Elektrohemijske karakteristike oksidnih i polimernih prevlaka na modifikovanim površinama metala

Link to this page

info:eu-repo/grantAgreement/MESTD/MPN2006-2010/142061/RS//

Elektrohemijske karakteristike oksidnih i polimernih prevlaka na modifikovanim površinama metala (en)
Електрохемијске карактеристике оксидних и полимерних превлака на модификованим површинама метала (sr)
Elektrohemijske karakteristike oksidnih i polimernih prevlaka na modifikovanim površinama metala (sr_RS)
Authors

Publications

Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution

Bajat, Jelena; Milosev, Ingrid; Jovanović, Ž.; Jančić-Heinemann, Radmila; Dimitrijević, Marija M.; Mišković-Stanković, Vesna

(2010)

TY  - JOUR
AU  - Bajat, Jelena
AU  - Milosev, Ingrid
AU  - Jovanović, Ž.
AU  - Jančić-Heinemann, Radmila
AU  - Dimitrijević, Marija M.
AU  - Mišković-Stanković, Vesna
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10670
AB  - The corrosion protection of vinyltriethoxysilane (VTES) films on aluminium during exposure to 3% NaCl was investigated using electrochemical impedance spectroscopy (EIS), potential-time measurements and optical microscopy coupled with image analysis. Composition and thickness of films were analyzed using Auger electron spectroscopy (AES) combined with depth profiling. It was shown that films deposited from 5% solution were significantly thicker and exhibited lower porosity and better corrosion stability, as compared to films deposited from 2 vol.% solution. VTES films deposited from 5 vol.% solutions and cured for 30 min exhibited better protection properties than other investigated films.
T2  - Corrosion Science
T1  - Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution
VL  - 52
IS  - 3
SP  - 1060
EP  - 1069
DO  - 10.1016/j.corsci.2009.11.035
ER  - 
@article{
author = "Bajat, Jelena and Milosev, Ingrid and Jovanović, Ž. and Jančić-Heinemann, Radmila and Dimitrijević, Marija M. and Mišković-Stanković, Vesna",
year = "2010",
abstract = "The corrosion protection of vinyltriethoxysilane (VTES) films on aluminium during exposure to 3% NaCl was investigated using electrochemical impedance spectroscopy (EIS), potential-time measurements and optical microscopy coupled with image analysis. Composition and thickness of films were analyzed using Auger electron spectroscopy (AES) combined with depth profiling. It was shown that films deposited from 5% solution were significantly thicker and exhibited lower porosity and better corrosion stability, as compared to films deposited from 2 vol.% solution. VTES films deposited from 5 vol.% solutions and cured for 30 min exhibited better protection properties than other investigated films.",
journal = "Corrosion Science",
title = "Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution",
volume = "52",
number = "3",
pages = "1060-1069",
doi = "10.1016/j.corsci.2009.11.035"
}
Bajat, J., Milosev, I., Jovanović, Ž., Jančić-Heinemann, R., Dimitrijević, M. M.,& Mišković-Stanković, V.. (2010). Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution. in Corrosion Science, 52(3), 1060-1069.
https://doi.org/10.1016/j.corsci.2009.11.035
Bajat J, Milosev I, Jovanović Ž, Jančić-Heinemann R, Dimitrijević MM, Mišković-Stanković V. Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution. in Corrosion Science. 2010;52(3):1060-1069.
doi:10.1016/j.corsci.2009.11.035 .
Bajat, Jelena, Milosev, Ingrid, Jovanović, Ž., Jančić-Heinemann, Radmila, Dimitrijević, Marija M., Mišković-Stanković, Vesna, "Corrosion protection of aluminium pretreated by vinyltriethoxysilane in sodium chloride solution" in Corrosion Science, 52, no. 3 (2010):1060-1069,
https://doi.org/10.1016/j.corsci.2009.11.035 . .
3
62
50
66

Methacryloxypropyltrimethoxysilane films on aluminium: Electrochemical characteristics, adhesion and morphology

Jovanović, Ž.; Bajat, Jelena; Jančić-Heinemann, Radmila; Dimitrijević, Marija M.; Mišković-Stanković, Vesna

(2009)

TY  - JOUR
AU  - Jovanović, Ž.
AU  - Bajat, Jelena
AU  - Jančić-Heinemann, Radmila
AU  - Dimitrijević, Marija M.
AU  - Mišković-Stanković, Vesna
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10671
AB  - The electrochemical characteristics, adhesion and morphology of methacryloxypropyltrimethoxysilane (MAPT) films on aluminium were investigated during exposure to 3 wt.% NaCl. The MAPT films were deposited on aluminium surface from 2 to 5 vol.% methacryloxypropyltrimethoxysilane solutions, with the aim to investigate the influence of deposition parameters (silane solution concentration and curing time) on electrochemical characteristics, adhesion and morphology of MAPT films on aluminium. Using electrochemical impedance spectroscopy (EIS), potential-time measurements, adhesion measurements and optical microscopy coupled with image analysis, it was shown that films deposited from 5 vol.% solution exhibited better corrosion stability and adhesion, as well as lower porosity comparing to 2 vol.% solution and improved the corrosion protection of aluminium substrate, while the curing time had no influence on these characteristics.
T2  - Progress in Organic Coatings
T1  - Methacryloxypropyltrimethoxysilane films on aluminium: Electrochemical characteristics, adhesion and morphology
VL  - 66
IS  - 4
SP  - 393
EP  - 399
DO  - 10.1016/j.porgcoat.2009.09.002
ER  - 
@article{
author = "Jovanović, Ž. and Bajat, Jelena and Jančić-Heinemann, Radmila and Dimitrijević, Marija M. and Mišković-Stanković, Vesna",
year = "2009",
abstract = "The electrochemical characteristics, adhesion and morphology of methacryloxypropyltrimethoxysilane (MAPT) films on aluminium were investigated during exposure to 3 wt.% NaCl. The MAPT films were deposited on aluminium surface from 2 to 5 vol.% methacryloxypropyltrimethoxysilane solutions, with the aim to investigate the influence of deposition parameters (silane solution concentration and curing time) on electrochemical characteristics, adhesion and morphology of MAPT films on aluminium. Using electrochemical impedance spectroscopy (EIS), potential-time measurements, adhesion measurements and optical microscopy coupled with image analysis, it was shown that films deposited from 5 vol.% solution exhibited better corrosion stability and adhesion, as well as lower porosity comparing to 2 vol.% solution and improved the corrosion protection of aluminium substrate, while the curing time had no influence on these characteristics.",
journal = "Progress in Organic Coatings",
title = "Methacryloxypropyltrimethoxysilane films on aluminium: Electrochemical characteristics, adhesion and morphology",
volume = "66",
number = "4",
pages = "393-399",
doi = "10.1016/j.porgcoat.2009.09.002"
}
Jovanović, Ž., Bajat, J., Jančić-Heinemann, R., Dimitrijević, M. M.,& Mišković-Stanković, V.. (2009). Methacryloxypropyltrimethoxysilane films on aluminium: Electrochemical characteristics, adhesion and morphology. in Progress in Organic Coatings, 66(4), 393-399.
https://doi.org/10.1016/j.porgcoat.2009.09.002
Jovanović Ž, Bajat J, Jančić-Heinemann R, Dimitrijević MM, Mišković-Stanković V. Methacryloxypropyltrimethoxysilane films on aluminium: Electrochemical characteristics, adhesion and morphology. in Progress in Organic Coatings. 2009;66(4):393-399.
doi:10.1016/j.porgcoat.2009.09.002 .
Jovanović, Ž., Bajat, Jelena, Jančić-Heinemann, Radmila, Dimitrijević, Marija M., Mišković-Stanković, Vesna, "Methacryloxypropyltrimethoxysilane films on aluminium: Electrochemical characteristics, adhesion and morphology" in Progress in Organic Coatings, 66, no. 4 (2009):393-399,
https://doi.org/10.1016/j.porgcoat.2009.09.002 . .
17
18
19

Corrosion behavior and thermal stability of electrodeposited PANI/epoxy coating system on mild steel in sodium chloride solution

Grgur, Branimir N.; Gvozdenović, M.; Mišković-Stanković, Vesna B.; Kačarević-Popović, Zorica M.

(2006)

TY  - JOUR
AU  - Grgur, Branimir N.
AU  - Gvozdenović, M.
AU  - Mišković-Stanković, Vesna B.
AU  - Kačarević-Popović, Zorica M.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3052
AB  - The corrosion behavior, sorption characteristics and thermal stability of epoxy coatings electrodeposited on mild steel (MS) and mild steel with electrochemically deposited polyaniline (PANI) film were investigated in 3% NaCl solution using electrochemical impedance spectroscopy (EIS) and thermogravimetric analysis (TGA). Electrochemical deposition of PANI film on mild steel was performed from aqueous solution of 0.5 M sodium benzoate and 0.1 M aniline at constant current density of 1.5 mA cm(-2). Epoxy coatings on mild steel and mild steel with PANI film were deposited at constant voltage. It was shown that during initial time of exposure to 3% NaCl, PANI/epoxy coating system on mild steel has lower values of pore resistance (obtained from EIS), greater amount of absorbed water and lower thermal stability (obtained from TGA) which indicate more porous structure comparing to epoxy coating on mild steel. During prolonged exposure to 3% NaCl, PANI/epoxy coating system exhibited increased corrosion protection of mild steel comparing to epoxy coating due to the barrier effect of PANI film and the influence of the dissolved molecular oxygen on cathodic and anodic reaction. Differences between corrosion behavior of epoxy coated and PANI/epoxy coated mild steel in acid and neutral solutions has been discussed. (C) 2006 Elsevier B.V. All rights reserved.
T2  - Progress in Organic Coatings
T1  - Corrosion behavior and thermal stability of electrodeposited PANI/epoxy coating system on mild steel in sodium chloride solution
VL  - 56
IS  - 2-3
SP  - 214
EP  - 219
DO  - 10.1016/j.porgcoat.2006.05.003
ER  - 
@article{
author = "Grgur, Branimir N. and Gvozdenović, M. and Mišković-Stanković, Vesna B. and Kačarević-Popović, Zorica M.",
year = "2006",
abstract = "The corrosion behavior, sorption characteristics and thermal stability of epoxy coatings electrodeposited on mild steel (MS) and mild steel with electrochemically deposited polyaniline (PANI) film were investigated in 3% NaCl solution using electrochemical impedance spectroscopy (EIS) and thermogravimetric analysis (TGA). Electrochemical deposition of PANI film on mild steel was performed from aqueous solution of 0.5 M sodium benzoate and 0.1 M aniline at constant current density of 1.5 mA cm(-2). Epoxy coatings on mild steel and mild steel with PANI film were deposited at constant voltage. It was shown that during initial time of exposure to 3% NaCl, PANI/epoxy coating system on mild steel has lower values of pore resistance (obtained from EIS), greater amount of absorbed water and lower thermal stability (obtained from TGA) which indicate more porous structure comparing to epoxy coating on mild steel. During prolonged exposure to 3% NaCl, PANI/epoxy coating system exhibited increased corrosion protection of mild steel comparing to epoxy coating due to the barrier effect of PANI film and the influence of the dissolved molecular oxygen on cathodic and anodic reaction. Differences between corrosion behavior of epoxy coated and PANI/epoxy coated mild steel in acid and neutral solutions has been discussed. (C) 2006 Elsevier B.V. All rights reserved.",
journal = "Progress in Organic Coatings",
title = "Corrosion behavior and thermal stability of electrodeposited PANI/epoxy coating system on mild steel in sodium chloride solution",
volume = "56",
number = "2-3",
pages = "214-219",
doi = "10.1016/j.porgcoat.2006.05.003"
}
Grgur, B. N., Gvozdenović, M., Mišković-Stanković, V. B.,& Kačarević-Popović, Z. M.. (2006). Corrosion behavior and thermal stability of electrodeposited PANI/epoxy coating system on mild steel in sodium chloride solution. in Progress in Organic Coatings, 56(2-3), 214-219.
https://doi.org/10.1016/j.porgcoat.2006.05.003
Grgur BN, Gvozdenović M, Mišković-Stanković VB, Kačarević-Popović ZM. Corrosion behavior and thermal stability of electrodeposited PANI/epoxy coating system on mild steel in sodium chloride solution. in Progress in Organic Coatings. 2006;56(2-3):214-219.
doi:10.1016/j.porgcoat.2006.05.003 .
Grgur, Branimir N., Gvozdenović, M., Mišković-Stanković, Vesna B., Kačarević-Popović, Zorica M., "Corrosion behavior and thermal stability of electrodeposited PANI/epoxy coating system on mild steel in sodium chloride solution" in Progress in Organic Coatings, 56, no. 2-3 (2006):214-219,
https://doi.org/10.1016/j.porgcoat.2006.05.003 . .
52
45
56

Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route

Panić, Vladimir; Dekanski, Aleksandar B.; Milonjić, Slobodan K.; Mišković-Stanković, Vesna B.; Nikolić, Branislav Ž.

(2006)

TY  - JOUR
AU  - Panić, Vladimir
AU  - Dekanski, Aleksandar B.
AU  - Milonjić, Slobodan K.
AU  - Mišković-Stanković, Vesna B.
AU  - Nikolić, Branislav Ž.
PY  - 2006
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3143
AB  - Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol (ink method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in ail ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical propel-ties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass.
T2  - Journal of the Serbian Chemical Society
T1  - Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route
VL  - 71
IS  - 11
SP  - 1173
EP  - 1186
DO  - 10.2298/JSC0611173P
ER  - 
@article{
author = "Panić, Vladimir and Dekanski, Aleksandar B. and Milonjić, Slobodan K. and Mišković-Stanković, Vesna B. and Nikolić, Branislav Ž.",
year = "2006",
abstract = "Titanium anodes with an active RuO2 coating of two different thicknesses were prepared from the oxide suspended in ethanol (ink method), while the oxide itself was synthesized by the hydrolysis of ruthenium ethoxide in ail ethanolic solution (alkoxide route). The morphology of prepared oxide was examined by scanning electron microscopy. The electrochemical propel-ties of the prepared Ti/RuO2 anodes, involving their cyclic voltammetric behavior in H2SO4 and NaCl solutions, activity in the chlorine and oxygen evolution reaction, impedance behavior in H2SO4, and stability during electrolysis in dilute chloride solutions, were investigated. The performances of the anodes are compared to those of a Ti/RuO2 anode prepared by the sol-gel procedure from an oxide sol obtained by the forced hydrolysis of ruthenium chloride in acid solution. The anodes prepared via the alkoxide route showed a higher capacitance and activity for the chlorine evolution reaction than the anode prepared by the inorganic sol-gel procedure. The results of the stability test showed that the utilization of the coating active material is better when the anodes were prepared via the alkoxide route than via the inorganic sol-gel procedure, particularly for anodes with a smaller mass of coating. The different rates of loss of activity indicate a degradation mechanism for the anodes prepared via the alkoxide route in which electrochemical dissolution of RuO2 from the coating surface prevails over the growth of an insulating TiO2 layer in the coating/Ti substrate interphase. The effect of RuO2 dissolution from the coating surface increases with increasing coating mass.",
journal = "Journal of the Serbian Chemical Society",
title = "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route",
volume = "71",
number = "11",
pages = "1173-1186",
doi = "10.2298/JSC0611173P"
}
Panić, V., Dekanski, A. B., Milonjić, S. K., Mišković-Stanković, V. B.,& Nikolić, B. Ž.. (2006). Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society, 71(11), 1173-1186.
https://doi.org/10.2298/JSC0611173P
Panić V, Dekanski AB, Milonjić SK, Mišković-Stanković VB, Nikolić BŽ. Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route. in Journal of the Serbian Chemical Society. 2006;71(11):1173-1186.
doi:10.2298/JSC0611173P .
Panić, Vladimir, Dekanski, Aleksandar B., Milonjić, Slobodan K., Mišković-Stanković, Vesna B., Nikolić, Branislav Ž., "Activity and stability of RuO2-coated titanium anodes prepared via the alkoxide route" in Journal of the Serbian Chemical Society, 71, no. 11 (2006):1173-1186,
https://doi.org/10.2298/JSC0611173P . .
7
8
8