Ognjanović, Miloš, Stanković, Dalibor M., Fabian, Martin, Vukadinović, Aleksandar, Prijović, Željko, Dojčinović, Biljana P., Antić, Bratislav, "A Voltammetric Sensor Based on MgFe2O4 Decorated on Reduced Graphene Oxide-modified Electrode for Sensitive and Simultaneous Determination of Catechol and Hydroquinone" in Electroanalysis, 30, no. 11 (2018):2620-2627,
https://doi.org/10.1002/elan.201800357 . .

TY  - JOUR
AU  - Jevtić, Sonja
AU  - Vukojević, Vesna
AU  - Đurđić, Slađana
AU  - Pergal, Marija V.
AU  - Manojlović, Dragan D.
AU  - Petković, Branka B.
AU  - Stanković, Dalibor M.
PY  - 2018
UR  - http://linkinghub.elsevier.com/retrieve/pii/S0013468618310089
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7689
AB  - This work present a new approach for the detection of relatively new herbicide pethoxamid (POA), a first electrochemical behavior and determination based on its oxidation on boron-doped diamond electrode in Britton-Robinson buffer solution at pH 4. Square wave voltammetric technique was used for quantification of POA at anodic potential of 1.35 V vs reference Ag/AgCl electrode. The proposed electroanalytical method is operational in the linear working range from 3 to 100 μM of POA with a limit of detection of 1.37 μM. The developed analytical procedure was successfully tested for determination of this herbicide in standard/spiked river water samples and commercial herbicide Successor T SE/spiked river water samples, offering a simple, fast and inexpensive alternative way of pesticide determining to chromatographic methods employed for this purpose.
T2  - Electrochimica Acta
T1  - First electrochemistry of herbicide pethoxamid and its quantification using electroanalytical approach from mixed commercial product
VL  - 277
SP  - 136
EP  - 142
DO  - 10.1016/j.electacta.2018.05.004
ER  - 

@article{
author = "Jevtić, Sonja and Vukojević, Vesna and Đurđić, Slađana and Pergal, Marija V. and Manojlović, Dragan D. and Petković, Branka B. and Stanković, Dalibor M.",
year = "2018",
abstract = "This work present a new approach for the detection of relatively new herbicide pethoxamid (POA), a first electrochemical behavior and determination based on its oxidation on boron-doped diamond electrode in Britton-Robinson buffer solution at pH 4. Square wave voltammetric technique was used for quantification of POA at anodic potential of 1.35 V vs reference Ag/AgCl electrode. The proposed electroanalytical method is operational in the linear working range from 3 to 100 μM of POA with a limit of detection of 1.37 μM. The developed analytical procedure was successfully tested for determination of this herbicide in standard/spiked river water samples and commercial herbicide Successor T SE/spiked river water samples, offering a simple, fast and inexpensive alternative way of pesticide determining to chromatographic methods employed for this purpose.",
journal = "Electrochimica Acta",
title = "First electrochemistry of herbicide pethoxamid and its quantification using electroanalytical approach from mixed commercial product",
volume = "277",
pages = "136-142",
doi = "10.1016/j.electacta.2018.05.004"
}

Jevtić, S., Vukojević, V., Đurđić, S., Pergal, M. V., Manojlović, D. D., Petković, B. B.,& Stanković, D. M.. (2018). First electrochemistry of herbicide pethoxamid and its quantification using electroanalytical approach from mixed commercial product. in Electrochimica Acta, 277, 136-142.
https://doi.org/10.1016/j.electacta.2018.05.004

Jevtić S, Vukojević V, Đurđić S, Pergal MV, Manojlović DD, Petković BB, Stanković DM. First electrochemistry of herbicide pethoxamid and its quantification using electroanalytical approach from mixed commercial product. in Electrochimica Acta. 2018;277:136-142.
doi:10.1016/j.electacta.2018.05.004 .

Jevtić, Sonja, Vukojević, Vesna, Đurđić, Slađana, Pergal, Marija V., Manojlović, Dragan D., Petković, Branka B., Stanković, Dalibor M., "First electrochemistry of herbicide pethoxamid and its quantification using electroanalytical approach from mixed commercial product" in Electrochimica Acta, 277 (2018):136-142,
https://doi.org/10.1016/j.electacta.2018.05.004 . .

TY  - JOUR
AU  - Pergal, Marija V.
AU  - Kodranov, Igor D.
AU  - Pergal, Miodrag M.
AU  - Dojčinović, Biljana P.
AU  - Stanković, Dalibor M.
AU  - Petković, Branka B.
AU  - Manojlović, Dragan D.
PY  - 2018
UR  - http://link.springer.com/10.1007/s11270-018-3947-2
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7847
AB  - The degradation of two sulfonylurea herbicides, nicosulfuron and thifensulfuron methyl in water by chlorine dioxide, was studied for the first time in this paper. In order to examine the optimal parameters for degradation of both herbicides, degradation was investigated under light or dark conditions with different amount of chlorine dioxide, different degradation periods, and at different pH values. Degradation efficiency of herbicides was monitored using high-performance liquid chromatography with photodiode array detection (HPLC-DAD). The degradation products were analyzed by gas chromatography with triple quadrupole mass detector (GC–QQQ). Three products were identified after degradation of nicosulfuron and two products after degradation of thifensulfuron methyl. Total organic analysis (TOC) gave insight into some differences in degradation mechanisms and degrees of mineralization after degradation of the herbicides using chlorine dioxide. A simple mechanism of herbicide degradation was proposed. Acute toxicity tests were performed on the products produced after degradation with chlorine dioxide, and the results showed that the degradation products were less toxic than the parent compounds. The findings of the present study are very useful for the treatment of wastewaters contaminated with herbicides. © 2018, Springer Nature Switzerland AG.
T2  - Water, Air, & Soil Pollution
T1  - Assessment of Degradation of Sulfonylurea Herbicides in Water by Chlorine Dioxide
VL  - 229
IS  - 9
SP  - 287
DO  - 10.1007/s11270-018-3947-2
ER  - 

@article{
author = "Pergal, Marija V. and Kodranov, Igor D. and Pergal, Miodrag M. and Dojčinović, Biljana P. and Stanković, Dalibor M. and Petković, Branka B. and Manojlović, Dragan D.",
year = "2018",
abstract = "The degradation of two sulfonylurea herbicides, nicosulfuron and thifensulfuron methyl in water by chlorine dioxide, was studied for the first time in this paper. In order to examine the optimal parameters for degradation of both herbicides, degradation was investigated under light or dark conditions with different amount of chlorine dioxide, different degradation periods, and at different pH values. Degradation efficiency of herbicides was monitored using high-performance liquid chromatography with photodiode array detection (HPLC-DAD). The degradation products were analyzed by gas chromatography with triple quadrupole mass detector (GC–QQQ). Three products were identified after degradation of nicosulfuron and two products after degradation of thifensulfuron methyl. Total organic analysis (TOC) gave insight into some differences in degradation mechanisms and degrees of mineralization after degradation of the herbicides using chlorine dioxide. A simple mechanism of herbicide degradation was proposed. Acute toxicity tests were performed on the products produced after degradation with chlorine dioxide, and the results showed that the degradation products were less toxic than the parent compounds. The findings of the present study are very useful for the treatment of wastewaters contaminated with herbicides. © 2018, Springer Nature Switzerland AG.",
journal = "Water, Air, & Soil Pollution",
title = "Assessment of Degradation of Sulfonylurea Herbicides in Water by Chlorine Dioxide",
volume = "229",
number = "9",
pages = "287",
doi = "10.1007/s11270-018-3947-2"
}

Pergal, M. V., Kodranov, I. D., Pergal, M. M., Dojčinović, B. P., Stanković, D. M., Petković, B. B.,& Manojlović, D. D.. (2018). Assessment of Degradation of Sulfonylurea Herbicides in Water by Chlorine Dioxide. in Water, Air, & Soil Pollution, 229(9), 287.
https://doi.org/10.1007/s11270-018-3947-2

Pergal MV, Kodranov ID, Pergal MM, Dojčinović BP, Stanković DM, Petković BB, Manojlović DD. Assessment of Degradation of Sulfonylurea Herbicides in Water by Chlorine Dioxide. in Water, Air, & Soil Pollution. 2018;229(9):287.
doi:10.1007/s11270-018-3947-2 .

Pergal, Marija V., Kodranov, Igor D., Pergal, Miodrag M., Dojčinović, Biljana P., Stanković, Dalibor M., Petković, Branka B., Manojlović, Dragan D., "Assessment of Degradation of Sulfonylurea Herbicides in Water by Chlorine Dioxide" in Water, Air, & Soil Pollution, 229, no. 9 (2018):287,
https://doi.org/10.1007/s11270-018-3947-2 . .

TY  - JOUR
AU  - Mihajlović-Lalić, Ljiljana E.
AU  - Stanković, Dalibor M.
AU  - Poljarević, Jelena M.
AU  - Sabo, Tibor J.
AU  - Manojlović, Dragan D.
PY  - 2018
UR  - http://jes.ecsdl.org/lookup/doi/10.1149/2.1121810jes
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7892
AB  - The electrochemical behavior of four dialkyl esters (methyl, ethyl, n-propyl and n-butyl) of (S,S)-α,α ′-(1,2-ethanediyldiimino)- bis[cyclohexanepropanoic acid] with moderate antitumor activity has been studied by cyclic voltammetry. I-E curves recorded at boron-doped diamond electrode in -2.00 < Ep < 0.00 V range show a single oxidative peak located in the -0.95 < Ep,a < -0.52 V region in a form of one-electron wave. The electrochemical processes appear to be irreversible for all compounds except for the compound with methyl substituent which demonstrates well-defined reversible electron transfer. Derivatives with bulkier moieties are easier to oxidize. For all investigated compounds an amine-centered redox process is dominant. Further investigation indicates that electrochemical reaction is diffusion controlled, chemically irreversible process. The results are discussed in terms of linking their electrochemical activity to antitumor effect. © 2018 The Electrochemical Society.
T2  - Journal of The Electrochemical Society
T1  - Voltammetric Study of Antitumor Efficient Ethylenediamine-Type of Ligands
VL  - 165
IS  - 10
SP  - G123
EP  - G127
DO  - 10.1149/2.1121810jes
ER  - 

@article{
author = "Mihajlović-Lalić, Ljiljana E. and Stanković, Dalibor M. and Poljarević, Jelena M. and Sabo, Tibor J. and Manojlović, Dragan D.",
year = "2018",
abstract = "The electrochemical behavior of four dialkyl esters (methyl, ethyl, n-propyl and n-butyl) of (S,S)-α,α ′-(1,2-ethanediyldiimino)- bis[cyclohexanepropanoic acid] with moderate antitumor activity has been studied by cyclic voltammetry. I-E curves recorded at boron-doped diamond electrode in -2.00 < Ep < 0.00 V range show a single oxidative peak located in the -0.95 < Ep,a < -0.52 V region in a form of one-electron wave. The electrochemical processes appear to be irreversible for all compounds except for the compound with methyl substituent which demonstrates well-defined reversible electron transfer. Derivatives with bulkier moieties are easier to oxidize. For all investigated compounds an amine-centered redox process is dominant. Further investigation indicates that electrochemical reaction is diffusion controlled, chemically irreversible process. The results are discussed in terms of linking their electrochemical activity to antitumor effect. © 2018 The Electrochemical Society.",
journal = "Journal of The Electrochemical Society",
title = "Voltammetric Study of Antitumor Efficient Ethylenediamine-Type of Ligands",
volume = "165",
number = "10",
pages = "G123-G127",
doi = "10.1149/2.1121810jes"
}

Mihajlović-Lalić, L. E., Stanković, D. M., Poljarević, J. M., Sabo, T. J.,& Manojlović, D. D.. (2018). Voltammetric Study of Antitumor Efficient Ethylenediamine-Type of Ligands. in Journal of The Electrochemical Society, 165(10), G123-G127.
https://doi.org/10.1149/2.1121810jes

Mihajlović-Lalić LE, Stanković DM, Poljarević JM, Sabo TJ, Manojlović DD. Voltammetric Study of Antitumor Efficient Ethylenediamine-Type of Ligands. in Journal of The Electrochemical Society. 2018;165(10):G123-G127.
doi:10.1149/2.1121810jes .

Mihajlović-Lalić, Ljiljana E., Stanković, Dalibor M., Poljarević, Jelena M., Sabo, Tibor J., Manojlović, Dragan D., "Voltammetric Study of Antitumor Efficient Ethylenediamine-Type of Ligands" in Journal of The Electrochemical Society, 165, no. 10 (2018):G123-G127,
https://doi.org/10.1149/2.1121810jes . .

TY  - JOUR
AU  - Korać, Jelena
AU  - Stanković, Dalibor M.
AU  - Stanić, Marina
AU  - Bajuk-Bogdanović, Danica V.
AU  - Žižić, Milan
AU  - Bogdanović-Pristov, Jelena
AU  - Grgurić-Šipka, Sanja
AU  - Popović-Bijelić, Ana D.
AU  - Spasojević, Ivan
PY  - 2018
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7582
AB  - Coordinate and redox interactions of epinephrine (Epi) with iron at physiological pH are essential for understanding two very different phenomena - the detrimental effects of chronic stress on the cardiovascular system and the cross-linking of catecholamine-rich biopolymers and frameworks. Here we show that Epi and Fe3+ form stable high-spin complexes in the 1:1 or 3:1 stoichiometry, depending on the Epi/Fe3+ concentration ratio (low or high). Oxygen atoms on the catechol ring represent the sites of coordinate bond formation within physiologically relevant bidentate 1:1 complex. Redox properties of Epi are slightly impacted by Fe3+. On the other hand, Epi and Fe2+ form a complex that acts as a strong reducing agent, which leads to the production of hydrogen peroxide via O-2 reduction, and to a facilitated formation of the Epi-Fe3+ complexes. Epi is not oxidized in this process, i.e. Fe2+ is not an electron shuttle, but the electron donor. Epi-catalyzed oxidation of Fe2+ represents a plausible chemical basis of stress-related damage to heart cells. In addition, our results support the previous findings on the interactions of catecholamine moieties in polymers with iron and provide a novel strategy for improving the efficiency of cross-linking.
T2  - Scientific Reports
T1  - Coordinate and redox interactions of epinephrine with ferric and ferrous iron at physiological pH
VL  - 8
SP  - 3530
DO  - 10.1038/s41598-018-21940-7
ER  - 

@article{
author = "Korać, Jelena and Stanković, Dalibor M. and Stanić, Marina and Bajuk-Bogdanović, Danica V. and Žižić, Milan and Bogdanović-Pristov, Jelena and Grgurić-Šipka, Sanja and Popović-Bijelić, Ana D. and Spasojević, Ivan",
year = "2018",
abstract = "Coordinate and redox interactions of epinephrine (Epi) with iron at physiological pH are essential for understanding two very different phenomena - the detrimental effects of chronic stress on the cardiovascular system and the cross-linking of catecholamine-rich biopolymers and frameworks. Here we show that Epi and Fe3+ form stable high-spin complexes in the 1:1 or 3:1 stoichiometry, depending on the Epi/Fe3+ concentration ratio (low or high). Oxygen atoms on the catechol ring represent the sites of coordinate bond formation within physiologically relevant bidentate 1:1 complex. Redox properties of Epi are slightly impacted by Fe3+. On the other hand, Epi and Fe2+ form a complex that acts as a strong reducing agent, which leads to the production of hydrogen peroxide via O-2 reduction, and to a facilitated formation of the Epi-Fe3+ complexes. Epi is not oxidized in this process, i.e. Fe2+ is not an electron shuttle, but the electron donor. Epi-catalyzed oxidation of Fe2+ represents a plausible chemical basis of stress-related damage to heart cells. In addition, our results support the previous findings on the interactions of catecholamine moieties in polymers with iron and provide a novel strategy for improving the efficiency of cross-linking.",
journal = "Scientific Reports",
title = "Coordinate and redox interactions of epinephrine with ferric and ferrous iron at physiological pH",
volume = "8",
pages = "3530",
doi = "10.1038/s41598-018-21940-7"
}

Korać, J., Stanković, D. M., Stanić, M., Bajuk-Bogdanović, D. V., Žižić, M., Bogdanović-Pristov, J., Grgurić-Šipka, S., Popović-Bijelić, A. D.,& Spasojević, I.. (2018). Coordinate and redox interactions of epinephrine with ferric and ferrous iron at physiological pH. in Scientific Reports, 8, 3530.
https://doi.org/10.1038/s41598-018-21940-7

Korać J, Stanković DM, Stanić M, Bajuk-Bogdanović DV, Žižić M, Bogdanović-Pristov J, Grgurić-Šipka S, Popović-Bijelić AD, Spasojević I. Coordinate and redox interactions of epinephrine with ferric and ferrous iron at physiological pH. in Scientific Reports. 2018;8:3530.
doi:10.1038/s41598-018-21940-7 .

Korać, Jelena, Stanković, Dalibor M., Stanić, Marina, Bajuk-Bogdanović, Danica V., Žižić, Milan, Bogdanović-Pristov, Jelena, Grgurić-Šipka, Sanja, Popović-Bijelić, Ana D., Spasojević, Ivan, "Coordinate and redox interactions of epinephrine with ferric and ferrous iron at physiological pH" in Scientific Reports, 8 (2018):3530,
https://doi.org/10.1038/s41598-018-21940-7 . .

TY  - JOUR
AU  - Božić, Bojana
AU  - Korać, Jelena
AU  - Stanković, Dalibor M.
AU  - Stanić, Marina
AU  - Romanović, Mima Č.
AU  - Bogdanović-Pristov, Jelena
AU  - Spasić, Snežana D.
AU  - Popović-Bijelić, Ana D.
AU  - Spasojević, Ivan
AU  - Bajčetić, Milica
PY  - 2018
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0891584918311213
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7896
AB  - An increase in the copper pool in body fluids has been related to a number of pathological conditions, including infections. Copper ions may affect antibiotics via the formation of coordination bonds and/or redox reactions. Herein, we analyzed the interactions of Cu2+ with eight β-lactam antibiotics using UV–Vis spectrophotometry, EPR spectroscopy, and electrochemical methods. Penicillin G did not show any detectable interactions with Cu2+. Ampicillin, amoxicillin and cephalexin formed stable colored complexes with octahedral coordination environment of Cu2+ with tetragonal distortion, and primary amine group as the site of coordinate bond formation. These β-lactams increased the solubility of Cu2+ in the phosphate buffer. Ceftazidime and Cu2+ formed a complex with a similar geometry and gave rise to an organic radical. Ceftriaxone-Cu2+ complex appears to exhibit different geometry. All complexes showed 1:1 stoichiometry. Cefaclor reduced Cu2+ to Cu1+ that further reacted with molecular oxygen to produce hydrogen peroxide. Finally, meropenem underwent degradation in the presence of copper. The analysis of activity against Escherichia coli and Staphylococcus aureus showed that the effects of meropenem, amoxicillin, ampicillin, and ceftriaxone were significantly hindered in the presence of copper ions. The interactions with copper ions should be taken into account regarding the problem of antibiotic resistance and in the selection of the most efficient antimicrobial therapy for patients with altered copper homeostasis. © 2018 Elsevier Inc.
T2  - Free Radical Biology and Medicine
T1  - Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity
VL  - 129
SP  - 279
EP  - 285
DO  - 10.1016/j.freeradbiomed.2018.09.038
ER  - 

@article{
author = "Božić, Bojana and Korać, Jelena and Stanković, Dalibor M. and Stanić, Marina and Romanović, Mima Č. and Bogdanović-Pristov, Jelena and Spasić, Snežana D. and Popović-Bijelić, Ana D. and Spasojević, Ivan and Bajčetić, Milica",
year = "2018",
abstract = "An increase in the copper pool in body fluids has been related to a number of pathological conditions, including infections. Copper ions may affect antibiotics via the formation of coordination bonds and/or redox reactions. Herein, we analyzed the interactions of Cu2+ with eight β-lactam antibiotics using UV–Vis spectrophotometry, EPR spectroscopy, and electrochemical methods. Penicillin G did not show any detectable interactions with Cu2+. Ampicillin, amoxicillin and cephalexin formed stable colored complexes with octahedral coordination environment of Cu2+ with tetragonal distortion, and primary amine group as the site of coordinate bond formation. These β-lactams increased the solubility of Cu2+ in the phosphate buffer. Ceftazidime and Cu2+ formed a complex with a similar geometry and gave rise to an organic radical. Ceftriaxone-Cu2+ complex appears to exhibit different geometry. All complexes showed 1:1 stoichiometry. Cefaclor reduced Cu2+ to Cu1+ that further reacted with molecular oxygen to produce hydrogen peroxide. Finally, meropenem underwent degradation in the presence of copper. The analysis of activity against Escherichia coli and Staphylococcus aureus showed that the effects of meropenem, amoxicillin, ampicillin, and ceftriaxone were significantly hindered in the presence of copper ions. The interactions with copper ions should be taken into account regarding the problem of antibiotic resistance and in the selection of the most efficient antimicrobial therapy for patients with altered copper homeostasis. © 2018 Elsevier Inc.",
journal = "Free Radical Biology and Medicine",
title = "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity",
volume = "129",
pages = "279-285",
doi = "10.1016/j.freeradbiomed.2018.09.038"
}

Božić, B., Korać, J., Stanković, D. M., Stanić, M., Romanović, M. Č., Bogdanović-Pristov, J., Spasić, S. D., Popović-Bijelić, A. D., Spasojević, I.,& Bajčetić, M.. (2018). Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity. in Free Radical Biology and Medicine, 129, 279-285.
https://doi.org/10.1016/j.freeradbiomed.2018.09.038

Božić B, Korać J, Stanković DM, Stanić M, Romanović MČ, Bogdanović-Pristov J, Spasić SD, Popović-Bijelić AD, Spasojević I, Bajčetić M. Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity. in Free Radical Biology and Medicine. 2018;129:279-285.
doi:10.1016/j.freeradbiomed.2018.09.038 .

Božić, Bojana, Korać, Jelena, Stanković, Dalibor M., Stanić, Marina, Romanović, Mima Č., Bogdanović-Pristov, Jelena, Spasić, Snežana D., Popović-Bijelić, Ana D., Spasojević, Ivan, Bajčetić, Milica, "Coordination and redox interactions of β-lactam antibiotics with Cu2+ in physiological settings and the impact on antibacterial activity" in Free Radical Biology and Medicine, 129 (2018):279-285,
https://doi.org/10.1016/j.freeradbiomed.2018.09.038 . .