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Auto-combustion synthesis as a method for preparing BiFeO3 powders and flexible BiFeO3/PVDF films with improved magnetic properties. Influence of doping ion position, size and valence on electric properties

Ilić, Nikola; Teixeira, Guilhermina F.; Bobić, Jelena; Spasojević, Vojislav; Džunuzović, Adis; Petrović, Mirjana Vijatović; Zaghete, Maria Ap.; Stojanović, Biljana

(2022)

TY  - JOUR
AU  - Ilić, Nikola
AU  - Teixeira, Guilhermina F.
AU  - Bobić, Jelena
AU  - Spasojević, Vojislav
AU  - Džunuzović, Adis
AU  - Petrović, Mirjana Vijatović
AU  - Zaghete, Maria Ap.
AU  - Stojanović, Biljana
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10211
AB  - Bismuth ferrite (BiFeO3) powders were synthesized by auto-combustion method using glycine as a fuel. Doping ions of different valence were used to study the influence on electrical conductivity and ferroelectric properties. Powders were mixed and hot-pressed with α-PVDF to form flexible composite samples. Composites endured significantly higher electrical fields with lower leakage and retained the weak ferromagnetism present in powders. Dielectric properties were improved by doping with Zr4+, Y3+ and Ca2+ as well as the electrical resistivity. Flexible composites exhibited improved electrical resistivity and modified conduction mechanism. Relatively high magnetization of powders completely originates from magnetite particles formed during the combustion, while sintered samples exhibited typical antiferromagnetic behaviour.
T2  - Materials Science and Engineering: B
T1  - Auto-combustion synthesis as a method for preparing BiFeO3 powders and flexible BiFeO3/PVDF films with improved magnetic properties. Influence of doping ion position, size and valence on electric properties
VL  - 280
SP  - 115686
DO  - 10.1016/j.mseb.2022.115686
ER  - 
@article{
author = "Ilić, Nikola and Teixeira, Guilhermina F. and Bobić, Jelena and Spasojević, Vojislav and Džunuzović, Adis and Petrović, Mirjana Vijatović and Zaghete, Maria Ap. and Stojanović, Biljana",
year = "2022",
abstract = "Bismuth ferrite (BiFeO3) powders were synthesized by auto-combustion method using glycine as a fuel. Doping ions of different valence were used to study the influence on electrical conductivity and ferroelectric properties. Powders were mixed and hot-pressed with α-PVDF to form flexible composite samples. Composites endured significantly higher electrical fields with lower leakage and retained the weak ferromagnetism present in powders. Dielectric properties were improved by doping with Zr4+, Y3+ and Ca2+ as well as the electrical resistivity. Flexible composites exhibited improved electrical resistivity and modified conduction mechanism. Relatively high magnetization of powders completely originates from magnetite particles formed during the combustion, while sintered samples exhibited typical antiferromagnetic behaviour.",
journal = "Materials Science and Engineering: B",
title = "Auto-combustion synthesis as a method for preparing BiFeO3 powders and flexible BiFeO3/PVDF films with improved magnetic properties. Influence of doping ion position, size and valence on electric properties",
volume = "280",
pages = "115686",
doi = "10.1016/j.mseb.2022.115686"
}
Ilić, N., Teixeira, G. F., Bobić, J., Spasojević, V., Džunuzović, A., Petrović, M. V., Zaghete, M. Ap.,& Stojanović, B.. (2022). Auto-combustion synthesis as a method for preparing BiFeO3 powders and flexible BiFeO3/PVDF films with improved magnetic properties. Influence of doping ion position, size and valence on electric properties. in Materials Science and Engineering: B, 280, 115686.
https://doi.org/10.1016/j.mseb.2022.115686
Ilić N, Teixeira GF, Bobić J, Spasojević V, Džunuzović A, Petrović MV, Zaghete MA, Stojanović B. Auto-combustion synthesis as a method for preparing BiFeO3 powders and flexible BiFeO3/PVDF films with improved magnetic properties. Influence of doping ion position, size and valence on electric properties. in Materials Science and Engineering: B. 2022;280:115686.
doi:10.1016/j.mseb.2022.115686 .
Ilić, Nikola, Teixeira, Guilhermina F., Bobić, Jelena, Spasojević, Vojislav, Džunuzović, Adis, Petrović, Mirjana Vijatović, Zaghete, Maria Ap., Stojanović, Biljana, "Auto-combustion synthesis as a method for preparing BiFeO3 powders and flexible BiFeO3/PVDF films with improved magnetic properties. Influence of doping ion position, size and valence on electric properties" in Materials Science and Engineering: B, 280 (2022):115686,
https://doi.org/10.1016/j.mseb.2022.115686 . .
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Electrical and microstructural properties of Yb-doped CeO2

Matović, Branko; Stojmenović, Marija; Pantić, Jelena R.; Varela, A.; Žunić, Milan; Jiraborvornpongsa, Noppasint; Yano, Toyohiko

(2014)

TY  - JOUR
AU  - Matović, Branko
AU  - Stojmenović, Marija
AU  - Pantić, Jelena R.
AU  - Varela, A.
AU  - Žunić, Milan
AU  - Jiraborvornpongsa, Noppasint
AU  - Yano, Toyohiko
PY  - 2014
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/9202
AB  - Nanopowdered Ce1−xYbxO2−δ solid solutions (0 ≤ x ≤ 0.2) were synthesized by a self-propagating room temperature synthesis. XRD and SEM were used to study the properties of these materials as well as the Yb solubility in CeO2 lattice. Results showed that all the obtained powders were solid solutions with a fluorite-type crystal structure and with nanometric particle size. The average size of Ce1−xYbxO2−δ particles was approximately 3 nm. Electrochemical impedance spectroscopy for the sintered pellets depicted that it was possible to separate Rbulk and Rgb in the temperature interval of 550–800 °C. The activation energy for the bulk conduction was 1.03 eV and for grain boundary conduction was 1.14 eV. Grain boundary resistivity dominates over the other resistivities. These measurements confirmed that Yb3+-doped CeO2 material had a potential as electrolyte for intermediate-temperature solid oxide fuel cell applications.
T2  - Journal of Asian Ceramic Societies
T1  - Electrical and microstructural properties of Yb-doped CeO2
VL  - 2
IS  - 2
SP  - 117
EP  - 122
DO  - 10.1016/j.jascer.2014.01.008
ER  - 
@article{
author = "Matović, Branko and Stojmenović, Marija and Pantić, Jelena R. and Varela, A. and Žunić, Milan and Jiraborvornpongsa, Noppasint and Yano, Toyohiko",
year = "2014",
abstract = "Nanopowdered Ce1−xYbxO2−δ solid solutions (0 ≤ x ≤ 0.2) were synthesized by a self-propagating room temperature synthesis. XRD and SEM were used to study the properties of these materials as well as the Yb solubility in CeO2 lattice. Results showed that all the obtained powders were solid solutions with a fluorite-type crystal structure and with nanometric particle size. The average size of Ce1−xYbxO2−δ particles was approximately 3 nm. Electrochemical impedance spectroscopy for the sintered pellets depicted that it was possible to separate Rbulk and Rgb in the temperature interval of 550–800 °C. The activation energy for the bulk conduction was 1.03 eV and for grain boundary conduction was 1.14 eV. Grain boundary resistivity dominates over the other resistivities. These measurements confirmed that Yb3+-doped CeO2 material had a potential as electrolyte for intermediate-temperature solid oxide fuel cell applications.",
journal = "Journal of Asian Ceramic Societies",
title = "Electrical and microstructural properties of Yb-doped CeO2",
volume = "2",
number = "2",
pages = "117-122",
doi = "10.1016/j.jascer.2014.01.008"
}
Matović, B., Stojmenović, M., Pantić, J. R., Varela, A., Žunić, M., Jiraborvornpongsa, N.,& Yano, T.. (2014). Electrical and microstructural properties of Yb-doped CeO2. in Journal of Asian Ceramic Societies, 2(2), 117-122.
https://doi.org/10.1016/j.jascer.2014.01.008
Matović B, Stojmenović M, Pantić JR, Varela A, Žunić M, Jiraborvornpongsa N, Yano T. Electrical and microstructural properties of Yb-doped CeO2. in Journal of Asian Ceramic Societies. 2014;2(2):117-122.
doi:10.1016/j.jascer.2014.01.008 .
Matović, Branko, Stojmenović, Marija, Pantić, Jelena R., Varela, A., Žunić, Milan, Jiraborvornpongsa, Noppasint, Yano, Toyohiko, "Electrical and microstructural properties of Yb-doped CeO2" in Journal of Asian Ceramic Societies, 2, no. 2 (2014):117-122,
https://doi.org/10.1016/j.jascer.2014.01.008 . .
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