Ministry of Science, Republic of Serbia [142001]

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Ministry of Science, Republic of Serbia [142001]

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Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters

Veličković, Suzana; Đorđević, Vesna R.; Cvetićanin, Jelena M.; Đustebek, Jasmina B.; Veljković, Miomir V.; Nešković, Olivera M.

(2008)

TY  - JOUR
AU  - Veličković, Suzana
AU  - Đorđević, Vesna R.
AU  - Cvetićanin, Jelena M.
AU  - Đustebek, Jasmina B.
AU  - Veljković, Miomir V.
AU  - Nešković, Olivera M.
PY  - 2008
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3547
AB  - Ionization energies of non-stoichiometric LinFn-1 (n =3,4, 6) clusters determined by a thermal ionization mass spectrometry (TIMS) were 4.2 +/- 0.2 eV for Li3F2, 4.3 +/- 0.2 eV for Li4F3 and 4.1 +/- 0.2 eV for Li6F5. The ionization energy of Li6F5 cluster was obtained experimentally for the first time. The ionization energies of Li3F2 and Li4F3 are in correlation with the results obtained by photoionization time-of-flight mass spectrometry. The determined ionization energies are comparable with theoretical ionization energies calculated by ab initio method. The theoretical predictions supported that the most stable isomers of a non-stoichiometric cluster LinFn-1 (n = 3 and n = 4) in which the excess electron localizes on a specific site have a segregated electronic structure composed of the metallic part and ionic part. (C) 2008 Elsevier Ltd. All rights reserved.
T2  - Vacuum
T1  - Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters
VL  - 83
IS  - 2
SP  - 378
EP  - 380
DO  - 10.1016/j.vacuum.2008.05.026
ER  - 
@article{
author = "Veličković, Suzana and Đorđević, Vesna R. and Cvetićanin, Jelena M. and Đustebek, Jasmina B. and Veljković, Miomir V. and Nešković, Olivera M.",
year = "2008",
abstract = "Ionization energies of non-stoichiometric LinFn-1 (n =3,4, 6) clusters determined by a thermal ionization mass spectrometry (TIMS) were 4.2 +/- 0.2 eV for Li3F2, 4.3 +/- 0.2 eV for Li4F3 and 4.1 +/- 0.2 eV for Li6F5. The ionization energy of Li6F5 cluster was obtained experimentally for the first time. The ionization energies of Li3F2 and Li4F3 are in correlation with the results obtained by photoionization time-of-flight mass spectrometry. The determined ionization energies are comparable with theoretical ionization energies calculated by ab initio method. The theoretical predictions supported that the most stable isomers of a non-stoichiometric cluster LinFn-1 (n = 3 and n = 4) in which the excess electron localizes on a specific site have a segregated electronic structure composed of the metallic part and ionic part. (C) 2008 Elsevier Ltd. All rights reserved.",
journal = "Vacuum",
title = "Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters",
volume = "83",
number = "2",
pages = "378-380",
doi = "10.1016/j.vacuum.2008.05.026"
}
Veličković, S., Đorđević, V. R., Cvetićanin, J. M., Đustebek, J. B., Veljković, M. V.,& Nešković, O. M.. (2008). Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters. in Vacuum, 83(2), 378-380.
https://doi.org/10.1016/j.vacuum.2008.05.026
Veličković S, Đorđević VR, Cvetićanin JM, Đustebek JB, Veljković MV, Nešković OM. Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters. in Vacuum. 2008;83(2):378-380.
doi:10.1016/j.vacuum.2008.05.026 .
Veličković, Suzana, Đorđević, Vesna R., Cvetićanin, Jelena M., Đustebek, Jasmina B., Veljković, Miomir V., Nešković, Olivera M., "Ionization energies of the non-stoichiometric LinFn-1 (n=3, 4, 6) clusters" in Vacuum, 83, no. 2 (2008):378-380,
https://doi.org/10.1016/j.vacuum.2008.05.026 . .
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