European Regional Development Fund [ITMS: 26220220179]

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European Regional Development Fund [ITMS: 26220220179]

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Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior

Kisić, Danilo; Nenadović, Miloš; Potočnik, Jelena; Novaković, Mirjana M.; Noga, Pavol; Vaňa, Dušan; Závacká, Anna; Rakočević, Zlatko Lj.

(2020)

TY  - JOUR
AU  - Kisić, Danilo
AU  - Nenadović, Miloš
AU  - Potočnik, Jelena
AU  - Novaković, Mirjana M.
AU  - Noga, Pavol
AU  - Vaňa, Dušan
AU  - Závacká, Anna
AU  - Rakočević, Zlatko Lj.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8587
AB  - Fe/Polyethylene nanocomposite was synthesized by ion beam implantation of 56Fe+ into bulk high-density polyethylene. Nanoscale surface morphology along with magnetic and optical behavior was investigated. The aim of the research was to investigate changes of polyethylene's surface layer morphology with the change of Fe implantation fluence in the high fluence range and to find correlations with the magnetic and optical behavior. Four implantation fluences were applied: 5 × 1016, 1 × 1017, 2 × 1017 and 5 × 1017 cm−2, while the implantation energy was 95 keV. Concentration profiles of implanted Fe were analyzed by Rutherford backscattering spectrometry, showing Fe concentration profile maxima closer to the surface with increasing implantation fluence. Cross-sectional transmission electron microscopy showed the formation of metallic nanoparticles with sizes in a range from below 1 nm up to few tens of nanometers, depending on the fluence, and for the highest implantation fluence, a continuous layer was formed. Magneto-optic Kerr effect magnetometry demonstrates weak ferromagnetic behavior for the 2 higher fluences, and superparamagnetic for the 2 lower fluences. The UV-VIS remission function spectra show the peak in the UV region, which we attribute to iron nanoparticles.
T2  - Vacuum
T1  - Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior
VL  - 171
SP  - 109016
DO  - 10.1016/j.vacuum.2019.109016
ER  - 
@article{
author = "Kisić, Danilo and Nenadović, Miloš and Potočnik, Jelena and Novaković, Mirjana M. and Noga, Pavol and Vaňa, Dušan and Závacká, Anna and Rakočević, Zlatko Lj.",
year = "2020",
abstract = "Fe/Polyethylene nanocomposite was synthesized by ion beam implantation of 56Fe+ into bulk high-density polyethylene. Nanoscale surface morphology along with magnetic and optical behavior was investigated. The aim of the research was to investigate changes of polyethylene's surface layer morphology with the change of Fe implantation fluence in the high fluence range and to find correlations with the magnetic and optical behavior. Four implantation fluences were applied: 5 × 1016, 1 × 1017, 2 × 1017 and 5 × 1017 cm−2, while the implantation energy was 95 keV. Concentration profiles of implanted Fe were analyzed by Rutherford backscattering spectrometry, showing Fe concentration profile maxima closer to the surface with increasing implantation fluence. Cross-sectional transmission electron microscopy showed the formation of metallic nanoparticles with sizes in a range from below 1 nm up to few tens of nanometers, depending on the fluence, and for the highest implantation fluence, a continuous layer was formed. Magneto-optic Kerr effect magnetometry demonstrates weak ferromagnetic behavior for the 2 higher fluences, and superparamagnetic for the 2 lower fluences. The UV-VIS remission function spectra show the peak in the UV region, which we attribute to iron nanoparticles.",
journal = "Vacuum",
title = "Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior",
volume = "171",
pages = "109016",
doi = "10.1016/j.vacuum.2019.109016"
}
Kisić, D., Nenadović, M., Potočnik, J., Novaković, M. M., Noga, P., Vaňa, D., Závacká, A.,& Rakočević, Z. Lj.. (2020). Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior. in Vacuum, 171, 109016.
https://doi.org/10.1016/j.vacuum.2019.109016
Kisić D, Nenadović M, Potočnik J, Novaković MM, Noga P, Vaňa D, Závacká A, Rakočević ZL. Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior. in Vacuum. 2020;171:109016.
doi:10.1016/j.vacuum.2019.109016 .
Kisić, Danilo, Nenadović, Miloš, Potočnik, Jelena, Novaković, Mirjana M., Noga, Pavol, Vaňa, Dušan, Závacká, Anna, Rakočević, Zlatko Lj., "Surface layer morphology of the high fluence Fe implanted polyethylene - Correlation with the magnetic and optical behavior" in Vacuum, 171 (2020):109016,
https://doi.org/10.1016/j.vacuum.2019.109016 . .
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Modification of polyethylene’s surface properties by high fluence Fe implantation

Kisić, Danilo; Nenadović, Miloš; Barudžija, Tanja; Noga, Pavol; Vaňa, Dušan; Muška, Martin; Rakočević, Zlatko Lj.

(2020)

TY  - JOUR
AU  - Kisić, Danilo
AU  - Nenadović, Miloš
AU  - Barudžija, Tanja
AU  - Noga, Pavol
AU  - Vaňa, Dušan
AU  - Muška, Martin
AU  - Rakočević, Zlatko Lj.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8646
AB  - In the presented paper, changes of high-density polyethylene's (HDPE) surface properties along with the changes of chemical composition, as a consequence of Fe ion implantation with different fluences, were investigated. Applied implantation fluences were as follows: 5 × 1016, 1 × 1017, 2 × 1017 and 5 × 1017 ions cm−2, while the implantation energy was 95 keV. The samples were analyzed by X-ray photoelectron spectroscopy (XPS), Atomic Force Microscopy (AFM), Four point contact probe, Fourier transform infrared spectroscopy (FTIR) and contact angle measurements. Significant changes in the chemical composition were found by XPS and FTIR, which were followed by changes in surface morphology, increase of roughness, and decrease of sheet resistance that has a percolation threshold that starts for the fluence of 1 × 1017 ions cm−2. Surface free energy increases as a consequence of implantation, up to the fluence of 1 × 1017 ions cm−2, and then decreases for the 2 higher fluences. © 2019 Elsevier B.V.
T2  - Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms
T1  - Modification of polyethylene’s surface properties by high fluence Fe implantation
VL  - 462
SP  - 143
EP  - 153
DO  - 10.1016/j.nimb.2019.11.022
ER  - 
@article{
author = "Kisić, Danilo and Nenadović, Miloš and Barudžija, Tanja and Noga, Pavol and Vaňa, Dušan and Muška, Martin and Rakočević, Zlatko Lj.",
year = "2020",
abstract = "In the presented paper, changes of high-density polyethylene's (HDPE) surface properties along with the changes of chemical composition, as a consequence of Fe ion implantation with different fluences, were investigated. Applied implantation fluences were as follows: 5 × 1016, 1 × 1017, 2 × 1017 and 5 × 1017 ions cm−2, while the implantation energy was 95 keV. The samples were analyzed by X-ray photoelectron spectroscopy (XPS), Atomic Force Microscopy (AFM), Four point contact probe, Fourier transform infrared spectroscopy (FTIR) and contact angle measurements. Significant changes in the chemical composition were found by XPS and FTIR, which were followed by changes in surface morphology, increase of roughness, and decrease of sheet resistance that has a percolation threshold that starts for the fluence of 1 × 1017 ions cm−2. Surface free energy increases as a consequence of implantation, up to the fluence of 1 × 1017 ions cm−2, and then decreases for the 2 higher fluences. © 2019 Elsevier B.V.",
journal = "Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms",
title = "Modification of polyethylene’s surface properties by high fluence Fe implantation",
volume = "462",
pages = "143-153",
doi = "10.1016/j.nimb.2019.11.022"
}
Kisić, D., Nenadović, M., Barudžija, T., Noga, P., Vaňa, D., Muška, M.,& Rakočević, Z. Lj.. (2020). Modification of polyethylene’s surface properties by high fluence Fe implantation. in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 462, 143-153.
https://doi.org/10.1016/j.nimb.2019.11.022
Kisić D, Nenadović M, Barudžija T, Noga P, Vaňa D, Muška M, Rakočević ZL. Modification of polyethylene’s surface properties by high fluence Fe implantation. in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms. 2020;462:143-153.
doi:10.1016/j.nimb.2019.11.022 .
Kisić, Danilo, Nenadović, Miloš, Barudžija, Tanja, Noga, Pavol, Vaňa, Dušan, Muška, Martin, Rakočević, Zlatko Lj., "Modification of polyethylene’s surface properties by high fluence Fe implantation" in Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, 462 (2020):143-153,
https://doi.org/10.1016/j.nimb.2019.11.022 . .
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