Serbia-France bilateral project

Link to this page

Serbia-France bilateral project

Authors

Publications

Silica-Coated and Bare Akaganeite Nanorods: Structural and Magnetic Properties

Tadić, Marin; Milošević, Irena; Kralj, Slavko; Mbodji, Mamadou; Motte, Laurence

(2015)

TY  - JOUR
AU  - Tadić, Marin
AU  - Milošević, Irena
AU  - Kralj, Slavko
AU  - Mbodji, Mamadou
AU  - Motte, Laurence
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/622
AB  - We report on structural and magnetic properties of uniform silica-coated akaganeite nanorods with length of L similar to 80 +/- 15 nm and diameter D similar to 15 +/- 5 nm as well as silica shell thickness of about 5 nm. Unexpected negative difference between field-cooled (FC) and zero-field-cooled (ZFC) magnetization Delta M = M-FC - M-ZFC LT 0, room temperature ferromagnetism, and exchange bias effect have been found. The nanorods are investigated by X-ray powder diffraction (XRPD), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM) measurements. The magnetic measurements were also performed on bare akaganeite nanorods in order to discriminate the effects of silica coating on the magnetic properties. The measured coercivity and exchange bias effect of bare beta-FeOOH nanorods are much lower compared with same properties of SiO2"beta-FeOOH nanorods, emphasizing the effect of silica coating on the magnetic properties. These results are discussed considering the core shell structure of akaganeite nanorods; i.e., the inner part of the akaganeite nanorod has antiferromagnetic ordering, whereas the nanorod surface exhibits some disorder spin state.
T2  - Journal of Physical Chemistry. C
T1  - Silica-Coated and Bare Akaganeite Nanorods: Structural and Magnetic Properties
VL  - 119
IS  - 24
SP  - 13868
EP  - 13875
DO  - 10.1021/acs.jpcc.5b01547
ER  - 
@article{
author = "Tadić, Marin and Milošević, Irena and Kralj, Slavko and Mbodji, Mamadou and Motte, Laurence",
year = "2015",
abstract = "We report on structural and magnetic properties of uniform silica-coated akaganeite nanorods with length of L similar to 80 +/- 15 nm and diameter D similar to 15 +/- 5 nm as well as silica shell thickness of about 5 nm. Unexpected negative difference between field-cooled (FC) and zero-field-cooled (ZFC) magnetization Delta M = M-FC - M-ZFC LT 0, room temperature ferromagnetism, and exchange bias effect have been found. The nanorods are investigated by X-ray powder diffraction (XRPD), transmission electron microscopy (TEM), and vibrating sample magnetometer (VSM) measurements. The magnetic measurements were also performed on bare akaganeite nanorods in order to discriminate the effects of silica coating on the magnetic properties. The measured coercivity and exchange bias effect of bare beta-FeOOH nanorods are much lower compared with same properties of SiO2"beta-FeOOH nanorods, emphasizing the effect of silica coating on the magnetic properties. These results are discussed considering the core shell structure of akaganeite nanorods; i.e., the inner part of the akaganeite nanorod has antiferromagnetic ordering, whereas the nanorod surface exhibits some disorder spin state.",
journal = "Journal of Physical Chemistry. C",
title = "Silica-Coated and Bare Akaganeite Nanorods: Structural and Magnetic Properties",
volume = "119",
number = "24",
pages = "13868-13875",
doi = "10.1021/acs.jpcc.5b01547"
}
Tadić, M., Milošević, I., Kralj, S., Mbodji, M.,& Motte, L.. (2015). Silica-Coated and Bare Akaganeite Nanorods: Structural and Magnetic Properties. in Journal of Physical Chemistry. C, 119(24), 13868-13875.
https://doi.org/10.1021/acs.jpcc.5b01547
Tadić M, Milošević I, Kralj S, Mbodji M, Motte L. Silica-Coated and Bare Akaganeite Nanorods: Structural and Magnetic Properties. in Journal of Physical Chemistry. C. 2015;119(24):13868-13875.
doi:10.1021/acs.jpcc.5b01547 .
Tadić, Marin, Milošević, Irena, Kralj, Slavko, Mbodji, Mamadou, Motte, Laurence, "Silica-Coated and Bare Akaganeite Nanorods: Structural and Magnetic Properties" in Journal of Physical Chemistry. C, 119, no. 24 (2015):13868-13875,
https://doi.org/10.1021/acs.jpcc.5b01547 . .
2
18
16
18

Ferromagnetic behavior and exchange bias effect in akaganeite nanorods

Tadić, Marin; Milošević, Irena; Kralj, Slavko; Saboungi, Marie-Louise; Motte, Laurence

(2015)

TY  - JOUR
AU  - Tadić, Marin
AU  - Milošević, Irena
AU  - Kralj, Slavko
AU  - Saboungi, Marie-Louise
AU  - Motte, Laurence
PY  - 2015
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/532
AB  - We report ferromagnetic-like properties and exchange bias effect in akaganeite (beta-FeOOH) nanorods. They exhibit a Neel temperature T-N = 259 K and ferromagnetic-like hysteresis behavior both below and above T-N. An exchange bias effect is observed below T-N and represents an interesting behavior for akaganeite nanorods. These results are explained on the basis of a core-shell structure in which the core has bulk akaganeite magnetic properties (i.e., antiferromagnetic ordering) while the shell exhibits a disordered spin state. Thus, the nanorods show ferromagnetic properties and an exchange bias effect at the same time, increasing their potential for use in practical applications. (c) 2015 AIP Publishing LLC.
T2  - Applied Physics Letters
T1  - Ferromagnetic behavior and exchange bias effect in akaganeite nanorods
VL  - 106
IS  - 18
DO  - 10.1063/1.4918930
ER  - 
@article{
author = "Tadić, Marin and Milošević, Irena and Kralj, Slavko and Saboungi, Marie-Louise and Motte, Laurence",
year = "2015",
abstract = "We report ferromagnetic-like properties and exchange bias effect in akaganeite (beta-FeOOH) nanorods. They exhibit a Neel temperature T-N = 259 K and ferromagnetic-like hysteresis behavior both below and above T-N. An exchange bias effect is observed below T-N and represents an interesting behavior for akaganeite nanorods. These results are explained on the basis of a core-shell structure in which the core has bulk akaganeite magnetic properties (i.e., antiferromagnetic ordering) while the shell exhibits a disordered spin state. Thus, the nanorods show ferromagnetic properties and an exchange bias effect at the same time, increasing their potential for use in practical applications. (c) 2015 AIP Publishing LLC.",
journal = "Applied Physics Letters",
title = "Ferromagnetic behavior and exchange bias effect in akaganeite nanorods",
volume = "106",
number = "18",
doi = "10.1063/1.4918930"
}
Tadić, M., Milošević, I., Kralj, S., Saboungi, M.,& Motte, L.. (2015). Ferromagnetic behavior and exchange bias effect in akaganeite nanorods. in Applied Physics Letters, 106(18).
https://doi.org/10.1063/1.4918930
Tadić M, Milošević I, Kralj S, Saboungi M, Motte L. Ferromagnetic behavior and exchange bias effect in akaganeite nanorods. in Applied Physics Letters. 2015;106(18).
doi:10.1063/1.4918930 .
Tadić, Marin, Milošević, Irena, Kralj, Slavko, Saboungi, Marie-Louise, Motte, Laurence, "Ferromagnetic behavior and exchange bias effect in akaganeite nanorods" in Applied Physics Letters, 106, no. 18 (2015),
https://doi.org/10.1063/1.4918930 . .
18
13
18