TY  - JOUR
AU  - Marković, Zoran M.
AU  - Budimir Filimonović, Milica
AU  - Milivojević, Dušan
AU  - Kovač, Janez
AU  - Todorović-Marković, Biljana
PY  - 2024
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/12997
AB  - The cost of treatment of antibiotic-resistant pathogens is on the level of tens of billions of dollars at the moment. It is of special interest to reduce or solve this problem using antimicrobial coatings, especially in hospitals or other healthcare facilities. The bacteria can transfer from medical staff or contaminated surfaces to patients. In this paper, we focused our attention on the antibacterial and antibiofouling activities of two types of photodynamic polyurethane composite films doped with carbon polymerized dots (CPDs) and fullerene C60. Detailed atomic force, electrostatic force and viscoelastic microscopy revealed topology, nanoelectrical and nanomechanical properties of used fillers and composites. A relationship between the electronic structure of the nanocarbon fillers and the antibacterial and antibiofouling activities of the composites was established. Thorough spectroscopic analysis of reactive oxygen species (ROS) generation was conducted for both composite films, and it was found that both of them were potent antibacterial agents against nosocomial bacteria (Klebsiela pneumoniae, Proteus mirabilis, Salmonela enterica, Enterococcus faecalis, Enterococcus epidermis and Pseudomonas aeruginosa). Antibiofouling testing of composite films indicated that the CPDs/PU composite films eradicated almost completely the biofilms of Pseudomonas aeruginosa and Staphylococcus aureus and about 50% of Escherichia coli biofilms.
T2  - Journal of Functional Biomaterials
T1  - Antibacterial and Antibiofouling Activities of Carbon Polymerized Dots/Polyurethane and C60/Polyurethane Composite Films
VL  - 15
IS  - 3
SP  - 73
DO  - 10.3390/jfb15030073
ER  - 

@article{
author = "Marković, Zoran M. and Budimir Filimonović, Milica and Milivojević, Dušan and Kovač, Janez and Todorović-Marković, Biljana",
year = "2024",
abstract = "The cost of treatment of antibiotic-resistant pathogens is on the level of tens of billions of dollars at the moment. It is of special interest to reduce or solve this problem using antimicrobial coatings, especially in hospitals or other healthcare facilities. The bacteria can transfer from medical staff or contaminated surfaces to patients. In this paper, we focused our attention on the antibacterial and antibiofouling activities of two types of photodynamic polyurethane composite films doped with carbon polymerized dots (CPDs) and fullerene C60. Detailed atomic force, electrostatic force and viscoelastic microscopy revealed topology, nanoelectrical and nanomechanical properties of used fillers and composites. A relationship between the electronic structure of the nanocarbon fillers and the antibacterial and antibiofouling activities of the composites was established. Thorough spectroscopic analysis of reactive oxygen species (ROS) generation was conducted for both composite films, and it was found that both of them were potent antibacterial agents against nosocomial bacteria (Klebsiela pneumoniae, Proteus mirabilis, Salmonela enterica, Enterococcus faecalis, Enterococcus epidermis and Pseudomonas aeruginosa). Antibiofouling testing of composite films indicated that the CPDs/PU composite films eradicated almost completely the biofilms of Pseudomonas aeruginosa and Staphylococcus aureus and about 50% of Escherichia coli biofilms.",
journal = "Journal of Functional Biomaterials",
title = "Antibacterial and Antibiofouling Activities of Carbon Polymerized Dots/Polyurethane and C60/Polyurethane Composite Films",
volume = "15",
number = "3",
pages = "73",
doi = "10.3390/jfb15030073"
}

Marković, Z. M., Budimir Filimonović, M., Milivojević, D., Kovač, J.,& Todorović-Marković, B.. (2024). Antibacterial and Antibiofouling Activities of Carbon Polymerized Dots/Polyurethane and C60/Polyurethane Composite Films. in Journal of Functional Biomaterials, 15(3), 73.
https://doi.org/10.3390/jfb15030073

Marković ZM, Budimir Filimonović M, Milivojević D, Kovač J, Todorović-Marković B. Antibacterial and Antibiofouling Activities of Carbon Polymerized Dots/Polyurethane and C60/Polyurethane Composite Films. in Journal of Functional Biomaterials. 2024;15(3):73.
doi:10.3390/jfb15030073 .

Marković, Zoran M., Budimir Filimonović, Milica, Milivojević, Dušan, Kovač, Janez, Todorović-Marković, Biljana, "Antibacterial and Antibiofouling Activities of Carbon Polymerized Dots/Polyurethane and C60/Polyurethane Composite Films" in Journal of Functional Biomaterials, 15, no. 3 (2024):73,
https://doi.org/10.3390/jfb15030073 . .

TY  - JOUR
AU  - Mravik, Željko
AU  - Bajuk-Bogdanović, Danica V.
AU  - Mraković, Ana Đ.
AU  - Vukosavljević, Ljubiša
AU  - Trajić, Ivan
AU  - Kovač, Janez
AU  - Peruško, Davor
AU  - Gavrilov, Nemanja
AU  - Jovanović, Zoran M.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9150
AB  - In recent years polyoxometalates (POMs) have attracted significant research interest due to versatile properties. These properties are determined by the size, structure and elemental composition of POMs and hence play an important role in their application. In the present study, the ion beam irradiation (10 keV C+ ions, 5 × 1014–2.5 × 1015 ions/cm2) has been utilized for modification of physicochemical properties of 120 nm-thick layer of 12-tungstophosphoric acid (WPA). Scanning electron microscopy analysis of irradiated films showed change of morphology i.e. an increase of WPA grain size with irradiation and coalescence of grains at the highest fluence. This was accompanied by structural changes. Attenuated total reflectance Fourier transform infrared analysis revealed that vibration bands of Keggin anion became less pronounced as fluence increased, while Raman spectra appeared as strongly modified. The effect of irradiation with 1.25 × 1015 ions/cm2 on the structure of WPA was similar to the effect of thermal treatment at 600 °C. Irradiation of WPA led to decrease of the band gap (from 4.07 to 3.92 eV), which was correlated to transformation Keggin anions into a network of WO6 octahedra and PO4 tetrahedra. This is in line with increased number of W=Od bonds observed by UV–Visible diffuse reflectance spectroscopy. Beside transformation to bronzes a reduction of WPA was observed by X-ray Photoelectron Spectroscopy (shift to lower binding energy) and Raman methods, whereas the Raman spectra of irradiated samples were similar to heteropoly blue. The electrochemical properties of irradiated WPA were also assessed. Cyclic voltammetry measurements showed that at up to 1.25 × 1015 ions/cm2 lithiation capacity of WPA increases and activity for hydrogen evolution reaction (HER) improves. The highest fluence caused interconnection of WO6 octahedra, closing of lithiation pathways and decrease in the number of active sites for HER. Our results provide a novel insight into the effects of ion beam irradiation on WPA and demonstrate high potential for tuning of physicochemical properties of POMs that are relevant in wide range of applications. © 2021 Elsevier Ltd
T2  - Radiation Physics and Chemistry
T1  - Structural and electrochemical properties of carbon ion beam irradiated 12-tungstophosphoric acid
VL  - 183
SP  - 109422
DO  - 10.1016/j.radphyschem.2021.109422
ER  - 

@article{
author = "Mravik, Željko and Bajuk-Bogdanović, Danica V. and Mraković, Ana Đ. and Vukosavljević, Ljubiša and Trajić, Ivan and Kovač, Janez and Peruško, Davor and Gavrilov, Nemanja and Jovanović, Zoran M.",
year = "2021",
abstract = "In recent years polyoxometalates (POMs) have attracted significant research interest due to versatile properties. These properties are determined by the size, structure and elemental composition of POMs and hence play an important role in their application. In the present study, the ion beam irradiation (10 keV C+ ions, 5 × 1014–2.5 × 1015 ions/cm2) has been utilized for modification of physicochemical properties of 120 nm-thick layer of 12-tungstophosphoric acid (WPA). Scanning electron microscopy analysis of irradiated films showed change of morphology i.e. an increase of WPA grain size with irradiation and coalescence of grains at the highest fluence. This was accompanied by structural changes. Attenuated total reflectance Fourier transform infrared analysis revealed that vibration bands of Keggin anion became less pronounced as fluence increased, while Raman spectra appeared as strongly modified. The effect of irradiation with 1.25 × 1015 ions/cm2 on the structure of WPA was similar to the effect of thermal treatment at 600 °C. Irradiation of WPA led to decrease of the band gap (from 4.07 to 3.92 eV), which was correlated to transformation Keggin anions into a network of WO6 octahedra and PO4 tetrahedra. This is in line with increased number of W=Od bonds observed by UV–Visible diffuse reflectance spectroscopy. Beside transformation to bronzes a reduction of WPA was observed by X-ray Photoelectron Spectroscopy (shift to lower binding energy) and Raman methods, whereas the Raman spectra of irradiated samples were similar to heteropoly blue. The electrochemical properties of irradiated WPA were also assessed. Cyclic voltammetry measurements showed that at up to 1.25 × 1015 ions/cm2 lithiation capacity of WPA increases and activity for hydrogen evolution reaction (HER) improves. The highest fluence caused interconnection of WO6 octahedra, closing of lithiation pathways and decrease in the number of active sites for HER. Our results provide a novel insight into the effects of ion beam irradiation on WPA and demonstrate high potential for tuning of physicochemical properties of POMs that are relevant in wide range of applications. © 2021 Elsevier Ltd",
journal = "Radiation Physics and Chemistry",
title = "Structural and electrochemical properties of carbon ion beam irradiated 12-tungstophosphoric acid",
volume = "183",
pages = "109422",
doi = "10.1016/j.radphyschem.2021.109422"
}

Mravik, Ž., Bajuk-Bogdanović, D. V., Mraković, A. Đ., Vukosavljević, L., Trajić, I., Kovač, J., Peruško, D., Gavrilov, N.,& Jovanović, Z. M.. (2021). Structural and electrochemical properties of carbon ion beam irradiated 12-tungstophosphoric acid. in Radiation Physics and Chemistry, 183, 109422.
https://doi.org/10.1016/j.radphyschem.2021.109422

Mravik Ž, Bajuk-Bogdanović DV, Mraković AĐ, Vukosavljević L, Trajić I, Kovač J, Peruško D, Gavrilov N, Jovanović ZM. Structural and electrochemical properties of carbon ion beam irradiated 12-tungstophosphoric acid. in Radiation Physics and Chemistry. 2021;183:109422.
doi:10.1016/j.radphyschem.2021.109422 .

Mravik, Željko, Bajuk-Bogdanović, Danica V., Mraković, Ana Đ., Vukosavljević, Ljubiša, Trajić, Ivan, Kovač, Janez, Peruško, Davor, Gavrilov, Nemanja, Jovanović, Zoran M., "Structural and electrochemical properties of carbon ion beam irradiated 12-tungstophosphoric acid" in Radiation Physics and Chemistry, 183 (2021):109422,
https://doi.org/10.1016/j.radphyschem.2021.109422 . .

TY  - JOUR
AU  - Peruško, Davor
AU  - Kovač, Janez
AU  - Petrović, Suzana
AU  - Obradović, Marko O.
AU  - Mitrić, Miodrag
AU  - Pavlović, Vladimir B.
AU  - Salatić, Branislav
AU  - Jaksa, G.
AU  - Ciganović, Jovan
AU  - Milosavljević, Momir
PY  - 2017
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1725
AB  - Multilayers consisting of five (Al/Ti) bilayers were deposited on (100) silicon wafers. On top was deposited the Ti layer, aimed at preventing Al from diffusing to the surface upon laser treatment. The total thickness of the thin-film structure was 200 nm. Laser irradiations with Nd:YAG picoseconds laser pulses in the defocused regime were performed in air. Laser beam energy was 4 mJ and laser spot diameter on the sample surface was 3 mm (fluence 0.057 J cm(-2)). The samples were treated with different numbers of laser pulses. Structural characterizations were performed by different analytical methods and nano-hardness was also measured. Laser processing induced layer intermixing, formation of titanium aluminides, oxidation of the surface titanium layer and enhanced surface roughness. Aluminum appears at the sample surface only for the highest density of laser irradiation. Laser processing induces increment of nano-hardness by approximately 20% and decrease of residual Youngs modulus for a few percentages from the starting value of the untreated samples. These results can be interesting toward achieving structures with a selective extent of Al-Ti reactivity in this multilayered system, within the development of biocompatible materials.
T2  - Materials and Manufacturing Processes
T1  - Selective Al-Ti reactivity in laser-processed Al/Ti multilayers
VL  - 32
IS  - 14
SP  - 1622
EP  - 1627
DO  - 10.1080/10426914.2017.1279299
ER  - 

@article{
author = "Peruško, Davor and Kovač, Janez and Petrović, Suzana and Obradović, Marko O. and Mitrić, Miodrag and Pavlović, Vladimir B. and Salatić, Branislav and Jaksa, G. and Ciganović, Jovan and Milosavljević, Momir",
year = "2017",
abstract = "Multilayers consisting of five (Al/Ti) bilayers were deposited on (100) silicon wafers. On top was deposited the Ti layer, aimed at preventing Al from diffusing to the surface upon laser treatment. The total thickness of the thin-film structure was 200 nm. Laser irradiations with Nd:YAG picoseconds laser pulses in the defocused regime were performed in air. Laser beam energy was 4 mJ and laser spot diameter on the sample surface was 3 mm (fluence 0.057 J cm(-2)). The samples were treated with different numbers of laser pulses. Structural characterizations were performed by different analytical methods and nano-hardness was also measured. Laser processing induced layer intermixing, formation of titanium aluminides, oxidation of the surface titanium layer and enhanced surface roughness. Aluminum appears at the sample surface only for the highest density of laser irradiation. Laser processing induces increment of nano-hardness by approximately 20% and decrease of residual Youngs modulus for a few percentages from the starting value of the untreated samples. These results can be interesting toward achieving structures with a selective extent of Al-Ti reactivity in this multilayered system, within the development of biocompatible materials.",
journal = "Materials and Manufacturing Processes",
title = "Selective Al-Ti reactivity in laser-processed Al/Ti multilayers",
volume = "32",
number = "14",
pages = "1622-1627",
doi = "10.1080/10426914.2017.1279299"
}

Peruško, D., Kovač, J., Petrović, S., Obradović, M. O., Mitrić, M., Pavlović, V. B., Salatić, B., Jaksa, G., Ciganović, J.,& Milosavljević, M.. (2017). Selective Al-Ti reactivity in laser-processed Al/Ti multilayers. in Materials and Manufacturing Processes, 32(14), 1622-1627.
https://doi.org/10.1080/10426914.2017.1279299

Peruško D, Kovač J, Petrović S, Obradović MO, Mitrić M, Pavlović VB, Salatić B, Jaksa G, Ciganović J, Milosavljević M. Selective Al-Ti reactivity in laser-processed Al/Ti multilayers. in Materials and Manufacturing Processes. 2017;32(14):1622-1627.
doi:10.1080/10426914.2017.1279299 .

Peruško, Davor, Kovač, Janez, Petrović, Suzana, Obradović, Marko O., Mitrić, Miodrag, Pavlović, Vladimir B., Salatić, Branislav, Jaksa, G., Ciganović, Jovan, Milosavljević, Momir, "Selective Al-Ti reactivity in laser-processed Al/Ti multilayers" in Materials and Manufacturing Processes, 32, no. 14 (2017):1622-1627,
https://doi.org/10.1080/10426914.2017.1279299 . .

TY  - JOUR
AU  - Nastasović, Aleksandra B.
AU  - Ekmescic, Bojana M.
AU  - Sandić, Zvjezdana
AU  - Ranđelović, Danijela V.
AU  - Mozetic, Miran
AU  - Vesel, Alenka
AU  - Onjia, Antonije E.
PY  - 2016
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/1201
AB  - The mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) functionalized by reaction of the pendant epoxy groups with diethylene triamine (PGME-deta) was studied using X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) analysis. Atomic force microscopy (AFM) and scanning energy-dispersive X-ray spectroscopy (SEM-EDX) were used for the determination of surface morphology of the copolymer particles. The sorption behavior of heavy metals Cu(II), Cd(II) and Pb(II) ions sorption was investigated in batch static experiments under non-competitive conditions at room temperature (298 K). The obtained results were fitted to pseudo-first order, pseudo-second order and intraparticle diffusion kinetic model. The kinetics studies showed that Cu(II), Cd(II) and Pb(II) sorption obeys the pseudo-second-order model under all investigated operating conditions with evident influence of pore diffusion. (C) 2016 Elsevier B.V. All rights reserved.
T2  - Applied Surface Science
T1  - Mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)
VL  - 385
SP  - 605
EP  - 615
DO  - 10.1016/j.apsusc.2016.05.165
ER  - 

@article{
author = "Nastasović, Aleksandra B. and Ekmescic, Bojana M. and Sandić, Zvjezdana and Ranđelović, Danijela V. and Mozetic, Miran and Vesel, Alenka and Onjia, Antonije E.",
year = "2016",
abstract = "The mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate) (PGME) functionalized by reaction of the pendant epoxy groups with diethylene triamine (PGME-deta) was studied using X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FTIR) analysis. Atomic force microscopy (AFM) and scanning energy-dispersive X-ray spectroscopy (SEM-EDX) were used for the determination of surface morphology of the copolymer particles. The sorption behavior of heavy metals Cu(II), Cd(II) and Pb(II) ions sorption was investigated in batch static experiments under non-competitive conditions at room temperature (298 K). The obtained results were fitted to pseudo-first order, pseudo-second order and intraparticle diffusion kinetic model. The kinetics studies showed that Cu(II), Cd(II) and Pb(II) sorption obeys the pseudo-second-order model under all investigated operating conditions with evident influence of pore diffusion. (C) 2016 Elsevier B.V. All rights reserved.",
journal = "Applied Surface Science",
title = "Mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)",
volume = "385",
pages = "605-615",
doi = "10.1016/j.apsusc.2016.05.165"
}

Nastasović, A. B., Ekmescic, B. M., Sandić, Z., Ranđelović, D. V., Mozetic, M., Vesel, A.,& Onjia, A. E.. (2016). Mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate). in Applied Surface Science, 385, 605-615.
https://doi.org/10.1016/j.apsusc.2016.05.165

Nastasović AB, Ekmescic BM, Sandić Z, Ranđelović DV, Mozetic M, Vesel A, Onjia AE. Mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate). in Applied Surface Science. 2016;385:605-615.
doi:10.1016/j.apsusc.2016.05.165 .

Nastasović, Aleksandra B., Ekmescic, Bojana M., Sandić, Zvjezdana, Ranđelović, Danijela V., Mozetic, Miran, Vesel, Alenka, Onjia, Antonije E., "Mechanism of Cu(II), Cd(II) and Pb(II) ions sorption from aqueous solutions by macroporous poly(glycidyl methacrylate-co-ethylene glycol dimethacrylate)" in Applied Surface Science, 385 (2016):605-615,
https://doi.org/10.1016/j.apsusc.2016.05.165 . .

TY  - JOUR
AU  - Milosavljević, Momir
AU  - Stojanovic, N.
AU  - Peruško, Davor
AU  - Timotijević, B.
AU  - Toprek, Dragan
AU  - Kovač, Janez
AU  - Dražić, Goran
AU  - Jeynes, C.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4631
AB  - Interactions induced in Al/Ti multilayers by implantation of Ar ions at room temperature were investgated. Initial structures consisted of (Al/Ti) x 5 multilayers deposited by d.c. ion sputtering on Si(1 0 0) wafers, to a total thickness of similar to 250 nm. They were irradiated with 200 keV Ar+ ions, to the fluences from 5 x 10(15) to 4 x 10(16) ions/cm(2). It was found that ion irradiation induced a progressed intermixing of the multilayer constituents and Al-Ti nanoalloying for the highest applied fluence. The resulting nanocrystalline structure had a graded composition with non-reacted or interdiffused Al and Ti, and gamma-AlTi and AlTi3 intermetallic phases. Most intense reactivity was observed around mid depth of the multilayers, where most energy was deposited by the impact ions. It is presumed that Al-Ti chemical reaction is triggered by thermal spikes and further enhanced by chemical driving forces. The applied processing can be interesting for fabrication of tightly bond multilayered structures with gradual changes of their composition and properties. (C) 2011 Elsevier B. V. All rights reserved.
T2  - Applied Surface Science
T1  - Ion irradiation induced Al-Ti interaction in nano-scaled Al/Ti multilayers
VL  - 258
IS  - 6
SP  - 2043
EP  - 2046
DO  - 10.1016/j.apsusc.2011.04.107
ER  - 

@article{
author = "Milosavljević, Momir and Stojanovic, N. and Peruško, Davor and Timotijević, B. and Toprek, Dragan and Kovač, Janez and Dražić, Goran and Jeynes, C.",
year = "2012",
abstract = "Interactions induced in Al/Ti multilayers by implantation of Ar ions at room temperature were investgated. Initial structures consisted of (Al/Ti) x 5 multilayers deposited by d.c. ion sputtering on Si(1 0 0) wafers, to a total thickness of similar to 250 nm. They were irradiated with 200 keV Ar+ ions, to the fluences from 5 x 10(15) to 4 x 10(16) ions/cm(2). It was found that ion irradiation induced a progressed intermixing of the multilayer constituents and Al-Ti nanoalloying for the highest applied fluence. The resulting nanocrystalline structure had a graded composition with non-reacted or interdiffused Al and Ti, and gamma-AlTi and AlTi3 intermetallic phases. Most intense reactivity was observed around mid depth of the multilayers, where most energy was deposited by the impact ions. It is presumed that Al-Ti chemical reaction is triggered by thermal spikes and further enhanced by chemical driving forces. The applied processing can be interesting for fabrication of tightly bond multilayered structures with gradual changes of their composition and properties. (C) 2011 Elsevier B. V. All rights reserved.",
journal = "Applied Surface Science",
title = "Ion irradiation induced Al-Ti interaction in nano-scaled Al/Ti multilayers",
volume = "258",
number = "6",
pages = "2043-2046",
doi = "10.1016/j.apsusc.2011.04.107"
}

Milosavljević, M., Stojanovic, N., Peruško, D., Timotijević, B., Toprek, D., Kovač, J., Dražić, G.,& Jeynes, C.. (2012). Ion irradiation induced Al-Ti interaction in nano-scaled Al/Ti multilayers. in Applied Surface Science, 258(6), 2043-2046.
https://doi.org/10.1016/j.apsusc.2011.04.107

Milosavljević M, Stojanovic N, Peruško D, Timotijević B, Toprek D, Kovač J, Dražić G, Jeynes C. Ion irradiation induced Al-Ti interaction in nano-scaled Al/Ti multilayers. in Applied Surface Science. 2012;258(6):2043-2046.
doi:10.1016/j.apsusc.2011.04.107 .

Milosavljević, Momir, Stojanovic, N., Peruško, Davor, Timotijević, B., Toprek, Dragan, Kovač, Janez, Dražić, Goran, Jeynes, C., "Ion irradiation induced Al-Ti interaction in nano-scaled Al/Ti multilayers" in Applied Surface Science, 258, no. 6 (2012):2043-2046,
https://doi.org/10.1016/j.apsusc.2011.04.107 . .

TY  - JOUR
AU  - Milosavljević, Momir
AU  - Milinović, Velimir
AU  - Peruško, Davor
AU  - Grce, Ana
AU  - Stojanović, Mirjana
AU  - Pjević, Dejan J.
AU  - Mitrić, Miodrag
AU  - Kovač, Janez
AU  - Homewood, Kevin P.
PY  - 2011
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4487
AB  - The effects of argon ion irradiation on structural changes in Ta/Ti multilayers deposited on Si wafers were investigated. The starting structures consisted of sputter deposited 10 alternate Ta (similar to 23 nm) and Ti (similar to 17 nm) layers of a total thickness similar to 200 nm. They were irradiated at room temperature with 200 key Ar(+), to the fluences from 5 x 10(15) to 2 x 10(16) ions/cm(2). The projected ion range was around mid-depth of the multilayered structure, and maximum displacements per atom similar to 130. It was found that, despite of the relatively heavy ion irradiation, individual nanocrystalline Ta and Ti layers remain unmixed, keeping the same level of interface planarity. The changes observed in the mostly affected region are increase in lateral dimensions of crystal grains in individual layers, and incorporation of bubbles and defects that cause some stretching of the crystal lattice. Absence of interlayer mixing is assigned to Ta-Ti immiscibility (reaction enthalpy Delta H(f) = +2 kJ/mol). It is estimated that up to similar to 5 at.% interface mixing induced directly by collision cascades could be compensated by dynamic demixing due to chemical driving forces in the temperature relaxation regime. The results can be interesting towards developing radiation tolerant materials based on multilayered structures. (C) 2011 Elsevier B.V. All rights reserved.
T2  - Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms
T1  - Stability of nano-scaled Ta/Ti multilayers upon argon ion irradiation
VL  - 269
IS  - 19
SP  - 2090
EP  - 2097
DO  - 10.1016/j.nimb.2011.06.017
ER  - 

@article{
author = "Milosavljević, Momir and Milinović, Velimir and Peruško, Davor and Grce, Ana and Stojanović, Mirjana and Pjević, Dejan J. and Mitrić, Miodrag and Kovač, Janez and Homewood, Kevin P.",
year = "2011",
abstract = "The effects of argon ion irradiation on structural changes in Ta/Ti multilayers deposited on Si wafers were investigated. The starting structures consisted of sputter deposited 10 alternate Ta (similar to 23 nm) and Ti (similar to 17 nm) layers of a total thickness similar to 200 nm. They were irradiated at room temperature with 200 key Ar(+), to the fluences from 5 x 10(15) to 2 x 10(16) ions/cm(2). The projected ion range was around mid-depth of the multilayered structure, and maximum displacements per atom similar to 130. It was found that, despite of the relatively heavy ion irradiation, individual nanocrystalline Ta and Ti layers remain unmixed, keeping the same level of interface planarity. The changes observed in the mostly affected region are increase in lateral dimensions of crystal grains in individual layers, and incorporation of bubbles and defects that cause some stretching of the crystal lattice. Absence of interlayer mixing is assigned to Ta-Ti immiscibility (reaction enthalpy Delta H(f) = +2 kJ/mol). It is estimated that up to similar to 5 at.% interface mixing induced directly by collision cascades could be compensated by dynamic demixing due to chemical driving forces in the temperature relaxation regime. The results can be interesting towards developing radiation tolerant materials based on multilayered structures. (C) 2011 Elsevier B.V. All rights reserved.",
journal = "Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms",
title = "Stability of nano-scaled Ta/Ti multilayers upon argon ion irradiation",
volume = "269",
number = "19",
pages = "2090-2097",
doi = "10.1016/j.nimb.2011.06.017"
}

Milosavljević, M., Milinović, V., Peruško, D., Grce, A., Stojanović, M., Pjević, D. J., Mitrić, M., Kovač, J.,& Homewood, K. P.. (2011). Stability of nano-scaled Ta/Ti multilayers upon argon ion irradiation. in Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms, 269(19), 2090-2097.
https://doi.org/10.1016/j.nimb.2011.06.017

Milosavljević M, Milinović V, Peruško D, Grce A, Stojanović M, Pjević DJ, Mitrić M, Kovač J, Homewood KP. Stability of nano-scaled Ta/Ti multilayers upon argon ion irradiation. in Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms. 2011;269(19):2090-2097.
doi:10.1016/j.nimb.2011.06.017 .

Milosavljević, Momir, Milinović, Velimir, Peruško, Davor, Grce, Ana, Stojanović, Mirjana, Pjević, Dejan J., Mitrić, Miodrag, Kovač, Janez, Homewood, Kevin P., "Stability of nano-scaled Ta/Ti multilayers upon argon ion irradiation" in Nuclear Instruments and Methods in Physics Research. Section B: Beam Interactions with Materials and Atoms, 269, no. 19 (2011):2090-2097,
https://doi.org/10.1016/j.nimb.2011.06.017 . .

TY  - JOUR
AU  - Milivojević, Dušan
AU  - Babić-Stojić, Branka S.
AU  - Kovač, Janez
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4111
AB  - The existence of ferromagnetism in Zn-Mn-O semiconductor samples and dependence on the preparation condition were investigated. We systematically examined the samples with manganese concentration ranging from 0 to 10 at.%, prepared by a solid state reaction route using (ZnC(2)O(4)center dot 2H(2)O)(1-x) and (MnC(2)O(4)center dot 2H(2)O)(x) as precursors. Thermal treatment was carried out in air at temperatures ranging from 400 to 900 degrees C. The samples were investigated by X-ray diffraction, transmission electron microscopy, magnetization measurements and XPS spectroscopy. XPS surface composition, chemical analysis and depth profiling were successfully employed on powder revealing the chemical composition at the surface of the grains and underneath. The present investigation suggests that physical properties and observed room temperature ferromagnetism might be due to grain surface effects. It seems that the ferromagnetic phase is correlated with oxygen build up at the surface. (C) 2010 Elsevier B.V. All rights reserved.
T2  - Applied Surface Science
T1  - Surface of Zn-Mn-O and its role in room temperature ferromagnetism: An XPS analysis
VL  - 257
IS  - 3
SP  - 937
EP  - 943
DO  - 10.1016/j.apsusc.2010.07.096
ER  - 

@article{
author = "Milivojević, Dušan and Babić-Stojić, Branka S. and Kovač, Janez",
year = "2010",
abstract = "The existence of ferromagnetism in Zn-Mn-O semiconductor samples and dependence on the preparation condition were investigated. We systematically examined the samples with manganese concentration ranging from 0 to 10 at.%, prepared by a solid state reaction route using (ZnC(2)O(4)center dot 2H(2)O)(1-x) and (MnC(2)O(4)center dot 2H(2)O)(x) as precursors. Thermal treatment was carried out in air at temperatures ranging from 400 to 900 degrees C. The samples were investigated by X-ray diffraction, transmission electron microscopy, magnetization measurements and XPS spectroscopy. XPS surface composition, chemical analysis and depth profiling were successfully employed on powder revealing the chemical composition at the surface of the grains and underneath. The present investigation suggests that physical properties and observed room temperature ferromagnetism might be due to grain surface effects. It seems that the ferromagnetic phase is correlated with oxygen build up at the surface. (C) 2010 Elsevier B.V. All rights reserved.",
journal = "Applied Surface Science",
title = "Surface of Zn-Mn-O and its role in room temperature ferromagnetism: An XPS analysis",
volume = "257",
number = "3",
pages = "937-943",
doi = "10.1016/j.apsusc.2010.07.096"
}

Milivojević, D., Babić-Stojić, B. S.,& Kovač, J.. (2010). Surface of Zn-Mn-O and its role in room temperature ferromagnetism: An XPS analysis. in Applied Surface Science, 257(3), 937-943.
https://doi.org/10.1016/j.apsusc.2010.07.096

Milivojević D, Babić-Stojić BS, Kovač J. Surface of Zn-Mn-O and its role in room temperature ferromagnetism: An XPS analysis. in Applied Surface Science. 2010;257(3):937-943.
doi:10.1016/j.apsusc.2010.07.096 .

Milivojević, Dušan, Babić-Stojić, Branka S., Kovač, Janez, "Surface of Zn-Mn-O and its role in room temperature ferromagnetism: An XPS analysis" in Applied Surface Science, 257, no. 3 (2010):937-943,
https://doi.org/10.1016/j.apsusc.2010.07.096 . .