Ministry of Science, Republic of Serbia [141013]

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Ministry of Science, Republic of Serbia [141013]

Authors

Publications

Green synthesis and optical properties of silver-chitosan complexes and nanocomposites

Božanić, Dušan K.; Trandafilović, Lidija V.; Luyt, Adriaan S.; Đoković, Vladimir

(2010)

TY  - JOUR
AU  - Božanić, Dušan K.
AU  - Trandafilović, Lidija V.
AU  - Luyt, Adriaan S.
AU  - Đoković, Vladimir
PY  - 2010
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/4141
AB  - Silver nanoparticles were synthesized in a chitosan biopolymer by an in situ green chemical procedure. using D-glucose as the reducing agent. The reaction intermediates (silver-chitosan complexes) as well as the obtained nanocomposites were investigated using transmission electron microscopy, UV-vis, FTIR and photoluminescence spectroscopy. The theoretical analysis of the UV-vis absorption of the Ag-chitosan complexes suggested that the significant contribution to the complex spectrum arises from clusters of silver containing 4-9 atoms. The absorption spectrum of the nanocomposite exhibited a strong surface plasmon resonance band at 406 nm. The photoluminescence behavior of the pure chitosan, the silver-chitosan complexes and the nanocomposites were discussed in terms of morphology and silver weight content. (C) 2010 Elsevier Ltd. All rights reserved.
T2  - Reactive and Functional Polymers
T1  - Green synthesis and optical properties of silver-chitosan complexes and nanocomposites
VL  - 70
IS  - 11
SP  - 869
EP  - 873
DO  - 10.1016/j.reactfunctpolym.2010.08.001
ER  - 
@article{
author = "Božanić, Dušan K. and Trandafilović, Lidija V. and Luyt, Adriaan S. and Đoković, Vladimir",
year = "2010",
abstract = "Silver nanoparticles were synthesized in a chitosan biopolymer by an in situ green chemical procedure. using D-glucose as the reducing agent. The reaction intermediates (silver-chitosan complexes) as well as the obtained nanocomposites were investigated using transmission electron microscopy, UV-vis, FTIR and photoluminescence spectroscopy. The theoretical analysis of the UV-vis absorption of the Ag-chitosan complexes suggested that the significant contribution to the complex spectrum arises from clusters of silver containing 4-9 atoms. The absorption spectrum of the nanocomposite exhibited a strong surface plasmon resonance band at 406 nm. The photoluminescence behavior of the pure chitosan, the silver-chitosan complexes and the nanocomposites were discussed in terms of morphology and silver weight content. (C) 2010 Elsevier Ltd. All rights reserved.",
journal = "Reactive and Functional Polymers",
title = "Green synthesis and optical properties of silver-chitosan complexes and nanocomposites",
volume = "70",
number = "11",
pages = "869-873",
doi = "10.1016/j.reactfunctpolym.2010.08.001"
}
Božanić, D. K., Trandafilović, L. V., Luyt, A. S.,& Đoković, V.. (2010). Green synthesis and optical properties of silver-chitosan complexes and nanocomposites. in Reactive and Functional Polymers, 70(11), 869-873.
https://doi.org/10.1016/j.reactfunctpolym.2010.08.001
Božanić DK, Trandafilović LV, Luyt AS, Đoković V. Green synthesis and optical properties of silver-chitosan complexes and nanocomposites. in Reactive and Functional Polymers. 2010;70(11):869-873.
doi:10.1016/j.reactfunctpolym.2010.08.001 .
Božanić, Dušan K., Trandafilović, Lidija V., Luyt, Adriaan S., Đoković, Vladimir, "Green synthesis and optical properties of silver-chitosan complexes and nanocomposites" in Reactive and Functional Polymers, 70, no. 11 (2010):869-873,
https://doi.org/10.1016/j.reactfunctpolym.2010.08.001 . .
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Biopolymer-protected CdSe nanoparticles

Božanić, Dušan K.; Đoković, Vladimir; Bibić, Nataša M.; Nair, P. Sreekumari; Georges, M. K.; Radhakrishnan, T.

(2009)

TY  - JOUR
AU  - Božanić, Dušan K.
AU  - Đoković, Vladimir
AU  - Bibić, Nataša M.
AU  - Nair, P. Sreekumari
AU  - Georges, M. K.
AU  - Radhakrishnan, T.
PY  - 2009
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/3841
AB  - A synthetic procedure for the encapsulation of cadmium selenide (CdSe) nanoparticles in a sago starch matrix is introduced. The nanocomposite was investigated using structural, spectroscopic and thermal, methods. TEM micrographs of the nanocomposite showed spherical CdSe particles of 4-5 nm in size coated with a biopolymer layer. The absorption edges of both the aqueous solution and the thin film of the CdSe-starch nanocomposite were shifted toward lower wavelengths in comparison to the value of the bulk semiconductor. Infrared measurements revealed that the interaction of CdSe nanoparticles and starch chains takes place via OH groups. Although the onset of the temperature of decomposition of CdSe-starch nanocomposite is lower than that of the pure matrix, thermogravimetric analysis also showed that introduction of CdSe nanoparticles significantly reduced starch degradation rate leading to high residual mass at the end of the degradation process. (C) 2009 Elsevier Ltd. All rights reserved.
T2  - Carbohydrate Research
T1  - Biopolymer-protected CdSe nanoparticles
VL  - 344
IS  - 17
SP  - 2383
EP  - 2387
DO  - 10.1016/j.carres.2009.08.018
ER  - 
@article{
author = "Božanić, Dušan K. and Đoković, Vladimir and Bibić, Nataša M. and Nair, P. Sreekumari and Georges, M. K. and Radhakrishnan, T.",
year = "2009",
abstract = "A synthetic procedure for the encapsulation of cadmium selenide (CdSe) nanoparticles in a sago starch matrix is introduced. The nanocomposite was investigated using structural, spectroscopic and thermal, methods. TEM micrographs of the nanocomposite showed spherical CdSe particles of 4-5 nm in size coated with a biopolymer layer. The absorption edges of both the aqueous solution and the thin film of the CdSe-starch nanocomposite were shifted toward lower wavelengths in comparison to the value of the bulk semiconductor. Infrared measurements revealed that the interaction of CdSe nanoparticles and starch chains takes place via OH groups. Although the onset of the temperature of decomposition of CdSe-starch nanocomposite is lower than that of the pure matrix, thermogravimetric analysis also showed that introduction of CdSe nanoparticles significantly reduced starch degradation rate leading to high residual mass at the end of the degradation process. (C) 2009 Elsevier Ltd. All rights reserved.",
journal = "Carbohydrate Research",
title = "Biopolymer-protected CdSe nanoparticles",
volume = "344",
number = "17",
pages = "2383-2387",
doi = "10.1016/j.carres.2009.08.018"
}
Božanić, D. K., Đoković, V., Bibić, N. M., Nair, P. S., Georges, M. K.,& Radhakrishnan, T.. (2009). Biopolymer-protected CdSe nanoparticles. in Carbohydrate Research, 344(17), 2383-2387.
https://doi.org/10.1016/j.carres.2009.08.018
Božanić DK, Đoković V, Bibić NM, Nair PS, Georges MK, Radhakrishnan T. Biopolymer-protected CdSe nanoparticles. in Carbohydrate Research. 2009;344(17):2383-2387.
doi:10.1016/j.carres.2009.08.018 .
Božanić, Dušan K., Đoković, Vladimir, Bibić, Nataša M., Nair, P. Sreekumari, Georges, M. K., Radhakrishnan, T., "Biopolymer-protected CdSe nanoparticles" in Carbohydrate Research, 344, no. 17 (2009):2383-2387,
https://doi.org/10.1016/j.carres.2009.08.018 . .
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