Eureka project E! 13303 MED-BIO-TEST

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Eureka project E! 13303 MED-BIO-TEST

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Publications

A new voltammetric platform for reliable determination of the sport performance-enhancing stimulant synephrine in dietary supplements using a boron-doped diamond electrode

Haššo, Marek; Sarakhman, Olha; Stanković, Dalibor M.; Švorc, Lubomir

(2020)

TY  - JOUR
AU  - Haššo, Marek
AU  - Sarakhman, Olha
AU  - Stanković, Dalibor M.
AU  - Švorc, Lubomir
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9692
AB  - For the first time, we propose a new modification-free voltammetric platform for simple, fast and reliable quantification of the sport performance-enhancing stimulant synephrine (SYN) based on the usage of a commercial screen-printed boron-doped diamond (BDD) electrochemical sensor. Applying cyclic voltammetry, SYN exhibited one well-shaped, irreversible and diffusion-driven oxidation peak at a peak potential of +1.45 V (vs. the silver pseudoreference electrode) in the presence of 2 M HClO4. Under the selected experimental conditions, the following analytical parameters for determination of SYN were obtained: linear concentration ranges from 19.6 up to 1000 μM and from 9.9 up to 1000 μM for differential pulse (DPV) and square-wave voltammetry (SWV), respectively, detection limits at micromolar concentration levels and intra-day repeatability with a relative standard deviation below 4% for both pulse techniques. The interference study revealed fair selectivity when considering the target dietary supplements. The feasibility of the developed voltammetric platform was verified in the analysis of commercially available dietary supplements and reasonable recovery values were achieved by DPV and SWV, respectively. In addition, the method can be performed directly without higher consumption of chemicals, waste generation, complex sample extraction and higher instrumentation cost. The advanced BDD electrochemical sensor has appeared to be a suitable competitor for efficient applications in food quality control analysis.
T2  - Analytical Methods
T1  - A new voltammetric platform for reliable determination of the sport performance-enhancing stimulant synephrine in dietary supplements using a boron-doped diamond electrode
VL  - 12
IS  - 39
SP  - 4749
EP  - 4758
DO  - 10.1039/D0AY01425G
ER  - 
@article{
author = "Haššo, Marek and Sarakhman, Olha and Stanković, Dalibor M. and Švorc, Lubomir",
year = "2020",
abstract = "For the first time, we propose a new modification-free voltammetric platform for simple, fast and reliable quantification of the sport performance-enhancing stimulant synephrine (SYN) based on the usage of a commercial screen-printed boron-doped diamond (BDD) electrochemical sensor. Applying cyclic voltammetry, SYN exhibited one well-shaped, irreversible and diffusion-driven oxidation peak at a peak potential of +1.45 V (vs. the silver pseudoreference electrode) in the presence of 2 M HClO4. Under the selected experimental conditions, the following analytical parameters for determination of SYN were obtained: linear concentration ranges from 19.6 up to 1000 μM and from 9.9 up to 1000 μM for differential pulse (DPV) and square-wave voltammetry (SWV), respectively, detection limits at micromolar concentration levels and intra-day repeatability with a relative standard deviation below 4% for both pulse techniques. The interference study revealed fair selectivity when considering the target dietary supplements. The feasibility of the developed voltammetric platform was verified in the analysis of commercially available dietary supplements and reasonable recovery values were achieved by DPV and SWV, respectively. In addition, the method can be performed directly without higher consumption of chemicals, waste generation, complex sample extraction and higher instrumentation cost. The advanced BDD electrochemical sensor has appeared to be a suitable competitor for efficient applications in food quality control analysis.",
journal = "Analytical Methods",
title = "A new voltammetric platform for reliable determination of the sport performance-enhancing stimulant synephrine in dietary supplements using a boron-doped diamond electrode",
volume = "12",
number = "39",
pages = "4749-4758",
doi = "10.1039/D0AY01425G"
}
Haššo, M., Sarakhman, O., Stanković, D. M.,& Švorc, L.. (2020). A new voltammetric platform for reliable determination of the sport performance-enhancing stimulant synephrine in dietary supplements using a boron-doped diamond electrode. in Analytical Methods, 12(39), 4749-4758.
https://doi.org/10.1039/D0AY01425G
Haššo M, Sarakhman O, Stanković DM, Švorc L. A new voltammetric platform for reliable determination of the sport performance-enhancing stimulant synephrine in dietary supplements using a boron-doped diamond electrode. in Analytical Methods. 2020;12(39):4749-4758.
doi:10.1039/D0AY01425G .
Haššo, Marek, Sarakhman, Olha, Stanković, Dalibor M., Švorc, Lubomir, "A new voltammetric platform for reliable determination of the sport performance-enhancing stimulant synephrine in dietary supplements using a boron-doped diamond electrode" in Analytical Methods, 12, no. 39 (2020):4749-4758,
https://doi.org/10.1039/D0AY01425G . .
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TiO2/APTES cross-linked to carboxylic graphene based impedimetric glucose biosensor

Ognjanović, Miloš; Stanković, Vesna; Knežević, Sara; Antić, Bratislav; Vranješ-Đurić, Sanja; Stanković, Dalibor M.

(2020)

TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Stanković, Vesna
AU  - Knežević, Sara
AU  - Antić, Bratislav
AU  - Vranješ-Đurić, Sanja
AU  - Stanković, Dalibor M.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9040
AB  - Herein, we proposed a novel approach and state-of-the-art technology for the improvement of the materials and enzyme immobilization at the electrode surface and construction of impedimetric glucose biosensor. We silanized titanium dioxide nanoparticles using (3-aminopropyl)triethoxysilane (APTES), for the preparation of cross-linked material nanoparticles, with carboxylic graphene. The silanization of titanium dioxide nanoparticles and an increase in electron shuttle was proven feasible when this composite was able to achieve about 30% higher current than non-silanized material. The proposed approach was used for the modification of the printed three-electrode system and the development of the impedimetric glucose biosensor. The material morphology and electrochemical characteristics were confirmed by spectroscopic and electrochemical methods. The present combination effectively modified the electrode surface and serve as a promising basis for the construction of Point-of-Care devices. Developed biosensor possesses wide operating linear range toward glucose detection from 50 µmol to 1000 µmol, with the limit of detection of 24 µmol. Finally, negligible interference effect and application in the real sample indicate that the proposed mechanism can be successfully applied to the assessment of glucose level in only one drop of real sample.
T2  - Microchemical Journal
T1  - TiO2/APTES cross-linked to carboxylic graphene based impedimetric glucose biosensor
VL  - 158
SP  - 105150
DO  - 10.1016/j.microc.2020.105150
ER  - 
@article{
author = "Ognjanović, Miloš and Stanković, Vesna and Knežević, Sara and Antić, Bratislav and Vranješ-Đurić, Sanja and Stanković, Dalibor M.",
year = "2020",
abstract = "Herein, we proposed a novel approach and state-of-the-art technology for the improvement of the materials and enzyme immobilization at the electrode surface and construction of impedimetric glucose biosensor. We silanized titanium dioxide nanoparticles using (3-aminopropyl)triethoxysilane (APTES), for the preparation of cross-linked material nanoparticles, with carboxylic graphene. The silanization of titanium dioxide nanoparticles and an increase in electron shuttle was proven feasible when this composite was able to achieve about 30% higher current than non-silanized material. The proposed approach was used for the modification of the printed three-electrode system and the development of the impedimetric glucose biosensor. The material morphology and electrochemical characteristics were confirmed by spectroscopic and electrochemical methods. The present combination effectively modified the electrode surface and serve as a promising basis for the construction of Point-of-Care devices. Developed biosensor possesses wide operating linear range toward glucose detection from 50 µmol to 1000 µmol, with the limit of detection of 24 µmol. Finally, negligible interference effect and application in the real sample indicate that the proposed mechanism can be successfully applied to the assessment of glucose level in only one drop of real sample.",
journal = "Microchemical Journal",
title = "TiO2/APTES cross-linked to carboxylic graphene based impedimetric glucose biosensor",
volume = "158",
pages = "105150",
doi = "10.1016/j.microc.2020.105150"
}
Ognjanović, M., Stanković, V., Knežević, S., Antić, B., Vranješ-Đurić, S.,& Stanković, D. M.. (2020). TiO2/APTES cross-linked to carboxylic graphene based impedimetric glucose biosensor. in Microchemical Journal, 158, 105150.
https://doi.org/10.1016/j.microc.2020.105150
Ognjanović M, Stanković V, Knežević S, Antić B, Vranješ-Đurić S, Stanković DM. TiO2/APTES cross-linked to carboxylic graphene based impedimetric glucose biosensor. in Microchemical Journal. 2020;158:105150.
doi:10.1016/j.microc.2020.105150 .
Ognjanović, Miloš, Stanković, Vesna, Knežević, Sara, Antić, Bratislav, Vranješ-Đurić, Sanja, Stanković, Dalibor M., "TiO2/APTES cross-linked to carboxylic graphene based impedimetric glucose biosensor" in Microchemical Journal, 158 (2020):105150,
https://doi.org/10.1016/j.microc.2020.105150 . .
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