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COST actions [CM1101, MP1106]

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The influence of reaction media on CdIn2S4 and ZnIn2S4 nanocrystallite formation and growth of mesocrystal structures

Carević, Milica; Čomor, Mirjana; Mitrić, Miodrag; Barudžija, Tanja; Ahrenkiel, Scott Phillip; Abazović, Nadica

(2015)

TY  - JOUR
AU  - Carević, Milica
AU  - Čomor, Mirjana
AU  - Mitrić, Miodrag
AU  - Barudžija, Tanja
AU  - Ahrenkiel, Scott Phillip
AU  - Abazović, Nadica
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/804
AB  - A hot-injection method for the synthesis of CdIn2S4 in three different compositions of organic media/solvents was studied. Nanosized CdIn2S4 is successfully synthesized in an oleic acid/oleylamine mixture of complexing/capping agents. The obtained mesocrystals of 20-30 nm in diameter are self-organized in marigold-like structures. The estimated band-gap of synthesized semiconductor is in the visible spectral region and has a value of about 2.1 eV. The potential of the band edges is calculated using an empirical equation. The as-prepared material was successfully transferred from organic to aqueous media by using 2-mercaptoethanol in a surface ligand exchange process. Using a similar synthetic procedure, ZnIn2S4 synthesis was performed. The obtained materials were characterized using UV/vis spectroscopy, XRD and TEM. Formation and growth mechanisms of the synthesized materials are proposed.
T2  - CrystEngComm
T1  - The influence of reaction media on CdIn2S4 and ZnIn2S4 nanocrystallite formation and growth of mesocrystal structures
VL  - 17
IS  - 44
SP  - 8492
EP  - 8499
DO  - 10.1039/c5ce01432h
ER  - 
@article{
author = "Carević, Milica and Čomor, Mirjana and Mitrić, Miodrag and Barudžija, Tanja and Ahrenkiel, Scott Phillip and Abazović, Nadica",
year = "2015",
abstract = "A hot-injection method for the synthesis of CdIn2S4 in three different compositions of organic media/solvents was studied. Nanosized CdIn2S4 is successfully synthesized in an oleic acid/oleylamine mixture of complexing/capping agents. The obtained mesocrystals of 20-30 nm in diameter are self-organized in marigold-like structures. The estimated band-gap of synthesized semiconductor is in the visible spectral region and has a value of about 2.1 eV. The potential of the band edges is calculated using an empirical equation. The as-prepared material was successfully transferred from organic to aqueous media by using 2-mercaptoethanol in a surface ligand exchange process. Using a similar synthetic procedure, ZnIn2S4 synthesis was performed. The obtained materials were characterized using UV/vis spectroscopy, XRD and TEM. Formation and growth mechanisms of the synthesized materials are proposed.",
journal = "CrystEngComm",
title = "The influence of reaction media on CdIn2S4 and ZnIn2S4 nanocrystallite formation and growth of mesocrystal structures",
volume = "17",
number = "44",
pages = "8492-8499",
doi = "10.1039/c5ce01432h"
}
Carević, M., Čomor, M., Mitrić, M., Barudžija, T., Ahrenkiel, S. P.,& Abazović, N.. (2015). The influence of reaction media on CdIn2S4 and ZnIn2S4 nanocrystallite formation and growth of mesocrystal structures. in CrystEngComm, 17(44), 8492-8499.
https://doi.org/10.1039/c5ce01432h
Carević M, Čomor M, Mitrić M, Barudžija T, Ahrenkiel SP, Abazović N. The influence of reaction media on CdIn2S4 and ZnIn2S4 nanocrystallite formation and growth of mesocrystal structures. in CrystEngComm. 2015;17(44):8492-8499.
doi:10.1039/c5ce01432h .
Carević, Milica, Čomor, Mirjana, Mitrić, Miodrag, Barudžija, Tanja, Ahrenkiel, Scott Phillip, Abazović, Nadica, "The influence of reaction media on CdIn2S4 and ZnIn2S4 nanocrystallite formation and growth of mesocrystal structures" in CrystEngComm, 17, no. 44 (2015):8492-8499,
https://doi.org/10.1039/c5ce01432h . .
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