Slovenian Research Agency “Nanotheranostics based on magneto-responsive materials” (No. J1-7302)

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Slovenian Research Agency “Nanotheranostics based on magneto-responsive materials” (No. J1-7302)

Authors

Publications

Synthesis, particle shape characterization, magnetic properties and surface modification of superparamagnetic iron oxide nanochains

Tadić, Marin; Kralj, Slavko; Kopanja, Lazar

(2019)

TY  - JOUR
AU  - Tadić, Marin
AU  - Kralj, Slavko
AU  - Kopanja, Lazar
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S1044580318323763
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8005
AB  - We report monodisperse, chain-like particles (nanochains) consisted of silica-coated maghemite (γ-Fe2O3) nanoparticle clusters prepared by colloidal chemistry and magnetic field-induced self-assembly of nanoparticle clusters. In order to quantify the shapes of chain-like particles, we have used the measure for shape convexity which is also called solidity. We functionalize the surface of the nanochains with amino (–NH2) and carboxyl groups (–COOH) in order to modify surface charge. These surfaces of nanochains provide better colloidal stability and their potential for practical applications in biomedicine. The enhanced colloidal stability of the surface modified nanochains is confirmed by Zeta potential (ζ-potential) analysis. Magnetic properties of the nanochains show superparamagnetic state at room temperature since the nanochains are composed of tiny nanoparticles as their building blocks. The measured M(H) data at room temperature have been successfully fitted by the Langevin function and magnetic moment μp = 20,526 μB for sphere-like nanoparticle clusters and μp = 20,767 μB for nanochains are determined. The determined magnetic parameters have revealed that the nanochains show a magnetic moment of the nanoparticles higher than the one of individual nanoparticle clusters. These differences can be attributed to the collective magnetic properties of superparamagnetic iron oxide nanoparticles (SPION) assembled in different morphologies (isotropic and anisotropic morphology). © 2018
T2  - Materials Characterization
T1  - Synthesis, particle shape characterization, magnetic properties and surface modification of superparamagnetic iron oxide nanochains
VL  - 148
SP  - 123
EP  - 133
DO  - 10.1016/j.matchar.2018.12.014
ER  - 
@article{
author = "Tadić, Marin and Kralj, Slavko and Kopanja, Lazar",
year = "2019",
abstract = "We report monodisperse, chain-like particles (nanochains) consisted of silica-coated maghemite (γ-Fe2O3) nanoparticle clusters prepared by colloidal chemistry and magnetic field-induced self-assembly of nanoparticle clusters. In order to quantify the shapes of chain-like particles, we have used the measure for shape convexity which is also called solidity. We functionalize the surface of the nanochains with amino (–NH2) and carboxyl groups (–COOH) in order to modify surface charge. These surfaces of nanochains provide better colloidal stability and their potential for practical applications in biomedicine. The enhanced colloidal stability of the surface modified nanochains is confirmed by Zeta potential (ζ-potential) analysis. Magnetic properties of the nanochains show superparamagnetic state at room temperature since the nanochains are composed of tiny nanoparticles as their building blocks. The measured M(H) data at room temperature have been successfully fitted by the Langevin function and magnetic moment μp = 20,526 μB for sphere-like nanoparticle clusters and μp = 20,767 μB for nanochains are determined. The determined magnetic parameters have revealed that the nanochains show a magnetic moment of the nanoparticles higher than the one of individual nanoparticle clusters. These differences can be attributed to the collective magnetic properties of superparamagnetic iron oxide nanoparticles (SPION) assembled in different morphologies (isotropic and anisotropic morphology). © 2018",
journal = "Materials Characterization",
title = "Synthesis, particle shape characterization, magnetic properties and surface modification of superparamagnetic iron oxide nanochains",
volume = "148",
pages = "123-133",
doi = "10.1016/j.matchar.2018.12.014"
}
Tadić, M., Kralj, S.,& Kopanja, L.. (2019). Synthesis, particle shape characterization, magnetic properties and surface modification of superparamagnetic iron oxide nanochains. in Materials Characterization, 148, 123-133.
https://doi.org/10.1016/j.matchar.2018.12.014
Tadić M, Kralj S, Kopanja L. Synthesis, particle shape characterization, magnetic properties and surface modification of superparamagnetic iron oxide nanochains. in Materials Characterization. 2019;148:123-133.
doi:10.1016/j.matchar.2018.12.014 .
Tadić, Marin, Kralj, Slavko, Kopanja, Lazar, "Synthesis, particle shape characterization, magnetic properties and surface modification of superparamagnetic iron oxide nanochains" in Materials Characterization, 148 (2019):123-133,
https://doi.org/10.1016/j.matchar.2018.12.014 . .
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