Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča)

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Ministry of Education, Science and Technological Development, Republic of Serbia, Grant no. 451-03-68/2020-14/200017 (University of Belgrade, Institute of Nuclear Sciences 'Vinča', Belgrade-Vinča) (en)
Ministarstvo prosvete, nauke i tehnološkog razvoja Republike Srbije, Ugovor br. 451-03-68/2020-14/200017 (Univerzitet u Beogradu, Institut za nuklearne nauke Vinča, Beograd-Vinča) (sr_RS)
Министарство просвете, науке и технолошког развоја Републике Србије, Уговор бр. 451-03-68/2020-14/200017 (Универзитет у Београду, Институт за нуклеарне науке Винча, Београд-Винча) (sr)
Authors

Publications

Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour

Krstić, Marko Z.; Rogić Miladinović, Z.; Barudžija, Tanja S.; Mladenović, Aleksandar R.; Suljovrujić, Edin

(2022)

TY  - JOUR
AU  - Krstić, Marko Z.
AU  - Rogić Miladinović, Z.
AU  - Barudžija, Tanja S.
AU  - Mladenović, Aleksandar R.
AU  - Suljovrujić, Edin
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10097
AB  - Di(meth)acrylate (D(M)A) systems with pendant oligo(ethylene glycol) (OEG) chains are promising biomedical candidates. Homopolymeric P(OEG)D(M)A hydrogels have significant thermoresponsiveness demonstrated mainly at elevated temperatures which makes this class of materials unsuitable for bio-applications. Copolymerisation with less hydrophilic 2-hydroxyethyl methacrylate (HEMA) was performed in an effort to shift volume phase transition (VPT) closer to physiological temperatures and to widen their application as thermoresponsive materials. Various monomer-solvent mixtures, consisting of different mole ratios of OEGDMA and HEMA monomers (100/0, 50/50, 27.5/72.5, and 12.5/87.5) and water/ethanol as solvent, were exposed to gamma radiation up to 6, 12, 25, and 50 kGy. Furthermore, in an attempt to obtain multi- (thermo- and pH-) responsive hydrogels for biomedical applications new P(OEGDMA/HEMA/IA) terpolymers containing a small share (2.5, and 5 wt%) of itaconic acid (IA) were synthesised. The successful fabrication of the hydrogels was confirmed by gel measurements and FTIR spectroscopy. Swelling measurements indicated that obtained networks possessed tuneable thermal behaviour and swelling properties which could be significantly altered by hydrogel composition. The porous architecture was investigated using SEM, confirming swelling results. Cytotoxicity revealed relatively high cell viability for all hydrogels, indicating satisfactory in vitro biocompatibility. Therefore, new OEGDMA based hydrogels showed potential for biomedical applications.
T2  - Reactive and Functional Polymers
T1  - Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour
VL  - 170
SP  - 105140
DO  - 10.1016/j.reactfunctpolym.2021.105140
ER  - 
@article{
author = "Krstić, Marko Z. and Rogić Miladinović, Z. and Barudžija, Tanja S. and Mladenović, Aleksandar R. and Suljovrujić, Edin",
year = "2022",
abstract = "Di(meth)acrylate (D(M)A) systems with pendant oligo(ethylene glycol) (OEG) chains are promising biomedical candidates. Homopolymeric P(OEG)D(M)A hydrogels have significant thermoresponsiveness demonstrated mainly at elevated temperatures which makes this class of materials unsuitable for bio-applications. Copolymerisation with less hydrophilic 2-hydroxyethyl methacrylate (HEMA) was performed in an effort to shift volume phase transition (VPT) closer to physiological temperatures and to widen their application as thermoresponsive materials. Various monomer-solvent mixtures, consisting of different mole ratios of OEGDMA and HEMA monomers (100/0, 50/50, 27.5/72.5, and 12.5/87.5) and water/ethanol as solvent, were exposed to gamma radiation up to 6, 12, 25, and 50 kGy. Furthermore, in an attempt to obtain multi- (thermo- and pH-) responsive hydrogels for biomedical applications new P(OEGDMA/HEMA/IA) terpolymers containing a small share (2.5, and 5 wt%) of itaconic acid (IA) were synthesised. The successful fabrication of the hydrogels was confirmed by gel measurements and FTIR spectroscopy. Swelling measurements indicated that obtained networks possessed tuneable thermal behaviour and swelling properties which could be significantly altered by hydrogel composition. The porous architecture was investigated using SEM, confirming swelling results. Cytotoxicity revealed relatively high cell viability for all hydrogels, indicating satisfactory in vitro biocompatibility. Therefore, new OEGDMA based hydrogels showed potential for biomedical applications.",
journal = "Reactive and Functional Polymers",
title = "Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour",
volume = "170",
pages = "105140",
doi = "10.1016/j.reactfunctpolym.2021.105140"
}
Krstić, M. Z., Rogić Miladinović, Z., Barudžija, T. S., Mladenović, A. R.,& Suljovrujić, E.. (2022). Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour. in Reactive and Functional Polymers, 170, 105140.
https://doi.org/10.1016/j.reactfunctpolym.2021.105140
Krstić MZ, Rogić Miladinović Z, Barudžija TS, Mladenović AR, Suljovrujić E. Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour. in Reactive and Functional Polymers. 2022;170:105140.
doi:10.1016/j.reactfunctpolym.2021.105140 .
Krstić, Marko Z., Rogić Miladinović, Z., Barudžija, Tanja S., Mladenović, Aleksandar R., Suljovrujić, Edin, "Stimuli-responsive copolymeric hydrogels based on oligo(ethylene glycol) dimethacrylate for biomedical applications: An optimisation study of pH and thermoresponsive behaviour" in Reactive and Functional Polymers, 170 (2022):105140,
https://doi.org/10.1016/j.reactfunctpolym.2021.105140 . .

A comparison of alpha-particle and gamma-ray spectrometry methods for determination of 235U, 238U and 226Ra activity concentration in samples of coal, slag and fly-ash

Vukanac, Ivana; Šešlak, Bojan; Kandić, Aleksandar; Čeliković, Igor; Mladenović Nikolić, Nataša; Milanović, Tamara; Obradović, Zorica; Đurašević, Mirjana

(2022)

TY  - JOUR
AU  - Vukanac, Ivana
AU  - Šešlak, Bojan
AU  - Kandić, Aleksandar
AU  - Čeliković, Igor
AU  - Mladenović Nikolić, Nataša
AU  - Milanović, Tamara
AU  - Obradović, Zorica
AU  - Đurašević, Mirjana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10096
AB  - In order to compare alpha-particle and gamma-ray spectrometry, the activity concentrations of 235U, 238U and 226Ra in samples of coal, slag and fly-ash from the thermal power plant “Nikola Tesla A”, Serbia, were determined by these two methods. Methods were compared and discussed from the point of view of its precision, difficulty to apply and complexity. Gamma-ray spectrometry was performed with HPGe (High Purity Germanium) spectrometer, while alpha activity was measured by PIPS (Passivated Implanted Planar Silicon) detector. For the alpha-particle spectrometry, the chemical procedures applied were chromatographic resin extraction for uranium isotopes and micro-coprecipitation for 226Ra. Thin alpha sources were prepared by electrodeposition and filtration through polypropylene membrane filter for uranium determination, while filtration technique was performed for radium sources. For the evaluation of the statistical difference between individual measurement results obtained by application of two methods Z - test was used. In order to evaluate the difference between two methods used, paired samples t-test and F-test were applied. Results show that there is no statistical difference between two methods used and that gamma-ray spectrometry is a valid alternative to time consuming alpha spectrometry.
T2  - Radiation Physics and Chemistry
T1  - A comparison of alpha-particle and gamma-ray spectrometry methods for determination of 235U, 238U and 226Ra activity concentration in samples of coal, slag and fly-ash
VL  - 193
SP  - 109933
DO  - 10.1016/j.radphyschem.2021.109933
ER  - 
@article{
author = "Vukanac, Ivana and Šešlak, Bojan and Kandić, Aleksandar and Čeliković, Igor and Mladenović Nikolić, Nataša and Milanović, Tamara and Obradović, Zorica and Đurašević, Mirjana",
year = "2022",
abstract = "In order to compare alpha-particle and gamma-ray spectrometry, the activity concentrations of 235U, 238U and 226Ra in samples of coal, slag and fly-ash from the thermal power plant “Nikola Tesla A”, Serbia, were determined by these two methods. Methods were compared and discussed from the point of view of its precision, difficulty to apply and complexity. Gamma-ray spectrometry was performed with HPGe (High Purity Germanium) spectrometer, while alpha activity was measured by PIPS (Passivated Implanted Planar Silicon) detector. For the alpha-particle spectrometry, the chemical procedures applied were chromatographic resin extraction for uranium isotopes and micro-coprecipitation for 226Ra. Thin alpha sources were prepared by electrodeposition and filtration through polypropylene membrane filter for uranium determination, while filtration technique was performed for radium sources. For the evaluation of the statistical difference between individual measurement results obtained by application of two methods Z - test was used. In order to evaluate the difference between two methods used, paired samples t-test and F-test were applied. Results show that there is no statistical difference between two methods used and that gamma-ray spectrometry is a valid alternative to time consuming alpha spectrometry.",
journal = "Radiation Physics and Chemistry",
title = "A comparison of alpha-particle and gamma-ray spectrometry methods for determination of 235U, 238U and 226Ra activity concentration in samples of coal, slag and fly-ash",
volume = "193",
pages = "109933",
doi = "10.1016/j.radphyschem.2021.109933"
}
Vukanac, I., Šešlak, B., Kandić, A., Čeliković, I., Mladenović Nikolić, N., Milanović, T., Obradović, Z.,& Đurašević, M.. (2022). A comparison of alpha-particle and gamma-ray spectrometry methods for determination of 235U, 238U and 226Ra activity concentration in samples of coal, slag and fly-ash. in Radiation Physics and Chemistry, 193, 109933.
https://doi.org/10.1016/j.radphyschem.2021.109933
Vukanac I, Šešlak B, Kandić A, Čeliković I, Mladenović Nikolić N, Milanović T, Obradović Z, Đurašević M. A comparison of alpha-particle and gamma-ray spectrometry methods for determination of 235U, 238U and 226Ra activity concentration in samples of coal, slag and fly-ash. in Radiation Physics and Chemistry. 2022;193:109933.
doi:10.1016/j.radphyschem.2021.109933 .
Vukanac, Ivana, Šešlak, Bojan, Kandić, Aleksandar, Čeliković, Igor, Mladenović Nikolić, Nataša, Milanović, Tamara, Obradović, Zorica, Đurašević, Mirjana, "A comparison of alpha-particle and gamma-ray spectrometry methods for determination of 235U, 238U and 226Ra activity concentration in samples of coal, slag and fly-ash" in Radiation Physics and Chemistry, 193 (2022):109933,
https://doi.org/10.1016/j.radphyschem.2021.109933 . .

Properties of free-standing graphene oxide/silver nanowires films and effects of chemical reduction and gamma irradiation

Mišović, Aleksandra; Bajuk-Bogdanović, Danica V.; Kepić, Dejan; Pavlović, Vladimir B.; Huskić, Miroslav; Hasheminejad, Navid; Vuye, Cedric; Zorić, Nemanja; Jovanović, Svetlana

(2022)

TY  - JOUR
AU  - Mišović, Aleksandra
AU  - Bajuk-Bogdanović, Danica V.
AU  - Kepić, Dejan
AU  - Pavlović, Vladimir B.
AU  - Huskić, Miroslav
AU  - Hasheminejad, Navid
AU  - Vuye, Cedric
AU  - Zorić, Nemanja
AU  - Jovanović, Svetlana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10078
AB  - The need for stable, chemical resistant and conductive materials is on the rise in recent times. Graphene shows promising electrical conductivity and chemical stability, but the production of a continual, conductive layer is limited and expensive. Silver nanowires (AgNWs) are both conducive and economically viable, but they are sensitive to water and oxygen. In this study, graphene oxide (GO) and AgNWs were synthesized and combined in different mass ratios (3:1, 2.5:1.5, and 1:1) to obtain chemically stable composites with improved electrical properties. Composites were reduced using ascorbic acid. With the increase of AgNWs to GO mass ratio, the surface of the free-standing composite film improved: the root mean square roughness was lowered from 376 nm for GO to 168 nm for the composite with the mass ratio of GO:AgNWs 1:1, while the sheet resistance was lowered from 146 × 106 Ω/□ to 4 Ω/□. For the first time, the effects of gamma irradiation on the structure of the composites were studied. Doses of 15, 25, and 35 kGy were applied.
T2  - Synthetic Metals
T1  - Properties of free-standing graphene oxide/silver nanowires films and effects of chemical reduction and gamma irradiation
VL  - 283
SP  - 116980
DO  - 10.1016/j.synthmet.2021.116980
ER  - 
@article{
author = "Mišović, Aleksandra and Bajuk-Bogdanović, Danica V. and Kepić, Dejan and Pavlović, Vladimir B. and Huskić, Miroslav and Hasheminejad, Navid and Vuye, Cedric and Zorić, Nemanja and Jovanović, Svetlana",
year = "2022",
abstract = "The need for stable, chemical resistant and conductive materials is on the rise in recent times. Graphene shows promising electrical conductivity and chemical stability, but the production of a continual, conductive layer is limited and expensive. Silver nanowires (AgNWs) are both conducive and economically viable, but they are sensitive to water and oxygen. In this study, graphene oxide (GO) and AgNWs were synthesized and combined in different mass ratios (3:1, 2.5:1.5, and 1:1) to obtain chemically stable composites with improved electrical properties. Composites were reduced using ascorbic acid. With the increase of AgNWs to GO mass ratio, the surface of the free-standing composite film improved: the root mean square roughness was lowered from 376 nm for GO to 168 nm for the composite with the mass ratio of GO:AgNWs 1:1, while the sheet resistance was lowered from 146 × 106 Ω/□ to 4 Ω/□. For the first time, the effects of gamma irradiation on the structure of the composites were studied. Doses of 15, 25, and 35 kGy were applied.",
journal = "Synthetic Metals",
title = "Properties of free-standing graphene oxide/silver nanowires films and effects of chemical reduction and gamma irradiation",
volume = "283",
pages = "116980",
doi = "10.1016/j.synthmet.2021.116980"
}
Mišović, A., Bajuk-Bogdanović, D. V., Kepić, D., Pavlović, V. B., Huskić, M., Hasheminejad, N., Vuye, C., Zorić, N.,& Jovanović, S.. (2022). Properties of free-standing graphene oxide/silver nanowires films and effects of chemical reduction and gamma irradiation. in Synthetic Metals, 283, 116980.
https://doi.org/10.1016/j.synthmet.2021.116980
Mišović A, Bajuk-Bogdanović DV, Kepić D, Pavlović VB, Huskić M, Hasheminejad N, Vuye C, Zorić N, Jovanović S. Properties of free-standing graphene oxide/silver nanowires films and effects of chemical reduction and gamma irradiation. in Synthetic Metals. 2022;283:116980.
doi:10.1016/j.synthmet.2021.116980 .
Mišović, Aleksandra, Bajuk-Bogdanović, Danica V., Kepić, Dejan, Pavlović, Vladimir B., Huskić, Miroslav, Hasheminejad, Navid, Vuye, Cedric, Zorić, Nemanja, Jovanović, Svetlana, "Properties of free-standing graphene oxide/silver nanowires films and effects of chemical reduction and gamma irradiation" in Synthetic Metals, 283 (2022):116980,
https://doi.org/10.1016/j.synthmet.2021.116980 . .

Development and Validation of an Open-Source Finite-Volume Method Solver for Viscoplastic Flows

Mirkov, Nikola S.; Ouyahia, Seif Eddine; Lahlou, Sara; Pezo, Milada L.; Jovanović, Rastko D.

(2022)

TY  - CHAP
AU  - Mirkov, Nikola S.
AU  - Ouyahia, Seif Eddine
AU  - Lahlou, Sara
AU  - Pezo, Milada L.
AU  - Jovanović, Rastko D.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10065
AB  - In the present paper, we discuss implementation details of a free and open-source numerical solver based on the finite volume method for numerical simulation of viscoplastic non-Newtonian fluids. In addition to the fact that they are involved in many industrial applications, both their physical properties and their rheological behavior make them challenging for numerical simulation. Viscoplastic fluids are known to behave as solid unless the shear stress reaches a critical level, known as yield-stress, beyond which they behave as liquid. In most cases, both yielded and unyielded regions coexist in the fluid domain. In mathematical model of viscoplastic fluid, the constitutive equation is a non-differentiable function. This is often overcome by using the approximate constitutive equation that has a regularized form, e.g. the Papanastasiou regularization model. Using the same approach, we assess the influence of regularization parameters on simulation convergence and results accuracy. In this study, we give implementation details of viscoplastic fluid models in freeCappuccino open-source Computational Fluid Dynamics code. Moreover, we perform validation on several well known benchmark cases and compare proposed approach with those existing in published literature. We also perform a parametric analysis and show the effect of Reynolds and Bingham numbers on the extent of the yielded regions. Conclusions of the study have relevance in practical application of computational fluid dynamics to viscoplastic fluids in particular and to non-Newtonian fluids in general. © 2022, The Author(s), under exclusive license to Springer Nature Switzerland AG.
T2  - Lecture Notes in Networks and Systems
T1  - Development and Validation of an Open-Source Finite-Volume Method Solver for Viscoplastic Flows
VL  - 323
SP  - 223
EP  - 238
DO  - 10.1007/978-3-030-86009-7_12
ER  - 
@inbook{
author = "Mirkov, Nikola S. and Ouyahia, Seif Eddine and Lahlou, Sara and Pezo, Milada L. and Jovanović, Rastko D.",
year = "2022",
abstract = "In the present paper, we discuss implementation details of a free and open-source numerical solver based on the finite volume method for numerical simulation of viscoplastic non-Newtonian fluids. In addition to the fact that they are involved in many industrial applications, both their physical properties and their rheological behavior make them challenging for numerical simulation. Viscoplastic fluids are known to behave as solid unless the shear stress reaches a critical level, known as yield-stress, beyond which they behave as liquid. In most cases, both yielded and unyielded regions coexist in the fluid domain. In mathematical model of viscoplastic fluid, the constitutive equation is a non-differentiable function. This is often overcome by using the approximate constitutive equation that has a regularized form, e.g. the Papanastasiou regularization model. Using the same approach, we assess the influence of regularization parameters on simulation convergence and results accuracy. In this study, we give implementation details of viscoplastic fluid models in freeCappuccino open-source Computational Fluid Dynamics code. Moreover, we perform validation on several well known benchmark cases and compare proposed approach with those existing in published literature. We also perform a parametric analysis and show the effect of Reynolds and Bingham numbers on the extent of the yielded regions. Conclusions of the study have relevance in practical application of computational fluid dynamics to viscoplastic fluids in particular and to non-Newtonian fluids in general. © 2022, The Author(s), under exclusive license to Springer Nature Switzerland AG.",
journal = "Lecture Notes in Networks and Systems",
booktitle = "Development and Validation of an Open-Source Finite-Volume Method Solver for Viscoplastic Flows",
volume = "323",
pages = "223-238",
doi = "10.1007/978-3-030-86009-7_12"
}
Mirkov, N. S., Ouyahia, S. E., Lahlou, S., Pezo, M. L.,& Jovanović, R. D.. (2022). Development and Validation of an Open-Source Finite-Volume Method Solver for Viscoplastic Flows. in Lecture Notes in Networks and Systems, 323, 223-238.
https://doi.org/10.1007/978-3-030-86009-7_12
Mirkov NS, Ouyahia SE, Lahlou S, Pezo ML, Jovanović RD. Development and Validation of an Open-Source Finite-Volume Method Solver for Viscoplastic Flows. in Lecture Notes in Networks and Systems. 2022;323:223-238.
doi:10.1007/978-3-030-86009-7_12 .
Mirkov, Nikola S., Ouyahia, Seif Eddine, Lahlou, Sara, Pezo, Milada L., Jovanović, Rastko D., "Development and Validation of an Open-Source Finite-Volume Method Solver for Viscoplastic Flows" in Lecture Notes in Networks and Systems, 323 (2022):223-238,
https://doi.org/10.1007/978-3-030-86009-7_12 . .

Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study

Pijović, Milena; Manić, Nebojša; Vasić Anićijević, Dragana D.; Krstić, Aleksandar; Mitrić, Miodrag; Matić, Tamara; Janković, Bojan

(2022)

TY  - JOUR
AU  - Pijović, Milena
AU  - Manić, Nebojša
AU  - Vasić Anićijević, Dragana D.
AU  - Krstić, Aleksandar
AU  - Mitrić, Miodrag
AU  - Matić, Tamara
AU  - Janković, Bojan
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10077
AB  - Pyrolytic tire (PT) chars were first produced from waste car tires (WCT) through carbonization process at 800 °C, for different retention times. Then, best PT-char sample by its physicochemical properties (WCT 800(1 h)) was further tested for its ability to adsorb Rhodamine B (RhB) dye from aqueous solutions. Structural characterization of synthesized material showed existence of graphene-based material, with average pore diameter of 22.8 nm and specific surface area of 55.8 m2·g−1. Obtained carbon material meets specifications of commercial carbon black (CB). The yield of 33.6% of CB recovered has been achieved. Under the optimal conditions, 99.57% of RhB was removed. Adsorption of RhB obeys pseudo second-order model and Langmuir isotherm model. DFT (the density functional theory) was revealed that effective bonding of RhB onto WCT 800 originates from π-electron interactions with aromatic moieties and chemical (or at least the electrostatic) interactions, between positive nitrogen and electron-rich surface groups.
T2  - Diamond and Related Materials
T1  - Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study
VL  - 121
SP  - 108768
DO  - 10.1016/j.diamond.2021.108768
ER  - 
@article{
author = "Pijović, Milena and Manić, Nebojša and Vasić Anićijević, Dragana D. and Krstić, Aleksandar and Mitrić, Miodrag and Matić, Tamara and Janković, Bojan",
year = "2022",
abstract = "Pyrolytic tire (PT) chars were first produced from waste car tires (WCT) through carbonization process at 800 °C, for different retention times. Then, best PT-char sample by its physicochemical properties (WCT 800(1 h)) was further tested for its ability to adsorb Rhodamine B (RhB) dye from aqueous solutions. Structural characterization of synthesized material showed existence of graphene-based material, with average pore diameter of 22.8 nm and specific surface area of 55.8 m2·g−1. Obtained carbon material meets specifications of commercial carbon black (CB). The yield of 33.6% of CB recovered has been achieved. Under the optimal conditions, 99.57% of RhB was removed. Adsorption of RhB obeys pseudo second-order model and Langmuir isotherm model. DFT (the density functional theory) was revealed that effective bonding of RhB onto WCT 800 originates from π-electron interactions with aromatic moieties and chemical (or at least the electrostatic) interactions, between positive nitrogen and electron-rich surface groups.",
journal = "Diamond and Related Materials",
title = "Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study",
volume = "121",
pages = "108768",
doi = "10.1016/j.diamond.2021.108768"
}
Pijović, M., Manić, N., Vasić Anićijević, D. D., Krstić, A., Mitrić, M., Matić, T.,& Janković, B.. (2022). Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study. in Diamond and Related Materials, 121, 108768.
https://doi.org/10.1016/j.diamond.2021.108768
Pijović M, Manić N, Vasić Anićijević DD, Krstić A, Mitrić M, Matić T, Janković B. Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study. in Diamond and Related Materials. 2022;121:108768.
doi:10.1016/j.diamond.2021.108768 .
Pijović, Milena, Manić, Nebojša, Vasić Anićijević, Dragana D., Krstić, Aleksandar, Mitrić, Miodrag, Matić, Tamara, Janković, Bojan, "Simple and effective one-step production of high-quality mesoporous pyrolytic char from waste tires: Rhodamine B adsorption kinetics and density functional theory (DFT) study" in Diamond and Related Materials, 121 (2022):108768,
https://doi.org/10.1016/j.diamond.2021.108768 . .

Laser-induced breakdown spectroscopy analysis of water solutions deposited on PTFE surface: Influence of copper oxide nanoparticles and NELIBS effect

Kiris, Vasili; Savović, Jelena; Nevar, Alena; Kuzmanović, Miroslav; Nedelko, Mikhail; Ranković, Dragan; Tarasenko, Nikolai

(2022)

TY  - JOUR
AU  - Kiris, Vasili
AU  - Savović, Jelena
AU  - Nevar, Alena
AU  - Kuzmanović, Miroslav
AU  - Nedelko, Mikhail
AU  - Ranković, Dragan
AU  - Tarasenko, Nikolai
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10059
AB  - The analytical potential of LIBS for the analysis of liquid solutions was evaluated using two experimental setups, one based on a TEA CO2 laser and the other in which Nd:YAG laser was used. Polytetrafluoroethylene (PTFE) was used as a substrate on which a 10 μL drop of analyte solutions with different concentrations of analyte elements, Be, Cr, Ni, Co, Pb, Tl, and V, were deposited and dried. The samples were deposited either directly on the PTFE or over the pre-deposited layer of copper oxide nanoparticles to study the influence of nanoparticles (NPs) on the ablation and plasma excitation. The obtained results imply that the presence of Cu oxide NPs does not significantly affect the analytical performance of LIBS based on TEA CO2 laser for analysis of solutions. At the same time, it was shown that plasma created by TEA CO2 laser radiation efficiently excited ablated material, making metal elements detectable in the sub-ppm concentration range. On the other hand, Cu oxide NPs significantly influence the formation and the analytical properties of plasma induced by Nd:YAG laser. Without the presence of NPs, the intensities of analyte lines were very low, unsuitable for spectrochemical analysis. At the optimal surface concentration of NPs, 0.36 mg/cm2, the intensity of analyte lines was increased more than ten times. Limits of detection of Be and Cr were 5.3 ppb and 33 ppb, with good linearity of curves of growth.
T2  - Spectrochimica Acta Part B: Atomic Spectroscopy
T1  - Laser-induced breakdown spectroscopy analysis of water solutions deposited on PTFE surface: Influence of copper oxide nanoparticles and NELIBS effect
VL  - 187
SP  - 106333
DO  - 10.1016/j.sab.2021.106333
ER  - 
@article{
author = "Kiris, Vasili and Savović, Jelena and Nevar, Alena and Kuzmanović, Miroslav and Nedelko, Mikhail and Ranković, Dragan and Tarasenko, Nikolai",
year = "2022",
abstract = "The analytical potential of LIBS for the analysis of liquid solutions was evaluated using two experimental setups, one based on a TEA CO2 laser and the other in which Nd:YAG laser was used. Polytetrafluoroethylene (PTFE) was used as a substrate on which a 10 μL drop of analyte solutions with different concentrations of analyte elements, Be, Cr, Ni, Co, Pb, Tl, and V, were deposited and dried. The samples were deposited either directly on the PTFE or over the pre-deposited layer of copper oxide nanoparticles to study the influence of nanoparticles (NPs) on the ablation and plasma excitation. The obtained results imply that the presence of Cu oxide NPs does not significantly affect the analytical performance of LIBS based on TEA CO2 laser for analysis of solutions. At the same time, it was shown that plasma created by TEA CO2 laser radiation efficiently excited ablated material, making metal elements detectable in the sub-ppm concentration range. On the other hand, Cu oxide NPs significantly influence the formation and the analytical properties of plasma induced by Nd:YAG laser. Without the presence of NPs, the intensities of analyte lines were very low, unsuitable for spectrochemical analysis. At the optimal surface concentration of NPs, 0.36 mg/cm2, the intensity of analyte lines was increased more than ten times. Limits of detection of Be and Cr were 5.3 ppb and 33 ppb, with good linearity of curves of growth.",
journal = "Spectrochimica Acta Part B: Atomic Spectroscopy",
title = "Laser-induced breakdown spectroscopy analysis of water solutions deposited on PTFE surface: Influence of copper oxide nanoparticles and NELIBS effect",
volume = "187",
pages = "106333",
doi = "10.1016/j.sab.2021.106333"
}
Kiris, V., Savović, J., Nevar, A., Kuzmanović, M., Nedelko, M., Ranković, D.,& Tarasenko, N.. (2022). Laser-induced breakdown spectroscopy analysis of water solutions deposited on PTFE surface: Influence of copper oxide nanoparticles and NELIBS effect. in Spectrochimica Acta Part B: Atomic Spectroscopy, 187, 106333.
https://doi.org/10.1016/j.sab.2021.106333
Kiris V, Savović J, Nevar A, Kuzmanović M, Nedelko M, Ranković D, Tarasenko N. Laser-induced breakdown spectroscopy analysis of water solutions deposited on PTFE surface: Influence of copper oxide nanoparticles and NELIBS effect. in Spectrochimica Acta Part B: Atomic Spectroscopy. 2022;187:106333.
doi:10.1016/j.sab.2021.106333 .
Kiris, Vasili, Savović, Jelena, Nevar, Alena, Kuzmanović, Miroslav, Nedelko, Mikhail, Ranković, Dragan, Tarasenko, Nikolai, "Laser-induced breakdown spectroscopy analysis of water solutions deposited on PTFE surface: Influence of copper oxide nanoparticles and NELIBS effect" in Spectrochimica Acta Part B: Atomic Spectroscopy, 187 (2022):106333,
https://doi.org/10.1016/j.sab.2021.106333 . .

Tag Variants of LGALS-3 Containing Haplotype Block in Advanced Carotid Atherosclerosis

Đorđević, Ana; Živković, Maja; Končar, Igor; Stanković, Aleksandra; Kuveljić, Jovana; Đurić, Tamara

(2022)

TY  - JOUR
AU  - Đorđević, Ana
AU  - Živković, Maja
AU  - Končar, Igor
AU  - Stanković, Aleksandra
AU  - Kuveljić, Jovana
AU  - Đurić, Tamara
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10046
AB  - ObjectivesGalectin-3 affects a variety of biological processes. It is encoded by LGALS-3, located in unique haplotype block in Caucasians. Most of the studies regarding the gal-3 role in atherosclerosis are focused exclusively on protein/mRNA levels. Genetic analyses of LGALS-3 are scarce. We sought to thoroughly examine the genetic background of gal-3 and to analyze tag variants that cover more than 80% variability of the LGALS-3 containing hap-block in association with carotid plaque presence (CPP). According to Tagger server, rs4040064 G/T, rs11628437 G/A and rs7159490 C/T cover 82% (r2 > 0.8) of the genetic variance of this hap-block. Our aims were to investigate possible association of rs4040064, rs11628437 and rs7159490 haplotypes with CPP in patients with advanced carotid atherosclerosis (CA) and to analyze their possible effect on LGALS-3 mRNA expression in carotid plaques.Materials and methodsStudy group consisted of 468 patients and 296 controls. Rs4040064, rs11628437, rs7159490 and LGALS-3 mRNA expression were detected by TaqMan® technology.ResultsWe have found that haplotype TAC was associated with the cerebrovascular insult (CVI) occurrence (OR = 1.68, 95% CI = 1.09-2.58, p = 0.02), compared to the referent haplotype. OR was adjusted for hypertension, age and BMI. TAC also showed higher, but not statistically significant, LGALS-3 expression in carotid plaques.ConclusionsOur results suggest that rs4040064, rs11628437 and rs7159490 bear no association with CPP, neither they affect LGALS-3 mRNA in carotid plaques. However, we showed a significant association of haplotype TAC with the CVI occurrence in CA patients from Serbia. Replication and validation of our results are required.
T2  - Journal of Stroke and Cerebrovascular Diseases
T2  - Journal of Stroke and Cerebrovascular DiseasesJournal of Stroke and Cerebrovascular Diseases
T1  - Tag Variants of LGALS-3 Containing Haplotype Block in Advanced Carotid Atherosclerosis
VL  - 31
IS  - 1
SP  - 106212
DO  - 10.1016/j.jstrokecerebrovasdis.2021.106212
ER  - 
@article{
author = "Đorđević, Ana and Živković, Maja and Končar, Igor and Stanković, Aleksandra and Kuveljić, Jovana and Đurić, Tamara",
year = "2022",
abstract = "ObjectivesGalectin-3 affects a variety of biological processes. It is encoded by LGALS-3, located in unique haplotype block in Caucasians. Most of the studies regarding the gal-3 role in atherosclerosis are focused exclusively on protein/mRNA levels. Genetic analyses of LGALS-3 are scarce. We sought to thoroughly examine the genetic background of gal-3 and to analyze tag variants that cover more than 80% variability of the LGALS-3 containing hap-block in association with carotid plaque presence (CPP). According to Tagger server, rs4040064 G/T, rs11628437 G/A and rs7159490 C/T cover 82% (r2 > 0.8) of the genetic variance of this hap-block. Our aims were to investigate possible association of rs4040064, rs11628437 and rs7159490 haplotypes with CPP in patients with advanced carotid atherosclerosis (CA) and to analyze their possible effect on LGALS-3 mRNA expression in carotid plaques.Materials and methodsStudy group consisted of 468 patients and 296 controls. Rs4040064, rs11628437, rs7159490 and LGALS-3 mRNA expression were detected by TaqMan® technology.ResultsWe have found that haplotype TAC was associated with the cerebrovascular insult (CVI) occurrence (OR = 1.68, 95% CI = 1.09-2.58, p = 0.02), compared to the referent haplotype. OR was adjusted for hypertension, age and BMI. TAC also showed higher, but not statistically significant, LGALS-3 expression in carotid plaques.ConclusionsOur results suggest that rs4040064, rs11628437 and rs7159490 bear no association with CPP, neither they affect LGALS-3 mRNA in carotid plaques. However, we showed a significant association of haplotype TAC with the CVI occurrence in CA patients from Serbia. Replication and validation of our results are required.",
journal = "Journal of Stroke and Cerebrovascular Diseases, Journal of Stroke and Cerebrovascular DiseasesJournal of Stroke and Cerebrovascular Diseases",
title = "Tag Variants of LGALS-3 Containing Haplotype Block in Advanced Carotid Atherosclerosis",
volume = "31",
number = "1",
pages = "106212",
doi = "10.1016/j.jstrokecerebrovasdis.2021.106212"
}
Đorđević, A., Živković, M., Končar, I., Stanković, A., Kuveljić, J.,& Đurić, T.. (2022). Tag Variants of LGALS-3 Containing Haplotype Block in Advanced Carotid Atherosclerosis. in Journal of Stroke and Cerebrovascular Diseases, 31(1), 106212.
https://doi.org/10.1016/j.jstrokecerebrovasdis.2021.106212
Đorđević A, Živković M, Končar I, Stanković A, Kuveljić J, Đurić T. Tag Variants of LGALS-3 Containing Haplotype Block in Advanced Carotid Atherosclerosis. in Journal of Stroke and Cerebrovascular Diseases. 2022;31(1):106212.
doi:10.1016/j.jstrokecerebrovasdis.2021.106212 .
Đorđević, Ana, Živković, Maja, Končar, Igor, Stanković, Aleksandra, Kuveljić, Jovana, Đurić, Tamara, "Tag Variants of LGALS-3 Containing Haplotype Block in Advanced Carotid Atherosclerosis" in Journal of Stroke and Cerebrovascular Diseases, 31, no. 1 (2022):106212,
https://doi.org/10.1016/j.jstrokecerebrovasdis.2021.106212 . .

TEA CO2 Laser – Polymethyl Methacrylate Interaction: LIBS Hydrogen Analysis

Trtica, Milan; Kuzmanović, Miroslav; Savović, Jelena; Ranković, Dragan

(2022)

TY  - JOUR
AU  - Trtica, Milan
AU  - Kuzmanović, Miroslav
AU  - Savović, Jelena
AU  - Ranković, Dragan
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9972
AB  - The interaction of a Transversely Excited Atmospheric (TEA) CO2 laser with a polymer polymethyl methacrylate (PMMA) sample in a vacuum ambiance was studied. The main goal was to demonstrate the feasibility of laser-induced breakdown spectroscopy (LIBS) to detect hydrogen. The generation of plasma over the PMMA surface, using a low laser intensity of ∼ 48 MW/cm2 and fluence of ∼ 16.5 J/cm2, required the application of a metal sub-target. Besides hydrogen, the recorded spectra were dominated by atomic lines of carbon and oxygen and band emission of the C2 and CN molecules. The electron number density and temperature (ionic, vibrational, and rotational) were evaluated to characterize the laser-induced plasma. In addition, PMMA micro-damages (diameter ∼ 45 µm) created by a multipulse laser ablation could find potential applications in sensor technologies.
T2  - Applied Surface Science
T1  - TEA CO2 Laser – Polymethyl Methacrylate Interaction: LIBS Hydrogen Analysis
VL  - 572
SP  - 151424
DO  - 10.1016/j.apsusc.2021.151424
ER  - 
@article{
author = "Trtica, Milan and Kuzmanović, Miroslav and Savović, Jelena and Ranković, Dragan",
year = "2022",
abstract = "The interaction of a Transversely Excited Atmospheric (TEA) CO2 laser with a polymer polymethyl methacrylate (PMMA) sample in a vacuum ambiance was studied. The main goal was to demonstrate the feasibility of laser-induced breakdown spectroscopy (LIBS) to detect hydrogen. The generation of plasma over the PMMA surface, using a low laser intensity of ∼ 48 MW/cm2 and fluence of ∼ 16.5 J/cm2, required the application of a metal sub-target. Besides hydrogen, the recorded spectra were dominated by atomic lines of carbon and oxygen and band emission of the C2 and CN molecules. The electron number density and temperature (ionic, vibrational, and rotational) were evaluated to characterize the laser-induced plasma. In addition, PMMA micro-damages (diameter ∼ 45 µm) created by a multipulse laser ablation could find potential applications in sensor technologies.",
journal = "Applied Surface Science",
title = "TEA CO2 Laser – Polymethyl Methacrylate Interaction: LIBS Hydrogen Analysis",
volume = "572",
pages = "151424",
doi = "10.1016/j.apsusc.2021.151424"
}
Trtica, M., Kuzmanović, M., Savović, J.,& Ranković, D.. (2022). TEA CO2 Laser – Polymethyl Methacrylate Interaction: LIBS Hydrogen Analysis. in Applied Surface Science, 572, 151424.
https://doi.org/10.1016/j.apsusc.2021.151424
Trtica M, Kuzmanović M, Savović J, Ranković D. TEA CO2 Laser – Polymethyl Methacrylate Interaction: LIBS Hydrogen Analysis. in Applied Surface Science. 2022;572:151424.
doi:10.1016/j.apsusc.2021.151424 .
Trtica, Milan, Kuzmanović, Miroslav, Savović, Jelena, Ranković, Dragan, "TEA CO2 Laser – Polymethyl Methacrylate Interaction: LIBS Hydrogen Analysis" in Applied Surface Science, 572 (2022):151424,
https://doi.org/10.1016/j.apsusc.2021.151424 . .

Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties

Mirković, Miljana; Kljajević, Ljiljana; Dolenec, Sabina; Nenadović, Miloš; Pavlović, Vladimir; Rajačić, Milica; Nenadović, Snežana

(2021)

TY  - JOUR
AU  - Mirković, Miljana
AU  - Kljajević, Ljiljana
AU  - Dolenec, Sabina
AU  - Nenadović, Miloš
AU  - Pavlović, Vladimir
AU  - Rajačić, Milica
AU  - Nenadović, Snežana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10092
AB  - Since recycled technologies usage is mandatory for environmental safety, and in this regard, it is important to examine new materials that can be used in construction and are primarily produced from fly ash. In addition to characteristics such as hardness and compressive strength, the given materials must also be radiologically and environmentally safe. The main concept of engineered geopolymer gel composites based on fly ash residues is focused on developing binder materials via gel formation processes that can replace ordinary cement materials. This study is unique in researching the potential use of fly ash from the Nikola Tesla thermal power plant in Serbia, where the hybrid geopolymeric materials synthesized from fly ash are experimentally examined with the addition 1 wt% and 2 wt% of polyvinyl alcohol (PVA). This paper aims to investigate the structural, morphological, mechanical, and radiological properties of hybrid materials with the addition of PVA and without additive in the period of ageing for 28 days at room temperature. The phase composition was investigated using X-ray powder diffraction (XRPD) analysis, while morphological characteristics of these materials were examined using scanning electron microscopy and energy dispersive X-ray analysis (SEM-EDS). Vibrational spectra of obtained samples are investigated using diffuse reflectance infrared Fourier transform (DRIFT) and Fourier transform infrared (FTIR) techniques. The hardness and compressive strength are also examined, indicating that the 1 wt% addition in geopolymeric matrix results in the best mechanical properties. Radiological measurements of investigated all geopolymer samples show decreasing activity concentrations of radionuclides for 50% compared to fly ash.
T2  - Gels
T1  - Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties
VL  - 7
IS  - 4
SP  - 270
DO  - 10.3390/gels7040270
ER  - 
@article{
author = "Mirković, Miljana and Kljajević, Ljiljana and Dolenec, Sabina and Nenadović, Miloš and Pavlović, Vladimir and Rajačić, Milica and Nenadović, Snežana",
year = "2021",
abstract = "Since recycled technologies usage is mandatory for environmental safety, and in this regard, it is important to examine new materials that can be used in construction and are primarily produced from fly ash. In addition to characteristics such as hardness and compressive strength, the given materials must also be radiologically and environmentally safe. The main concept of engineered geopolymer gel composites based on fly ash residues is focused on developing binder materials via gel formation processes that can replace ordinary cement materials. This study is unique in researching the potential use of fly ash from the Nikola Tesla thermal power plant in Serbia, where the hybrid geopolymeric materials synthesized from fly ash are experimentally examined with the addition 1 wt% and 2 wt% of polyvinyl alcohol (PVA). This paper aims to investigate the structural, morphological, mechanical, and radiological properties of hybrid materials with the addition of PVA and without additive in the period of ageing for 28 days at room temperature. The phase composition was investigated using X-ray powder diffraction (XRPD) analysis, while morphological characteristics of these materials were examined using scanning electron microscopy and energy dispersive X-ray analysis (SEM-EDS). Vibrational spectra of obtained samples are investigated using diffuse reflectance infrared Fourier transform (DRIFT) and Fourier transform infrared (FTIR) techniques. The hardness and compressive strength are also examined, indicating that the 1 wt% addition in geopolymeric matrix results in the best mechanical properties. Radiological measurements of investigated all geopolymer samples show decreasing activity concentrations of radionuclides for 50% compared to fly ash.",
journal = "Gels",
title = "Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties",
volume = "7",
number = "4",
pages = "270",
doi = "10.3390/gels7040270"
}
Mirković, M., Kljajević, L., Dolenec, S., Nenadović, M., Pavlović, V., Rajačić, M.,& Nenadović, S.. (2021). Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties. in Gels, 7(4), 270.
https://doi.org/10.3390/gels7040270
Mirković M, Kljajević L, Dolenec S, Nenadović M, Pavlović V, Rajačić M, Nenadović S. Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties. in Gels. 2021;7(4):270.
doi:10.3390/gels7040270 .
Mirković, Miljana, Kljajević, Ljiljana, Dolenec, Sabina, Nenadović, Miloš, Pavlović, Vladimir, Rajačić, Milica, Nenadović, Snežana, "Potential Usage of Hybrid Polymers Binders Based on Fly Ash with the Addition of PVA with Satisfying Mechanical and Radiological Properties" in Gels, 7, no. 4 (2021):270,
https://doi.org/10.3390/gels7040270 . .

Fabrication and characterization of high entropy pyrochlore ceramics

Matović, Branko; Zagorac, Dejan; Cvijović-Alagić, Ivana; Zagorac, Jelena; Butulija, Svetlana; Erčić, Jelena; Hanzel, Ondrej; Sedlák, Richard; Lisnichuk, Maksym; Tatarko, Peter

(2021)

TY  - JOUR
AU  - Matović, Branko
AU  - Zagorac, Dejan
AU  - Cvijović-Alagić, Ivana
AU  - Zagorac, Jelena
AU  - Butulija, Svetlana
AU  - Erčić, Jelena
AU  - Hanzel, Ondrej
AU  - Sedlák, Richard
AU  - Lisnichuk, Maksym
AU  - Tatarko, Peter
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10083
AB  - High-entropy rare-earth (RE) zirconates with pyrochlore structure were successfully fabricated by pressureless and spark plasma sintering. RE2Zr2O7 compound with nominal composition (La0.2Y0.2Gd0.2Nd0.2Sm0.2)Zr2O7 was prepared by simple glycine nitrate procedure (GNP). GNP process yielded powders with low crystallinity and after subsequent calcination, well crystalline ceramics were formed. During calcination defective fluorite (F-RE2Zr2O7) and crystal pyrochlore (Py-RE2Zr2O7) structures coexist. Formation of pure crystalline pyrochlore occurs after sintering at 1450°C. High-density ceramics, free of any additives, were obtained after powders compaction and pressureless (PS), as well as field assisted sintering technique (FAST) at 1450°C. Theoretical investigations of the high-entropy RE2Zr2O7 pyrochlore systems were performed. Unit cell parameter of the obtained Py-RE2Zr2O7 is 10.5892(2)Å and 10.5999(2)Å for PS and FAST sintering, respectively, which is in good agreement with the results of Density Functional Theory (DFT) calculations. The thermal diffusivity of sintered samples at room temperature was ∼0.7mm2/s for both sintering methods.ResumenSe fabricaron con éxito, mediante sinterización por plasma sin presión y por chispa, los circonatos de tierras raras (RE) de alta entropía con estructura de pirocloro. El compuesto RE2Zr2O7 con composición nominal (La0,2Y0,2Gd0,2Nd0,2Sm0,2)Zr2O7 se preparó mediante un procedimiento simple de nitrato de glicina (GNP). El proceso GNP produjo polvos con baja cristalinidad y después de la posterior calcinación, se formaron cerámicas bien cristalinas. Durante la calcinación coexisten estructuras defectuosas de fluorita (F-RE2Zr2O7) y pirocloro cristalino (Py-RE2Zr2O7). La formación de pirocloro cristalino puro se produce después de la sinterización a 1.450°C. Después de la compactación de polvos y sin presión (PS), así como por la técnica de sinterización asistida en campo (FAST) a 1.450 oC, se obtuvieron cerámicas de alta densidad, libres de aditivos. Se realizaron investigaciones teóricas de los sistemas de pirocloro RE2Zr2O7 de alta entropía. El parámetro de celda unitaria del Py-RE2Zr2O7 obtenido es 105.892(2) Å y 105.999(2) Å para la sinterización PS y FAST, respectivamente, lo que está de acuerdo con los resultados de los cálculos de la teoría funcional de la densidad (DFT). La difusividad térmica de las muestras sinterizadas a temperatura ambiente fue de ∼ 0,7 mm2/s para ambos métodos de sinterización.
T2  - Boletín de la Sociedad Española de Cerámica y Vidrio
T1  - Fabrication and characterization of high entropy pyrochlore ceramics
DO  - 10.1016/j.bsecv.2021.11.002
ER  - 
@article{
author = "Matović, Branko and Zagorac, Dejan and Cvijović-Alagić, Ivana and Zagorac, Jelena and Butulija, Svetlana and Erčić, Jelena and Hanzel, Ondrej and Sedlák, Richard and Lisnichuk, Maksym and Tatarko, Peter",
year = "2021",
abstract = "High-entropy rare-earth (RE) zirconates with pyrochlore structure were successfully fabricated by pressureless and spark plasma sintering. RE2Zr2O7 compound with nominal composition (La0.2Y0.2Gd0.2Nd0.2Sm0.2)Zr2O7 was prepared by simple glycine nitrate procedure (GNP). GNP process yielded powders with low crystallinity and after subsequent calcination, well crystalline ceramics were formed. During calcination defective fluorite (F-RE2Zr2O7) and crystal pyrochlore (Py-RE2Zr2O7) structures coexist. Formation of pure crystalline pyrochlore occurs after sintering at 1450°C. High-density ceramics, free of any additives, were obtained after powders compaction and pressureless (PS), as well as field assisted sintering technique (FAST) at 1450°C. Theoretical investigations of the high-entropy RE2Zr2O7 pyrochlore systems were performed. Unit cell parameter of the obtained Py-RE2Zr2O7 is 10.5892(2)Å and 10.5999(2)Å for PS and FAST sintering, respectively, which is in good agreement with the results of Density Functional Theory (DFT) calculations. The thermal diffusivity of sintered samples at room temperature was ∼0.7mm2/s for both sintering methods.ResumenSe fabricaron con éxito, mediante sinterización por plasma sin presión y por chispa, los circonatos de tierras raras (RE) de alta entropía con estructura de pirocloro. El compuesto RE2Zr2O7 con composición nominal (La0,2Y0,2Gd0,2Nd0,2Sm0,2)Zr2O7 se preparó mediante un procedimiento simple de nitrato de glicina (GNP). El proceso GNP produjo polvos con baja cristalinidad y después de la posterior calcinación, se formaron cerámicas bien cristalinas. Durante la calcinación coexisten estructuras defectuosas de fluorita (F-RE2Zr2O7) y pirocloro cristalino (Py-RE2Zr2O7). La formación de pirocloro cristalino puro se produce después de la sinterización a 1.450°C. Después de la compactación de polvos y sin presión (PS), así como por la técnica de sinterización asistida en campo (FAST) a 1.450 oC, se obtuvieron cerámicas de alta densidad, libres de aditivos. Se realizaron investigaciones teóricas de los sistemas de pirocloro RE2Zr2O7 de alta entropía. El parámetro de celda unitaria del Py-RE2Zr2O7 obtenido es 105.892(2) Å y 105.999(2) Å para la sinterización PS y FAST, respectivamente, lo que está de acuerdo con los resultados de los cálculos de la teoría funcional de la densidad (DFT). La difusividad térmica de las muestras sinterizadas a temperatura ambiente fue de ∼ 0,7 mm2/s para ambos métodos de sinterización.",
journal = "Boletín de la Sociedad Española de Cerámica y Vidrio",
title = "Fabrication and characterization of high entropy pyrochlore ceramics",
doi = "10.1016/j.bsecv.2021.11.002"
}
Matović, B., Zagorac, D., Cvijović-Alagić, I., Zagorac, J., Butulija, S., Erčić, J., Hanzel, O., Sedlák, R., Lisnichuk, M.,& Tatarko, P.. (2021). Fabrication and characterization of high entropy pyrochlore ceramics. in Boletín de la Sociedad Española de Cerámica y Vidrio.
https://doi.org/10.1016/j.bsecv.2021.11.002
Matović B, Zagorac D, Cvijović-Alagić I, Zagorac J, Butulija S, Erčić J, Hanzel O, Sedlák R, Lisnichuk M, Tatarko P. Fabrication and characterization of high entropy pyrochlore ceramics. in Boletín de la Sociedad Española de Cerámica y Vidrio. 2021;.
doi:10.1016/j.bsecv.2021.11.002 .
Matović, Branko, Zagorac, Dejan, Cvijović-Alagić, Ivana, Zagorac, Jelena, Butulija, Svetlana, Erčić, Jelena, Hanzel, Ondrej, Sedlák, Richard, Lisnichuk, Maksym, Tatarko, Peter, "Fabrication and characterization of high entropy pyrochlore ceramics" in Boletín de la Sociedad Española de Cerámica y Vidrio (2021),
https://doi.org/10.1016/j.bsecv.2021.11.002 . .
1

Dugovremenska stabilnost kalibracionih standarda različitih matriksa u gamaspektrometriji

Đurašević, Mirjana M.; Kandić, Aleksandar; Vukanac, Ivana; Čeliković, Igor T.; Mladenović-Nikolić, Nataša; Milanović, Tamara; Obradović, Zorica

(Institut za nuklearne nauke "Vinča", 2021)

TY  - CONF
AU  - Đurašević, Mirjana M.
AU  - Kandić, Aleksandar
AU  - Vukanac, Ivana
AU  - Čeliković, Igor T.
AU  - Mladenović-Nikolić, Nataša
AU  - Milanović, Tamara
AU  - Obradović, Zorica
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10011
AB  - Da bi se postigla tačnost i preciznost dobijenih rezultata pri gamaspektrometrijskom merenju uzoraka iz životne sredine neophodno je obezbediti odgovarajuće kalibracione standarde. Imajući u vidu da i sami standardi vremenom gube na kvalitetu zbog degradacije matriksa, od izuzetne je važnosti praćenje stabilnosti standarda koji se koriste. U ovom radu prikazani su rezultati ispitivanja karakteristika krivih efikasnosti u odnosu na starenje matriksa. Napravljeni su radni kalibracioni standardi sa tri različita matriksa (aktivni ugalj, zemlja i pesak), upakovani u cilindričnu geometriju kutijice od 120 ml i 250 ml i mereni na poluprovodničkom HPGe detektoru. Isti standardi ponovo su mereni nakon četiri godine u kontakt geometriji u odnosu na detektor i izvrnuto sa poklopcem kutijice ka detektoru. Analiza dobijenih rezultata pokazala je odstupanja u vrednostima efikasnosti, što ukazuje na degradaciju svih standarda u smislu narušavanja njihove homogenosti. Takvi standardi se ne mogu smatrati pouzdanim za korišćenje.
AB  - The gammaspectrometric measurement of the environmental samples requires the use of appropriate calibration standards in order to achieve the accuracy and precision of the obtained results. Taking into account that the standards lose their quality over time due to the degradation of the matrix, it is extremely important to keep tracking their stability. Comprehensive reconsideration on efficiency curves with respect to the ageing of calibration standards is presented in this paper. Spiked laboratory standards of different matrices (active coal, soil and sand) were prepared in two measurement geometries, PVC cylindrical 120 ml and 250 ml boxes. The same standards were measured after four years in contact geometry on the detector and upside down (box cover towards the detector). The analysis of the obtained results showed discrepancies in efficiency values and it indicates that the homogeneity of standards is disturbed. Such standards are not reliable for use.
PB  - Institut za nuklearne nauke "Vinča"
PB  - Društvo za zaštitu od zračenja Srbije i Crne Gore
C3  - 31. симпозијум ДЗЗСЦГ : зборник радова
T1  - Dugovremenska stabilnost kalibracionih standarda različitih matriksa u gamaspektrometriji
T1  - On the Long-Term Stability of the Calibration Standards in Different Matrices for Gamma-Ray Spectrometry
SP  - 181
EP  - 186
ER  - 
@conference{
author = "Đurašević, Mirjana M. and Kandić, Aleksandar and Vukanac, Ivana and Čeliković, Igor T. and Mladenović-Nikolić, Nataša and Milanović, Tamara and Obradović, Zorica",
year = "2021",
abstract = "Da bi se postigla tačnost i preciznost dobijenih rezultata pri gamaspektrometrijskom merenju uzoraka iz životne sredine neophodno je obezbediti odgovarajuće kalibracione standarde. Imajući u vidu da i sami standardi vremenom gube na kvalitetu zbog degradacije matriksa, od izuzetne je važnosti praćenje stabilnosti standarda koji se koriste. U ovom radu prikazani su rezultati ispitivanja karakteristika krivih efikasnosti u odnosu na starenje matriksa. Napravljeni su radni kalibracioni standardi sa tri različita matriksa (aktivni ugalj, zemlja i pesak), upakovani u cilindričnu geometriju kutijice od 120 ml i 250 ml i mereni na poluprovodničkom HPGe detektoru. Isti standardi ponovo su mereni nakon četiri godine u kontakt geometriji u odnosu na detektor i izvrnuto sa poklopcem kutijice ka detektoru. Analiza dobijenih rezultata pokazala je odstupanja u vrednostima efikasnosti, što ukazuje na degradaciju svih standarda u smislu narušavanja njihove homogenosti. Takvi standardi se ne mogu smatrati pouzdanim za korišćenje., The gammaspectrometric measurement of the environmental samples requires the use of appropriate calibration standards in order to achieve the accuracy and precision of the obtained results. Taking into account that the standards lose their quality over time due to the degradation of the matrix, it is extremely important to keep tracking their stability. Comprehensive reconsideration on efficiency curves with respect to the ageing of calibration standards is presented in this paper. Spiked laboratory standards of different matrices (active coal, soil and sand) were prepared in two measurement geometries, PVC cylindrical 120 ml and 250 ml boxes. The same standards were measured after four years in contact geometry on the detector and upside down (box cover towards the detector). The analysis of the obtained results showed discrepancies in efficiency values and it indicates that the homogeneity of standards is disturbed. Such standards are not reliable for use.",
publisher = "Institut za nuklearne nauke "Vinča", Društvo za zaštitu od zračenja Srbije i Crne Gore",
journal = "31. симпозијум ДЗЗСЦГ : зборник радова",
title = "Dugovremenska stabilnost kalibracionih standarda različitih matriksa u gamaspektrometriji, On the Long-Term Stability of the Calibration Standards in Different Matrices for Gamma-Ray Spectrometry",
pages = "181-186"
}
Đurašević, M. M., Kandić, A., Vukanac, I., Čeliković, I. T., Mladenović-Nikolić, N., Milanović, T.,& Obradović, Z.. (2021). Dugovremenska stabilnost kalibracionih standarda različitih matriksa u gamaspektrometriji. in 31. симпозијум ДЗЗСЦГ : зборник радова
Institut za nuklearne nauke "Vinča"., 181-186.
Đurašević MM, Kandić A, Vukanac I, Čeliković IT, Mladenović-Nikolić N, Milanović T, Obradović Z. Dugovremenska stabilnost kalibracionih standarda različitih matriksa u gamaspektrometriji. in 31. симпозијум ДЗЗСЦГ : зборник радова. 2021;:181-186..
Đurašević, Mirjana M., Kandić, Aleksandar, Vukanac, Ivana, Čeliković, Igor T., Mladenović-Nikolić, Nataša, Milanović, Tamara, Obradović, Zorica, "Dugovremenska stabilnost kalibracionih standarda različitih matriksa u gamaspektrometriji" in 31. симпозијум ДЗЗСЦГ : зборник радова (2021):181-186.

Efekti svojstava tla različitih poljoprivrednih koncepata na migraciju antropogenih radionuklida

Sarap, Nataša; Janković, Marija M.; Rajačić, Milica; Krneta-Nikolić, Jelena D.; Todorović, Dragana; Vukanac, Ivana; Pantelić, Gordana K.

(Institut za nuklearne nauke "Vinča", 2021)

TY  - CONF
AU  - Sarap, Nataša
AU  - Janković, Marija M.
AU  - Rajačić, Milica
AU  - Krneta-Nikolić, Jelena D.
AU  - Todorović, Dragana
AU  - Vukanac, Ivana
AU  - Pantelić, Gordana K.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9997
AB  - Istraživanja obuhvaćena ovom studijom predstavljaju prikaz efekata svojstava tla različitih poljoprivrednih koncepata na migraciju antropogenih radionuklida, 90Sr i 137Cs. Za potrebe ovog rada, izvršeno je uzorkovanje obradivog zemljišta na dve dubine na teritoriji grada Beograda tokom 2014. godine. U uzorcima zemljišta su određene fizičko−hemijske osobine i specifične aktivnosti ispitanih radionuklida. Radiohemijska analitička metoda je primenjena za određivanje sadržaja 90Sr, dok je specifična aktivnost 137Cs određena primenom gamaspektrometrijske metode. Ispitivanje efekata svojstava analiziranih uzoraka obradivog zemljišta na migraciju 90Sr i 137Cs, izvršeno je statističkim metodama analize. Primenom linearne korelacione analize utvrđeni su dominantni fizičko−hemijski parametri koji utiču na migraciju 90Sr i 137Cs u poljoprivrednom zemljištu.
AB  - The research included by this study presents the effects of soil properties of different agricultural concepts to the migration of anthropogenic radionuclides, 90Sr and 137Cs. For the purposes of this paper, sampling of agricultural soil at two depths on the territory of the city of Belgrade during 2014 was performed. The physico−chemical properties of investigated soil, as well as the specific activities of the mentioned radionuclides were determined. The radiochemical analytical method was used to determine the 90Sr content, while the specific activity of 137Cs was determined using the gamma spectrometric method. Examination of the effects of soil properties on the migration of anthropogenic radionuclides 90Sr and 137Cs, based on the analyzed soil samples, was performed by statistical methods of analysis. By applying linear correlation analysis, the dominant physico−chemical parameters that affect the migration of 90Sr and 137Cs in agricultural soil were determined.
PB  - Institut za nuklearne nauke "Vinča"
PB  - Društvo za zaštitu od zračenja Srbije i Crne Gore
C3  - 31. симпозијум ДЗЗСЦГ : зборник радова
T1  - Efekti svojstava tla različitih poljoprivrednih koncepata na migraciju antropogenih radionuklida
T1  - Effects of Soil Properties of Different Agricultural Concepts to Migration of the Artificial Radionuclides
SP  - 19
EP  - 26
ER  - 
@conference{
author = "Sarap, Nataša and Janković, Marija M. and Rajačić, Milica and Krneta-Nikolić, Jelena D. and Todorović, Dragana and Vukanac, Ivana and Pantelić, Gordana K.",
year = "2021",
abstract = "Istraživanja obuhvaćena ovom studijom predstavljaju prikaz efekata svojstava tla različitih poljoprivrednih koncepata na migraciju antropogenih radionuklida, 90Sr i 137Cs. Za potrebe ovog rada, izvršeno je uzorkovanje obradivog zemljišta na dve dubine na teritoriji grada Beograda tokom 2014. godine. U uzorcima zemljišta su određene fizičko−hemijske osobine i specifične aktivnosti ispitanih radionuklida. Radiohemijska analitička metoda je primenjena za određivanje sadržaja 90Sr, dok je specifična aktivnost 137Cs određena primenom gamaspektrometrijske metode. Ispitivanje efekata svojstava analiziranih uzoraka obradivog zemljišta na migraciju 90Sr i 137Cs, izvršeno je statističkim metodama analize. Primenom linearne korelacione analize utvrđeni su dominantni fizičko−hemijski parametri koji utiču na migraciju 90Sr i 137Cs u poljoprivrednom zemljištu., The research included by this study presents the effects of soil properties of different agricultural concepts to the migration of anthropogenic radionuclides, 90Sr and 137Cs. For the purposes of this paper, sampling of agricultural soil at two depths on the territory of the city of Belgrade during 2014 was performed. The physico−chemical properties of investigated soil, as well as the specific activities of the mentioned radionuclides were determined. The radiochemical analytical method was used to determine the 90Sr content, while the specific activity of 137Cs was determined using the gamma spectrometric method. Examination of the effects of soil properties on the migration of anthropogenic radionuclides 90Sr and 137Cs, based on the analyzed soil samples, was performed by statistical methods of analysis. By applying linear correlation analysis, the dominant physico−chemical parameters that affect the migration of 90Sr and 137Cs in agricultural soil were determined.",
publisher = "Institut za nuklearne nauke "Vinča", Društvo za zaštitu od zračenja Srbije i Crne Gore",
journal = "31. симпозијум ДЗЗСЦГ : зборник радова",
title = "Efekti svojstava tla različitih poljoprivrednih koncepata na migraciju antropogenih radionuklida, Effects of Soil Properties of Different Agricultural Concepts to Migration of the Artificial Radionuclides",
pages = "19-26"
}
Sarap, N., Janković, M. M., Rajačić, M., Krneta-Nikolić, J. D., Todorović, D., Vukanac, I.,& Pantelić, G. K.. (2021). Efekti svojstava tla različitih poljoprivrednih koncepata na migraciju antropogenih radionuklida. in 31. симпозијум ДЗЗСЦГ : зборник радова
Institut za nuklearne nauke "Vinča"., 19-26.
Sarap N, Janković MM, Rajačić M, Krneta-Nikolić JD, Todorović D, Vukanac I, Pantelić GK. Efekti svojstava tla različitih poljoprivrednih koncepata na migraciju antropogenih radionuklida. in 31. симпозијум ДЗЗСЦГ : зборник радова. 2021;:19-26..
Sarap, Nataša, Janković, Marija M., Rajačić, Milica, Krneta-Nikolić, Jelena D., Todorović, Dragana, Vukanac, Ivana, Pantelić, Gordana K., "Efekti svojstava tla različitih poljoprivrednih koncepata na migraciju antropogenih radionuklida" in 31. симпозијум ДЗЗСЦГ : зборник радова (2021):19-26.

Radioaktivnost okoline u procesu iskopavanja bunara - selo Poganovo

Todorović, Dragana; Rajačić, Milica; Krneta-Nikolić, Jelena D.; Janković, Marija M.; Vukanac, Ivana; Pantelić, Gordana K.; Sarap, Nataša

(Institut za nuklearne nauke "Vinča", 2021)

TY  - CONF
AU  - Todorović, Dragana
AU  - Rajačić, Milica
AU  - Krneta-Nikolić, Jelena D.
AU  - Janković, Marija M.
AU  - Vukanac, Ivana
AU  - Pantelić, Gordana K.
AU  - Sarap, Nataša
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9998
AB  - Rezultati merenja radioaktivnosti zemljišta, mulja i vode u procesu iskopavanja bunara do maksimalne dubine od 13,5 m u selu Poganovu, u opštini Dimitrovgrad, prikazani su u ovom radu. Uzorci mulja i zemljišta, analizirani su spektrometrijom gama emitera i određivanjem sadržaja 90Sr. U slučaju uzorka vode, određena je ukupna alfa i ukupna beta aktivnost, i koncentracija radionuklida gama emitera. Pored navedenih uzoraka, sa iste lokacije su mereni i uzorci mahovina i lišajeva. Osim u uzorku mahovine i zemljišta sa dubine 0-10 cm u kojima je detektovano prisustvo 137Cs u veoma niskim koncentracijama za ovu vrstu uzoraka, ni u jednom uzorku nije detektovano prisustvo proizvedenih radionuklida, 137Cs i 90Sr. U slučaju prirodnih radionuklida, dobijene vrednosti koncentracija, karakteristične su za ovakve vrste uzoraka i ne razlikuju se u odnosu na druge lokacije na našim prostorima. Svi rezultati merenja ukazuju na to da se ova lokacija može koristiti kao nulta tačka monitoringa radioaktivnosti na našim prostorima.
AB  - The results of radioactivity measurements in the soil, sludge and water samples in the process of finding water and digging wells to a maximum depth of 13.5 m, in the village of Poganovo, in the municipality of Dimitrovgrad, are presented in this paper. Sludge and soil samples were analyzed by gamma-ray spectrometry and 90Sr measurements. In the case of water samples, gross alpha and gross beta activity, as well as content of radionuclides gamma emitter were determined. In addition, samples of mosses and lichens from the same location were also measured. Presence of the artificial radionuclides 90Sr and 137Cs were not detected in measured samples, with an exception of the sample of moss and soil from a depth of 0-10 cm, where 137Cs was detected in very low concentrations for this type of samples. In the case of natural radionuclides, the obtained values of concentrations are characteristic of these types of samples and do not differ from other locations in our area. All measurement results indicate that this location can be used as a zero point for monitoring radioactivity in our area.
PB  - Institut za nuklearne nauke "Vinča"
PB  - Društvo za zaštitu od zračenja Srbije i Crne Gore
C3  - 31. симпозијум ДЗЗСЦГ : зборник радова
T1  - Radioaktivnost okoline u procesu iskopavanja bunara - selo Poganovo
T1  - Radioactivity of the Environment in the Process of Excavation of Wells - Village Poganovo
SP  - 32
EP  - 37
ER  - 
@conference{
author = "Todorović, Dragana and Rajačić, Milica and Krneta-Nikolić, Jelena D. and Janković, Marija M. and Vukanac, Ivana and Pantelić, Gordana K. and Sarap, Nataša",
year = "2021",
abstract = "Rezultati merenja radioaktivnosti zemljišta, mulja i vode u procesu iskopavanja bunara do maksimalne dubine od 13,5 m u selu Poganovu, u opštini Dimitrovgrad, prikazani su u ovom radu. Uzorci mulja i zemljišta, analizirani su spektrometrijom gama emitera i određivanjem sadržaja 90Sr. U slučaju uzorka vode, određena je ukupna alfa i ukupna beta aktivnost, i koncentracija radionuklida gama emitera. Pored navedenih uzoraka, sa iste lokacije su mereni i uzorci mahovina i lišajeva. Osim u uzorku mahovine i zemljišta sa dubine 0-10 cm u kojima je detektovano prisustvo 137Cs u veoma niskim koncentracijama za ovu vrstu uzoraka, ni u jednom uzorku nije detektovano prisustvo proizvedenih radionuklida, 137Cs i 90Sr. U slučaju prirodnih radionuklida, dobijene vrednosti koncentracija, karakteristične su za ovakve vrste uzoraka i ne razlikuju se u odnosu na druge lokacije na našim prostorima. Svi rezultati merenja ukazuju na to da se ova lokacija može koristiti kao nulta tačka monitoringa radioaktivnosti na našim prostorima., The results of radioactivity measurements in the soil, sludge and water samples in the process of finding water and digging wells to a maximum depth of 13.5 m, in the village of Poganovo, in the municipality of Dimitrovgrad, are presented in this paper. Sludge and soil samples were analyzed by gamma-ray spectrometry and 90Sr measurements. In the case of water samples, gross alpha and gross beta activity, as well as content of radionuclides gamma emitter were determined. In addition, samples of mosses and lichens from the same location were also measured. Presence of the artificial radionuclides 90Sr and 137Cs were not detected in measured samples, with an exception of the sample of moss and soil from a depth of 0-10 cm, where 137Cs was detected in very low concentrations for this type of samples. In the case of natural radionuclides, the obtained values of concentrations are characteristic of these types of samples and do not differ from other locations in our area. All measurement results indicate that this location can be used as a zero point for monitoring radioactivity in our area.",
publisher = "Institut za nuklearne nauke "Vinča", Društvo za zaštitu od zračenja Srbije i Crne Gore",
journal = "31. симпозијум ДЗЗСЦГ : зборник радова",
title = "Radioaktivnost okoline u procesu iskopavanja bunara - selo Poganovo, Radioactivity of the Environment in the Process of Excavation of Wells - Village Poganovo",
pages = "32-37"
}
Todorović, D., Rajačić, M., Krneta-Nikolić, J. D., Janković, M. M., Vukanac, I., Pantelić, G. K.,& Sarap, N.. (2021). Radioaktivnost okoline u procesu iskopavanja bunara - selo Poganovo. in 31. симпозијум ДЗЗСЦГ : зборник радова
Institut za nuklearne nauke "Vinča"., 32-37.
Todorović D, Rajačić M, Krneta-Nikolić JD, Janković MM, Vukanac I, Pantelić GK, Sarap N. Radioaktivnost okoline u procesu iskopavanja bunara - selo Poganovo. in 31. симпозијум ДЗЗСЦГ : зборник радова. 2021;:32-37..
Todorović, Dragana, Rajačić, Milica, Krneta-Nikolić, Jelena D., Janković, Marija M., Vukanac, Ivana, Pantelić, Gordana K., Sarap, Nataša, "Radioaktivnost okoline u procesu iskopavanja bunara - selo Poganovo" in 31. симпозијум ДЗЗСЦГ : зборник радова (2021):32-37.

Sadržaj radionuklida u izvorskim vodama u okolini Smederevske Palanke

Janković, Marija M.; Rajačić, Milica; Krneta-Nikolić, Jelena D.; Vukanac, Ivana; Todorović, Dragana; Pantelić, Gordana K.; Sarap, Nataša

(Institut za nuklearne nauke "Vinča", 2021)

TY  - CONF
AU  - Janković, Marija M.
AU  - Rajačić, Milica
AU  - Krneta-Nikolić, Jelena D.
AU  - Vukanac, Ivana
AU  - Todorović, Dragana
AU  - Pantelić, Gordana K.
AU  - Sarap, Nataša
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9999
AB  - U radu su prikazani rezultati merenja radioaktivnosti u izvorskim vodama u okolini Smederevske Palanke. Određivanje sadržaja radionuklida urađeno je gamaspektrometrijskom metodom sa HPGe detektorom, dok je za merenje ukupne alfa i ukupne beta aktivnosti u uzorcima korišćen gasni proporcionalni alfa beta brojač THERMO-EBERLINE FHT 770T. Uzorci su sakupljani tokom proleća 2021. godine. Dobijeni rezultati upoređeni su sa dozvoljenim vrednostima sadržaja radionuklida u vodi za piće propisanim Zakonskom regulativom.
AB  - The results of gamma spectrometric analysis and determination of gross alpha and gross beta activity in spring waters in the vicinity of Smederevska Palanka are presented in this paper. Determination of radionuclide content was performed with HPGe gamma spectrometry, while determination of gross alpha and gross beta activity was performed using gas proportional alpha/beta counter THERMO-EBERLINE FHT 770T. Samples were collected in spring of 2021. The obtained results were compared with the permitted values of radionuclide content in drinking water prescribed by the Legislation.
PB  - Institut za nuklearne nauke "Vinča"
PB  - Društvo za zaštitu od zračenja Srbije i Crne Gore
C3  - 31. симпозијум ДЗЗСЦГ : зборник радова
T1  - Sadržaj radionuklida u izvorskim vodama u okolini Smederevske Palanke
T1  - Content of Radionuclides in Spring Waters in the Vicinity of Smederevska Palanka
SP  - 82
EP  - 86
ER  - 
@conference{
author = "Janković, Marija M. and Rajačić, Milica and Krneta-Nikolić, Jelena D. and Vukanac, Ivana and Todorović, Dragana and Pantelić, Gordana K. and Sarap, Nataša",
year = "2021",
abstract = "U radu su prikazani rezultati merenja radioaktivnosti u izvorskim vodama u okolini Smederevske Palanke. Određivanje sadržaja radionuklida urađeno je gamaspektrometrijskom metodom sa HPGe detektorom, dok je za merenje ukupne alfa i ukupne beta aktivnosti u uzorcima korišćen gasni proporcionalni alfa beta brojač THERMO-EBERLINE FHT 770T. Uzorci su sakupljani tokom proleća 2021. godine. Dobijeni rezultati upoređeni su sa dozvoljenim vrednostima sadržaja radionuklida u vodi za piće propisanim Zakonskom regulativom., The results of gamma spectrometric analysis and determination of gross alpha and gross beta activity in spring waters in the vicinity of Smederevska Palanka are presented in this paper. Determination of radionuclide content was performed with HPGe gamma spectrometry, while determination of gross alpha and gross beta activity was performed using gas proportional alpha/beta counter THERMO-EBERLINE FHT 770T. Samples were collected in spring of 2021. The obtained results were compared with the permitted values of radionuclide content in drinking water prescribed by the Legislation.",
publisher = "Institut za nuklearne nauke "Vinča", Društvo za zaštitu od zračenja Srbije i Crne Gore",
journal = "31. симпозијум ДЗЗСЦГ : зборник радова",
title = "Sadržaj radionuklida u izvorskim vodama u okolini Smederevske Palanke, Content of Radionuclides in Spring Waters in the Vicinity of Smederevska Palanka",
pages = "82-86"
}
Janković, M. M., Rajačić, M., Krneta-Nikolić, J. D., Vukanac, I., Todorović, D., Pantelić, G. K.,& Sarap, N.. (2021). Sadržaj radionuklida u izvorskim vodama u okolini Smederevske Palanke. in 31. симпозијум ДЗЗСЦГ : зборник радова
Institut za nuklearne nauke "Vinča"., 82-86.
Janković MM, Rajačić M, Krneta-Nikolić JD, Vukanac I, Todorović D, Pantelić GK, Sarap N. Sadržaj radionuklida u izvorskim vodama u okolini Smederevske Palanke. in 31. симпозијум ДЗЗСЦГ : зборник радова. 2021;:82-86..
Janković, Marija M., Rajačić, Milica, Krneta-Nikolić, Jelena D., Vukanac, Ivana, Todorović, Dragana, Pantelić, Gordana K., Sarap, Nataša, "Sadržaj radionuklida u izvorskim vodama u okolini Smederevske Palanke" in 31. симпозијум ДЗЗСЦГ : зборник радова (2021):82-86.

Radonski ravnotežni faktor u izabranim rezidencijalnim i radnim objektima u Srbiji i Crnoj Gori

Čeliković, Igor T.; Zekić, Ranko; Svrkota, Nikola; Vukanac, Ivana; Živanović, Miloš Z.; Krneta-Nikolić, Jelena D.; Vukotić, Perko; Pantelić, Gordana K.

(Institut za nuklearne nauke "Vinča", 2021)

TY  - CONF
AU  - Čeliković, Igor T.
AU  - Zekić, Ranko
AU  - Svrkota, Nikola
AU  - Vukanac, Ivana
AU  - Živanović, Miloš Z.
AU  - Krneta-Nikolić, Jelena D.
AU  - Vukotić, Perko
AU  - Pantelić, Gordana K.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10002
AB  - U radu su prikazani rezultati merenja radonskog ravnotežnog faktora aktivnom metodom na 5 lokacija u Crnoj Gori i Srbiji. Dobijeni rezultati su u rasponu od 0.36 do 0.7, što je u proseku veće od preporučene vrednosti od 0.4. Na istim lokacijama su izvršena interkomparativna merenja koncentracije radona (uređajima Alpha Guard Pro, RAD7 i RTM1688-2), ravnotežne ekvivalentne koncentracije radona (uređajima RNWL i RPM2200) i radonskog ravnotežnog faktora. Slaganje rezultata je testirano Z-testom koji ukazuje da ne postoji statistički značajno odstupanje između rezultata dobijenih različitim mernim uređajima, odnosno ne postoji nekonzistentnost između različitih metodologija merenja kao ni potrebe za harmonizacijom različitih procedura merenja.
AB  - In this contribution, the results of radon equilibrium factor measurement in selected dwelling and workplaces in Montenegro and Serbia are presented. Radon equilibrium factor was derived from measurements of indoor radon concentration and equilibrium equivalent radon concentration. Measurements were performed one day for each of 5 locations by using different active devices. Obtained radon equilibrium factors range from 0.36 to 0.7 which is in average larger than worldwide average of 0.4 Results are not surprising since measuring locations were kept closed during the measuring time, reducing therefore ventilation rate which as a consequence has an increase of equilibrium factor. Individual measuring results of indoor radon concentrations, equilibrium equivalent radon concentrations and radon equilibrium factors obtained with different detectors systems from 2 research teams was tested using Z – test. Obtained Z – score for each measurement vas below critical value, indication that there is no statistical difference between different measuring devices.
PB  - Institut za nuklearne nauke "Vinča"
PB  - Društvo za zaštitu od zračenja Srbije i Crne Gore
C3  - 31. симпозијум ДЗЗСЦГ : зборник радова
T1  - Radonski ravnotežni faktor u izabranim rezidencijalnim i radnim objektima u Srbiji i Crnoj Gori
T1  - Radon Equilibrium Factor in Selected Dwellings and Workplaces in Montenegro and Serbia
SP  - 121
EP  - 127
ER  - 
@conference{
author = "Čeliković, Igor T. and Zekić, Ranko and Svrkota, Nikola and Vukanac, Ivana and Živanović, Miloš Z. and Krneta-Nikolić, Jelena D. and Vukotić, Perko and Pantelić, Gordana K.",
year = "2021",
abstract = "U radu su prikazani rezultati merenja radonskog ravnotežnog faktora aktivnom metodom na 5 lokacija u Crnoj Gori i Srbiji. Dobijeni rezultati su u rasponu od 0.36 do 0.7, što je u proseku veće od preporučene vrednosti od 0.4. Na istim lokacijama su izvršena interkomparativna merenja koncentracije radona (uređajima Alpha Guard Pro, RAD7 i RTM1688-2), ravnotežne ekvivalentne koncentracije radona (uređajima RNWL i RPM2200) i radonskog ravnotežnog faktora. Slaganje rezultata je testirano Z-testom koji ukazuje da ne postoji statistički značajno odstupanje između rezultata dobijenih različitim mernim uređajima, odnosno ne postoji nekonzistentnost između različitih metodologija merenja kao ni potrebe za harmonizacijom različitih procedura merenja., In this contribution, the results of radon equilibrium factor measurement in selected dwelling and workplaces in Montenegro and Serbia are presented. Radon equilibrium factor was derived from measurements of indoor radon concentration and equilibrium equivalent radon concentration. Measurements were performed one day for each of 5 locations by using different active devices. Obtained radon equilibrium factors range from 0.36 to 0.7 which is in average larger than worldwide average of 0.4 Results are not surprising since measuring locations were kept closed during the measuring time, reducing therefore ventilation rate which as a consequence has an increase of equilibrium factor. Individual measuring results of indoor radon concentrations, equilibrium equivalent radon concentrations and radon equilibrium factors obtained with different detectors systems from 2 research teams was tested using Z – test. Obtained Z – score for each measurement vas below critical value, indication that there is no statistical difference between different measuring devices.",
publisher = "Institut za nuklearne nauke "Vinča", Društvo za zaštitu od zračenja Srbije i Crne Gore",
journal = "31. симпозијум ДЗЗСЦГ : зборник радова",
title = "Radonski ravnotežni faktor u izabranim rezidencijalnim i radnim objektima u Srbiji i Crnoj Gori, Radon Equilibrium Factor in Selected Dwellings and Workplaces in Montenegro and Serbia",
pages = "121-127"
}
Čeliković, I. T., Zekić, R., Svrkota, N., Vukanac, I., Živanović, M. Z., Krneta-Nikolić, J. D., Vukotić, P.,& Pantelić, G. K.. (2021). Radonski ravnotežni faktor u izabranim rezidencijalnim i radnim objektima u Srbiji i Crnoj Gori. in 31. симпозијум ДЗЗСЦГ : зборник радова
Institut za nuklearne nauke "Vinča"., 121-127.
Čeliković IT, Zekić R, Svrkota N, Vukanac I, Živanović MZ, Krneta-Nikolić JD, Vukotić P, Pantelić GK. Radonski ravnotežni faktor u izabranim rezidencijalnim i radnim objektima u Srbiji i Crnoj Gori. in 31. симпозијум ДЗЗСЦГ : зборник радова. 2021;:121-127..
Čeliković, Igor T., Zekić, Ranko, Svrkota, Nikola, Vukanac, Ivana, Živanović, Miloš Z., Krneta-Nikolić, Jelena D., Vukotić, Perko, Pantelić, Gordana K., "Radonski ravnotežni faktor u izabranim rezidencijalnim i radnim objektima u Srbiji i Crnoj Gori" in 31. симпозијум ДЗЗСЦГ : зборник радова (2021):121-127.

Sistematsko ispitivanje koncentracije radona na teritoriji Beograda

Rajačić, Milica; Todorović, Dragana; Krneta-Nikolić, Jelena D.; Pantelić, Gordana K.; Vukanac, Ivana; Janković, Marija M.; Sarap, Nataša

(Institut za nuklearne nauke "Vinča", 2021)

TY  - CONF
AU  - Rajačić, Milica
AU  - Todorović, Dragana
AU  - Krneta-Nikolić, Jelena D.
AU  - Pantelić, Gordana K.
AU  - Vukanac, Ivana
AU  - Janković, Marija M.
AU  - Sarap, Nataša
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10008
AB  - Programom sistematskog ispitivanja nivoa radioaktivnosti u životnoj sredini na teritoriji Beograda predviđeno je merenje koncentracije radona (222Rn) u stambenim objektima, školskim i predškolskim ustanovama. Laboratorija "Zaštita", Instituta za nuklearne nauke "Vinča" je u periodu 2016-2020. izvršila ispitivanja u 547 prostorija (99 u stambenim objektima, 341 u školskim ustanovama i 107 u predškolskim jedinicama). Prosečna koncentracija 222Rn je iznosila 105 Bq/m3, a koncentarcija ispod 100 Bq/m3 je izmerena u 76,60 % prostorija. Vrednost od 400 Bq/m3 je prekoračena u 4,94 % prostorija. Od 15 beogradskih opština, koliko je pokriveno ovim istraživanjem, u 8 je detektovana koncentracija iznad 400 Bq/m3. Maksimalna izmerena vrednost u stambenim objektima je iznosila 3550 Bq/m3, dok je u vaspitno-obrazovnim ustanovama najveća detektovana koncentracija bila 1910 Bq/m3.
AB  - The program of the level of radioactivity in the environment monitoring on the territory of Belgrade envisages measuring the concentration of radon in residential buildings, schools and kindergartens. The Department of Radiation and Environmental Protection of the Institute of Nuclear Sciences "Vinca" conducted examination in 547 rooms (99 in residential buildings, 341 in schools and 107 in kindergartens) in the period 2016-2020. The average concentration of 222Rn is 105 Bq/m3, and the concentration below 100 Bq/m3 was measured in 76.60 % of the rooms. The value of 400 Bq/m3 was exceeded in 4.94 % of the rooms. Out of 15 Belgrade municipalities covered by this research, a concentration above 400 Bq/m3 was detected in 8 municipalities. The maximum measured value in residential buildings was 3550 Bq/m3, while in educational institutions the highest detected concentration was 1910 Bq/m3.
PB  - Institut za nuklearne nauke "Vinča"
PB  - Društvo za zaštitu od zračenja Srbije i Crne Gore
C3  - 31. симпозијум ДЗЗСЦГ : зборник радова
T1  - Sistematsko ispitivanje koncentracije radona na teritoriji Beograda
T1  - Systematic Investigation of Radon Concentration on the Territory of Belgrade
SP  - 128
EP  - 133
ER  - 
@conference{
author = "Rajačić, Milica and Todorović, Dragana and Krneta-Nikolić, Jelena D. and Pantelić, Gordana K. and Vukanac, Ivana and Janković, Marija M. and Sarap, Nataša",
year = "2021",
abstract = "Programom sistematskog ispitivanja nivoa radioaktivnosti u životnoj sredini na teritoriji Beograda predviđeno je merenje koncentracije radona (222Rn) u stambenim objektima, školskim i predškolskim ustanovama. Laboratorija "Zaštita", Instituta za nuklearne nauke "Vinča" je u periodu 2016-2020. izvršila ispitivanja u 547 prostorija (99 u stambenim objektima, 341 u školskim ustanovama i 107 u predškolskim jedinicama). Prosečna koncentracija 222Rn je iznosila 105 Bq/m3, a koncentarcija ispod 100 Bq/m3 je izmerena u 76,60 % prostorija. Vrednost od 400 Bq/m3 je prekoračena u 4,94 % prostorija. Od 15 beogradskih opština, koliko je pokriveno ovim istraživanjem, u 8 je detektovana koncentracija iznad 400 Bq/m3. Maksimalna izmerena vrednost u stambenim objektima je iznosila 3550 Bq/m3, dok je u vaspitno-obrazovnim ustanovama najveća detektovana koncentracija bila 1910 Bq/m3., The program of the level of radioactivity in the environment monitoring on the territory of Belgrade envisages measuring the concentration of radon in residential buildings, schools and kindergartens. The Department of Radiation and Environmental Protection of the Institute of Nuclear Sciences "Vinca" conducted examination in 547 rooms (99 in residential buildings, 341 in schools and 107 in kindergartens) in the period 2016-2020. The average concentration of 222Rn is 105 Bq/m3, and the concentration below 100 Bq/m3 was measured in 76.60 % of the rooms. The value of 400 Bq/m3 was exceeded in 4.94 % of the rooms. Out of 15 Belgrade municipalities covered by this research, a concentration above 400 Bq/m3 was detected in 8 municipalities. The maximum measured value in residential buildings was 3550 Bq/m3, while in educational institutions the highest detected concentration was 1910 Bq/m3.",
publisher = "Institut za nuklearne nauke "Vinča", Društvo za zaštitu od zračenja Srbije i Crne Gore",
journal = "31. симпозијум ДЗЗСЦГ : зборник радова",
title = "Sistematsko ispitivanje koncentracije radona na teritoriji Beograda, Systematic Investigation of Radon Concentration on the Territory of Belgrade",
pages = "128-133"
}
Rajačić, M., Todorović, D., Krneta-Nikolić, J. D., Pantelić, G. K., Vukanac, I., Janković, M. M.,& Sarap, N.. (2021). Sistematsko ispitivanje koncentracije radona na teritoriji Beograda. in 31. симпозијум ДЗЗСЦГ : зборник радова
Institut za nuklearne nauke "Vinča"., 128-133.
Rajačić M, Todorović D, Krneta-Nikolić JD, Pantelić GK, Vukanac I, Janković MM, Sarap N. Sistematsko ispitivanje koncentracije radona na teritoriji Beograda. in 31. симпозијум ДЗЗСЦГ : зборник радова. 2021;:128-133..
Rajačić, Milica, Todorović, Dragana, Krneta-Nikolić, Jelena D., Pantelić, Gordana K., Vukanac, Ivana, Janković, Marija M., Sarap, Nataša, "Sistematsko ispitivanje koncentracije radona na teritoriji Beograda" in 31. симпозијум ДЗЗСЦГ : зборник радова (2021):128-133.

Ispitivanje aktivnosti radionuklida u otpadnom materijalu – budžet merne nesigurnosti

Vukanac, Ivana; Rajačić, Milica; Andrić, Velibor; Krneta-Nikolić, Jelena D.; Todorović, Dragana; Pantelić, Gordana K.; Janković, Marija M.

(Institut za nuklearne nauke "Vinča", 2021)

TY  - CONF
AU  - Vukanac, Ivana
AU  - Rajačić, Milica
AU  - Andrić, Velibor
AU  - Krneta-Nikolić, Jelena D.
AU  - Todorović, Dragana
AU  - Pantelić, Gordana K.
AU  - Janković, Marija M.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10010
AB  - Prema važećoj zakonskoj regulativi u Republici Srbiji kontrola radiološke ispravnosti otpadnih materijala vrši se na graničnim prelazima, kao i kada postoji namera odlaganja u životnu sredinu. Sadržaj radionuklida u otpadnim materijalima u najvećem broju slučajeva odredjuje se gamaspektrometrijskim ispitivanjem. Ova merenja podrazumevaju adekvatnu pripremu uzorka u cilju postizanja željene geometrije merenja za koju je izvršena kalibracija efikasnosti gama spektrometra. U postupku pripreme uzorka otpadnog materijala često nije moguće postići zadovoljavajuću homogenost. Takodje, matriks merenog materijala u većini slučajeva ne odgovara matriksu standarda pomoću kojeg je izvršena kalibracija spektrometra. Iz ovih razloga je potrebno izvršiti odredjene korekcije rezultata merenja (transfer efikasnosti, na pr.), kao i proširenje budžeta merne nesigurnosti. U radu je detaljno prikazan postupak procene doprinosa nehomogenosti uzorka mernoj nesigurnosti, kao i doprinosa koji u budžet merne nesigurnosti unosi transfer efikasnosti i primena korekcionih faktora za koincidentno sumiranje.
AB  - According to the current legislation in the Republic of Serbia, the radiological control of waste materials is performed at border crossings, as well as when there is an intention to dispose these materials in the environment. The gamma ray spectrometry is commonly used for determination of radionuclide content in waste materials. These measurements imply adequate sample preparation in order to achieve the desired measurement geometry for which the efficiency of the gamma spectrometer has been calibrated. Satisfactory homogeneity is often not possible to achieve in the sample preparation process. Also, the matrix of the measured material in most cases does not correspond to the matrix of the standard used for efficiency calibration of the spectrometer. For these reasons, it is necessary to make certain corrections to the measurement results (efficiency transfer, for example), as well as to expand the measurement uncertainty budget. The paper presents in detail the procedure for assessing the contribution of inhomogeneity of the sample to the measurement uncertainty, as well as the contribution that the efficiency transfer and coincidence summing corrections introduce to the measurement uncertainty budget.
PB  - Institut za nuklearne nauke "Vinča"
PB  - Društvo za zaštitu od zračenja Srbije i Crne Gore
C3  - 31. симпозијум ДЗЗСЦГ : зборник радова
T1  - Ispitivanje aktivnosti radionuklida u otpadnom materijalu – budžet merne nesigurnosti
T1  - Testing of Radionuclide Activity in Waste Material - Measurement Uncertainty Budget
SP  - 162
EP  - 168
ER  - 
@conference{
author = "Vukanac, Ivana and Rajačić, Milica and Andrić, Velibor and Krneta-Nikolić, Jelena D. and Todorović, Dragana and Pantelić, Gordana K. and Janković, Marija M.",
year = "2021",
abstract = "Prema važećoj zakonskoj regulativi u Republici Srbiji kontrola radiološke ispravnosti otpadnih materijala vrši se na graničnim prelazima, kao i kada postoji namera odlaganja u životnu sredinu. Sadržaj radionuklida u otpadnim materijalima u najvećem broju slučajeva odredjuje se gamaspektrometrijskim ispitivanjem. Ova merenja podrazumevaju adekvatnu pripremu uzorka u cilju postizanja željene geometrije merenja za koju je izvršena kalibracija efikasnosti gama spektrometra. U postupku pripreme uzorka otpadnog materijala često nije moguće postići zadovoljavajuću homogenost. Takodje, matriks merenog materijala u većini slučajeva ne odgovara matriksu standarda pomoću kojeg je izvršena kalibracija spektrometra. Iz ovih razloga je potrebno izvršiti odredjene korekcije rezultata merenja (transfer efikasnosti, na pr.), kao i proširenje budžeta merne nesigurnosti. U radu je detaljno prikazan postupak procene doprinosa nehomogenosti uzorka mernoj nesigurnosti, kao i doprinosa koji u budžet merne nesigurnosti unosi transfer efikasnosti i primena korekcionih faktora za koincidentno sumiranje., According to the current legislation in the Republic of Serbia, the radiological control of waste materials is performed at border crossings, as well as when there is an intention to dispose these materials in the environment. The gamma ray spectrometry is commonly used for determination of radionuclide content in waste materials. These measurements imply adequate sample preparation in order to achieve the desired measurement geometry for which the efficiency of the gamma spectrometer has been calibrated. Satisfactory homogeneity is often not possible to achieve in the sample preparation process. Also, the matrix of the measured material in most cases does not correspond to the matrix of the standard used for efficiency calibration of the spectrometer. For these reasons, it is necessary to make certain corrections to the measurement results (efficiency transfer, for example), as well as to expand the measurement uncertainty budget. The paper presents in detail the procedure for assessing the contribution of inhomogeneity of the sample to the measurement uncertainty, as well as the contribution that the efficiency transfer and coincidence summing corrections introduce to the measurement uncertainty budget.",
publisher = "Institut za nuklearne nauke "Vinča", Društvo za zaštitu od zračenja Srbije i Crne Gore",
journal = "31. симпозијум ДЗЗСЦГ : зборник радова",
title = "Ispitivanje aktivnosti radionuklida u otpadnom materijalu – budžet merne nesigurnosti, Testing of Radionuclide Activity in Waste Material - Measurement Uncertainty Budget",
pages = "162-168"
}
Vukanac, I., Rajačić, M., Andrić, V., Krneta-Nikolić, J. D., Todorović, D., Pantelić, G. K.,& Janković, M. M.. (2021). Ispitivanje aktivnosti radionuklida u otpadnom materijalu – budžet merne nesigurnosti. in 31. симпозијум ДЗЗСЦГ : зборник радова
Institut za nuklearne nauke "Vinča"., 162-168.
Vukanac I, Rajačić M, Andrić V, Krneta-Nikolić JD, Todorović D, Pantelić GK, Janković MM. Ispitivanje aktivnosti radionuklida u otpadnom materijalu – budžet merne nesigurnosti. in 31. симпозијум ДЗЗСЦГ : зборник радова. 2021;:162-168..
Vukanac, Ivana, Rajačić, Milica, Andrić, Velibor, Krneta-Nikolić, Jelena D., Todorović, Dragana, Pantelić, Gordana K., Janković, Marija M., "Ispitivanje aktivnosti radionuklida u otpadnom materijalu – budžet merne nesigurnosti" in 31. симпозијум ДЗЗСЦГ : зборник радова (2021):162-168.

Radiological and physico-chemical characterization of red mud as an Al-containing precursor in inorganic binders for the building industry

Kljajević, Ljiljana M.; Mirković, Miljana M.; Dolenec, Sabina; Šter, Katarina; Hadžalić, Mustafa; Vukanac, Ivana; Nenadović, Miloš T.

(2021)

TY  - JOUR
AU  - Kljajević, Ljiljana M.
AU  - Mirković, Miljana M.
AU  - Dolenec, Sabina
AU  - Šter, Katarina
AU  - Hadžalić, Mustafa
AU  - Vukanac, Ivana
AU  - Nenadović, Miloš T.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10069
AB  - The potential re-use of red mud in the building and construction industry has been the subject of research of many scientists. The presented research is a contribution to the potential solution of this environmental issue through the synthesis of potential construction materials based on red mud. A promising way of recycling these secondary raw materials is the synthesis of alkali-activated binders or alkali activated materials. Alkali-activated materials or inorganic binders based on red mud are a new class of materials obtained by activation of inorganic precursors mainly constituted by silica, alumina and low content of calcium oxide. Since red mud contains radioactive elements like 226Ra and 232Th, this may be a problem for its further utilization. The content of naturally occurring radionuclides in manufactured material products with potential application in the building and construction industry is important from the standpoint of radiation protection. Gamma radiation of the primordial radionuclides, 40K and members of the uranium and thorium series, increases the external gamma dose rate. However, more and more precedence is being given to limiting the radiological dose originating from building materials on the population these days. The aim of this research was to investigate the possible influence of alkali activation-polymerization processes on the natural radioactivity of alkali activated materials synthesized by red mud (BOKSIT a. d. Milići, Zvornik, Bosnia and Herzegovina) and their structural properties. This research confirmed that during the polymerization process the natural radioactivity was reduced, and that the process of alkali activation of raw materials has an influence on natural radioactivity of synthesized materials.
T2  - Nuclear Technology and Radiation Protection
T1  - Radiological and physico-chemical characterization of red mud as an Al-containing precursor in inorganic binders for the building industry
VL  - 36
IS  - 2
SP  - 182
EP  - 191
DO  - 10.2298/NTRP2002182K
ER  - 
@article{
author = "Kljajević, Ljiljana M. and Mirković, Miljana M. and Dolenec, Sabina and Šter, Katarina and Hadžalić, Mustafa and Vukanac, Ivana and Nenadović, Miloš T.",
year = "2021",
abstract = "The potential re-use of red mud in the building and construction industry has been the subject of research of many scientists. The presented research is a contribution to the potential solution of this environmental issue through the synthesis of potential construction materials based on red mud. A promising way of recycling these secondary raw materials is the synthesis of alkali-activated binders or alkali activated materials. Alkali-activated materials or inorganic binders based on red mud are a new class of materials obtained by activation of inorganic precursors mainly constituted by silica, alumina and low content of calcium oxide. Since red mud contains radioactive elements like 226Ra and 232Th, this may be a problem for its further utilization. The content of naturally occurring radionuclides in manufactured material products with potential application in the building and construction industry is important from the standpoint of radiation protection. Gamma radiation of the primordial radionuclides, 40K and members of the uranium and thorium series, increases the external gamma dose rate. However, more and more precedence is being given to limiting the radiological dose originating from building materials on the population these days. The aim of this research was to investigate the possible influence of alkali activation-polymerization processes on the natural radioactivity of alkali activated materials synthesized by red mud (BOKSIT a. d. Milići, Zvornik, Bosnia and Herzegovina) and their structural properties. This research confirmed that during the polymerization process the natural radioactivity was reduced, and that the process of alkali activation of raw materials has an influence on natural radioactivity of synthesized materials.",
journal = "Nuclear Technology and Radiation Protection",
title = "Radiological and physico-chemical characterization of red mud as an Al-containing precursor in inorganic binders for the building industry",
volume = "36",
number = "2",
pages = "182-191",
doi = "10.2298/NTRP2002182K"
}
Kljajević, L. M., Mirković, M. M., Dolenec, S., Šter, K., Hadžalić, M., Vukanac, I.,& Nenadović, M. T.. (2021). Radiological and physico-chemical characterization of red mud as an Al-containing precursor in inorganic binders for the building industry. in Nuclear Technology and Radiation Protection, 36(2), 182-191.
https://doi.org/10.2298/NTRP2002182K
Kljajević LM, Mirković MM, Dolenec S, Šter K, Hadžalić M, Vukanac I, Nenadović MT. Radiological and physico-chemical characterization of red mud as an Al-containing precursor in inorganic binders for the building industry. in Nuclear Technology and Radiation Protection. 2021;36(2):182-191.
doi:10.2298/NTRP2002182K .
Kljajević, Ljiljana M., Mirković, Miljana M., Dolenec, Sabina, Šter, Katarina, Hadžalić, Mustafa, Vukanac, Ivana, Nenadović, Miloš T., "Radiological and physico-chemical characterization of red mud as an Al-containing precursor in inorganic binders for the building industry" in Nuclear Technology and Radiation Protection, 36, no. 2 (2021):182-191,
https://doi.org/10.2298/NTRP2002182K . .

Fly ash as a raw material for low-carbon cement clinkers and its radiological properties

Mirković, Miljana; Kljajević, Ljiljana; Nenadović, Snežana S.; Dolenec, Sabina; Šter, Katarina; Žibret, Lea; Rajačić, Milica

(2021)

TY  - JOUR
AU  - Mirković, Miljana
AU  - Kljajević, Ljiljana
AU  - Nenadović, Snežana S.
AU  - Dolenec, Sabina
AU  - Šter, Katarina
AU  - Žibret, Lea
AU  - Rajačić, Milica
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9812
AB  - Potential comprehensive solutions in order to protect environment is the synthesis of alternative mineral binders such as belite-sulfoaluminate cement clinkers, which are considered as energy and carbon reducing, allowing the substitution of natural raw materials with secondary ones. In this study, three different samples of fly ash (FA) from "Nikola Tesla" Thermal power plant (Serbia) were used in clinker synthesis with the targeted phase composition of 65 wt.% belite, 20 wt.% calcium sulfoaluminate and 5 wt.% ferrite. Fly ashes and cement clinkers were investigated in terms of physical–chemical, mineralogical and also radiological characterization. Results showed that incorporation of fly ash in raw mixture resulted in achieving the targeted phase composition of cement clinkers with satisfactory radiological properties.
T2  - Journal of Radioanalytical and Nuclear Chemistry
T1  - Fly ash as a raw material for low-carbon cement clinkers and its radiological properties
VL  - 328
IS  - 3
SP  - 1391
EP  - 1398
DO  - 10.1007/s10967-021-07719-7
ER  - 
@article{
author = "Mirković, Miljana and Kljajević, Ljiljana and Nenadović, Snežana S. and Dolenec, Sabina and Šter, Katarina and Žibret, Lea and Rajačić, Milica",
year = "2021",
abstract = "Potential comprehensive solutions in order to protect environment is the synthesis of alternative mineral binders such as belite-sulfoaluminate cement clinkers, which are considered as energy and carbon reducing, allowing the substitution of natural raw materials with secondary ones. In this study, three different samples of fly ash (FA) from "Nikola Tesla" Thermal power plant (Serbia) were used in clinker synthesis with the targeted phase composition of 65 wt.% belite, 20 wt.% calcium sulfoaluminate and 5 wt.% ferrite. Fly ashes and cement clinkers were investigated in terms of physical–chemical, mineralogical and also radiological characterization. Results showed that incorporation of fly ash in raw mixture resulted in achieving the targeted phase composition of cement clinkers with satisfactory radiological properties.",
journal = "Journal of Radioanalytical and Nuclear Chemistry",
title = "Fly ash as a raw material for low-carbon cement clinkers and its radiological properties",
volume = "328",
number = "3",
pages = "1391-1398",
doi = "10.1007/s10967-021-07719-7"
}
Mirković, M., Kljajević, L., Nenadović, S. S., Dolenec, S., Šter, K., Žibret, L.,& Rajačić, M.. (2021). Fly ash as a raw material for low-carbon cement clinkers and its radiological properties. in Journal of Radioanalytical and Nuclear Chemistry, 328(3), 1391-1398.
https://doi.org/10.1007/s10967-021-07719-7
Mirković M, Kljajević L, Nenadović SS, Dolenec S, Šter K, Žibret L, Rajačić M. Fly ash as a raw material for low-carbon cement clinkers and its radiological properties. in Journal of Radioanalytical and Nuclear Chemistry. 2021;328(3):1391-1398.
doi:10.1007/s10967-021-07719-7 .
Mirković, Miljana, Kljajević, Ljiljana, Nenadović, Snežana S., Dolenec, Sabina, Šter, Katarina, Žibret, Lea, Rajačić, Milica, "Fly ash as a raw material for low-carbon cement clinkers and its radiological properties" in Journal of Radioanalytical and Nuclear Chemistry, 328, no. 3 (2021):1391-1398,
https://doi.org/10.1007/s10967-021-07719-7 . .
1

Controllable ablative machining of Al/Ti and Ti/Al nano-layers on a Si substrate by single-pulse femtosecond laser irradiation

Gaković, Biljana M.; Kudryashov, S. I.; Danilov, P. A.; Milovanović, D.; Panjan, P.; Bezhanov, S. G.; Uryupin, S. A.; Ionin, A. A.

(2021)

TY  - JOUR
AU  - Gaković, Biljana M.
AU  - Kudryashov, S. I.
AU  - Danilov, P. A.
AU  - Milovanović, D.
AU  - Panjan, P.
AU  - Bezhanov, S. G.
AU  - Uryupin, S. A.
AU  - Ionin, A. A.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10012
AB  - Results concerning the controllable ablation of nano-layered thin films (NLTF) by femtosecond laser pulses are presented. Investigated samples were titanium-aluminum bilayers, deposited on a silicon substrate, with the top titanium or aluminum layer of variable thickness on the surface. Irradiation was done in ambient air with single femtosecond laser pulses under standard laboratory conditions. The samples were analyzed by complementary methods of optical and scanning electron microscopy and optical profilometry, exhibiting laser-fluence-dependent ablative removal either of the top layer or the entire bilayer or even partial ablation of the underlying silicon substrate. The removal (spallation) threshold fluences for the topmost layer are scalable versus its thickness almost irrespectively of its material, being rather selective for the Ti-coated samples and much less selective for the Al-coated samples. The removal of the entire bilayers was found to be strongly influenced by electronic properties of the underlying metallic layer, dictating the NLTF-Si adhesion, heat conduction, and capacity in the NLTFs toward the NLTF-Si interface and beyond, as well as by their thermophysical characteristics, e.g., almost twice higher melting temperature and enthalpy for Ti. As a result, precise fs-laser machining of the entire NLTFs is pronounced and selective for the samples with the fusible Al at the low-adhesion Al-Si interfaces, compared with the incomplete NLTF removal from the high-adhesion and refractory Ti-Si interfaces.
T2  - Applied Optics
T1  - Controllable ablative machining of Al/Ti and Ti/Al nano-layers on a Si substrate by single-pulse femtosecond laser irradiation
VL  - 60
IS  - 31
SP  - H12
EP  - H19
DO  - 10.1364/AO.432691
ER  - 
@article{
author = "Gaković, Biljana M. and Kudryashov, S. I. and Danilov, P. A. and Milovanović, D. and Panjan, P. and Bezhanov, S. G. and Uryupin, S. A. and Ionin, A. A.",
year = "2021",
abstract = "Results concerning the controllable ablation of nano-layered thin films (NLTF) by femtosecond laser pulses are presented. Investigated samples were titanium-aluminum bilayers, deposited on a silicon substrate, with the top titanium or aluminum layer of variable thickness on the surface. Irradiation was done in ambient air with single femtosecond laser pulses under standard laboratory conditions. The samples were analyzed by complementary methods of optical and scanning electron microscopy and optical profilometry, exhibiting laser-fluence-dependent ablative removal either of the top layer or the entire bilayer or even partial ablation of the underlying silicon substrate. The removal (spallation) threshold fluences for the topmost layer are scalable versus its thickness almost irrespectively of its material, being rather selective for the Ti-coated samples and much less selective for the Al-coated samples. The removal of the entire bilayers was found to be strongly influenced by electronic properties of the underlying metallic layer, dictating the NLTF-Si adhesion, heat conduction, and capacity in the NLTFs toward the NLTF-Si interface and beyond, as well as by their thermophysical characteristics, e.g., almost twice higher melting temperature and enthalpy for Ti. As a result, precise fs-laser machining of the entire NLTFs is pronounced and selective for the samples with the fusible Al at the low-adhesion Al-Si interfaces, compared with the incomplete NLTF removal from the high-adhesion and refractory Ti-Si interfaces.",
journal = "Applied Optics",
title = "Controllable ablative machining of Al/Ti and Ti/Al nano-layers on a Si substrate by single-pulse femtosecond laser irradiation",
volume = "60",
number = "31",
pages = "H12-H19",
doi = "10.1364/AO.432691"
}
Gaković, B. M., Kudryashov, S. I., Danilov, P. A., Milovanović, D., Panjan, P., Bezhanov, S. G., Uryupin, S. A.,& Ionin, A. A.. (2021). Controllable ablative machining of Al/Ti and Ti/Al nano-layers on a Si substrate by single-pulse femtosecond laser irradiation. in Applied Optics, 60(31), H12-H19.
https://doi.org/10.1364/AO.432691
Gaković BM, Kudryashov SI, Danilov PA, Milovanović D, Panjan P, Bezhanov SG, Uryupin SA, Ionin AA. Controllable ablative machining of Al/Ti and Ti/Al nano-layers on a Si substrate by single-pulse femtosecond laser irradiation. in Applied Optics. 2021;60(31):H12-H19.
doi:10.1364/AO.432691 .
Gaković, Biljana M., Kudryashov, S. I., Danilov, P. A., Milovanović, D., Panjan, P., Bezhanov, S. G., Uryupin, S. A., Ionin, A. A., "Controllable ablative machining of Al/Ti and Ti/Al nano-layers on a Si substrate by single-pulse femtosecond laser irradiation" in Applied Optics, 60, no. 31 (2021):H12-H19,
https://doi.org/10.1364/AO.432691 . .

The morphological and compositional changes of bimetallic Ti/Al thin film induced by ultra-short laser pulses

Gaković, Biljana M.; Danilov, Pavel A.; Kudryashov, Sergey I.; Milovanović, Dubravka S.; Radulović, Aleksandra M.; Panjan, Peter; Ionin, Andrey A.

(2021)

TY  - JOUR
AU  - Gaković, Biljana M.
AU  - Danilov, Pavel A.
AU  - Kudryashov, Sergey I.
AU  - Milovanović, Dubravka S.
AU  - Radulović, Aleksandra M.
AU  - Panjan, Peter
AU  - Ionin, Andrey A.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10038
AB  - Results regarding morphological and compositional changes of bimetallic thin film (BMTF), composed of aluminium (Al) and titanium (Ti) nano-layers, by single fs laser pulses, are presented. Laser irradiation was conducted in the air with focused, linearly polarized laser pulses, the duration being 300 fs, wavelength 515 nm, and pulse energy up to 1.2μJ. Effects of the variations of the pulse energy on the changes were studied. In the experiment, single pulse energy values from 0.03 to 0.08 μ J caused ablation–photomechanical spallation of the upper part of BMTF layer from the Si substrate, without ablation of the whole film. Irradiation at higher pulse energies gradually removed the whole BMTF and even a part of the Si substrate. We explained the influence of different electron–phonon dynamics, in the case of multilayered thin films composed of Al and Ti, on BMTF ablation. Damage/ablation threshold, which is minimal pulse energy/fluence sufficient for starting ablation, was calculated. Graphic abstract: [Figure not available: see fulltext.] © 2021, The Author(s), under exclusive licence to EDP Sciences, SIF and Springer-Verlag GmbH Germany, part of Springer Nature.
T2  - European Physical Journal D
T1  - The morphological and compositional changes of bimetallic Ti/Al thin film induced by ultra-short laser pulses
VL  - 75
IS  - 11
DO  - 10.1140/epjd/s10053-021-00292-4
ER  - 
@article{
author = "Gaković, Biljana M. and Danilov, Pavel A. and Kudryashov, Sergey I. and Milovanović, Dubravka S. and Radulović, Aleksandra M. and Panjan, Peter and Ionin, Andrey A.",
year = "2021",
abstract = "Results regarding morphological and compositional changes of bimetallic thin film (BMTF), composed of aluminium (Al) and titanium (Ti) nano-layers, by single fs laser pulses, are presented. Laser irradiation was conducted in the air with focused, linearly polarized laser pulses, the duration being 300 fs, wavelength 515 nm, and pulse energy up to 1.2μJ. Effects of the variations of the pulse energy on the changes were studied. In the experiment, single pulse energy values from 0.03 to 0.08 μ J caused ablation–photomechanical spallation of the upper part of BMTF layer from the Si substrate, without ablation of the whole film. Irradiation at higher pulse energies gradually removed the whole BMTF and even a part of the Si substrate. We explained the influence of different electron–phonon dynamics, in the case of multilayered thin films composed of Al and Ti, on BMTF ablation. Damage/ablation threshold, which is minimal pulse energy/fluence sufficient for starting ablation, was calculated. Graphic abstract: [Figure not available: see fulltext.] © 2021, The Author(s), under exclusive licence to EDP Sciences, SIF and Springer-Verlag GmbH Germany, part of Springer Nature.",
journal = "European Physical Journal D",
title = "The morphological and compositional changes of bimetallic Ti/Al thin film induced by ultra-short laser pulses",
volume = "75",
number = "11",
doi = "10.1140/epjd/s10053-021-00292-4"
}
Gaković, B. M., Danilov, P. A., Kudryashov, S. I., Milovanović, D. S., Radulović, A. M., Panjan, P.,& Ionin, A. A.. (2021). The morphological and compositional changes of bimetallic Ti/Al thin film induced by ultra-short laser pulses. in European Physical Journal D, 75(11).
https://doi.org/10.1140/epjd/s10053-021-00292-4
Gaković BM, Danilov PA, Kudryashov SI, Milovanović DS, Radulović AM, Panjan P, Ionin AA. The morphological and compositional changes of bimetallic Ti/Al thin film induced by ultra-short laser pulses. in European Physical Journal D. 2021;75(11).
doi:10.1140/epjd/s10053-021-00292-4 .
Gaković, Biljana M., Danilov, Pavel A., Kudryashov, Sergey I., Milovanović, Dubravka S., Radulović, Aleksandra M., Panjan, Peter, Ionin, Andrey A., "The morphological and compositional changes of bimetallic Ti/Al thin film induced by ultra-short laser pulses" in European Physical Journal D, 75, no. 11 (2021),
https://doi.org/10.1140/epjd/s10053-021-00292-4 . .

Characteristics of radioactivity in the surface air along the 45°N zonal belt in South-Eastern Europe

Ajtić, Jelena V.; Zorko, Benjamin; Nečemer, Marijan; Sarvan, Darko Z.; Rajačić, Milica M.; Krneta-Nikolić, Jelena D.; Todorović, Dragana J.; Đurđević, Vladimir S.; Vodenik, Branko; Glavič-Cindro, Denis; Kožar Logar, Jasmina Koar

(2021)

TY  - JOUR
AU  - Ajtić, Jelena V.
AU  - Zorko, Benjamin
AU  - Nečemer, Marijan
AU  - Sarvan, Darko Z.
AU  - Rajačić, Milica M.
AU  - Krneta-Nikolić, Jelena D.
AU  - Todorović, Dragana J.
AU  - Đurđević, Vladimir S.
AU  - Vodenik, Branko
AU  - Glavič-Cindro, Denis
AU  - Kožar Logar, Jasmina Koar
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10075
AB  - This study investigates the beryllium-7, lead-210 and caesium-137 activity concentrations in aerosol filter samples collected monthly along the 45°N zonal belt over 1991–2019. Sampling was performed in three locations, one in Serbia and two in Slovenia, and the Slovenian data records are published here for the first time. The activity concentrations were determined by standard gamma spectrometry. The obtained results are in general agreement with the literature data for Europe. The data sets at different sites display similarities in measurement ranges, overall means and seasonal cycles. Still, statistical tests show significant differences among the radionuclides’ concentrations across the locations. To investigate underlying processes that affect radioactivity in the surface air in this region, multivariate statistical concepts are applied to the radionuclides’ concentrations and local meteorological parameters. Discriminant analysis shows that all three sites are well separated from each other. Principal component analysis gives common pattern of interconnection between the observables: temperature has a stronger influence on the behaviour of beryllium-7 and lead-210 than that of caesium-137, but a negative correlation of the radionuclides’ concentrations with precipitation seems the strongest for caesium-137. Principal component analysis also shows local differences in the degree of relationship between the meteorological parameters and activity concentrations of the investigated radionuclides. This is an important finding for future atmospheric transport studies.
T2  - International Journal of Environmental Science and Technology
T1  - Characteristics of radioactivity in the surface air along the 45°N zonal belt in South-Eastern Europe
DO  - 10.1007/s13762-021-03814-0
ER  - 
@article{
author = "Ajtić, Jelena V. and Zorko, Benjamin and Nečemer, Marijan and Sarvan, Darko Z. and Rajačić, Milica M. and Krneta-Nikolić, Jelena D. and Todorović, Dragana J. and Đurđević, Vladimir S. and Vodenik, Branko and Glavič-Cindro, Denis and Kožar Logar, Jasmina Koar",
year = "2021",
abstract = "This study investigates the beryllium-7, lead-210 and caesium-137 activity concentrations in aerosol filter samples collected monthly along the 45°N zonal belt over 1991–2019. Sampling was performed in three locations, one in Serbia and two in Slovenia, and the Slovenian data records are published here for the first time. The activity concentrations were determined by standard gamma spectrometry. The obtained results are in general agreement with the literature data for Europe. The data sets at different sites display similarities in measurement ranges, overall means and seasonal cycles. Still, statistical tests show significant differences among the radionuclides’ concentrations across the locations. To investigate underlying processes that affect radioactivity in the surface air in this region, multivariate statistical concepts are applied to the radionuclides’ concentrations and local meteorological parameters. Discriminant analysis shows that all three sites are well separated from each other. Principal component analysis gives common pattern of interconnection between the observables: temperature has a stronger influence on the behaviour of beryllium-7 and lead-210 than that of caesium-137, but a negative correlation of the radionuclides’ concentrations with precipitation seems the strongest for caesium-137. Principal component analysis also shows local differences in the degree of relationship between the meteorological parameters and activity concentrations of the investigated radionuclides. This is an important finding for future atmospheric transport studies.",
journal = "International Journal of Environmental Science and Technology",
title = "Characteristics of radioactivity in the surface air along the 45°N zonal belt in South-Eastern Europe",
doi = "10.1007/s13762-021-03814-0"
}
Ajtić, J. V., Zorko, B., Nečemer, M., Sarvan, D. Z., Rajačić, M. M., Krneta-Nikolić, J. D., Todorović, D. J., Đurđević, V. S., Vodenik, B., Glavič-Cindro, D.,& Kožar Logar, J. K.. (2021). Characteristics of radioactivity in the surface air along the 45°N zonal belt in South-Eastern Europe. in International Journal of Environmental Science and Technology.
https://doi.org/10.1007/s13762-021-03814-0
Ajtić JV, Zorko B, Nečemer M, Sarvan DZ, Rajačić MM, Krneta-Nikolić JD, Todorović DJ, Đurđević VS, Vodenik B, Glavič-Cindro D, Kožar Logar JK. Characteristics of radioactivity in the surface air along the 45°N zonal belt in South-Eastern Europe. in International Journal of Environmental Science and Technology. 2021;.
doi:10.1007/s13762-021-03814-0 .
Ajtić, Jelena V., Zorko, Benjamin, Nečemer, Marijan, Sarvan, Darko Z., Rajačić, Milica M., Krneta-Nikolić, Jelena D., Todorović, Dragana J., Đurđević, Vladimir S., Vodenik, Branko, Glavič-Cindro, Denis, Kožar Logar, Jasmina Koar, "Characteristics of radioactivity in the surface air along the 45°N zonal belt in South-Eastern Europe" in International Journal of Environmental Science and Technology (2021),
https://doi.org/10.1007/s13762-021-03814-0 . .

Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride

Veljković, Filip; Radović, Ivana M.; Toprek, Dragan; Petrović, Đorđe; Stoiljković, Milovan; Mitić, Vojislav V.; Veličković, Suzana R.

(2021)

TY  - JOUR
AU  - Veljković, Filip
AU  - Radović, Ivana M.
AU  - Toprek, Dragan
AU  - Petrović, Đorđe
AU  - Stoiljković, Milovan
AU  - Mitić, Vojislav V.
AU  - Veličković, Suzana R.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10084
AB  - Due to the increased use of yttrium in agriculture and industry, there is a growing interest in the impact of yttrium on the environment and human health. Developing novel procedures to detect and quantify species of yttrium represents an important task. In this work, we apply laser desorption/ionization-mass spectrometry (LDI-MS) to detect cluster ions of the solution of yttrium(III) chloride (YCl3) at different pH values. The density functional theory (DFT) calculations were used to reveal the energetically most favored structures of the anions and cations chosen from the LDI-MS results. Examination of the positive and negative mode LDI mass spectra of YCl3 showed the presence of the heterogeneous mononuclear and polynuclear clusters, such as [YCl(OH) (H2O)3]++, [Y2(H2O)]++, [Y4H2(H2O)4]++, and [Y5O4H3]++ (at pH 2 and 5) and [Y2Cl2(H2O)2]−−, [Y2O5(HCl)(OH)]−−, and [Y3OH3(OH)2(H2O)]−− (at pH 2, 5, and 10). The variation in the pH solution of YCl3 slightly affects the LDI mass spectrum of these yttrium clusters. It has only been noticed that the [Y4H2(H2O)4]++ cluster ions were not detected at pH 10. These results can become a guide in the detection of yttrium chloride by LDI-MS in real samples in different fields (ecological, food, and human).
T2  - Modern Physics Letters B
T1  - Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride
VL  - 35
IS  - 35
SP  - 2150454
DO  - 10.1142/S0217984921504546
ER  - 
@article{
author = "Veljković, Filip and Radović, Ivana M. and Toprek, Dragan and Petrović, Đorđe and Stoiljković, Milovan and Mitić, Vojislav V. and Veličković, Suzana R.",
year = "2021",
abstract = "Due to the increased use of yttrium in agriculture and industry, there is a growing interest in the impact of yttrium on the environment and human health. Developing novel procedures to detect and quantify species of yttrium represents an important task. In this work, we apply laser desorption/ionization-mass spectrometry (LDI-MS) to detect cluster ions of the solution of yttrium(III) chloride (YCl3) at different pH values. The density functional theory (DFT) calculations were used to reveal the energetically most favored structures of the anions and cations chosen from the LDI-MS results. Examination of the positive and negative mode LDI mass spectra of YCl3 showed the presence of the heterogeneous mononuclear and polynuclear clusters, such as [YCl(OH) (H2O)3]++, [Y2(H2O)]++, [Y4H2(H2O)4]++, and [Y5O4H3]++ (at pH 2 and 5) and [Y2Cl2(H2O)2]−−, [Y2O5(HCl)(OH)]−−, and [Y3OH3(OH)2(H2O)]−− (at pH 2, 5, and 10). The variation in the pH solution of YCl3 slightly affects the LDI mass spectrum of these yttrium clusters. It has only been noticed that the [Y4H2(H2O)4]++ cluster ions were not detected at pH 10. These results can become a guide in the detection of yttrium chloride by LDI-MS in real samples in different fields (ecological, food, and human).",
journal = "Modern Physics Letters B",
title = "Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride",
volume = "35",
number = "35",
pages = "2150454",
doi = "10.1142/S0217984921504546"
}
Veljković, F., Radović, I. M., Toprek, D., Petrović, Đ., Stoiljković, M., Mitić, V. V.,& Veličković, S. R.. (2021). Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride. in Modern Physics Letters B, 35(35), 2150454.
https://doi.org/10.1142/S0217984921504546
Veljković F, Radović IM, Toprek D, Petrović Đ, Stoiljković M, Mitić VV, Veličković SR. Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride. in Modern Physics Letters B. 2021;35(35):2150454.
doi:10.1142/S0217984921504546 .
Veljković, Filip, Radović, Ivana M., Toprek, Dragan, Petrović, Đorđe, Stoiljković, Milovan, Mitić, Vojislav V., Veličković, Suzana R., "Laser desorption/ionization time-of-flight mass spectrometry of yttrium(III) chloride" in Modern Physics Letters B, 35, no. 35 (2021):2150454,
https://doi.org/10.1142/S0217984921504546 . .

Carbon cryogel preparation and characterization

Matović, Branko Ž.; Gorshkova, Yulia E.; Kottsov, Sergey Yu; Kopitsa, Gennady; Butulija, Svetlana; Minović Arsić, T.; Cvijović-Alagić, Ivana

(2021)

TY  - JOUR
AU  - Matović, Branko Ž.
AU  - Gorshkova, Yulia E.
AU  - Kottsov, Sergey Yu
AU  - Kopitsa, Gennady
AU  - Butulija, Svetlana
AU  - Minović Arsić, T.
AU  - Cvijović-Alagić, Ivana
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10073
AB  - The carbon cryogels (CCs) show significant potential for application in a wide variety of applications, from absorbents and catalysts to supercapacitors and fuel cells, due to their high specific surface area, multimodal pore-size distribution, electrical conductivity, and thermo-mechanical stability. In the present study, the CC material was prepared by a sol-gel process from resorcinol with formaldehyde and heat treatment in an inert atmosphere. The Brunauer Emmett Teller (BET) measurements, X-ray diffraction (XRD), Raman spectroscopy, Fourier-transform infrared spectroscopy (FT-IR), differential thermal analysis with thermogravimetric measurements (DTA-TG), scanning electron microscopy (SEM), and small-angle X-ray scattering (SAXS) analysis, as complementary techniques, were used to characterize the obtained CC. It was found that the obtained CC is a porous amorphous material with high open porosity (≈82.5%) and complex porous structure organization. Using the small-angle neutron scattering (SANS) with the contrast variation technique and the adsorption of deuterated water by carbon cryogel it was possible to separately study the structure of open and closed pores, as well as to estimate both the volume fraction of closed pores (φclose pore ≈ 1%) and the total porosity (φtotal ≈ 83.5%) of the obtained CC.
T2  - Diamond and Related Materials
T1  - Carbon cryogel preparation and characterization
SP  - 108727
DO  - 10.1016/j.diamond.2021.108727
ER  - 
@article{
author = "Matović, Branko Ž. and Gorshkova, Yulia E. and Kottsov, Sergey Yu and Kopitsa, Gennady and Butulija, Svetlana and Minović Arsić, T. and Cvijović-Alagić, Ivana",
year = "2021",
abstract = "The carbon cryogels (CCs) show significant potential for application in a wide variety of applications, from absorbents and catalysts to supercapacitors and fuel cells, due to their high specific surface area, multimodal pore-size distribution, electrical conductivity, and thermo-mechanical stability. In the present study, the CC material was prepared by a sol-gel process from resorcinol with formaldehyde and heat treatment in an inert atmosphere. The Brunauer Emmett Teller (BET) measurements, X-ray diffraction (XRD), Raman spectroscopy, Fourier-transform infrared spectroscopy (FT-IR), differential thermal analysis with thermogravimetric measurements (DTA-TG), scanning electron microscopy (SEM), and small-angle X-ray scattering (SAXS) analysis, as complementary techniques, were used to characterize the obtained CC. It was found that the obtained CC is a porous amorphous material with high open porosity (≈82.5%) and complex porous structure organization. Using the small-angle neutron scattering (SANS) with the contrast variation technique and the adsorption of deuterated water by carbon cryogel it was possible to separately study the structure of open and closed pores, as well as to estimate both the volume fraction of closed pores (φclose pore ≈ 1%) and the total porosity (φtotal ≈ 83.5%) of the obtained CC.",
journal = "Diamond and Related Materials",
title = "Carbon cryogel preparation and characterization",
pages = "108727",
doi = "10.1016/j.diamond.2021.108727"
}
Matović, B. Ž., Gorshkova, Y. E., Kottsov, S. Y., Kopitsa, G., Butulija, S., Minović Arsić, T.,& Cvijović-Alagić, I.. (2021). Carbon cryogel preparation and characterization. in Diamond and Related Materials, 108727.
https://doi.org/10.1016/j.diamond.2021.108727
Matović BŽ, Gorshkova YE, Kottsov SY, Kopitsa G, Butulija S, Minović Arsić T, Cvijović-Alagić I. Carbon cryogel preparation and characterization. in Diamond and Related Materials. 2021;:108727.
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Matović, Branko Ž., Gorshkova, Yulia E., Kottsov, Sergey Yu, Kopitsa, Gennady, Butulija, Svetlana, Minović Arsić, T., Cvijović-Alagić, Ivana, "Carbon cryogel preparation and characterization" in Diamond and Related Materials (2021):108727,
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Radionuclides’ content in forest ecosystem located in southwestern part of Serbia

Hadrović, Sabahudin H.; Čeliković, Igor T.; Krneta-Nikolić, Jelena D.; Rajačić, Milica M.; Todorović, Dragana J.

(2021)

TY  - JOUR
AU  - Hadrović, Sabahudin H.
AU  - Čeliković, Igor T.
AU  - Krneta-Nikolić, Jelena D.
AU  - Rajačić, Milica M.
AU  - Todorović, Dragana J.
PY  - 2021
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10071
AB  - The results of the gamma-spectrometric measurements in a 16500 ha large region of south-western Serbia, are presented. Activity concentrations of 40K, 137Cs, and 210Pb in different deciduous and evergreen trees in the region are investigated. For all the investigated isotopes, there is a tendency that, on average, the lowest activity concentrations were found in tree stems, then in leaves, while the highest ones were in the soil. Statistical analysis did not show any differences between activity concentrations of leaves and needles, showing that both leaves and needles could be equally well used as a biomonitors.
T2  - Nuclear Technology and Radiation Protection
T1  - Radionuclides’ content in forest ecosystem located in southwestern part of Serbia
VL  - 36
IS  - 2
SP  - 192
EP  - 196
DO  - 10.2298/NTRP210112014H
ER  - 
@article{
author = "Hadrović, Sabahudin H. and Čeliković, Igor T. and Krneta-Nikolić, Jelena D. and Rajačić, Milica M. and Todorović, Dragana J.",
year = "2021",
abstract = "The results of the gamma-spectrometric measurements in a 16500 ha large region of south-western Serbia, are presented. Activity concentrations of 40K, 137Cs, and 210Pb in different deciduous and evergreen trees in the region are investigated. For all the investigated isotopes, there is a tendency that, on average, the lowest activity concentrations were found in tree stems, then in leaves, while the highest ones were in the soil. Statistical analysis did not show any differences between activity concentrations of leaves and needles, showing that both leaves and needles could be equally well used as a biomonitors.",
journal = "Nuclear Technology and Radiation Protection",
title = "Radionuclides’ content in forest ecosystem located in southwestern part of Serbia",
volume = "36",
number = "2",
pages = "192-196",
doi = "10.2298/NTRP210112014H"
}
Hadrović, S. H., Čeliković, I. T., Krneta-Nikolić, J. D., Rajačić, M. M.,& Todorović, D. J.. (2021). Radionuclides’ content in forest ecosystem located in southwestern part of Serbia. in Nuclear Technology and Radiation Protection, 36(2), 192-196.
https://doi.org/10.2298/NTRP210112014H
Hadrović SH, Čeliković IT, Krneta-Nikolić JD, Rajačić MM, Todorović DJ. Radionuclides’ content in forest ecosystem located in southwestern part of Serbia. in Nuclear Technology and Radiation Protection. 2021;36(2):192-196.
doi:10.2298/NTRP210112014H .
Hadrović, Sabahudin H., Čeliković, Igor T., Krneta-Nikolić, Jelena D., Rajačić, Milica M., Todorović, Dragana J., "Radionuclides’ content in forest ecosystem located in southwestern part of Serbia" in Nuclear Technology and Radiation Protection, 36, no. 2 (2021):192-196,
https://doi.org/10.2298/NTRP210112014H . .