Ministry of Education, Science and Technological Development of the Republic of Serbia through the Eureka Project (E!9982)

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Ministry of Education, Science and Technological Development of the Republic of Serbia through the Eureka Project (E!9982)

Authors

Publications

Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye

Ognjanović, Miloš; Stanković, Dalibor M.; Fabian, Martin; Vranješ-Đurić, Sanja; Antić, Bratislav; Dojčinović, Biljana P.

(2020)

TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor M.
AU  - Fabian, Martin
AU  - Vranješ-Đurić, Sanja
AU  - Antić, Bratislav
AU  - Dojčinović, Biljana P.
PY  - 2020
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/8810
AB  - Iron oxide nanoparticles (IONP) with different distinctive morphologies (spherical, cubic, flower-like and needles) were utilized for modification of screen-printed carbon electrodes (SPCE) to be used for synthetic organic dye degradation by an electrochemical approach. This platform was implemented for removal of the synthetic organic dye, Reactive Black 5 (RB5) in aqueous solution. Modified SPCE with spherically shaped IONP (IONS) had the highest dye removal efficiency. Thus, IONS were then used for surface decoration of the most common carbon-based materials (graphene, graphene oxide, carboxylated graphene, graphene nanoribbons, graphene nanoplatelets, single- and multi-wall carbon nanotubes), and the nanocomposites formed were deposited on the electrode surfaces. Using IONS/graphene composite (IONS@GN) for electrode modification resulted in the best effect. Removal of RB5 with this electrode was 51% better in comparison with bare SPCE, reducing the time required for complete dye degradation from 61 to 30 min Using IONS-modified SPCE, total RB5 removal occurred in 51 min, improving the performance by 16% over that of bare SPCE. The effects determined, i.e., the best IONP morphology and best type of carbon-based material for nanocomposite formation to enhance RB5 removal will provide guidelines for further modifications of SPCE with nanomaterials and nanocomposites, for application of this electrochemical approach in the degradation of organic pollutants. © 2020 The Author(s). Published by IOP Publishing Ltd.
T2  - Materials Research Express
T1  - Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye
VL  - 7
IS  - 1
SP  - 015509
DO  - 10.1088/2053-1591/ab6490
ER  - 
@article{
author = "Ognjanović, Miloš and Stanković, Dalibor M. and Fabian, Martin and Vranješ-Đurić, Sanja and Antić, Bratislav and Dojčinović, Biljana P.",
year = "2020",
abstract = "Iron oxide nanoparticles (IONP) with different distinctive morphologies (spherical, cubic, flower-like and needles) were utilized for modification of screen-printed carbon electrodes (SPCE) to be used for synthetic organic dye degradation by an electrochemical approach. This platform was implemented for removal of the synthetic organic dye, Reactive Black 5 (RB5) in aqueous solution. Modified SPCE with spherically shaped IONP (IONS) had the highest dye removal efficiency. Thus, IONS were then used for surface decoration of the most common carbon-based materials (graphene, graphene oxide, carboxylated graphene, graphene nanoribbons, graphene nanoplatelets, single- and multi-wall carbon nanotubes), and the nanocomposites formed were deposited on the electrode surfaces. Using IONS/graphene composite (IONS@GN) for electrode modification resulted in the best effect. Removal of RB5 with this electrode was 51% better in comparison with bare SPCE, reducing the time required for complete dye degradation from 61 to 30 min Using IONS-modified SPCE, total RB5 removal occurred in 51 min, improving the performance by 16% over that of bare SPCE. The effects determined, i.e., the best IONP morphology and best type of carbon-based material for nanocomposite formation to enhance RB5 removal will provide guidelines for further modifications of SPCE with nanomaterials and nanocomposites, for application of this electrochemical approach in the degradation of organic pollutants. © 2020 The Author(s). Published by IOP Publishing Ltd.",
journal = "Materials Research Express",
title = "Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye",
volume = "7",
number = "1",
pages = "015509",
doi = "10.1088/2053-1591/ab6490"
}
Ognjanović, M., Stanković, D. M., Fabian, M., Vranješ-Đurić, S., Antić, B.,& Dojčinović, B. P.. (2020). Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye. in Materials Research Express, 7(1), 015509.
https://doi.org/10.1088/2053-1591/ab6490
Ognjanović M, Stanković DM, Fabian M, Vranješ-Đurić S, Antić B, Dojčinović BP. Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye. in Materials Research Express. 2020;7(1):015509.
doi:10.1088/2053-1591/ab6490 .
Ognjanović, Miloš, Stanković, Dalibor M., Fabian, Martin, Vranješ-Đurić, Sanja, Antić, Bratislav, Dojčinović, Biljana P., "Tailoring IONP shape and designing nanocomposite IONS@GN toward modification of SPCE to enhance electrochemical degradation of organic dye" in Materials Research Express, 7, no. 1 (2020):015509,
https://doi.org/10.1088/2053-1591/ab6490 . .
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Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia

Ognjanović, Miloš; Stanković, Dalibor M.; Ming, Yue; Zhang, Hongguo; Jančar, Boštjan; Dojčinović, Biljana P.; Prijović, Željko; Antić, Bratislav

(2019)

TY  - JOUR
AU  - Ognjanović, Miloš
AU  - Stanković, Dalibor M.
AU  - Ming, Yue
AU  - Zhang, Hongguo
AU  - Jančar, Boštjan
AU  - Dojčinović, Biljana P.
AU  - Prijović, Željko
AU  - Antić, Bratislav
PY  - 2019
UR  - https://linkinghub.elsevier.com/retrieve/pii/S0925838818340684
UR  - https://vinar.vin.bg.ac.rs/handle/123456789/7942
AB  - In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully applied for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration. © 2018 Elsevier B.V.
T2  - Journal of Alloys and Compounds
T1  - Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia
VL  - 777
SP  - 454
EP  - 462
DO  - 10.1016/j.jallcom.2018.10.369
ER  - 
@article{
author = "Ognjanović, Miloš and Stanković, Dalibor M. and Ming, Yue and Zhang, Hongguo and Jančar, Boštjan and Dojčinović, Biljana P. and Prijović, Željko and Antić, Bratislav",
year = "2019",
abstract = "In a new approach based on a two-step procedure, co-precipitation method followed by hydrothermal treatment in a microwave field, Zn-substituted Fe3O4 nanoparticles (ZnxFe3-xO4) were synthesized. Results of XRD, FT–IR and TEM analysis clearly demonstrate that nanoparticles were single phase, crystallizing in the spinel structure type (S.G. Fd3¯m) with crystallite size in the range of 2–20 nm, which strongly depends on Zn concentration. The produced nanoparticles were used for fabrication of modified carbon paste electrodes as a novel system for electrochemical non-enzymatic glucose detection. It was found that the increase of zinc concentration up to the value of x = 0.56 (Zn0.56Fe2.44O4) of as-prepared nanoparticles was followed with an increase of a performance of the modified carbon paste electrode toward glucose detection. Linear working range from 0.1 to 2 mM was obtained with detection limit of 0.03 mM, and with fast response time (<3 s). Proposed sensor was successfully applied for the determination of glucose level in real samples with satisfactory recovery. The synthesized zinc-ferrite samples were also tested as potential heating agents in magnetic hyperthermia. The heating ability (SAR value) increases with x value, reaching maximum for x = 0.37. This is correlated with changes of particle size and magnetic characteristics which strongly depend on Zn concentration. © 2018 Elsevier B.V.",
journal = "Journal of Alloys and Compounds",
title = "Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia",
volume = "777",
pages = "454-462",
doi = "10.1016/j.jallcom.2018.10.369"
}
Ognjanović, M., Stanković, D. M., Ming, Y., Zhang, H., Jančar, B., Dojčinović, B. P., Prijović, Ž.,& Antić, B.. (2019). Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia. in Journal of Alloys and Compounds, 777, 454-462.
https://doi.org/10.1016/j.jallcom.2018.10.369
Ognjanović M, Stanković DM, Ming Y, Zhang H, Jančar B, Dojčinović BP, Prijović Ž, Antić B. Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia. in Journal of Alloys and Compounds. 2019;777:454-462.
doi:10.1016/j.jallcom.2018.10.369 .
Ognjanović, Miloš, Stanković, Dalibor M., Ming, Yue, Zhang, Hongguo, Jančar, Boštjan, Dojčinović, Biljana P., Prijović, Željko, Antić, Bratislav, "Bifunctional (Zn,Fe)3O4 nanoparticles: Tuning their efficiency for potential application in reagentless glucose biosensors and magnetic hyperthermia" in Journal of Alloys and Compounds, 777 (2019):454-462,
https://doi.org/10.1016/j.jallcom.2018.10.369 . .
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