Ministry of Science of the Republic of Montenegro/Natonal project

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Ministry of Science of the Republic of Montenegro/Natonal project

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Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand

Jaćimović, Željko K.; Kosović, Milica; Novaković, Slađana B.; Giester, Gerald; Radović, Ana

(2015)

TY  - JOUR
AU  - Jaćimović, Željko K.
AU  - Kosović, Milica
AU  - Novaković, Slađana B.
AU  - Giester, Gerald
AU  - Radović, Ana
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/695
AB  - In the reaction of 1,3-dimethylpyrazole-5-carboxylic acid (HL) with M(OAc)(2)center dot 4H(2)O, (M = Cu or Co), two novel complexes were prepared, the square-planar [CuL2(H2O)(2)] and the octahedral [CoL2(MeOH)(4)]. The crystal structures were determined by single-crystal X-ray diffraction. In both complexes, the deprotonated acid displays monodentate coordination to the metal ions. According to the results of a CSD survey, this is the first structural report on the metal complexes with an N-1-substituted pyrazole-5-carboxylic ligand.
T2  - Journal of the Serbian Chemical Society
T1  - Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand
VL  - 80
IS  - 7
SP  - 867
EP  - 875
DO  - 10.2298/JSC140722009J
ER  - 
@article{
author = "Jaćimović, Željko K. and Kosović, Milica and Novaković, Slađana B. and Giester, Gerald and Radović, Ana",
year = "2015",
abstract = "In the reaction of 1,3-dimethylpyrazole-5-carboxylic acid (HL) with M(OAc)(2)center dot 4H(2)O, (M = Cu or Co), two novel complexes were prepared, the square-planar [CuL2(H2O)(2)] and the octahedral [CoL2(MeOH)(4)]. The crystal structures were determined by single-crystal X-ray diffraction. In both complexes, the deprotonated acid displays monodentate coordination to the metal ions. According to the results of a CSD survey, this is the first structural report on the metal complexes with an N-1-substituted pyrazole-5-carboxylic ligand.",
journal = "Journal of the Serbian Chemical Society",
title = "Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand",
volume = "80",
number = "7",
pages = "867-875",
doi = "10.2298/JSC140722009J"
}
Jaćimović, Ž. K., Kosović, M., Novaković, S. B., Giester, G.,& Radović, A.. (2015). Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand. in Journal of the Serbian Chemical Society, 80(7), 867-875.
https://doi.org/10.2298/JSC140722009J
Jaćimović ŽK, Kosović M, Novaković SB, Giester G, Radović A. Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand. in Journal of the Serbian Chemical Society. 2015;80(7):867-875.
doi:10.2298/JSC140722009J .
Jaćimović, Željko K., Kosović, Milica, Novaković, Slađana B., Giester, Gerald, Radović, Ana, "Synthesis and crystal structure of Cu(II) and Co(II) complexes with the 1,3-dimethylpyrazole-5-carboxylic acid ligand" in Journal of the Serbian Chemical Society, 80, no. 7 (2015):867-875,
https://doi.org/10.2298/JSC140722009J . .
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