Slovenian Research Agency - Slovenia [P2-0091]

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Slovenian Research Agency - Slovenia [P2-0091]

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Luminescence properties of Eu3+ activated Y2MoO6 powders calcined at different temperatures

Stanković, Nadežda; Nikolić, Marko G.; Jelenković, Branislav; Daneu, Nina; Maletaškić, Jelena; Prekajski-Đorđević, Marija D.; Matović, Branko

(2020)

TY  - JOUR
AU  - Stanković, Nadežda
AU  - Nikolić, Marko G.
AU  - Jelenković, Branislav
AU  - Daneu, Nina
AU  - Maletaškić, Jelena
AU  - Prekajski-Đorđević, Marija D.
AU  - Matović, Branko
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9009
AB  - In the last decade, an immense progress has been made in white LEDs, mainly due to the development of red-emitting phosphors. In this paper, we report on the synthesis of Eu3+ activated Y2MoO6 by a self-initiated and self-sustained method. The obtained powder was calcined at various temperatures in the 600–1400 °C range and examined by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and photoluminescence spectroscopy (PL). The results revealed that all powders are single phase Y2MoO6:Eu3+, with particle size in the nanorange at lower treatment temperatures (600 and 800 °C) and in the microrange at higher calcination temperatures (1000–1400 °C). The obtained powders are promising materials for white light-emitting diodes as they can efficiently absorb energy in 324–425 nm region (near-UV to blue light region) and emit at 611 nm in the red region of the spectrum, while exhibiting high thermal and chemical stability.
T2  - Processing and Application of Ceramics
T1  - Luminescence properties of Eu3+ activated Y2MoO6 powders calcined at different temperatures
VL  - 14
IS  - 1
SP  - 71
EP  - 76
DO  - 10.2298/PAC2001071S
ER  - 
@article{
author = "Stanković, Nadežda and Nikolić, Marko G. and Jelenković, Branislav and Daneu, Nina and Maletaškić, Jelena and Prekajski-Đorđević, Marija D. and Matović, Branko",
year = "2020",
abstract = "In the last decade, an immense progress has been made in white LEDs, mainly due to the development of red-emitting phosphors. In this paper, we report on the synthesis of Eu3+ activated Y2MoO6 by a self-initiated and self-sustained method. The obtained powder was calcined at various temperatures in the 600–1400 °C range and examined by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM) and photoluminescence spectroscopy (PL). The results revealed that all powders are single phase Y2MoO6:Eu3+, with particle size in the nanorange at lower treatment temperatures (600 and 800 °C) and in the microrange at higher calcination temperatures (1000–1400 °C). The obtained powders are promising materials for white light-emitting diodes as they can efficiently absorb energy in 324–425 nm region (near-UV to blue light region) and emit at 611 nm in the red region of the spectrum, while exhibiting high thermal and chemical stability.",
journal = "Processing and Application of Ceramics",
title = "Luminescence properties of Eu3+ activated Y2MoO6 powders calcined at different temperatures",
volume = "14",
number = "1",
pages = "71-76",
doi = "10.2298/PAC2001071S"
}
Stanković, N., Nikolić, M. G., Jelenković, B., Daneu, N., Maletaškić, J., Prekajski-Đorđević, M. D.,& Matović, B.. (2020). Luminescence properties of Eu3+ activated Y2MoO6 powders calcined at different temperatures. in Processing and Application of Ceramics, 14(1), 71-76.
https://doi.org/10.2298/PAC2001071S
Stanković N, Nikolić MG, Jelenković B, Daneu N, Maletaškić J, Prekajski-Đorđević MD, Matović B. Luminescence properties of Eu3+ activated Y2MoO6 powders calcined at different temperatures. in Processing and Application of Ceramics. 2020;14(1):71-76.
doi:10.2298/PAC2001071S .
Stanković, Nadežda, Nikolić, Marko G., Jelenković, Branislav, Daneu, Nina, Maletaškić, Jelena, Prekajski-Đorđević, Marija D., Matović, Branko, "Luminescence properties of Eu3+ activated Y2MoO6 powders calcined at different temperatures" in Processing and Application of Ceramics, 14, no. 1 (2020):71-76,
https://doi.org/10.2298/PAC2001071S . .
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Tailoring the electrochemical charge storage properties of carbonaceous support by redox properties of heteropoly acids: where does the synergy come from?

Bajuk-Bogdanović, Danica V.; Holclajtner-Antunović, Ivanka D.; Jovanović, Zoran M.; Mravik, Željko; Krstić, Jugoslav B.; Uskoković-Marković, Snežana; Vujković, Milica

(2019)

TY  - JOUR
AU  - Bajuk-Bogdanović, Danica V.
AU  - Holclajtner-Antunović, Ivanka D.
AU  - Jovanović, Zoran M.
AU  - Mravik, Željko
AU  - Krstić, Jugoslav B.
AU  - Uskoković-Marković, Snežana
AU  - Vujković, Milica
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8500
AB  - The synergistic effects between two Keggin-type heteropoly acids (HPAs) and carbon surface were examined and elucidated. An improved high rate capability (and potential high capacitor electrode for supercapacitors) of the hybrid materials, obtained by anchoring of α-dodecamolybdophosphoric (MoPA), α-dodecatungstophosphoric (WPA), and their mixture to activated carbon (AC), was achieved through the different mechanism of interaction. In order to elaborate this, a detailed analysis of AC-HPA composites has been performed by scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) analysis, temperature-programmed desorption (TPD), Fourier-transform infrared spectroscopy (FTIR), micro Raman spectroscopy, and zeta potential measurements. The zeta potential measurements revealed positive charge of carbon surface thus indicating attractive interactions with negatively charged Keggin anion. The surface analysis has shown that WPA spontaneously reduces the carbon surface, while interaction with MoPA leads to its oxidation. As the consequence of the tailoring of the functional groups at carbon surface through HPAs’ action, the distortion of cyclic voltammograms (CVs) decreased in the following order: AC-MoPA, AC-MoPA-WPA, and AC-WPA. A prominent rectangular shape of AC-WPA, even at an extremely high scan rate of 400 mVs−1, was measured, which is rarely demonstrated for carbon-based composites. By applying the theory of electrode potentials, the HPA-AC synergistic effect was explained and discussed in terms of charge storage improvement of HPA-modified carbon. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.
T2  - Journal of Solid State Electrochemistry
T1  - Tailoring the electrochemical charge storage properties of carbonaceous support by redox properties of heteropoly acids: where does the synergy come from?
VL  - 23
IS  - 9
SP  - 2747
EP  - 2758
DO  - 10.1007/s10008-019-04369-4
ER  - 
@article{
author = "Bajuk-Bogdanović, Danica V. and Holclajtner-Antunović, Ivanka D. and Jovanović, Zoran M. and Mravik, Željko and Krstić, Jugoslav B. and Uskoković-Marković, Snežana and Vujković, Milica",
year = "2019",
abstract = "The synergistic effects between two Keggin-type heteropoly acids (HPAs) and carbon surface were examined and elucidated. An improved high rate capability (and potential high capacitor electrode for supercapacitors) of the hybrid materials, obtained by anchoring of α-dodecamolybdophosphoric (MoPA), α-dodecatungstophosphoric (WPA), and their mixture to activated carbon (AC), was achieved through the different mechanism of interaction. In order to elaborate this, a detailed analysis of AC-HPA composites has been performed by scanning electron microscopy (SEM), Brunauer–Emmett–Teller (BET) analysis, temperature-programmed desorption (TPD), Fourier-transform infrared spectroscopy (FTIR), micro Raman spectroscopy, and zeta potential measurements. The zeta potential measurements revealed positive charge of carbon surface thus indicating attractive interactions with negatively charged Keggin anion. The surface analysis has shown that WPA spontaneously reduces the carbon surface, while interaction with MoPA leads to its oxidation. As the consequence of the tailoring of the functional groups at carbon surface through HPAs’ action, the distortion of cyclic voltammograms (CVs) decreased in the following order: AC-MoPA, AC-MoPA-WPA, and AC-WPA. A prominent rectangular shape of AC-WPA, even at an extremely high scan rate of 400 mVs−1, was measured, which is rarely demonstrated for carbon-based composites. By applying the theory of electrode potentials, the HPA-AC synergistic effect was explained and discussed in terms of charge storage improvement of HPA-modified carbon. © 2019, Springer-Verlag GmbH Germany, part of Springer Nature.",
journal = "Journal of Solid State Electrochemistry",
title = "Tailoring the electrochemical charge storage properties of carbonaceous support by redox properties of heteropoly acids: where does the synergy come from?",
volume = "23",
number = "9",
pages = "2747-2758",
doi = "10.1007/s10008-019-04369-4"
}
Bajuk-Bogdanović, D. V., Holclajtner-Antunović, I. D., Jovanović, Z. M., Mravik, Ž., Krstić, J. B., Uskoković-Marković, S.,& Vujković, M.. (2019). Tailoring the electrochemical charge storage properties of carbonaceous support by redox properties of heteropoly acids: where does the synergy come from?. in Journal of Solid State Electrochemistry, 23(9), 2747-2758.
https://doi.org/10.1007/s10008-019-04369-4
Bajuk-Bogdanović DV, Holclajtner-Antunović ID, Jovanović ZM, Mravik Ž, Krstić JB, Uskoković-Marković S, Vujković M. Tailoring the electrochemical charge storage properties of carbonaceous support by redox properties of heteropoly acids: where does the synergy come from?. in Journal of Solid State Electrochemistry. 2019;23(9):2747-2758.
doi:10.1007/s10008-019-04369-4 .
Bajuk-Bogdanović, Danica V., Holclajtner-Antunović, Ivanka D., Jovanović, Zoran M., Mravik, Željko, Krstić, Jugoslav B., Uskoković-Marković, Snežana, Vujković, Milica, "Tailoring the electrochemical charge storage properties of carbonaceous support by redox properties of heteropoly acids: where does the synergy come from?" in Journal of Solid State Electrochemistry, 23, no. 9 (2019):2747-2758,
https://doi.org/10.1007/s10008-019-04369-4 . .
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