TY  - JOUR
AU  - Fischer, Dieter
AU  - Zagorac, Dejan
AU  - Schön, Christian J.
PY  - 2022
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/10419
AB  - Zinc oxide exhibits unique properties that are reflected in a wide variety of applications, particularly in the field of transparent, conductive films. However, less attention has been paid to their color. Here, we present the synthesis of yellow-gray ZnO films at room temperature by femtosecond pulsed laser deposition. In situ Raman investigations of these polycrystalline ZnO films reveal the existence of superoxide ions, O2−, in zinc oxide, which are responsible for the yellow color, and are also detected in ZnO powder and single crystals. In addition, further dioxygen species are identified in the samples, including the O2-molecule. The negative charge excess caused by the dioxygen species creates metallic zinc as a byproduct. Structural analysis reveals an unforced realization of the dioxygen species in the ZnO lattice. Density functional theory (DFT) calculations support the assumed structural displacements as well as the observed, unexpected Raman bands. These results open up completely new insights into the behavior of ZnO.
T2  - Journal of Raman Spectroscopy
T1  - The presence of superoxide ions and related dioxygen species in zinc oxide—A structural characterization by in situ Raman spectroscopy
VL  - n/a
IS  - n/a
DO  - 10.1002/jrs.6441
ER  - 

@article{
author = "Fischer, Dieter and Zagorac, Dejan and Schön, Christian J.",
year = "2022",
abstract = "Zinc oxide exhibits unique properties that are reflected in a wide variety of applications, particularly in the field of transparent, conductive films. However, less attention has been paid to their color. Here, we present the synthesis of yellow-gray ZnO films at room temperature by femtosecond pulsed laser deposition. In situ Raman investigations of these polycrystalline ZnO films reveal the existence of superoxide ions, O2−, in zinc oxide, which are responsible for the yellow color, and are also detected in ZnO powder and single crystals. In addition, further dioxygen species are identified in the samples, including the O2-molecule. The negative charge excess caused by the dioxygen species creates metallic zinc as a byproduct. Structural analysis reveals an unforced realization of the dioxygen species in the ZnO lattice. Density functional theory (DFT) calculations support the assumed structural displacements as well as the observed, unexpected Raman bands. These results open up completely new insights into the behavior of ZnO.",
journal = "Journal of Raman Spectroscopy",
title = "The presence of superoxide ions and related dioxygen species in zinc oxide—A structural characterization by in situ Raman spectroscopy",
volume = "n/a",
number = "n/a",
doi = "10.1002/jrs.6441"
}

Fischer, D., Zagorac, D.,& Schön, C. J.. (2022). The presence of superoxide ions and related dioxygen species in zinc oxide—A structural characterization by in situ Raman spectroscopy. in Journal of Raman Spectroscopy, n/a(n/a).
https://doi.org/10.1002/jrs.6441

Fischer D, Zagorac D, Schön CJ. The presence of superoxide ions and related dioxygen species in zinc oxide—A structural characterization by in situ Raman spectroscopy. in Journal of Raman Spectroscopy. 2022;n/a(n/a).
doi:10.1002/jrs.6441 .

Fischer, Dieter, Zagorac, Dejan, Schön, Christian J., "The presence of superoxide ions and related dioxygen species in zinc oxide—A structural characterization by in situ Raman spectroscopy" in Journal of Raman Spectroscopy, n/a, no. n/a (2022),
https://doi.org/10.1002/jrs.6441 . .