European Union under REA (609427)

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European Union under REA (609427)

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Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity

Kepić, Dejan P.; Ristić, Ivan S.; Marinović-Cincović, Milena; Peruško, Davor; Špitalsky, Zdenko; Pavlović, Vladimir B.; Budimir, Milica; Šiffalovič, Peter; Dramićanin, Miroslav; Mičušik, Matej; Kleinova, Angela; Janigova, Ivica; Marković, Zoran M.; Todorović-Marković, Biljana

(2018)

TY  - JOUR
AU  - Kepić, Dejan P.
AU  - Ristić, Ivan S.
AU  - Marinović-Cincović, Milena
AU  - Peruško, Davor
AU  - Špitalsky, Zdenko
AU  - Pavlović, Vladimir B.
AU  - Budimir, Milica
AU  - Šiffalovič, Peter
AU  - Dramićanin, Miroslav
AU  - Mičušik, Matej
AU  - Kleinova, Angela
AU  - Janigova, Ivica
AU  - Marković, Zoran M.
AU  - Todorović-Marković, Biljana
PY  - 2018
UR  - http://doi.wiley.com/10.1002/pi.5620
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7796
AB  - This paper reports a simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene.
T2  - Polymer International
T1  - Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity
VL  - 67
IS  - 8
SP  - 1118
EP  - 1127
DO  - 10.1002/pi.5620
ER  - 
@article{
author = "Kepić, Dejan P. and Ristić, Ivan S. and Marinović-Cincović, Milena and Peruško, Davor and Špitalsky, Zdenko and Pavlović, Vladimir B. and Budimir, Milica and Šiffalovič, Peter and Dramićanin, Miroslav and Mičušik, Matej and Kleinova, Angela and Janigova, Ivica and Marković, Zoran M. and Todorović-Marković, Biljana",
year = "2018",
abstract = "This paper reports a simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) (SBS) nanocomposite films employing a vacuum filtration method. Graphene is exfoliated well by an electrochemical procedure and homogeneously dispersed in the polymer matrix. The prepared nanocomposite films were characterized by XRD, Fourier transform IR (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, AFM and SEM. Morphological studies showed that graphene formed a smooth coating over the surface of SBS. The increase in graphene concentration induces the wrinkling of graphene sheets at the composite surface which causes a further increase in surface roughness. The FTIR, Raman and XPS spectra of graphene/SBS nanocomposite films indicate the strong interactions between graphene and the polymer matrix. According to the XRD patterns, introducing SBS into graphene did not modify the graphene structure additionally, i.e. the crystal lattice parameters do not depend on SBS content in graphene/SBS nanocomposite films. The graphene/SBS nanocomposite films also exhibited better hydrophobicity due to the increased surface roughness and lower sheet resistivity (reduced 10 times) compared to exfoliated graphene.",
journal = "Polymer International",
title = "Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity",
volume = "67",
number = "8",
pages = "1118-1127",
doi = "10.1002/pi.5620"
}
Kepić, D. P., Ristić, I. S., Marinović-Cincović, M., Peruško, D., Špitalsky, Z., Pavlović, V. B., Budimir, M., Šiffalovič, P., Dramićanin, M., Mičušik, M., Kleinova, A., Janigova, I., Marković, Z. M.,& Todorović-Marković, B.. (2018). Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity. in Polymer International, 67(8), 1118-1127.
https://doi.org/10.1002/pi.5620
Kepić DP, Ristić IS, Marinović-Cincović M, Peruško D, Špitalsky Z, Pavlović VB, Budimir M, Šiffalovič P, Dramićanin M, Mičušik M, Kleinova A, Janigova I, Marković ZM, Todorović-Marković B. Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity. in Polymer International. 2018;67(8):1118-1127.
doi:10.1002/pi.5620 .
Kepić, Dejan P., Ristić, Ivan S., Marinović-Cincović, Milena, Peruško, Davor, Špitalsky, Zdenko, Pavlović, Vladimir B., Budimir, Milica, Šiffalovič, Peter, Dramićanin, Miroslav, Mičušik, Matej, Kleinova, Angela, Janigova, Ivica, Marković, Zoran M., Todorović-Marković, Biljana, "Simple route for the preparation of graphene/poly(styrene-b-butadiene-b-styrene) nanocomposite films with enhanced electrical conductivity and hydrophobicity" in Polymer International, 67, no. 8 (2018):1118-1127,
https://doi.org/10.1002/pi.5620 . .
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