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Room temperature ferromagnetism in Cu2+ doped TiO2 nanocrystals: The impact of their size, shape and dopant concentration

Vranješ, Mila; Kuljanin-Jakovljević, Jadranka Ž.; Konstantinović, Zorica; Pomar, Alberto; Ahrenkiel, Scott Phillip; Radetić, Tamara; Stoiljković, Milovan; Mitrić, Miodrag; Šaponjić, Zoran

(Elsevier, 2016)

TY  - JOUR
AU  - Vranješ, Mila
AU  - Kuljanin-Jakovljević, Jadranka Ž.
AU  - Konstantinović, Zorica
AU  - Pomar, Alberto
AU  - Ahrenkiel, Scott Phillip
AU  - Radetić, Tamara
AU  - Stoiljković, Milovan
AU  - Mitrić, Miodrag
AU  - Šaponjić, Zoran
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1024
AB  - Cu2+ doped TiO2 nanocrystals were synthesized using dispersions of titania nanotubes in the presence of Cu2+ ions as a precursors. The morphologies of nanotubular titania precursors and resulted Cu2+ doped TiO2 nanocrystals were characterized by TEM. Structural and optical properties were studied by XRPD analysis and UV-vis spectroscopy in reflectance mode, respectively. Their magnetic properties were investigated using SQUID magnetometer. Tetragonal anatase crystalline structure was confirmed in all synthesized samples. Polygonal (d similar to 15 nm) and spheroid like (length, up to 90 nm) Cu2+ doped TiO2 nanocrystals in samples synthesized at different pHs were observed by TEM. Ferromagnetic ordering with almost closed loop (H-c similar to 200 Oe) was detected in all Cu2+ doped TiO2 nanoparticle films. The saturation magnetization values varied depending on the Cu2+ concentration, nanoparticles shape, size and consequently different number of oxygen vacancies. This study revealed possibility to control magnetic ordering by changing the shape/aspect ratio of Cu2+ doped TiO2 nanocrystals. (C) 2015 Elsevier Ltd. All rights reserved.
PB  - Elsevier
T2  - Materials Research Bulletin
T1  - Room temperature ferromagnetism in Cu2+ doped TiO2 nanocrystals: The impact of their size, shape and dopant concentration
VL  - 76
SP  - 100
EP  - 106
DO  - 10.1016/j.materresbull.2015.11.051
ER  - 
@article{
author = "Vranješ, Mila and Kuljanin-Jakovljević, Jadranka Ž. and Konstantinović, Zorica and Pomar, Alberto and Ahrenkiel, Scott Phillip and Radetić, Tamara and Stoiljković, Milovan and Mitrić, Miodrag and Šaponjić, Zoran",
year = "2016",
abstract = "Cu2+ doped TiO2 nanocrystals were synthesized using dispersions of titania nanotubes in the presence of Cu2+ ions as a precursors. The morphologies of nanotubular titania precursors and resulted Cu2+ doped TiO2 nanocrystals were characterized by TEM. Structural and optical properties were studied by XRPD analysis and UV-vis spectroscopy in reflectance mode, respectively. Their magnetic properties were investigated using SQUID magnetometer. Tetragonal anatase crystalline structure was confirmed in all synthesized samples. Polygonal (d similar to 15 nm) and spheroid like (length, up to 90 nm) Cu2+ doped TiO2 nanocrystals in samples synthesized at different pHs were observed by TEM. Ferromagnetic ordering with almost closed loop (H-c similar to 200 Oe) was detected in all Cu2+ doped TiO2 nanoparticle films. The saturation magnetization values varied depending on the Cu2+ concentration, nanoparticles shape, size and consequently different number of oxygen vacancies. This study revealed possibility to control magnetic ordering by changing the shape/aspect ratio of Cu2+ doped TiO2 nanocrystals. (C) 2015 Elsevier Ltd. All rights reserved.",
publisher = "Elsevier",
journal = "Materials Research Bulletin",
title = "Room temperature ferromagnetism in Cu2+ doped TiO2 nanocrystals: The impact of their size, shape and dopant concentration",
volume = "76",
pages = "100-106",
doi = "10.1016/j.materresbull.2015.11.051"
}
Vranješ, M., Kuljanin-Jakovljević, J. Ž., Konstantinović, Z., Pomar, A., Ahrenkiel, S. P., Radetić, T., Stoiljković, M., Mitrić, M.,& Šaponjić, Z.. (2016). Room temperature ferromagnetism in Cu2+ doped TiO2 nanocrystals: The impact of their size, shape and dopant concentration. in Materials Research Bulletin
Elsevier., 76, 100-106.
https://doi.org/10.1016/j.materresbull.2015.11.051
Vranješ M, Kuljanin-Jakovljević JŽ, Konstantinović Z, Pomar A, Ahrenkiel SP, Radetić T, Stoiljković M, Mitrić M, Šaponjić Z. Room temperature ferromagnetism in Cu2+ doped TiO2 nanocrystals: The impact of their size, shape and dopant concentration. in Materials Research Bulletin. 2016;76:100-106.
doi:10.1016/j.materresbull.2015.11.051 .
Vranješ, Mila, Kuljanin-Jakovljević, Jadranka Ž., Konstantinović, Zorica, Pomar, Alberto, Ahrenkiel, Scott Phillip, Radetić, Tamara, Stoiljković, Milovan, Mitrić, Miodrag, Šaponjić, Zoran, "Room temperature ferromagnetism in Cu2+ doped TiO2 nanocrystals: The impact of their size, shape and dopant concentration" in Materials Research Bulletin, 76 (2016):100-106,
https://doi.org/10.1016/j.materresbull.2015.11.051 . .
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