TY  - JOUR
AU  - Ashrafi, Amir M.
AU  - Đorđević, Jelena S.
AU  - Guzsvany, Valeria
AU  - Svancara, Ivan
AU  - Trtić-Petrović, Tatjana M.
AU  - Purenović, Milovan M.
AU  - Vytras, Karel
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5235
AB  - In this study, a carbon paste electrode based on tricresyl phosphate (TCP-CPE) as a binder has been applied to the voltammetric characterization and determination of Carbendazim fungicide (methyl-1H-benzimidazol-2-yl-carbamate, MBC). The pH effect (in Britton-Robinson buffers, pH 2.0-8.0), as well as the presence of 2-hydroxypropyl-beta-cyclodextrin (HPCD) on the electrochemical behavior of MBC were investigated. In the potential range of interest, the oxidation signal was observed with the overall shape strongly dependent upon pH and exhibiting the most favorable signal-to-noise ratio in mild acidic solutions (pH 4.0). This has indicated that also protons are involved in the electrode transformation of MBC. Furthermore, it was confirmed that addition of 3.6.10(-5) mol L-1 HPCD significantly enhanced the sensitivity towards the target analyte. The experimental conditions optimised for the determination of MBC in the differential pulse adsorptive stripping voltammetric mode (DPAdSV) were as follows: initial potential, -0.10 V vs. Ag/AgCl; final potential, +1.30 V; accumulation potential, -0.35 V; accumulation time, 120 s, and the scan rate, 100 mV s(-1). The method developed offers linearity in the concentration range of 5.0 .10(-7) - 1.0.10(-5) mol L-1 MBC, with r = 0.995 and the limit of detection of about 3.0.10(-7) mol L-1. In a model sample of spiked river water, the recovery rate achieved was 101.9 % (at the concentrations from 1.0.10(-6) to 3.0.10(-6) mol L-1 MBC), suggesting one that the procedure can be applied in analysis of real samples.
T2  - International Journal of Electrochemical Science
T1  - Trace Determination of Carbendazim Fungicide Using Adsorptive Stripping Voltammetry with a Carbon Paste Electrode Containing Tricresyl Phosphate
VL  - 7
IS  - 10
SP  - 9717
EP  - 9731
UR  - https://hdl.handle.net/21.15107/rcub_vinar_5235
ER  - 

@article{
author = "Ashrafi, Amir M. and Đorđević, Jelena S. and Guzsvany, Valeria and Svancara, Ivan and Trtić-Petrović, Tatjana M. and Purenović, Milovan M. and Vytras, Karel",
year = "2012",
abstract = "In this study, a carbon paste electrode based on tricresyl phosphate (TCP-CPE) as a binder has been applied to the voltammetric characterization and determination of Carbendazim fungicide (methyl-1H-benzimidazol-2-yl-carbamate, MBC). The pH effect (in Britton-Robinson buffers, pH 2.0-8.0), as well as the presence of 2-hydroxypropyl-beta-cyclodextrin (HPCD) on the electrochemical behavior of MBC were investigated. In the potential range of interest, the oxidation signal was observed with the overall shape strongly dependent upon pH and exhibiting the most favorable signal-to-noise ratio in mild acidic solutions (pH 4.0). This has indicated that also protons are involved in the electrode transformation of MBC. Furthermore, it was confirmed that addition of 3.6.10(-5) mol L-1 HPCD significantly enhanced the sensitivity towards the target analyte. The experimental conditions optimised for the determination of MBC in the differential pulse adsorptive stripping voltammetric mode (DPAdSV) were as follows: initial potential, -0.10 V vs. Ag/AgCl; final potential, +1.30 V; accumulation potential, -0.35 V; accumulation time, 120 s, and the scan rate, 100 mV s(-1). The method developed offers linearity in the concentration range of 5.0 .10(-7) - 1.0.10(-5) mol L-1 MBC, with r = 0.995 and the limit of detection of about 3.0.10(-7) mol L-1. In a model sample of spiked river water, the recovery rate achieved was 101.9 % (at the concentrations from 1.0.10(-6) to 3.0.10(-6) mol L-1 MBC), suggesting one that the procedure can be applied in analysis of real samples.",
journal = "International Journal of Electrochemical Science",
title = "Trace Determination of Carbendazim Fungicide Using Adsorptive Stripping Voltammetry with a Carbon Paste Electrode Containing Tricresyl Phosphate",
volume = "7",
number = "10",
pages = "9717-9731",
url = "https://hdl.handle.net/21.15107/rcub_vinar_5235"
}

Ashrafi, A. M., Đorđević, J. S., Guzsvany, V., Svancara, I., Trtić-Petrović, T. M., Purenović, M. M.,& Vytras, K.. (2012). Trace Determination of Carbendazim Fungicide Using Adsorptive Stripping Voltammetry with a Carbon Paste Electrode Containing Tricresyl Phosphate. in International Journal of Electrochemical Science, 7(10), 9717-9731.
https://hdl.handle.net/21.15107/rcub_vinar_5235

Ashrafi AM, Đorđević JS, Guzsvany V, Svancara I, Trtić-Petrović TM, Purenović MM, Vytras K. Trace Determination of Carbendazim Fungicide Using Adsorptive Stripping Voltammetry with a Carbon Paste Electrode Containing Tricresyl Phosphate. in International Journal of Electrochemical Science. 2012;7(10):9717-9731.
https://hdl.handle.net/21.15107/rcub_vinar_5235 .

Ashrafi, Amir M., Đorđević, Jelena S., Guzsvany, Valeria, Svancara, Ivan, Trtić-Petrović, Tatjana M., Purenović, Milovan M., Vytras, Karel, "Trace Determination of Carbendazim Fungicide Using Adsorptive Stripping Voltammetry with a Carbon Paste Electrode Containing Tricresyl Phosphate" in International Journal of Electrochemical Science, 7, no. 10 (2012):9717-9731,
https://hdl.handle.net/21.15107/rcub_vinar_5235 .