Development of Methods of Monitoring and Removal of Biologically Actives Substances Aimed at Improving the Quality of the Environment

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Development of Methods of Monitoring and Removal of Biologically Actives Substances Aimed at Improving the Quality of the Environment (en)
Развој метода праћења и уклањања биолошки активних супстанци у циљу унапређења квалитета животне средине (sr)
Razvoj metoda praćenja i uklanjanja biološki aktivnih supstanci u cilju unapređenja kvaliteta životne sredine (sr_RS)
Authors

Publications

Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation

Banić, Nemanja D.; Abramović, Biljana F.; Krstić, Jugoslav B.; Šojić Merkulov, Daniela V.; Finčur, Nina L.; Mitrić, Miodrag

(2019)

TY  - JOUR
AU  - Banić, Nemanja D.
AU  - Abramović, Biljana F.
AU  - Krstić, Jugoslav B.
AU  - Šojić Merkulov, Daniela V.
AU  - Finčur, Nina L.
AU  - Mitrić, Miodrag
PY  - 2019
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8446
AB  - This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed. © 2018 The Korean Society of Industrial and Engineering Chemistry
T2  - Journal of Industrial and Engineering Chemistry
T1  - Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation
VL  - 70
SP  - 264
EP  - 275
DO  - 10.1016/j.jiec.2018.10.025
ER  - 
@article{
author = "Banić, Nemanja D. and Abramović, Biljana F. and Krstić, Jugoslav B. and Šojić Merkulov, Daniela V. and Finčur, Nina L. and Mitrić, Miodrag",
year = "2019",
abstract = "This work presents the characterization of novel synthesized WO3/Fe3O4 catalysts and investigates their photocatalytic activity for thiacloprid decomposition under UV and simulated sunlight radiation. Four WO3/Fe3O4 nanopowders with different amounts of WO3 were synthesized by chemical co-precipitation method. XRD analysis showed the presence of hematite and magnetite nano-dimensional phases of Fe3O4 in the catalysts. The magnetite phase content increased with increasing WO3 content. Degradation efficiency of thiacloprid in the presence of 6.1WO3/Fe3O4/H2O2 under simulated solar radiation was 2.2 times higher compared to Fe3O4. Under an external magnetic field, a significant increase in the catalysts separation from reaction mixture was observed. © 2018 The Korean Society of Industrial and Engineering Chemistry",
journal = "Journal of Industrial and Engineering Chemistry",
title = "Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation",
volume = "70",
pages = "264-275",
doi = "10.1016/j.jiec.2018.10.025"
}
Banić, N. D., Abramović, B. F., Krstić, J. B., Šojić Merkulov, D. V., Finčur, N. L.,& Mitrić, M.. (2019). Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation. in Journal of Industrial and Engineering Chemistry, 70, 264-275.
https://doi.org/10.1016/j.jiec.2018.10.025
Banić ND, Abramović BF, Krstić JB, Šojić Merkulov DV, Finčur NL, Mitrić M. Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation. in Journal of Industrial and Engineering Chemistry. 2019;70:264-275.
doi:10.1016/j.jiec.2018.10.025 .
Banić, Nemanja D., Abramović, Biljana F., Krstić, Jugoslav B., Šojić Merkulov, Daniela V., Finčur, Nina L., Mitrić, Miodrag, "Novel WO3/Fe3O4 magnetic photocatalysts: Preparation, characterization and thiacloprid photodegradation" in Journal of Industrial and Engineering Chemistry, 70 (2019):264-275,
https://doi.org/10.1016/j.jiec.2018.10.025 . .
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Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment

Šojić Merkulov, Daniela V.; Despotović, Vesna N.; Banić, Nemanja D.; Armaković, Sanja J.; Finčur, Nina L.; Lazarević, Marina J.; Četojević-Simin, Dragana D.; Orčić, Dejan Z.; Radoičić, Marija B.; Šaponjić, Zoran; Čomor, Mirjana; Abramović, Biljana F.

(2018)

TY  - JOUR
AU  - Šojić Merkulov, Daniela V.
AU  - Despotović, Vesna N.
AU  - Banić, Nemanja D.
AU  - Armaković, Sanja J.
AU  - Finčur, Nina L.
AU  - Lazarević, Marina J.
AU  - Četojević-Simin, Dragana D.
AU  - Orčić, Dejan Z.
AU  - Radoičić, Marija B.
AU  - Šaponjić, Zoran
AU  - Čomor, Mirjana
AU  - Abramović, Biljana F.
PY  - 2018
UR  - http://linkinghub.elsevier.com/retrieve/pii/S0269749117352053
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7699
AB  - A comprehensive study of the removal of selected biologically active compounds (pharmaceuticals and pesticides) from different water types was conducted using bare TiO2nanoparticles and TiO2/polyaniline (TP-50, TP-100, and TP-150) nanocomposite powders. In order to investigate how molecular structure of the substrate influences the rate of its removal, we compared degradation efficiency of the initial substrates and degree of mineralization for the active components of pharmaceuticals (propranolol, and amitriptyline) and pesticides (sulcotrione, and clomazone) in double distilled (DDW) and environmental waters. The results indicate that the efficiency of photocatalytic degradation of propranolol and amitriptyline was higher in environmental waters: rivers (Danube, Tisa, and Begej) and lakes (Moharač, and Sot) in comparison with DDW. On the contrary, degradation efficacy of sulcotrione and clomazone was lower in environmental waters. Further, of the all catalysts applied, bare TiO2and TP-100 were found to be most effective in the mineralization of propranolol and amitriptyline, respectively, while TP-150 appeared to be the most efficient in terms of sulcotrione and clomazone mineralization. Also, there was no significant toxicity observed after the irradiation of pharmaceuticals or pesticides solutions using appropriate catalysts on rat hepatoma (H-4-II-E), mouse neuroblastoma (Neuro-2a), human colon adenocarcinoma (HT-29), and human fetal lung (MRC-5) cell lines. Subsequently, detection and identification of the formed intermediates in the case of sulcotrione photocatalytic degradation using bare TiO2and TP-150 showed slightly different pathways of degradation. Furthermore, tentative pathways of sulcotrione photocatalytic degradation were proposed and discussed. Kinetics, toxicity and intermediates assessment of biologically active compounds (pesticides and pharmaceuticals) in environmental waters.
T2  - Environmental Pollution
T1  - Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment
VL  - 239
SP  - 457
EP  - 465
DO  - 10.1016/j.envpol.2018.04.039
ER  - 
@article{
author = "Šojić Merkulov, Daniela V. and Despotović, Vesna N. and Banić, Nemanja D. and Armaković, Sanja J. and Finčur, Nina L. and Lazarević, Marina J. and Četojević-Simin, Dragana D. and Orčić, Dejan Z. and Radoičić, Marija B. and Šaponjić, Zoran and Čomor, Mirjana and Abramović, Biljana F.",
year = "2018",
abstract = "A comprehensive study of the removal of selected biologically active compounds (pharmaceuticals and pesticides) from different water types was conducted using bare TiO2nanoparticles and TiO2/polyaniline (TP-50, TP-100, and TP-150) nanocomposite powders. In order to investigate how molecular structure of the substrate influences the rate of its removal, we compared degradation efficiency of the initial substrates and degree of mineralization for the active components of pharmaceuticals (propranolol, and amitriptyline) and pesticides (sulcotrione, and clomazone) in double distilled (DDW) and environmental waters. The results indicate that the efficiency of photocatalytic degradation of propranolol and amitriptyline was higher in environmental waters: rivers (Danube, Tisa, and Begej) and lakes (Moharač, and Sot) in comparison with DDW. On the contrary, degradation efficacy of sulcotrione and clomazone was lower in environmental waters. Further, of the all catalysts applied, bare TiO2and TP-100 were found to be most effective in the mineralization of propranolol and amitriptyline, respectively, while TP-150 appeared to be the most efficient in terms of sulcotrione and clomazone mineralization. Also, there was no significant toxicity observed after the irradiation of pharmaceuticals or pesticides solutions using appropriate catalysts on rat hepatoma (H-4-II-E), mouse neuroblastoma (Neuro-2a), human colon adenocarcinoma (HT-29), and human fetal lung (MRC-5) cell lines. Subsequently, detection and identification of the formed intermediates in the case of sulcotrione photocatalytic degradation using bare TiO2and TP-150 showed slightly different pathways of degradation. Furthermore, tentative pathways of sulcotrione photocatalytic degradation were proposed and discussed. Kinetics, toxicity and intermediates assessment of biologically active compounds (pesticides and pharmaceuticals) in environmental waters.",
journal = "Environmental Pollution",
title = "Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment",
volume = "239",
pages = "457-465",
doi = "10.1016/j.envpol.2018.04.039"
}
Šojić Merkulov, D. V., Despotović, V. N., Banić, N. D., Armaković, S. J., Finčur, N. L., Lazarević, M. J., Četojević-Simin, D. D., Orčić, D. Z., Radoičić, M. B., Šaponjić, Z., Čomor, M.,& Abramović, B. F.. (2018). Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment. in Environmental Pollution, 239, 457-465.
https://doi.org/10.1016/j.envpol.2018.04.039
Šojić Merkulov DV, Despotović VN, Banić ND, Armaković SJ, Finčur NL, Lazarević MJ, Četojević-Simin DD, Orčić DZ, Radoičić MB, Šaponjić Z, Čomor M, Abramović BF. Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment. in Environmental Pollution. 2018;239:457-465.
doi:10.1016/j.envpol.2018.04.039 .
Šojić Merkulov, Daniela V., Despotović, Vesna N., Banić, Nemanja D., Armaković, Sanja J., Finčur, Nina L., Lazarević, Marina J., Četojević-Simin, Dragana D., Orčić, Dejan Z., Radoičić, Marija B., Šaponjić, Zoran, Čomor, Mirjana, Abramović, Biljana F., "Photocatalytic decomposition of selected biologically active compounds in environmental waters using TiO 2 /polyaniline nanocomposites: Kinetics, toxicity and intermediates assessment" in Environmental Pollution, 239 (2018):457-465,
https://doi.org/10.1016/j.envpol.2018.04.039 . .
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Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route

Tomić, Nataša; Grujić-Brojčin, Mirjana; Finčur, Nina L.; Abramović, Biljana F.; Simović, Bojana; Krstić, Jugoslav B.; Matović, Branko; Šćepanović, Maja

(Elsevier, 2015)

TY  - JOUR
AU  - Tomić, Nataša
AU  - Grujić-Brojčin, Mirjana
AU  - Finčur, Nina L.
AU  - Abramović, Biljana F.
AU  - Simović, Bojana
AU  - Krstić, Jugoslav B.
AU  - Matović, Branko
AU  - Šćepanović, Maja
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/821
AB  - Two series of nanocrystalline brookite-type powders have been synthesized by using combined sal gel hydrothermal method with titanium tetrachloride (TiCI4) as a precursor and hydrothermal temperature and reaction time varied in the range of 120-200 degrees C and 12-48 h, respectively. The effects of chosen synthesis parameters on structural, morphological and optical properties of synthesized powders have been investigated by the XRPD, SEM, EDS and BET measurements, as well Raman spectroscopy and spectroscopic ellipsometry. The XRPD results have shown that pure brookite phase, with mean crystallite size of -33 nm, has been obtained only in the sample synthesized at 200 degrees C, after 24 h of hydrothermal process. In all other samples anatase phase also appears, whereas rutile and sodium titanate phases have been noticed in the samples synthesized at lower temperatures. The presence of different titania phases has also been confirmed and analyzed by Raman scattering measurements. The SEM measurements have shown spindle-like particles in brookite-rich samples synthesized at 200 degrees C, whereas BET measurements have detected mesoporous structure in these samples. The properties of synthesized powders have been correlated to their photocatalytic efficiency, tested in degradation of alprazolam, one of the 5th generation benzodiazepines. The sample consisted of pure brookite has shown the highest efficiency in the photodegradation of alprazolam, practically equal to the activity of Degussa P25. (C) 2015 Elsevier B.V. All rights reserved.
PB  - Elsevier
T2  - Materials Chemistry and Physics
T1  - Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route
VL  - 163
SP  - 518
EP  - 528
DO  - 10.1016/j.matchemphys.2015.08.008
ER  - 
@article{
author = "Tomić, Nataša and Grujić-Brojčin, Mirjana and Finčur, Nina L. and Abramović, Biljana F. and Simović, Bojana and Krstić, Jugoslav B. and Matović, Branko and Šćepanović, Maja",
year = "2015",
abstract = "Two series of nanocrystalline brookite-type powders have been synthesized by using combined sal gel hydrothermal method with titanium tetrachloride (TiCI4) as a precursor and hydrothermal temperature and reaction time varied in the range of 120-200 degrees C and 12-48 h, respectively. The effects of chosen synthesis parameters on structural, morphological and optical properties of synthesized powders have been investigated by the XRPD, SEM, EDS and BET measurements, as well Raman spectroscopy and spectroscopic ellipsometry. The XRPD results have shown that pure brookite phase, with mean crystallite size of -33 nm, has been obtained only in the sample synthesized at 200 degrees C, after 24 h of hydrothermal process. In all other samples anatase phase also appears, whereas rutile and sodium titanate phases have been noticed in the samples synthesized at lower temperatures. The presence of different titania phases has also been confirmed and analyzed by Raman scattering measurements. The SEM measurements have shown spindle-like particles in brookite-rich samples synthesized at 200 degrees C, whereas BET measurements have detected mesoporous structure in these samples. The properties of synthesized powders have been correlated to their photocatalytic efficiency, tested in degradation of alprazolam, one of the 5th generation benzodiazepines. The sample consisted of pure brookite has shown the highest efficiency in the photodegradation of alprazolam, practically equal to the activity of Degussa P25. (C) 2015 Elsevier B.V. All rights reserved.",
publisher = "Elsevier",
journal = "Materials Chemistry and Physics",
title = "Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route",
volume = "163",
pages = "518-528",
doi = "10.1016/j.matchemphys.2015.08.008"
}
Tomić, N., Grujić-Brojčin, M., Finčur, N. L., Abramović, B. F., Simović, B., Krstić, J. B., Matović, B.,& Šćepanović, M.. (2015). Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route. in Materials Chemistry and Physics
Elsevier., 163, 518-528.
https://doi.org/10.1016/j.matchemphys.2015.08.008
Tomić N, Grujić-Brojčin M, Finčur NL, Abramović BF, Simović B, Krstić JB, Matović B, Šćepanović M. Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route. in Materials Chemistry and Physics. 2015;163:518-528.
doi:10.1016/j.matchemphys.2015.08.008 .
Tomić, Nataša, Grujić-Brojčin, Mirjana, Finčur, Nina L., Abramović, Biljana F., Simović, Bojana, Krstić, Jugoslav B., Matović, Branko, Šćepanović, Maja, "Photocatalytic degradation of alprazolam in water suspension of brookite type TiO2 nanopowders prepared using hydrothermal route" in Materials Chemistry and Physics, 163 (2015):518-528,
https://doi.org/10.1016/j.matchemphys.2015.08.008 . .
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Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam

Golubović, Aleksandar V.; Tomić, Nataša; Finčur, Nina L.; Abramović, Biljana F.; Veljkovic, I.; Zdravkovic, J.; Grujić-Brojčin, Mirjana; Babić, Biljana M.; Stojadinovic, B.; Šćepanović, Maja

(2014)

TY  - JOUR
AU  - Golubović, Aleksandar V.
AU  - Tomić, Nataša
AU  - Finčur, Nina L.
AU  - Abramović, Biljana F.
AU  - Veljkovic, I.
AU  - Zdravkovic, J.
AU  - Grujić-Brojčin, Mirjana
AU  - Babić, Biljana M.
AU  - Stojadinovic, B.
AU  - Šćepanović, Maja
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/127
AB  - Pure and La3+ doped titanium dioxide (TiO2) nanopowders were obtained by sol gel and hydrothermal methods. A precursor was titanium tetrachloride and concentrations of dopants were 0.5 and 1.0 mol%. Procedures of both methods were the same, up to the last part of synthesis (the transformation from the mother liquor to oxide nanopowders), in order to find the influence of applied methods on the properties of nanopowders. XRD results have shown that all synthesized nanopowders were in the anatase phase. It was seen from DSC measurements that anatase to rutile phase transition took place at a higher temperature with a higher concentration of dopant (La3+). The samples obtained by the sol gel method had a higher temperature of phase transition than related samples obtained by the hydrothermal method. Nanopowder properties have been related to the photocatalytic activity, tested in degradation of the pharmaceutical alprazolam. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.
T2  - Ceramics International
T1  - Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam
VL  - 40
IS  - 8
SP  - 13409
EP  - 13418
DO  - 10.1016/j.ceramint.2014.05.060
ER  - 
@article{
author = "Golubović, Aleksandar V. and Tomić, Nataša and Finčur, Nina L. and Abramović, Biljana F. and Veljkovic, I. and Zdravkovic, J. and Grujić-Brojčin, Mirjana and Babić, Biljana M. and Stojadinovic, B. and Šćepanović, Maja",
year = "2014",
abstract = "Pure and La3+ doped titanium dioxide (TiO2) nanopowders were obtained by sol gel and hydrothermal methods. A precursor was titanium tetrachloride and concentrations of dopants were 0.5 and 1.0 mol%. Procedures of both methods were the same, up to the last part of synthesis (the transformation from the mother liquor to oxide nanopowders), in order to find the influence of applied methods on the properties of nanopowders. XRD results have shown that all synthesized nanopowders were in the anatase phase. It was seen from DSC measurements that anatase to rutile phase transition took place at a higher temperature with a higher concentration of dopant (La3+). The samples obtained by the sol gel method had a higher temperature of phase transition than related samples obtained by the hydrothermal method. Nanopowder properties have been related to the photocatalytic activity, tested in degradation of the pharmaceutical alprazolam. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.",
journal = "Ceramics International",
title = "Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam",
volume = "40",
number = "8",
pages = "13409-13418",
doi = "10.1016/j.ceramint.2014.05.060"
}
Golubović, A. V., Tomić, N., Finčur, N. L., Abramović, B. F., Veljkovic, I., Zdravkovic, J., Grujić-Brojčin, M., Babić, B. M., Stojadinovic, B.,& Šćepanović, M.. (2014). Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam. in Ceramics International, 40(8), 13409-13418.
https://doi.org/10.1016/j.ceramint.2014.05.060
Golubović AV, Tomić N, Finčur NL, Abramović BF, Veljkovic I, Zdravkovic J, Grujić-Brojčin M, Babić BM, Stojadinovic B, Šćepanović M. Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam. in Ceramics International. 2014;40(8):13409-13418.
doi:10.1016/j.ceramint.2014.05.060 .
Golubović, Aleksandar V., Tomić, Nataša, Finčur, Nina L., Abramović, Biljana F., Veljkovic, I., Zdravkovic, J., Grujić-Brojčin, Mirjana, Babić, Biljana M., Stojadinovic, B., Šćepanović, Maja, "Synthesis of pure and La-doped anatase nanopowders by sol-gel and hydrothermal methods and their efficiency in photocatalytic degradation of alprazolam" in Ceramics International, 40, no. 8 (2014):13409-13418,
https://doi.org/10.1016/j.ceramint.2014.05.060 . .
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Elongated titania nanostructures as efficient photocatalysts for degradation of selected herbicides

Vranješ, Mila; Šaponjić, Zoran; Živković, Ljiljana; Despotović, Vesna N.; Šojić, Daniela V.; Abramović, Biljana F.; Čomor, Mirjana

(2014)

TY  - JOUR
AU  - Vranješ, Mila
AU  - Šaponjić, Zoran
AU  - Živković, Ljiljana
AU  - Despotović, Vesna N.
AU  - Šojić, Daniela V.
AU  - Abramović, Biljana F.
AU  - Čomor, Mirjana
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/75
AB  - Titanium dioxide nanotubes (TNT) were synthesized via hydrothermal method and calcined at various temperatures. The obtained calcined TiO2 nanomaterials with specific elongation orientation were characterized by transmission and scanning electron microscopy (TEM, SEM), X-ray diffraction (XRD), UV/Vis diffuse reflection spectroscopy (DRS), Laser Doppler electrophoresis (LDE) and their textural properties were evaluated. The photocatalytic activity of obtained nanopowders was evaluated considering photodegradation rate of herbicide clomazone, rarely studied herbicide. The influence of calcination temperature of catalysts with elongated morphology on their photocatalytic activity was evaluated. The best results were obtained with TNT annealed at 700 degrees C, which can be assigned to the best balance between crystal structure, morphology and surface properties of nanoparticles induced by annealing. Also, the photocatalytic degradation rates of another two herbicides (picloram, and mecoprop) were compared, due to possibility that the efficiency of photo catalytic degradation is greatly influenced by the molecular structure. The mineralization degree of selected herbicides in the presence of TiO2 based photocatalysts was evaluated applying total organic carbon (TOC) measurements. (C) 2014 Elsevier B.V. All rights reserved.
T2  - Applied Catalysis. B: Environmental
T1  - Elongated titania nanostructures as efficient photocatalysts for degradation of selected herbicides
VL  - 160
SP  - 589
EP  - 596
DO  - 10.1016/j.apcatb.2014.06.005
ER  - 
@article{
author = "Vranješ, Mila and Šaponjić, Zoran and Živković, Ljiljana and Despotović, Vesna N. and Šojić, Daniela V. and Abramović, Biljana F. and Čomor, Mirjana",
year = "2014",
abstract = "Titanium dioxide nanotubes (TNT) were synthesized via hydrothermal method and calcined at various temperatures. The obtained calcined TiO2 nanomaterials with specific elongation orientation were characterized by transmission and scanning electron microscopy (TEM, SEM), X-ray diffraction (XRD), UV/Vis diffuse reflection spectroscopy (DRS), Laser Doppler electrophoresis (LDE) and their textural properties were evaluated. The photocatalytic activity of obtained nanopowders was evaluated considering photodegradation rate of herbicide clomazone, rarely studied herbicide. The influence of calcination temperature of catalysts with elongated morphology on their photocatalytic activity was evaluated. The best results were obtained with TNT annealed at 700 degrees C, which can be assigned to the best balance between crystal structure, morphology and surface properties of nanoparticles induced by annealing. Also, the photocatalytic degradation rates of another two herbicides (picloram, and mecoprop) were compared, due to possibility that the efficiency of photo catalytic degradation is greatly influenced by the molecular structure. The mineralization degree of selected herbicides in the presence of TiO2 based photocatalysts was evaluated applying total organic carbon (TOC) measurements. (C) 2014 Elsevier B.V. All rights reserved.",
journal = "Applied Catalysis. B: Environmental",
title = "Elongated titania nanostructures as efficient photocatalysts for degradation of selected herbicides",
volume = "160",
pages = "589-596",
doi = "10.1016/j.apcatb.2014.06.005"
}
Vranješ, M., Šaponjić, Z., Živković, L., Despotović, V. N., Šojić, D. V., Abramović, B. F.,& Čomor, M.. (2014). Elongated titania nanostructures as efficient photocatalysts for degradation of selected herbicides. in Applied Catalysis. B: Environmental, 160, 589-596.
https://doi.org/10.1016/j.apcatb.2014.06.005
Vranješ M, Šaponjić Z, Živković L, Despotović VN, Šojić DV, Abramović BF, Čomor M. Elongated titania nanostructures as efficient photocatalysts for degradation of selected herbicides. in Applied Catalysis. B: Environmental. 2014;160:589-596.
doi:10.1016/j.apcatb.2014.06.005 .
Vranješ, Mila, Šaponjić, Zoran, Živković, Ljiljana, Despotović, Vesna N., Šojić, Daniela V., Abramović, Biljana F., Čomor, Mirjana, "Elongated titania nanostructures as efficient photocatalysts for degradation of selected herbicides" in Applied Catalysis. B: Environmental, 160 (2014):589-596,
https://doi.org/10.1016/j.apcatb.2014.06.005 . .
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Surface modification of sol-gel synthesized TiO2 nanoparticles induced by La-doping

Grujić-Brojčin, Mirjana; Armaković, Sanja J.; Tomić, Nataša; Abramović, Biljana F.; Golubavic, A.; Stojadinovic, B.; Kremenović, Aleksandar S.; Babić, Biljana M.; Dohcevic-Mitrovic, Z.; Šćepanović, Maja

(2014)

TY  - JOUR
AU  - Grujić-Brojčin, Mirjana
AU  - Armaković, Sanja J.
AU  - Tomić, Nataša
AU  - Abramović, Biljana F.
AU  - Golubavic, A.
AU  - Stojadinovic, B.
AU  - Kremenović, Aleksandar S.
AU  - Babić, Biljana M.
AU  - Dohcevic-Mitrovic, Z.
AU  - Šćepanović, Maja
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5881
AB  - The influence of La-doping in the range of 0.5-6.0 mol% on structural and morphological properties of TiO2 nanopowders synthesized by sol-gel routine has been investigated by XRPD, AFM, EDS and BET measurements, as well as Raman spectroscopy. The XRPD and Raman measurements have revealed the anatase phase as dominant in all nanopowders, with crystallite size decreasing from similar to 15 nm in pure TiO2 to similar to 12 nm in La-doped samples. The BET data suggest that all samples are fully mesoporous, with mean pore diameters in the range of similar to 6-8 nm. The specific surface area and the complexity of pore structure are greater in doped samples than in pure TiO2 sample. The spectroscopic ellipsometry has apparently shown that the band gap has been gradually increased with the increase of La content. The STM and STS techniques have been used successfully to evaluate the surface morphology and electronic properties of La-doped nanopowders. All investigated properties have been related to photocatalytic activity, tested in degradation of a metoprolol tartrate salt (0.05 mM), and induced by UV-radiation. All doped samples showed increased photocatalytic activity compared to pure TiO2, among which the 0.65 mol% La-doped sample appeared to be the most efficient. (C) 2013 Elsevier Inc. All rights reserved.
T2  - Materials Characterization
T1  - Surface modification of sol-gel synthesized TiO2 nanoparticles induced by La-doping
VL  - 88
SP  - 30
EP  - 41
DO  - 10.1016/j.matchar.2013.12.002
ER  - 
@article{
author = "Grujić-Brojčin, Mirjana and Armaković, Sanja J. and Tomić, Nataša and Abramović, Biljana F. and Golubavic, A. and Stojadinovic, B. and Kremenović, Aleksandar S. and Babić, Biljana M. and Dohcevic-Mitrovic, Z. and Šćepanović, Maja",
year = "2014",
abstract = "The influence of La-doping in the range of 0.5-6.0 mol% on structural and morphological properties of TiO2 nanopowders synthesized by sol-gel routine has been investigated by XRPD, AFM, EDS and BET measurements, as well as Raman spectroscopy. The XRPD and Raman measurements have revealed the anatase phase as dominant in all nanopowders, with crystallite size decreasing from similar to 15 nm in pure TiO2 to similar to 12 nm in La-doped samples. The BET data suggest that all samples are fully mesoporous, with mean pore diameters in the range of similar to 6-8 nm. The specific surface area and the complexity of pore structure are greater in doped samples than in pure TiO2 sample. The spectroscopic ellipsometry has apparently shown that the band gap has been gradually increased with the increase of La content. The STM and STS techniques have been used successfully to evaluate the surface morphology and electronic properties of La-doped nanopowders. All investigated properties have been related to photocatalytic activity, tested in degradation of a metoprolol tartrate salt (0.05 mM), and induced by UV-radiation. All doped samples showed increased photocatalytic activity compared to pure TiO2, among which the 0.65 mol% La-doped sample appeared to be the most efficient. (C) 2013 Elsevier Inc. All rights reserved.",
journal = "Materials Characterization",
title = "Surface modification of sol-gel synthesized TiO2 nanoparticles induced by La-doping",
volume = "88",
pages = "30-41",
doi = "10.1016/j.matchar.2013.12.002"
}
Grujić-Brojčin, M., Armaković, S. J., Tomić, N., Abramović, B. F., Golubavic, A., Stojadinovic, B., Kremenović, A. S., Babić, B. M., Dohcevic-Mitrovic, Z.,& Šćepanović, M.. (2014). Surface modification of sol-gel synthesized TiO2 nanoparticles induced by La-doping. in Materials Characterization, 88, 30-41.
https://doi.org/10.1016/j.matchar.2013.12.002
Grujić-Brojčin M, Armaković SJ, Tomić N, Abramović BF, Golubavic A, Stojadinovic B, Kremenović AS, Babić BM, Dohcevic-Mitrovic Z, Šćepanović M. Surface modification of sol-gel synthesized TiO2 nanoparticles induced by La-doping. in Materials Characterization. 2014;88:30-41.
doi:10.1016/j.matchar.2013.12.002 .
Grujić-Brojčin, Mirjana, Armaković, Sanja J., Tomić, Nataša, Abramović, Biljana F., Golubavic, A., Stojadinovic, B., Kremenović, Aleksandar S., Babić, Biljana M., Dohcevic-Mitrovic, Z., Šćepanović, Maja, "Surface modification of sol-gel synthesized TiO2 nanoparticles induced by La-doping" in Materials Characterization, 88 (2014):30-41,
https://doi.org/10.1016/j.matchar.2013.12.002 . .
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The role of surface defect sites of titania nanoparticles in the photocatalysis: Aging and modification

Radoičić, Marija B.; Janković, Ivana A.; Despotović, Vesna N.; Šojić, Daniela V.; Savić, Tatjana D.; Šaponjić, Zoran; Abramović, Biljana F.; Čomor, Mirjana

(2013)

TY  - JOUR
AU  - Radoičić, Marija B.
AU  - Janković, Ivana A.
AU  - Despotović, Vesna N.
AU  - Šojić, Daniela V.
AU  - Savić, Tatjana D.
AU  - Šaponjić, Zoran
AU  - Abramović, Biljana F.
AU  - Čomor, Mirjana
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5511
AB  - A study of photocatalytic activity of bare as prepared, bare aged and dopamine surface modified colloidal TiO2 nanoparticles was obtained following degradation reaction of herbicide RS-2-(4-chloro-o-tolyloxy)propionic acid under UV light irradiation. Results showed that the most active photocatalyst is bare aged TiO2 and the least active are dopamine modified nanoparticles. Results are discussed in the light of surface structure of TiO2 nanoparticles. The study of surface modification of TiO2 nanoparticles (4.5 nm, TiO2 NPs) with dopamine was also performed. The formation of inner-sphere charge-transfer complexes results in red shift of semiconductor absorption threshold (600 nm), compared to bare TiO2 NPs (380 nm). Effective band gap energy of 3.2 eV for bare TiO2 NPs is reduced to 2.1 eV for TiO2/dopamine charge transfer complexes. The binding structure was investigated by UV-vis and FTIR spectroscopy. The obtained optimal geometry for binding of dopamine to surface Ti atoms was binuclear bidentate-bridging. From the Benesi-Hildebrand plot, stability constant of the order 10(3) M-1 has been determined. (C) 2013 Elsevier B.V. All rights reserved.
T2  - Applied Catalysis. B: Environmental
T1  - The role of surface defect sites of titania nanoparticles in the photocatalysis: Aging and modification
VL  - 138
SP  - 122
EP  - 127
DO  - 10.1016/j.apcatb.2013.02.032
ER  - 
@article{
author = "Radoičić, Marija B. and Janković, Ivana A. and Despotović, Vesna N. and Šojić, Daniela V. and Savić, Tatjana D. and Šaponjić, Zoran and Abramović, Biljana F. and Čomor, Mirjana",
year = "2013",
abstract = "A study of photocatalytic activity of bare as prepared, bare aged and dopamine surface modified colloidal TiO2 nanoparticles was obtained following degradation reaction of herbicide RS-2-(4-chloro-o-tolyloxy)propionic acid under UV light irradiation. Results showed that the most active photocatalyst is bare aged TiO2 and the least active are dopamine modified nanoparticles. Results are discussed in the light of surface structure of TiO2 nanoparticles. The study of surface modification of TiO2 nanoparticles (4.5 nm, TiO2 NPs) with dopamine was also performed. The formation of inner-sphere charge-transfer complexes results in red shift of semiconductor absorption threshold (600 nm), compared to bare TiO2 NPs (380 nm). Effective band gap energy of 3.2 eV for bare TiO2 NPs is reduced to 2.1 eV for TiO2/dopamine charge transfer complexes. The binding structure was investigated by UV-vis and FTIR spectroscopy. The obtained optimal geometry for binding of dopamine to surface Ti atoms was binuclear bidentate-bridging. From the Benesi-Hildebrand plot, stability constant of the order 10(3) M-1 has been determined. (C) 2013 Elsevier B.V. All rights reserved.",
journal = "Applied Catalysis. B: Environmental",
title = "The role of surface defect sites of titania nanoparticles in the photocatalysis: Aging and modification",
volume = "138",
pages = "122-127",
doi = "10.1016/j.apcatb.2013.02.032"
}
Radoičić, M. B., Janković, I. A., Despotović, V. N., Šojić, D. V., Savić, T. D., Šaponjić, Z., Abramović, B. F.,& Čomor, M.. (2013). The role of surface defect sites of titania nanoparticles in the photocatalysis: Aging and modification. in Applied Catalysis. B: Environmental, 138, 122-127.
https://doi.org/10.1016/j.apcatb.2013.02.032
Radoičić MB, Janković IA, Despotović VN, Šojić DV, Savić TD, Šaponjić Z, Abramović BF, Čomor M. The role of surface defect sites of titania nanoparticles in the photocatalysis: Aging and modification. in Applied Catalysis. B: Environmental. 2013;138:122-127.
doi:10.1016/j.apcatb.2013.02.032 .
Radoičić, Marija B., Janković, Ivana A., Despotović, Vesna N., Šojić, Daniela V., Savić, Tatjana D., Šaponjić, Zoran, Abramović, Biljana F., Čomor, Mirjana, "The role of surface defect sites of titania nanoparticles in the photocatalysis: Aging and modification" in Applied Catalysis. B: Environmental, 138 (2013):122-127,
https://doi.org/10.1016/j.apcatb.2013.02.032 . .
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Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol

Golubović, Aleksandar V.; Abramović, Biljana F.; Šćepanović, Maja; Grujić-Brojčin, Mirjana; Armaković, Sanja J.; Veljkovic, I.; Babić, Biljana M.; Dohcevic-Mitrovic, Z.; Popović, Zoran V.

(2013)

TY  - JOUR
AU  - Golubović, Aleksandar V.
AU  - Abramović, Biljana F.
AU  - Šćepanović, Maja
AU  - Grujić-Brojčin, Mirjana
AU  - Armaković, Sanja J.
AU  - Veljkovic, I.
AU  - Babić, Biljana M.
AU  - Dohcevic-Mitrovic, Z.
AU  - Popović, Zoran V.
PY  - 2013
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/5421
AB  - The structural and morphological properties of mesoporous anatase nanopowders, synthesized by sol-gel method, have been modified by varying the duration of calcination, in order to obtain more efficient photocatalyst than Degussa P25 in the degradation of relatively large pollutant molecules ( GT 1 nm in size). According to X-ray diffraction analysis, the crystallite size was increased from 13 to 17.5 nm with the increase of calcination time from 1 to 7 h. The analysis of nitrogen sorption experimental data revealed that all samples were mesoporous, with a mean pore diameters in the range of similar to 5-9 nm. The corrugated pore structure model was employed to evaluate pore structure tortuosity. Nanopowder properties have been related to the photocatalytic activity, tested in the degradation of metoprolol tartrate salt, selective beta(1)-blocker used in a variety of cardiovascular diseases, with molecular size of 0.610 nm x 1.347 nm. The study has demonstrated that samples calcined for 4 and 5 h have displayed higher photocatalytic performance than Degussa P25, whereas the sample calcined for 3 h has shown comparable activity. (C) 2013 Published by Elsevier Ltd.
T2  - Materials Research Bulletin
T1  - Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol
VL  - 48
IS  - 4
SP  - 1363
EP  - 1371
DO  - 10.1016/j.materresbull.2012.11.098
ER  - 
@article{
author = "Golubović, Aleksandar V. and Abramović, Biljana F. and Šćepanović, Maja and Grujić-Brojčin, Mirjana and Armaković, Sanja J. and Veljkovic, I. and Babić, Biljana M. and Dohcevic-Mitrovic, Z. and Popović, Zoran V.",
year = "2013",
abstract = "The structural and morphological properties of mesoporous anatase nanopowders, synthesized by sol-gel method, have been modified by varying the duration of calcination, in order to obtain more efficient photocatalyst than Degussa P25 in the degradation of relatively large pollutant molecules ( GT 1 nm in size). According to X-ray diffraction analysis, the crystallite size was increased from 13 to 17.5 nm with the increase of calcination time from 1 to 7 h. The analysis of nitrogen sorption experimental data revealed that all samples were mesoporous, with a mean pore diameters in the range of similar to 5-9 nm. The corrugated pore structure model was employed to evaluate pore structure tortuosity. Nanopowder properties have been related to the photocatalytic activity, tested in the degradation of metoprolol tartrate salt, selective beta(1)-blocker used in a variety of cardiovascular diseases, with molecular size of 0.610 nm x 1.347 nm. The study has demonstrated that samples calcined for 4 and 5 h have displayed higher photocatalytic performance than Degussa P25, whereas the sample calcined for 3 h has shown comparable activity. (C) 2013 Published by Elsevier Ltd.",
journal = "Materials Research Bulletin",
title = "Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol",
volume = "48",
number = "4",
pages = "1363-1371",
doi = "10.1016/j.materresbull.2012.11.098"
}
Golubović, A. V., Abramović, B. F., Šćepanović, M., Grujić-Brojčin, M., Armaković, S. J., Veljkovic, I., Babić, B. M., Dohcevic-Mitrovic, Z.,& Popović, Z. V.. (2013). Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol. in Materials Research Bulletin, 48(4), 1363-1371.
https://doi.org/10.1016/j.materresbull.2012.11.098
Golubović AV, Abramović BF, Šćepanović M, Grujić-Brojčin M, Armaković SJ, Veljkovic I, Babić BM, Dohcevic-Mitrovic Z, Popović ZV. Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol. in Materials Research Bulletin. 2013;48(4):1363-1371.
doi:10.1016/j.materresbull.2012.11.098 .
Golubović, Aleksandar V., Abramović, Biljana F., Šćepanović, Maja, Grujić-Brojčin, Mirjana, Armaković, Sanja J., Veljkovic, I., Babić, Biljana M., Dohcevic-Mitrovic, Z., Popović, Zoran V., "Improved efficiency of sol-gel synthesized mesoporous anatase nanopowders in photocatalytic degradation of metoprolol" in Materials Research Bulletin, 48, no. 4 (2013):1363-1371,
https://doi.org/10.1016/j.materresbull.2012.11.098 . .
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Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route

Šćepanović, Maja; Abramović, Biljana F.; Golubović, Aleksandar V.; Kler, Sanja; Grujić-Brojčin, Mirjana; Dohčević-Mitrović, Zorana ; Babić, Biljana M.; Matović, Branko; Popović, Zoran V.

(2012)

TY  - JOUR
AU  - Šćepanović, Maja
AU  - Abramović, Biljana F.
AU  - Golubović, Aleksandar V.
AU  - Kler, Sanja
AU  - Grujić-Brojčin, Mirjana
AU  - Dohčević-Mitrović, Zorana 
AU  - Babić, Biljana M.
AU  - Matović, Branko
AU  - Popović, Zoran V.
PY  - 2012
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4656
AB  - Nanocrystalline titanium dioxide (TiO2) powders have been synthesized by sol-gel method using titanium tetrachloride (TiCl4) or tetrabutyl titanate (Ti(OC4H9)(4) as precursors, different alcohols and calcination temperatures in the range from 400 to 650 A degrees C. The photocatalytic activity of as-prepared powders has been tested for the degradation of metoprolol tartrate salt, a selective beta-blocker used to treat a variety of cardiovascular diseases, and compared to photocatalytic activity obtained from Degussa P25. Nanosized TiO2 powders prepared from TiCl4 and amyl-alcohol, calcined at 550 A degrees C, displayed an activity comparable to Degussa P25, whereas the sample from the same series, calcined at 650 A degrees C, showed higher photocatalytic activity in the whole range of the catalyst loading. Structural, morphological and surface properties of synthesized TiO2 nanopowders have been investigated by XRD, SEM, EDS and BET measurements, as well as FTIR and Raman spectroscopy, in order to find out the material properties which enable rapid an efficient decomposition of metoprolol under UV radiation.
T2  - Journal of Sol-gel Science and Technology
T1  - Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route
VL  - 61
IS  - 2
SP  - 390
EP  - 402
DO  - 10.1007/s10971-011-2639-9
ER  - 
@article{
author = "Šćepanović, Maja and Abramović, Biljana F. and Golubović, Aleksandar V. and Kler, Sanja and Grujić-Brojčin, Mirjana and Dohčević-Mitrović, Zorana  and Babić, Biljana M. and Matović, Branko and Popović, Zoran V.",
year = "2012",
abstract = "Nanocrystalline titanium dioxide (TiO2) powders have been synthesized by sol-gel method using titanium tetrachloride (TiCl4) or tetrabutyl titanate (Ti(OC4H9)(4) as precursors, different alcohols and calcination temperatures in the range from 400 to 650 A degrees C. The photocatalytic activity of as-prepared powders has been tested for the degradation of metoprolol tartrate salt, a selective beta-blocker used to treat a variety of cardiovascular diseases, and compared to photocatalytic activity obtained from Degussa P25. Nanosized TiO2 powders prepared from TiCl4 and amyl-alcohol, calcined at 550 A degrees C, displayed an activity comparable to Degussa P25, whereas the sample from the same series, calcined at 650 A degrees C, showed higher photocatalytic activity in the whole range of the catalyst loading. Structural, morphological and surface properties of synthesized TiO2 nanopowders have been investigated by XRD, SEM, EDS and BET measurements, as well as FTIR and Raman spectroscopy, in order to find out the material properties which enable rapid an efficient decomposition of metoprolol under UV radiation.",
journal = "Journal of Sol-gel Science and Technology",
title = "Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route",
volume = "61",
number = "2",
pages = "390-402",
doi = "10.1007/s10971-011-2639-9"
}
Šćepanović, M., Abramović, B. F., Golubović, A. V., Kler, S., Grujić-Brojčin, M., Dohčević-Mitrović, Z., Babić, B. M., Matović, B.,& Popović, Z. V.. (2012). Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route. in Journal of Sol-gel Science and Technology, 61(2), 390-402.
https://doi.org/10.1007/s10971-011-2639-9
Šćepanović M, Abramović BF, Golubović AV, Kler S, Grujić-Brojčin M, Dohčević-Mitrović Z, Babić BM, Matović B, Popović ZV. Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route. in Journal of Sol-gel Science and Technology. 2012;61(2):390-402.
doi:10.1007/s10971-011-2639-9 .
Šćepanović, Maja, Abramović, Biljana F., Golubović, Aleksandar V., Kler, Sanja, Grujić-Brojčin, Mirjana, Dohčević-Mitrović, Zorana , Babić, Biljana M., Matović, Branko, Popović, Zoran V., "Photocatalytic degradation of metoprolol in water suspension of TiO2 nanopowders prepared using sol-gel route" in Journal of Sol-gel Science and Technology, 61, no. 2 (2012):390-402,
https://doi.org/10.1007/s10971-011-2639-9 . .
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